'/%3E%3C/svg%3E){kind=small}
1839302
2026
1
surface-science-reports
50
creator
asc
26952
https://www.ipcms.fr/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3Afalse%2C%22meta%22%3A%7B%22request_last%22%3A100%2C%22request_next%22%3A50%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22DAM24C9B%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Aliyeva%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BL.%20Aliyeva%2C%20A.%20Guliyeva%2C%20C.A.%20Serra%2C%20F.%20Lemaire%2C%20M.%20Lenertz%2C%20A.%20Carvalho%2C%20F.%20Vigneron%2C%20M.%20Florent%2C%20H.%20Kerdjoujd%2C%20U.%20Hasanova%2C%20D.%20Chan-Seng%2C%20Tuning%20the%20specific%20surface%20area%20of%20pure%20monophasic%20hydroxyapatite%20nanoparticles%20synthesized%20by%20sol-gel%20method%20using%20a%20capillary-based%20microfluidic%20process%2C%20Powder%20Technology%20476%20%282026%29%20122359.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.powtec.2026.122359%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.powtec.2026.122359%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tuning%20the%20specific%20surface%20area%20of%20pure%20monophasic%20hydroxyapatite%20nanoparticles%20synthesized%20by%20sol-gel%20method%20using%20a%20capillary-based%20microfluidic%20process%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leyla%22%2C%22lastName%22%3A%22Aliyeva%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Afsana%22%2C%22lastName%22%3A%22Guliyeva%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%20A.%22%2C%22lastName%22%3A%22Serra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Flora%22%2C%22lastName%22%3A%22Lemaire%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alain%22%2C%22lastName%22%3A%22Carvalho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Vigneron%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Florent%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Halima%22%2C%22lastName%22%3A%22Kerdjoujd%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ulviyya%22%2C%22lastName%22%3A%22Hasanova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Delphine%22%2C%22lastName%22%3A%22Chan-Seng%22%7D%5D%2C%22abstractNote%22%3A%22The%20surfactant-free%20sol-gel%20synthesis%20of%20hydroxyapatite%20nanoparticles%20was%20adapted%20for%20in-flow%20production%20using%20a%20capillary-based%20microfluidic%20device.%20Different%20parameters%20have%20been%20investigated%2C%20including%20the%20capillary%20arrangements%20%28core-shell%20and%20side-by-side%29%2C%20the%20capillary%20diameter%2C%20and%20the%20flow%20rate%20of%20the%20precursor%20solutions.%20The%20nanoparticles%20synthesized%20were%20characterized%20by%20X-ray%20diffraction%20%28XRD%29%2C%20Fourier-transform%20infrared%20%28FTIR%29%20spectroscopy%2C%20scanning%20electron%20microscopy%20%28SEM%29%2C%20transmission%20electron%20microscopy%20%28TEM%29%2C%20and%20specific%20surface%20area%20measurement%20according%20to%20the%20Brunauer-Emmett-Teller%20%28BET%29%20theory.%20The%20results%20were%20compared%20with%20those%20of%20hydroxyapatite%20nanoparticles%20obtained%20by%20the%20conventional%20batch%20sol-gel%20synthesis%20method.%20The%20morphology%20of%20the%20nanoparticles%20changed%20due%20to%20the%20use%20of%20different%20capillary%20arrangements%20and%20thus%20exhibited%20a%20higher%20specific%20surface%20area%20than%20the%20batch%20process.%20The%20highest%20specific%20surface%20area%20was%20observed%20when%20using%20a%20side-by-side%20arrangement%20using%20a%20capillary%20with%20an%20internal%20diameter%20of%20100%20mu%20m%20and%20a%20flow%20rate%20of%20100%20mu%20L%5C%2Fmin%20reaching%20an%20increase%20of%20the%20specific%20surface%20area%20by%20two-fold%20%2861%20m2%5C%2Fg%29%20as%20compared%20to%20the%20conventional%20batch%20sol-gel%20method%20%2829%20m2%5C%2Fg%29%20without%20affecting%20any%20of%20their%20other%20properties%20including%20cell%20viability.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.powtec.2026.122359%22%2C%22citationKey%22%3A%22aliyevaTuningSpecificSurface2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.powtec.2026.122359%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220032-5910%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222026-04-23T15%3A07%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22ADQU33MK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Allard%20and%20Weick%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.F.%20Allard%2C%20G.%20Weick%2C%20Reentrant%20localization%20transition%20in%20a%20dimerized%20quasiperiodic%20dipolar%20chain%2C%20Journal%20of%20Physics-Condensed%20Matter%2038%20%282026%29%20225401.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648X%5C%2Fae695d%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648X%5C%2Fae695d%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Reentrant%20localization%20transition%20in%20a%20dimerized%20quasiperiodic%20dipolar%20chain%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%20F.%22%2C%22lastName%22%3A%22Allard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Weick%22%7D%5D%2C%22abstractNote%22%3A%22Reentrant%20localization%20transitions%20%28RLTs%29%2C%20that%20is%2C%20the%20transitions%20of%20a%20portion%20of%20the%20eigenspectrum%20from%20localized%20to%20critical%20and%20then%20again%20to%20localized%20as%20the%20quasiperiodic%20modulation%20strength%20is%20increased%2C%20have%20been%20recently%20unveiled%20in%20various%20quasiperiodic%20models.%20However%2C%20both%20the%20physical%20mechanisms%20underlying%20these%20transitions%20and%20how%20they%20may%20extend%20to%20systems%20with%20long-range%20coupling%20and%20dissipation%20remain%20elusive.%20Here%20we%20investigate%20the%20fate%20of%20such%20a%20phenomenon%20in%20a%20dimerized%20quasiperiodic%20chain%20of%20lossy%20dipolar%20emitters%20with%20all-to-all%20coupling.%20We%20demonstrate%20that%20in%20this%20model%2C%20reentrant%20transitions%20survive%20to%20all-to-all%20couplings%20and%20occur%20from%20an%20interplay%20between%20the%20chain%20dimerization%20and%20an%20asymmetric%20quasiperiodic%20modulation%20of%20the%20emitter%20spacings.%20Transport%20simulations%20through%20a%20driven-dissipative%20open%20quantum%20system%20approach%20complete%20our%20study%20and%20reveal%20the%20detrimental%20effects%20of%20emitter%20losses%20on%20the%20RLT.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-648X%5C%2Fae695d%22%2C%22citationKey%22%3A%22WOS%3A001782668400001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648X%5C%2Fae695d%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220953-8984%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22EPW69HFA%22%2C%22QD76RV9Q%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-06-26T12%3A36%3A27Z%22%7D%7D%2C%7B%22key%22%3A%22TF23JY8Q%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Althubyani%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BH.%20Althubyani%2C%20D.%20Stoeffler%2C%20J.%20Bartringer%2C%20S.%20Roques%2C%20D.%20Ihiawakrim%2C%20A.%20Dinia%2C%20T.%20Fix%2C%20Investigation%20of%20CaZrO3-xSx%20oxysulfide%20perovskite%20thin%20films%20grown%20by%20pulsed%20laser%20deposition%2C%20Journal%20of%20Physics-Energy%208%20%282026%29%20015034.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2515-7655%5C%2Fae52b5%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2515-7655%5C%2Fae52b5%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Investigation%20of%20CaZrO3-xSx%20oxysulfide%20perovskite%20thin%20films%20grown%20by%20pulsed%20laser%20deposition%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hussain%22%2C%22lastName%22%3A%22Althubyani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Stoeffler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jeremy%22%2C%22lastName%22%3A%22Bartringer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Roques%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%5D%2C%22abstractNote%22%3A%22We%20aim%20to%20identify%20alternative%20perovskite%20candidates%20for%20optoelectronic%20and%20photovoltaic%20applications%20that%20would%20combine%20several%20key%20requirements%2C%20such%20as%20stability%2C%20low%20toxicity%2C%20scalability%2C%20abundance%2C%20and%20efficacy.%20Among%20the%20most%20promising%20candidates%20are%20chalcogenide%20and%20oxysulfide%20perovskites%2C%20such%20as%20CaZrS3%20or%20CaZrO3-xSx.%20While%20several%20methods%20to%20grow%20such%20materials%20involve%20post-sulfurization%20of%20precursors%2C%20in%20this%20work%2C%20we%20investigate%20the%20direct%20growth%20of%20CaZrO3-xSx%20films%20by%20pulsed%20laser%20deposition.%20Growth%20conditions%20were%20explored%20on%20various%20substrates%2C%20including%20LaAlO3%28001%29%20%28LAO%29%2C%20SrTiO3%28001%29%20%28STO%29%2C%20SrTiO3%3ANb%28001%29%20%28Nb%3ASTO%29%2C%20YAlO3%28001%29%20%28YAO%29%2C%20and%20Al2O3%281-102%29%20%28ALO%29%2C%20over%20a%20temperature%20range%20from%20600%20degrees%20C%20to%20900%20degrees%20C.%20The%20resulting%20films%20were%20systematically%20characterized%20in%20terms%20of%20their%20structural%2C%20optical%20and%20electrical%20properties%2C%20as%20well%20as%20their%20semiconducting%20energy%20levels.%20The%20most%20promising%20results%20were%20obtained%20on%20LAO%20substrates%20at%20a%20growth%20temperature%20of%20800%20degrees%20C%2C%20yielding%20improved%20crystallinity%20and%20a%20bandgap%20of%202.4%20eV%2C%20the%20lowest%20among%20the%20investigated%20films.%20This%20film%20also%20exhibited%20a%20very%20high%20and%20promising%20surface%20photovoltage%20signal%2C%20reaching%20900%20mV%20at%200.2%20sun.%20However%2C%20to%20further%20improve%20the%20material%26%23039%3Bs%20suitability%20for%20photovoltaic%20integration%2C%20particularly%20in%20single%20junction%20or%20tandem%20architectures%2C%20additional%20bandgap%20tuning%20via%20doping%20may%20be%20necessary%20to%20enhance%20electrical%20transport%20and%20broaden%20absorption.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F2515-7655%5C%2Fae52b5%22%2C%22citationKey%22%3A%22althubyaniInvestigationCaZrO3xSxOxysulfide2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2515-7655%5C%2Fae52b5%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222515-7655%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22GA3EX26X%22%2C%22SB8Q592R%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-04-23T15%3A06%3A35Z%22%7D%7D%2C%7B%22key%22%3A%22VB7MA2UB%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Althubyani%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BH.%20Althubyani%2C%20W.%20Couif%2C%20P.%20Pearson%2C%20A.%20Dinia%2C%20T.%20Fix%2C%20Environmental%20aging%20of%20CaZrO3-xSx%20oxychalcogenide%20perovskite%20thin%20films%2C%20EPJ%20Photovoltaics%2017%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1051%5C%2Fepjpv%5C%2F2026019%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1051%5C%2Fepjpv%5C%2F2026019%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Environmental%20aging%20of%20CaZrO3-xSx%20oxychalcogenide%20perovskite%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hussain%22%2C%22lastName%22%3A%22Althubyani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Couif%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Pearson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%5D%2C%22abstractNote%22%3A%22Organic-inorganic%20halide%20perovskites%20are%20naturally%20unstable%20when%20exposed%20to%20various%20environmental%20conditions%2C%20and%20the%20presence%20of%20lead%20raises%20significant%20ecological%20concerns.%20Herein%2C%20calcium%20zirconium%20oxysulfide%2C%20CaZrO3-xSx%2C%20a%20lead-free%20oxychalcogenide%20perovskite%2C%20is%20investigated%20as%20a%20potential%20alternative%20for%20optoelectronic%20and%20photovoltaic%20applications.%20The%20environmental%20aging%20of%20CaZrO3-xSx%20thin%20films%20was%20systematically%20investigated%20under%20various%20external%20stress%20conditions%2C%20including%20humidity%2C%20temperature%2C%20and%20illumination.%20Structural%20and%20optical%20investigations%20indicate%20that%20the%20film%20retains%20its%20crystallinity%20and%20remains%20optically%20responsive%20up%20to%20350%20degrees%20C%2C%20without%20detectable%20degradation%20or%20phase%20transformation.%20Under%20high%20%2880%25%29%20humidity%20conditions%2C%20the%20film%20remains%20stable%20for%20a%20few%20days%20before%20gradually%20converting%20into%20the%20oxide%20phase.%20The%20demonstrated%20environmental%20and%20thermal%20stability%20of%20CaZrO3-xSx%20highlights%20its%20potential%20as%20a%20promising%2C%20intrinsically%20stable%2C%20and%20lead-free%20material%20for%20durable%20photovoltaic%20and%20optoelectronic%20applications.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1051%5C%2Fepjpv%5C%2F2026019%22%2C%22citationKey%22%3A%22althubyaniEnvironmentalAgingCaZrO3xSx2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1051%5C%2Fepjpv%5C%2F2026019%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222105-0716%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%22CF4ZI7HM%22%2C%22P3EFAT9K%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A35%3A49Z%22%7D%7D%2C%7B%22key%22%3A%22N8ZCACCH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Babanly%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BD.%20Babanly%2C%20E.%20Orujlu%2C%20A.%20Dovlatov%2C%20J.%20Robert%2C%20F.%20Safarov%2C%20N.%20Parizel%2C%20B.%20Vileno%2C%20I.%20Amiraslanov%2C%20M.%20Babanly%2C%20P.%20Turek%2C%20MnTe-SnTe-Bi2Te3%20pseudo-ternary%20system%3A%20Solid-phase%20equilibria%20diagram%20and%20magnetic%20properties%20of%20Mn0.55Sn0.45Bi10Te16%20and%20Mn0.55Sn0.45Bi12Te19%2C%20Materials%20Chemistry%20and%20Physics%20357%20%282026%29%20132365.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2026.132365%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2026.132365%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22MnTe-SnTe-Bi2Te3%20pseudo-ternary%20system%3A%20Solid-phase%20equilibria%20diagram%20and%20magnetic%20properties%20of%20Mn0.55Sn0.45Bi10Te16%20and%20Mn0.55Sn0.45Bi12Te19%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dunya%22%2C%22lastName%22%3A%22Babanly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elnur%22%2C%22lastName%22%3A%22Orujlu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alihuseyn%22%2C%22lastName%22%3A%22Dovlatov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fuad%22%2C%22lastName%22%3A%22Safarov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Parizel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Vileno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Imamaddin%22%2C%22lastName%22%3A%22Amiraslanov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mahammad%22%2C%22lastName%22%3A%22Babanly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Turek%22%7D%5D%2C%22abstractNote%22%3A%22Solid-phase%20equilibria%20in%20the%20MnTe-SnTe-Bi2Te3%20pseudo-ternary%20system%20were%20experimentally%20investigated%20for%20the%20first%20time%20using%20powder%20X-ray%20diffraction%20%28XRD%29%20and%20scanning%20electron%20microscopy%20%28SEM%29%20with%20energy%20dispersive%20spectroscopy%20%28EDS%29.%20An%20isothermal%20section%20of%20the%20phase%20diagram%20at%20500%20degrees%20C%20was%20constructed.%20Three%20series%20of%20continuous%20solid%20solutions-%28Mn%5C%2FSn%29Bi2Te4%2C%20%28Mn%5C%2FSn%29Bi4Te7%2C%20and%20%28Mn%5C%2FSn%29Bi6Te10-with%20tetradymite-type%20structures%20were%20identified.%20In%20addition%2C%20boundary%20system%20compounds%20Sn3Bi2Te6%2C%20Sn2Bi2Te5%2C%20MnBi8Te13%2C%20MnBi10Te16%2C%20MnBi12Te19%2C%20and%20MnBi14Te22%20exhibit%20extended%20homogeneity%20ranges%20with%20significant%20Mn%20%26lt%3B-%26gt%3B%20Sn%20substitution.%20Magnetic%20properties%20of%20partially%20Mn-substituted%20%28Mn0.55Sn0.45Bi2Te4%29%28Bi2Te3%29%28m%29%20%28m%20%3D%204%2C%205%29%20were%20examined%20using%20SQUID%20magnetometry%20and%20electron%20paramagnetic%20resonance%20%28EPR%29.%20Preliminary%20results%20indicate%20competing%20ferro-%20and%20antiferromagnetic%20interactions%20persisting%20over%20large%20Mn-Mn%20distances%20%28%26gt%3B6%20nm%29%20as%20suggested%20by%20the%20crystal%20structure%2C%20although%20no%20magnetic%20order%20is%20observed.%20A%20transition%20from%202D%20to%203D%20spin%20diffusion%20occurs%20with%20increasing%20temperature.%20The%20disorder%20of%20Mn%20atoms%20within%20such%20a%20tetradymite-type%20structure%2C%20being%20much%20discussed%20recently%2C%20is%20considered%20to%20be%20the%20likely%20cause%20of%20this%20persistence.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.matchemphys.2026.132365%22%2C%22citationKey%22%3A%22babanlyMnTeSnTeBi2Te3PseudoternarySystem2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2026.132365%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220254-0584%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222026-04-23T15%3A03%3A24Z%22%7D%7D%2C%7B%22key%22%3A%22YU355EM9%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bakri%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BB.%20Bakri%2C%20N.%20Crouseilles%2C%20P.-A.%20Hervieux%2C%20G.%20Manfredi%2C%20Wave-particle%20interactions%20in%20a%20spin%20polarized%20plasma%2C%20Physics%20of%20Plasmas%2033%20%282026%29%20022111.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0312295%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0312295%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Wave-particle%20interactions%20in%20a%20spin%20polarized%20plasma%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Bakri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Crouseilles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giovanni%22%2C%22lastName%22%3A%22Manfredi%22%7D%5D%2C%22abstractNote%22%3A%22We%20study%20the%20interplay%20between%20electrons%20and%20spin%20waves%20%28magnons%29%20in%20a%20ferromagnetic%20material%2C%20using%20an%20augmented%20Vlasov-Poisson%20model%20that%20includes%20the%20electron%20spin%20dynamics.%20The%20ions%20are%20fixed%2C%20but%20their%20spins%20can%20evolve%20in%20time%20on%20the%20unit%20sphere%20according%20to%20the%20Landau-Lifshitz%20equation%2C%20which%20includes%20nearest-neighbor%20magnetic%20interactions.%20The%20two%20components%20interact%20not%20only%20through%20the%20electrostatic%20Coulomb%20force%2C%20but%20also%20via%20magnetic-exchange%20interaction%20terms.%20The%20linear%20response%20analysis%20reveals%20the%20existence%20of%20a%20wave-particle%20resonance%20occurring%20at%20the%20frequency%20of%20the%20magnons.%20This%20resonance%20gives%20rise%20to%20significant%20energy%20exchange%20between%20the%20magnons%20and%20the%20electrons%2C%20resulting%20in%20a%20rapid%20loss%20of%20the%20localized%20magnetism%2C%20which%20is%20analogous%20to%20the%20ultrafast%20demagnetization%20observed%20in%20experiments%20on%20thin%20ferromagnetic%20films.%20Depending%20on%20the%20initial%20electronic%20spin%20polarization%2C%20the%20resonance%20can%20lead%20to%20either%20damping%20or%20instability%20of%20the%20wave.%20These%20results%20show%20that%20wave-particle%20effects%2C%20similar%20to%20those%20frequently%20encountered%20in%20plasma%20physics%2C%20may%20play%20a%20key%20role%20in%20spin-polarized%20plasmas%20and%20electron%20beams.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0312295%22%2C%22citationKey%22%3A%22bakriWaveparticleInteractionsSpin2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0312295%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221070-664X%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222026-04-23T14%3A59%3A51Z%22%7D%7D%2C%7B%22key%22%3A%22U5EUNWNK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bakri%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BB.%20Bakri%2C%20G.%20Manfredi%2C%20P.-A.%20Hervieux%2C%20Ultrafast%20electron-magnon%20interactions%20in%20a%20spin-polarized%20electron%20gas%2C%20in%3A%20J.%20Wegrowe%2C%20H.%20Jaffres%20%28Eds.%29%2C%20Spintronics%20and%20Nanomagnetism%2C%20The%20International%20Society%20for%20Optics%20and%20Photonics%3B%20European%20Optical%20Society%3B%20Photonics21%2C%202026.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1117%5C%2F12.3102051%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1117%5C%2F12.3102051%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Ultrafast%20electron-magnon%20interactions%20in%20a%20spin-polarized%20electron%20gas%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Bakri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giovanni%22%2C%22lastName%22%3A%22Manfredi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22JE%22%2C%22lastName%22%3A%22Wegrowe%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22H%22%2C%22lastName%22%3A%22Jaffres%22%7D%5D%2C%22abstractNote%22%3A%22Since%20the%20seminal%20work%20of%20Beaurepaire%20et%20al.%20in%201996%2C%20ultrafast%20demagnetization%20%28UDM%29%20has%20been%20an%20actively%20explored%20field%2C%20and%20its%20technological%20impact%20continues%20to%20grow.%20Nevertheless%2C%20the%20fundamental%20origins%20of%20this%20phenomenon%20remain%20the%20subject%20of%20theoretical%20debate.%20The%20three-temperature%20model%20is%20a%20powerful%20tool%20for%20understanding%20how%20energy%20and%20angular%20momentum%20are%20transferred%20between%20the%20different%20components%20of%20the%20magnetic%20system%20under%20study.%20We%20use%20a%20semiclassical%20model%20from%20plasma%20physics%20to%20compute%20the%20electron-magnon%20interaction.%20This%20interaction%20exhibits%20wave-particle%20resonance%2C%20and%20we%20have%20shown%20that%20this%20phenomenon%20causes%20the%20magnetization%20of%20the%20ferromagnetic%20layer%20to%20decay.%22%2C%22proceedingsTitle%22%3A%22Spintronics%20and%20nanomagnetism%22%2C%22conferenceName%22%3A%22%22%2C%22date%22%3A%222026%22%2C%22eventPlace%22%3A%22%22%2C%22DOI%22%3A%2210.1117%5C%2F12.3102051%22%2C%22ISBN%22%3A%22979-8-90232-121-7%20979-8-90232-122-4%22%2C%22citationKey%22%3A%22WOS%3A001839113000010%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1117%5C%2F12.3102051%22%2C%22ISSN%22%3A%220277-786X%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%2C%22PLGT4TIP%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A03%3A29Z%22%7D%7D%2C%7B%22key%22%3A%228D9TWL2M%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ballerini%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BL.%20Ballerini%2C%20M.%20Liu%2C%20L.%20Arrico%2C%20S.%20Voci%2C%20C.%20Gourlaouen%2C%20C.%20Daniel%2C%20V.%20Cesar%2C%20S.%20Bellemin-laponnaz%2C%20F.%20Zinna%2C%20L.%20Bouffier%2C%20F.%20Polo%2C%20L.%20Di%20Bari%2C%20N.%20Sojic%2C%20M.%20Mauro%2C%20Bright%20Circularly%20Polarized%20Electrochemiluminescence%20from%20Heterobinuclear%20IrIII-AuI%20Enantiomers%2C%20Angewandte%20Chemie-International%20Edition%2065%20%282026%29%20e10787.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.202510787%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.202510787%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Bright%20Circularly%20Polarized%20Electrochemiluminescence%20from%20Heterobinuclear%20IrIII-AuI%20Enantiomers%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lavinia%22%2C%22lastName%22%3A%22Ballerini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Miaoxia%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Arrico%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silvia%22%2C%22lastName%22%3A%22Voci%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chantal%22%2C%22lastName%22%3A%22Daniel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Cesar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-laponnaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesco%22%2C%22lastName%22%3A%22Zinna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Bouffier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Di%20Bari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Neso%22%2C%22lastName%22%3A%22Sojic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22The%20development%20of%20efficient%20circularly%20polarized%20electrochemiluminescence%20%28CP-ECL%29%20probes%20is%20still%20at%20its%20infancy%20and%20examples%20are%20still%20very%20limited.%20Yet%2C%20their%20achievement%20would%20enable%20gathering%20a%20readout%20that%20carries%20privileged%20information%20on%20the%20probe%26%23039%3Bs%20chiral%20environment%20by%20monitoring%20luminescence%20polarization%20bias%20with%20high%20signal-to-noise%20ratio.%20Notwithstanding%2C%20this%20is%20a%20highly%20challenging%20task%20and%20requires%20judicious%20chemical%20engineering%20of%20chiral%20ECL-active%20emitters.%20Herein%2C%20we%20aim%20at%20expanding%20the%20palette%20of%20CP-ECL%20luminophores%20by%20presenting%20a%20novel%20class%20of%20enantiopure%20heterobinuclear%20Ir%28III%29-Au%28I%29%20complexes%2C%20which%20are%20investigated%20thoroughly%20by%20means%20of%20chemical%2C%20structural%2C%20and%20%28chiro-%29optical%20techniques.%20The%20ground%20and%20excited%20state%20properties%20are%20also%20elucidated%20by%20using%20density%20functional%20theory%20%28DFT%29%20approaches%20including%20spin-orbital%20coupling%20%28SOC%29%20perturbation.%20The%20chiral-at-metal%20complexes%20display%20luminescence%20with%20a%20polarization%20bias%20of%20the%20emitted%20light%20that%20is%20function%20of%20the%20helical%20arrangement%20of%20the%20coordination%20sphere%20around%20the%20Ir%28III%29%20center.%20Overall%2C%20the%20photo-%20and%20electro-active%20complexes%20unraveled%20in%20this%20work%20combine%20unparallelly%20high%20photoluminescence%20quantum%20yield%20in%20the%20orange%20region%2C%20excellent%20circularly%20polarized%20luminescence%20%28CPL%29%20brightness%20up%20to%204.5%20M-1%20cm-1%20with%20a%20notable%20ECL%20activity.%20Finally%2C%20these%20features%20provide%20emitters%20with%20CP-ECL%20efficiency%20that%20encompass%20remarkably%20by%20a%20factor%203.5%20that%20of%20the%20well-known%20benchmark%20tris-%282%2C2%20%60-bipyridyl%29ruthenium%28II%29.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fanie.202510787%22%2C%22citationKey%22%3A%22balleriniBrightCircularlyPolarized2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.202510787%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222026-02-17T12%3A10%3A36Z%22%7D%7D%2C%7B%22key%22%3A%223VY4AWQ5%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Barloy%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BL.%20Barloy%2C%20B.%20Heinrich%2C%20N.%20del%20Giudice%2C%20M.%20Scarpi-Luttenauer%2C%20L.%20Douce%2C%20P.%20Mobian%2C%20Ionic%20liquid%20crystals%20based%20on%20a%20triscatecholatotitanate%28iv%29%20complex%20associated%20with%20imidazolium%20counter-ions%2C%20Dalton%20Transactions%2055%20%282026%29%2011607%26%23x2013%3B11617.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6dt00695g%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6dt00695g%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ionic%20liquid%20crystals%20based%20on%20a%20triscatecholatotitanate%28iv%29%20complex%20associated%20with%20imidazolium%20counter-ions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Barloy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22del%20Giudice%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthieu%22%2C%22lastName%22%3A%22Scarpi-Luttenauer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Douce%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Mobian%22%7D%5D%2C%22abstractNote%22%3A%22The%20triscatecholatotitanate%28iv%29%20anion%20%28Ti%28Cat%2932-%29%20interacts%20with%20various%20imidazolium%20cations%20%282-7%29%20to%20generate%20salts%20%28A-F%29%20where%20the%20titanium%20dianion%20complex%20is%20associated%20with%20two%20imidazolium%20monocations.%20Two%20types%20of%20cation%20form%20these%20salts%3B%20species%202-4%20bear%20methoxy%20groups%2C%20whereas%20one%2C%20two%20or%20three%20dodecyl%20linear%20alkyl%20chains%20are%20incorporated%20within%205%2C%206%20and%207%2C%20respectively.%20These%20salts%20were%20characterized%20in%20solution%20by%201H%20NMR%20and%20the%20crystal%20structure%20of%20salt%20C%20containing%20the%20complex%20Ti%28Cat%2932-%20with%20two%20imidazolium%20cations%20substituted%20by%20two%20methoxy%20groups%20%283%29%20was%20established.%20Differential%20scanning%20calorimetry%20%28DSC%29%20measurements%20and%20polarized%20optical%20microscopy%20%28POM%29%20observations%20attest%20to%20the%20thermotropic%20liquid%20crystal%20behavior%20of%20the%20salts%2C%20where%20long%20alkyl%20chains%20are%20present%20in%20salts%20containing%20imidazolium%20cations%20%285-7%29.%20The%20data%20extracted%20from%20the%20small-%20and%20wide-angle%20X-ray%20scattering%20%28SWAXS%29%20analysis%20of%20salts%205-7%20enable%20the%20proposal%20of%20the%20supramolecular%20organisations%20of%20the%20three%20mesophases.%20This%20organisation%20is%20dependent%20on%20the%20number%20of%20alkyl%20chains%20that%20compose%20the%20imidazolium%20cations.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd6dt00695g%22%2C%22citationKey%22%3A%22barloyIonicLiquidCrystals2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6dt00695g%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221477-9226%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22499C62Y9%22%2C%22HMIN5U62%22%2C%22TK3HH32E%22%2C%22VYTETDZF%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A36%3A10Z%22%7D%7D%2C%7B%22key%22%3A%2244V3USHE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bartsch%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Bartsch%2C%20A.%20Borzi%2C%20P.-A.%20Hervieux%2C%20G.%20Manfredi%2C%20Faster-than-adiabatic%20cooling%20of%20non-neutral%20plasmas%2C%20Physical%20Review%20E%20114%20%282026%29%20035208.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fyn72-3qrw%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fyn72-3qrw%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Faster-than-adiabatic%20cooling%20of%20non-neutral%20plasmas%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jan%22%2C%22lastName%22%3A%22Bartsch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alfio%22%2C%22lastName%22%3A%22Borzi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giovanni%22%2C%22lastName%22%3A%22Manfredi%22%7D%5D%2C%22abstractNote%22%3A%22Non-neutral%20plasmas%20can%20be%20confined%20for%20long%20times%20in%20electromagnetic%20traps.%20Adiabatic%20cooling%20of%20such%20plasmas%20can%20be%20achieved%20by%20slowly%20decreasing%20the%20effective%20trap%20stiffness%20and%20letting%20the%20plasma%20occupy%20a%20larger%20volume.%20Here%2C%20we%20propose%20an%20optimal%20control%20strategy%20to%20cool%20an%20antiproton%20plasma%20in%20a%20time%20much%20shorter%20than%20that%20required%20by%20an%20adiabatic%20process.%20The%20optimal%20cooling%20protocol%20is%20found%20by%20minimizing%20an%20appropriate%20cost%20functional%20that%20measures%20the%20distance%20of%20the%20system%20from%20the%20desired%20%5Cu201ccold%5Cu201d%20state%2C%20while%20keeping%20the%20stiffness%20amplitude%20within%20prescribed%20limits.%20The%20proposed%20optimal%20protocol%20is%20shown%20to%20outperform%20other%20expansion-based%20cooling%20methods%20in%20terms%20of%20stability%20of%20the%20plasma%2C%20duration%20of%20the%20process%2C%20and%20volume%20occupied%20by%20the%20final%20plasma.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Fyn72-3qrw%22%2C%22citationKey%22%3A%22WOS%3A001872226500001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2Fyn72-3qrw%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222470-0045%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%2C%22PLGT4TIP%22%5D%2C%22dateModified%22%3A%222026-10-22T11%3A40%3A10Z%22%7D%7D%2C%7B%22key%22%3A%224XZHEZFW%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Busato%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BF.%20Busato%2C%20M.%20De%20Felice%2C%20F.%20Petri%2C%20M.%20Fausti%2C%20B.%20Bruschi%2C%20P.%20Lenzi%2C%20F.%20Cella%20Zanacchi%2C%20D.%20Pisignano%2C%20L.%20Di%20Bari%2C%20L.%20Arrico%2C%20A%20bioconjugable%20eu%28III%29-based%20luminescent%20probe%20for%20multicolor%20and%20time-gated%20immunofluorescence%2C%20Chemical%20%26amp%3B%20Biomedical%20Imaging%20Early%20access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcbmi.6c00148%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcbmi.6c00148%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20bioconjugable%20eu%28III%29-based%20luminescent%20probe%20for%20multicolor%20and%20time-gated%20immunofluorescence%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesco%22%2C%22lastName%22%3A%22Busato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martina%22%2C%22lastName%22%3A%22De%20Felice%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Filippo%22%2C%22lastName%22%3A%22Petri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mattia%22%2C%22lastName%22%3A%22Fausti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Blanca%22%2C%22lastName%22%3A%22Bruschi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pietro%22%2C%22lastName%22%3A%22Lenzi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesca%22%2C%22lastName%22%3A%22Cella%20Zanacchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dario%22%2C%22lastName%22%3A%22Pisignano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Di%20Bari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Arrico%22%7D%5D%2C%22abstractNote%22%3A%22We%20present%20a%20pi-conjugated%20ligand%20endowed%20with%20blue%20emission%20and%20the%20ability%20to%20form%20a%20self-assembled%20red-emitting%20europium%28III%29%20complex%20with%20a%20long%20emission%20lifetime%20%28430%20mu%20s%29%2C%20even%20in%20a%20complex%20cellular%20environment.%20The%20ligand%20is%20easily%20synthesized%2C%20readily%20conjugated%20to%20antibodies%2C%20and%20suitable%20for%20multicolor%20and%20time-gated%20fluorescence%20microscopy%2C%20offering%20the%20possibility%20of%20imaging%20cellular%20structures%20in%20distinct%20spectral%20and%20temporal%20windows.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fcbmi.6c00148%22%2C%22citationKey%22%3A%22WOS%3A001886135600001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fcbmi.6c00148%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222832-3637%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22PLGT4TIP%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A03%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22KNBCYBR8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Chapel%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BP.%20Chapel%2C%20Y.%20Wang%2C%20C.%20Leuvrey%2C%20M.%20Lenertz%2C%20N.%20Parizel%2C%20A.%20Beauvois%2C%20V.%20Briois%2C%20D.%20Ihiawakrim%2C%20J.%20Poulizac%2C%20V.%20Rouchon%2C%20P.%20Rabu%2C%20C.%20Taviot-Gueho%2C%20G.%20Rogez%2C%20Multistep%20microwave-assisted%20approach%20for%20the%20controlled%20insertion%20of%20Cu%28ii%29%20into%20Dion-Jacobson%20and%20Ruddlesden-Popper%20layered%20perovskites%2C%20Materials%20Chemistry%20Frontiers%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6qm00623j%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6qm00623j%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Multistep%20microwave-assisted%20approach%20for%20the%20controlled%20insertion%20of%20Cu%28ii%29%20into%20Dion-Jacobson%20and%20Ruddlesden-Popper%20layered%20perovskites%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pacome%22%2C%22lastName%22%3A%22Chapel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yanhui%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Parizel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony%22%2C%22lastName%22%3A%22Beauvois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerie%22%2C%22lastName%22%3A%22Briois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julie%22%2C%22lastName%22%3A%22Poulizac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Virgile%22%2C%22lastName%22%3A%22Rouchon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Rabu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christine%22%2C%22lastName%22%3A%22Taviot-Gueho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Rogez%22%7D%5D%2C%22abstractNote%22%3A%22An%20innovative%20approach%20for%20inserting%20metal%20cations%20into%20layered%20perovskite%20oxides%20is%20investigated%20using%20a%20soft-chemistry%20route%20that%20enables%20controlled%20incorporation%20of%20cations%20such%20as%20Cu2%2B.%20Starting%20from%20the%20Ruddlesden-Popper%20phase%20H2Bi0.1Sr0.85Ta2O7%20and%20the%20Dion-Jacobson%20phase%20RbLaNb2O7%2C%20this%20work%20demonstrates%20hybrid%20compounds%2C%20such%20as%20alkylamine-intercalated%20derivatives%2C%20are%20superior%20intermediates%20for%20Cu2%2B%20insertion%20under%20mild%20conditions%20compared%20with%20pristine%20or%20protonated%20phases.%20A%20systematic%20study%20of%20the%20experimental%20parameters%20notably%20demonstrates%20that%20the%20amount%20of%20inserted%20copper%20is%20finely%20tunable%20via%20reaction%20temperature%20and%5C%2For%20the%20nature%20of%20the%20starting%20hybrid%20phase.%20A%20comprehensive%20structural%20investigation%20combining%20X-ray%20diffraction%20and%20high-resolution%20transmission%20electronic%20microscopy%20coupled%20to%20electron%20energy%20loss%20spectroscopy%20demonstrates%20copper%20insertion%20within%20the%20interlayer%20space%20while%20revealing%20that%20this%20insertion%20can%20induce%20stacking%20faults%20depending%20on%20the%20nature%20of%20the%20layered%20host%20phase.%20Insights%20into%20the%20oxidation%20state%2C%20local%20environment%20and%20Jahn-Teller%20distortion%20of%20the%20inserted%20copper%20are%20provided%20by%20a%20combination%20of%20spectroscopic%20techniques%20such%20as%20X-ray%20absorption%20spectroscopy%20and%20electron%20paramagnetic%20resonance.%20Finally%2C%20this%20approach%20demonstrates%20that%20copper%20insertion%20can%20lead%20to%20a%20reduction%20of%20the%20band%20gap%20of%20the%20material.%20This%20strategy%20overcomes%20key%20limitations%20currently%20reported%20in%20the%20literature%20for%20metal%20cation%20insertion%20into%20layered%20perovskite%20oxides%2C%20allowing%20low%20temperature%2C%20fast%20and%20efficient%20insertion%2C%20with%20fine%20control%20of%20the%20insertion%20rate%20and%20thus%20paving%20the%20way%20for%20the%20easy%2C%20efficient%20and%20versatile%20design%20of%20new%20functional%20materials.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd6qm00623j%22%2C%22citationKey%22%3A%22chapelMultistepMicrowaveassistedApproach2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6qm00623j%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222052-1537%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22DEB5KWFS%22%2C%22HMIN5U62%22%2C%22M244N6AF%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A36%3A37Z%22%7D%7D%2C%7B%22key%22%3A%226RX2A8GK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Chen%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BH.%20Chen%2C%20A.%20Borz%26%23xEC%3B%2C%20D.%20Jankovi%26%23x107%3B%2C%20J.-G.%20Hartmann%2C%20P.-A.%20Hervieux%2C%20Full-%20and%20Low-Rank%20Exponential%20Euler%20Integrators%20for%20the%20Lindblad%20Equation%2C%20SIAM%20Journal%20on%20Scientific%20Computing%2048%20%282026%29%20A1%26%23x2013%3BA26.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1137%5C%2F24M1690795%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1137%5C%2F24M1690795%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Full-%20and%20Low-Rank%20Exponential%20Euler%20Integrators%20for%20the%20Lindblad%20Equation%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hao%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alfio%22%2C%22lastName%22%3A%22Borz%5Cu00ec%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Denis%22%2C%22lastName%22%3A%22Jankovi%5Cu0107%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Gabriel%22%2C%22lastName%22%3A%22Hartmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%5D%2C%22abstractNote%22%3A%22Abstract.%20The%20Lindblad%20equation%20is%20a%20widely%20used%20quantum%20master%20equation%20to%20model%20the%20dynamical%20evolution%20of%20open%20quantum%20systems%20whose%20states%20are%20described%20by%20density%20matrices.%20These%20solution%20matrices%20are%20characterized%20by%20semipositiveness%20and%20trace%20preserving%20properties%2C%20which%20must%20be%20guaranteed%20in%20any%20physically%20meaningful%20numerical%20simulation.%20In%20this%20paper%2C%20novel%20full-%20and%20low-rank%20exponential%20Euler%20integrators%20are%20developed%20for%20approximating%20the%20Lindblad%20equation%20that%20preserve%20positivity%20and%20trace%20unconditionally.%20Theoretical%20results%20are%20presented%20that%20provide%20sharp%20error%20estimates%20for%20the%20two%20classes%20of%20exponential%20integration%20methods.%20Results%20of%20numerical%20experiments%20are%20discussed%20that%20illustrate%20the%20effectiveness%20of%20the%20proposed%20schemes%2C%20beyond%20present%20state-of-the-art%20capabilities.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1137%5C%2F24M1690795%22%2C%22citationKey%22%3A%22chenFullLowRankExponential2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1137%5C%2F24M1690795%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222026-04-23T14%3A58%3A53Z%22%7D%7D%2C%7B%22key%22%3A%224K9V922G%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Chico%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BR.%20Chico%2C%20M.J.%20Baena%2C%20C.%20Cuerva%2C%20R.%20Schmidt%2C%20B.%20Donnio%2C%20S.%20Coco%2C%20Ion%20transport%20in%20triphenylene%20metal-organic%20columnar%20mesophases%2C%20Journal%20of%20Materials%20Chemistry%20C%2014%20%282026%29%203306.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5tc03933a%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5tc03933a%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ion%20transport%20in%20triphenylene%20metal-organic%20columnar%20mesophases%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ruben%22%2C%22lastName%22%3A%22Chico%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Jesus%22%2C%22lastName%22%3A%22Baena%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristian%22%2C%22lastName%22%3A%22Cuerva%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rainer%22%2C%22lastName%22%3A%22Schmidt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silverio%22%2C%22lastName%22%3A%22Coco%22%7D%5D%2C%22abstractNote%22%3A%22Ionic%20liquid%20crystals%20%28iLCs%29%20constitute%20an%20emerging%20materials%20type%20that%20combines%20the%20properties%20of%20an%20ionic%20liquid%2C%20such%20as%20ionic%20mobility%2C%20with%20the%20supramolecular%20organization%20of%20a%20liquid%20crystal.%20This%20makes%20them%20suitable%20candidates%20for%20applications%20such%20as%20anisotropic%20ion%20conductors%20and%20next-generation%20energy%20storage%20systems.%20In%20this%20work%2C%20we%20report%20ion%20conducting%20columnar%20mesophases%20based%20on%20bis%28triphenylene-isocyanide%29%20metal%20complexes%20of%20the%20type%20%5BM%28CNR%292%5DY%20%28CNR%20%3D%202-%286-%284-isocyanophenoxy%29hexyloxy%29-3%2C6%2C7%2C10%2C11-pentakisdodecyloxy-triphen%20ylene%3B%20M%20%3D%20Ag%28i%29%2C%20Au%28i%29%3B%20Y%20%3D%20NO3-%2C%20BF4-%29.%20All%20the%20gold%20and%20silver%20complexes%20display%20enantiotropic%20mesomorphism%20in%20the%20temperature%20range%2035-80%20degrees%20C.%20They%20self-assemble%20into%20rectangular%20columnar%20mesophases%2C%20whose%20X-ray%20diffraction%20profiles%20reveal%20the%20simultaneous%20stacking%20of%20triphenylene%20disks%20into%20one-dimensional%20columns%20and%20the%20aggregation%20of%20metallic%20fragments%20assembled%20into%20filaments%20that%20are%20arranged%20parallel%20between%20the%20triphenylene%20columns.%20The%20ionic%20conductivity%20of%20these%20mesophases%20is%20based%20on%20the%20counterion%20mobility%20and%20increases%20regularly%20as%20the%20molecular%20slice%20thickness%20increases%20along%20the%20columns%2C%20ranging%20from%201.70%20x%2010-9%20to%201.64%20x%2010-8%20S%20cm-1.%20Although%20the%20conductivity%20values%20obtained%20so%20far%20are%20lower%20than%20those%20required%20for%20commercial%20displays%2C%20our%20results%20demonstrate%20the%20key%20role%20of%20packing%20efficiency%20in%20ion%20transport%20in%20soft%20materials%2C%20and%20the%20potential%20of%20organic%5C%2Finorganic%20nanosegregated%20mesophases%20to%20develop%20tailored%20and%20advanced%20ion-conducting%20materials.%20The%20gold%20and%20silver%20complexes%20display%20fluorescence%20behavior%20related%20to%20the%20triphenylene%20core%20in%20solution.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd5tc03933a%22%2C%22citationKey%22%3A%22chicoIonTransportTriphenylene2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd5tc03933a%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222050-7526%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222026-03-12T15%3A30%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22LDXD6FK8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cordova%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.S.%20Cordova%2C%20A.%20Friedel%2C%20Q.%20Rossi%2C%20J.%20Robert%2C%20Y.%20Henry%2C%20P.%20Pirro%2C%20S.%20Petit-Watelot%2C%20S.%20Andrieu%2C%20M.%20Bailleul%2C%20Spin%20polarization%20of%20the%20electric%20current%20in%20half-metallic%20Co2MnSi%20Heusler%20thin%20films%2C%20Physical%20Review%20B%20114%20%282026%29%20094436.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fw93y-w66w%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fw93y-w66w%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Spin%20polarization%20of%20the%20electric%20current%20in%20half-metallic%20Co2MnSi%20Heusler%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20Solano%22%2C%22lastName%22%3A%22Cordova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Friedel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Quentin%22%2C%22lastName%22%3A%22Rossi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J%5Cu00e9r%5Cu00f4me%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yves%22%2C%22lastName%22%3A%22Henry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Pirro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Petit-Watelot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Andrieu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathieu%22%2C%22lastName%22%3A%22Bailleul%22%7D%5D%2C%22abstractNote%22%3A%22Using%20propagating%20spin%20wave%20spectroscopy%20we%20measure%20the%20spin%20wave%20Doppler%20shift%20in%20patterned%20MgO%5C%2FCo2MnSi%5C%2FMgO%20thin%20films%20and%20determine%20the%20degree%20of%20spin%20polarization%20of%20the%20electric%20current.%20Our%20measurements%20reveal%20that%20the%20current%20is%20fully%20spin%20polarized%20in%20the%20devices.%20This%20shows%20that%20the%20half-metallic%20character%20of%20the%20electron%20band%20structure%20translates%20into%20a%20fully%20spin%20polarized%20current%20flowing%20across%20the%20patterned%20films.%20Additionally%2C%20we%20measure%20a%20current-induced%20change%20of%20the%20spin-wave%20attenuation%20from%20which%20we%20estimate%20the%20nonadiabatic%20spin-transfer-torque%20parameter.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Fw93y-w66w%22%2C%22citationKey%22%3A%22cordovaSpinPolarizationElectric2026%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2Fw93y-w66w%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222469-9950%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22GA3EX26X%22%2C%22PLGT4TIP%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A04%3A35Z%22%7D%7D%2C%7B%22key%22%3A%22X97AKP4J%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cretu%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20Cretu%2C%20A.A.%20Andelescu%2C%20M.%20La%20Deda%2C%20G.%20Di%20Maio%2C%20A.%20Len%2C%20Z.%20Dudas%2C%20L.%20Spina%2C%20F.%20Ciuchi%2C%20G.%20De%20Luca%2C%20B.%20Donnio%2C%20A.%20Crispini%2C%20F.%20Scarpelli%2C%20E.I.%20Szerb%2C%20Exploring%20the%20self-assembling%20ability%20of%20cyclometallated%20Rh%28iii%29%20complexes%20with%20different%20N%2CN-chelating%20ligands%20in%20water%2C%20Dalton%20Transactions%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6dt01255h%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6dt01255h%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Exploring%20the%20self-assembling%20ability%20of%20cyclometallated%20Rh%28iii%29%20complexes%20with%20different%20N%2CN-chelating%20ligands%20in%20water%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Carmen%22%2C%22lastName%22%3A%22Cretu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adelina%20A.%22%2C%22lastName%22%3A%22Andelescu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimo%22%2C%22lastName%22%3A%22La%20Deda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giuseppe%22%2C%22lastName%22%3A%22Di%20Maio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adel%22%2C%22lastName%22%3A%22Len%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zoltan%22%2C%22lastName%22%3A%22Dudas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenza%22%2C%22lastName%22%3A%22Spina%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federica%22%2C%22lastName%22%3A%22Ciuchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giuseppina%22%2C%22lastName%22%3A%22De%20Luca%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alessandra%22%2C%22lastName%22%3A%22Crispini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesca%22%2C%22lastName%22%3A%22Scarpelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elisabeta%20I.%22%2C%22lastName%22%3A%22Szerb%22%7D%5D%2C%22abstractNote%22%3A%22Ionic%20%5BRh%28ppy%292%28N%5Cu00a1%20%5Cu0302%5Cu00bfN%29%5DOOCCH3%20octahedral%20coordination%20complexes%20%28Rh_bpy%20and%20Rh_phen%3B%20ppy%20%3D%20phenylpyridine%3B%20N%5Cu00a1%20%5Cu0302%5Cu00bfN%20%3D%202%2C2%20%60-bipyridine%2C%20bpy%3B%20phenanthroline%2C%20phen%29%20are%20synthesized%2C%20and%20their%20behaviour%20in%20water%20is%20investigated%20in%20comparison%20with%20previously%20reported%20structurally%20analogous%20Ir%28iii%29%20complexes.%20Single-crystal%20X-ray%20analysis%20of%20both%20Rh%28iii%29%20complexes%20reveals%20significant%20structural%20differences%20upon%20the%20substitution%20of%20the%20N%5Cu00a1%20%5Cu0302%5Cu00bfN%20chelating%20ligand%2C%20substantially%20affecting%20their%20supramolecular%20organizations.%20The%20observed%20difference%20in%20the%20ability%20to%20self-assemble%20in%20water%20between%20Rh_bpy%20and%20Rh_phen%20highlights%20the%20essential%20role%20of%20the%20different%20N%5Cu00a1%20%5Cu0302%5Cu00bfN%20chelating%20ligands%20in%20the%20modulation%20of%20intermolecular%20interactions%2C%20leading%20to%20distinct%20hierarchical%20network%20structures.%20While%20the%20Rh_bpy%20complex%20self-assembles%20in%20water%20at%20a%20relatively%20low%20concentration%20%28from%201.9%25%20w%5C%2Fw%29%2C%20giving%20rise%20to%20a%20mesophase%20with%20a%20lyotropic%20chromonic-like%20characteristic%20nematic%20texture%2C%20Rh_phen%2C%20due%20to%20its%20limited%20dissolution%20in%20water%2C%20does%20not%20reach%20the%20concentrations%20required%20to%20form%20homogeneous%20mesophases.%20The%20lyotropic-like%20phase%20of%20Rh_bpy%20is%20characterised%20in%20detail%20by%20polarized%20optical%20microscopy%20%28POM%29%20observations%2C%20wide-angle%20X-ray%20scattering%20%28WAXS%29%20and%20small-angle%20neutron%20scattering%20%28SANS%29.%20These%20features%20contrast%20sharply%20with%20what%20has%20already%20been%20reported%20for%20structurally%20analogous%20Ir%28iii%29%20complexes%2C%20where%20a%20completely%20different%20behaviour%20in%20water%20is%20observed%20upon%20changing%20the%20ligand%20while%20keeping%20the%20metal%20ion%20constant.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd6dt01255h%22%2C%22citationKey%22%3A%22WOS%3A001850500100001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6dt01255h%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221477-9226%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22499C62Y9%22%2C%22HMIN5U62%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A36%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22ELXHPRZU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22D%27Aleo%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BAnthony.%20D%26%23x2019%3BAleo%2C%20A.K.%20Gupta%2C%20J.%20Gong%2C%20M.%20Kato%2C%20S.%20Tosun%2C%20L.%20Mager%2C%20J.C.%20Ribierre%2C%20Recent%20development%20of%20borondifluoride%20curcuminoid%20derivatives%20and%20their%20applications%2C%20CCS%20Chemistry%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.31635%5C%2Fccschem.026.202607299%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.31635%5C%2Fccschem.026.202607299%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Recent%20development%20of%20borondifluoride%20curcuminoid%20derivatives%20and%20their%20applications%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony.%22%2C%22lastName%22%3A%22D%27Aleo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20K.%22%2C%22lastName%22%3A%22Gupta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Gong%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Kato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Tosun%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lo%5Cu00efc%22%2C%22lastName%22%3A%22Mager%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20C.%22%2C%22lastName%22%3A%22Ribierre%22%7D%5D%2C%22abstractNote%22%3A%22In%20recent%20years%2C%20borondifluoride%20curcuminoid%20derivatives%20have%20emerged%20as%20a%20versatile%20class%20of%20functional%20organic%20materials%20that%20combine%20strong%20absorption%20with%20efficient%2C%20tunable%20emission.%20This%20review%20summarizes%20recent%20progress%20in%20the%20molecular%20design%2C%20photophysics%2C%20and%20applications%20of%20borondifluoride%20curcuminoid%20derivatives%20across%20bioimaging%2C%20organic%20optoelectronics%2C%20and%20epsilon-near-zero%20%28ENZ%29%20photonics.%20Their%20use%20as%20emitters%20and%20gain%20media%20in%20organic%20light-emitting%20diodes%20%28OLEDs%29%20and%20organic%20lasers%2C%20as%20well%20as%20their%20application%20in%20organic%20solar%20cells%20are%20discussed%2C%20highlighting%20the%20structureproperty%20relationships%20governing%20color%20tuning%2C%20excited-state%20dynamics%2C%20and%20emission%20efficiency.%20Their%20advantages%20for%20bioimaging%2C%20including%20high%20radiance%2C%20environment-sensitive%20fluorescence%2C%20and%20compatibility%20with%20visible%20and%20near-infrared%20windows%2C%20are%20reviewed.%20Finally%2C%20we%20highlight%20a%20recent%20work%20in%20which%20we%20demonstrated%20that%20neat%20films%20of%20some%20borondifluoride%20curcuminoid%20derivatives%20exhibited%20an%20ENZ%20response%2C%20opening%20new%20opportunities%20in%20organic%20photonics.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.31635%5C%2Fccschem.026.202607299%22%2C%22citationKey%22%3A%22WOS%3A001733564300001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.31635%5C%2Fccschem.026.202607299%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22CHW2VGSR%22%2C%22J5UPAUC3%22%2C%22VYTETDZF%22%2C%22WWGPR7DV%22%5D%2C%22dateModified%22%3A%222026-06-09T12%3A02%3A56Z%22%7D%7D%2C%7B%22key%22%3A%228ACZTIPM%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22D%27Aleo%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BA.%20D%26%23x2019%3BAleo%2C%20G.%20Michaluszko%2C%20A.%20Coron%2C%20D.-H.%20Kim%2C%20A.%20Gary%2C%20D.%20Valverde%2C%20E.%20Zaborova%2C%20E.%20Couzign%26%23xE9%3B%2C%20L.%20Engel%2C%20L.%20Mager%2C%20G.%20Canard%2C%20C.%20Adachi%2C%20Y.%20Olivier%2C%20J.-C.%20Ribierre%2C%20Donor-strength-driven%20evolution%20from%20charge-transfer%20to%20polymethine%20excited%20states%20in%20CurcBF2Derivatives%2C%20Advanced%20Optical%20Materials%20Early%20access%20%282026%29%20e71896.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.71896%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.71896%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Donor-strength-driven%20evolution%20from%20charge-transfer%20to%20polymethine%20excited%20states%20in%20CurcBF2Derivatives%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony%22%2C%22lastName%22%3A%22D%27Aleo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Michaluszko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amandine%22%2C%22lastName%22%3A%22Coron%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dae-%20Hyeon%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alban%22%2C%22lastName%22%3A%22Gary%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Danillo%22%2C%22lastName%22%3A%22Valverde%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elena%22%2C%22lastName%22%3A%22Zaborova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emilie%22%2C%22lastName%22%3A%22Couzign%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorry%22%2C%22lastName%22%3A%22Engel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Loic%22%2C%22lastName%22%3A%22Mager%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gabriel%22%2C%22lastName%22%3A%22Canard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chihaya%22%2C%22lastName%22%3A%22Adachi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoann%22%2C%22lastName%22%3A%22Olivier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-%20Charles%22%2C%22lastName%22%3A%22Ribierre%22%7D%5D%2C%22abstractNote%22%3A%22Thermally%20activated%20delayed%20fluorescence%20%28TADF%29%20has%20emerged%20as%20a%20powerful%20strategy%20to%20replace%20heavy-metal%20phosphorescent%20emitters%20in%20organic%20light-emitting%20diodes%20%28OLEDs%29%2C%20yet%20achieving%20highly%20efficient%20deep-red%20and%20near-infrared%20%28NIR%29%20emission%20remains%20challenging.%20Donor-acceptor-donor%20curcuminoid%20borondifluoride%20%28CurcBF2%29%20dyes%20have%20recently%20demonstrated%20promising%20NIR%20OLED%20emission%20through%20vibration-%20and%20spin-orbit-coupling-assisted%20TADF.%20Here%2C%20a%20series%20of%20CurcBF2%20derivatives%20bearing%20donor%20groups%20of%20varying%20strengths%20is%20synthesized%20and%20systematically%20investigated%20by%20steady-state%20and%20time-resolved%20spectroscopy%20in%20solution%20and%20thin%20films.%20The%20results%20reveal%20that%20the%20lowest%20singlet%20excited-state%20character%20is%20strongly%20governed%20by%20donor%20strength.%20Weak%20to%20moderately%20electron-donating%20substituents%20promote%20charge-transfer%20%28CT%29%20emission%20and%20TADF%20exciplex%20formation%20in%20thin%20films%2C%20whereas%20a%20stronger%20donor%2C%20such%20as%20TPA%2C%20enables%20TADF%20directly%20from%20the%20CurcBF2%20molecule.%20Further%20increasing%20donor%20strength%20induces%20a%20structural%20transformation%20toward%20a%20zwitterionic%20polymethine%2C%20resulting%20in%20predominantly%20local%20excited-state%20%28LE%29%20emission%20and%20suppressed%20TADF.%20These%20findings%20demonstrate%20that%20efficient%20TADF%20in%20CurcBF2%20systems%20requires%20a%20predominantly%20CT%20singlet%20excited%20state%20and%20highlight%20donor%20oxidation%20potential%20as%20a%20key%20parameter%20for%20controlling%20excited-state%20character.%20This%20work%20establishes%20molecular%20design%20principles%20for%20high-performance%20deep-red%20and%20NIR%20TADF%20emitters.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fadom.71896%22%2C%22citationKey%22%3A%22WOS%3A001895810600001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadom.71896%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222195-1071%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22CHW2VGSR%22%2C%22PLGT4TIP%22%2C%22TBP4QFHK%22%2C%22TK3HH32E%22%2C%22VYTETDZF%22%2C%22WWGPR7DV%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A05%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22QAZ5LRYM%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Darouich%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BO.%20Darouich%2C%20D.%20Ihiawakrim%2C%20S.%20Labidi%2C%20O.%20Ersen%2C%20W.%20Baaziz%2C%20Microstructural%20evolution%20and%20sintering%20of%20Pt%20nanoclusters%20on%20diatomite%20under%20CO%20oxidation%20conditions%3A%20An%20operando%20and%203D%20TEM%20study%2C%20Nano%20Research%2019%20%282026%29%2094908808.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.26599%5C%2FNR.2026.94908808%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.26599%5C%2FNR.2026.94908808%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Microstructural%20evolution%20and%20sintering%20of%20Pt%20nanoclusters%20on%20diatomite%20under%20CO%20oxidation%20conditions%3A%20An%20operando%20and%203D%20TEM%20study%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Othmane%22%2C%22lastName%22%3A%22Darouich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sana%22%2C%22lastName%22%3A%22Labidi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%5D%2C%22abstractNote%22%3A%22%5Cu00a1p%20style%3D%5Cu201dmargin-left%3A0px%3B%20margin-right%3A0px%5Cu201d%5Cu00bfIn%20this%20work%2C%20we%20investigated%20the%20microstructural%20evolution%20and%20thermal%20stability%20of%20platinum%20%28Pt%29%20nanoparticles%20supported%20on%20natural%20diatomite%20bio-silica%20%28SiO2%29%20during%20catalytic%20carbon%20monoxide%20%28CO%29%20oxidation%20using%20advanced%20transmission%20electron%20microscopy%20%28TEM%29%20techniques.%20Pt%20nanoparticles%20with%20an%20average%20size%20of%20similar%20to%201%20nm%20were%20obtained%20by%20impregnating%20purified%20diatomite%20fromCoscinodiscussp.%20with%20a%20Pt%28acac%29%282%29precursor%20and%20are%20preferentially%20located%20on%20the%20cribrum%5C%2Fforamen%20regions%2C%20where%20a%20native%20Fe%5C%2FAl-rich%20oxide%20layer%20promotes%20selective%20anchoring.OperandoTEM%20combined%20with%20mass%20spectrometry%20reveals%20that%20the%20Pt-diatomite%20catalyst%20is%20active%20from%20room%20temperature%20up%20to%20400%20degrees%20C%2C%20exhibiting%20fast%20reaction%20kinetics%20between%2025%20and%20100%20degrees%20C%20and%20at%20400%20degrees%20C.%20Three-dimensional%20electron%20tomography%20performed%20on%20the%20same%20Pt-diatomite%20grain%20before%20and%20after%20CO%20oxidation%20enables%20direct%20comparison%20of%20Pt%20nanoparticle%20positions%20and%20silica%20porosity%2C%20confirming%20the%20high%20structural%20stability%20of%20the%20catalyst%20under%20these%20conditions.%20The%20microstructural%20behavior%20was%20further%20examined%20up%20to%201000%20degrees%20C%20under%20reactive%20atmosphere%3A%20The%20catalyst%20remains%20stable%20up%20to%20600%20degrees%20C%2C%20while%20at%20higher%20temperatures%20%28600-800%20degrees%20C%29%20Pt%20nanoparticle%20sintering%20occurs%20as%20the%20Fe%5C%2FAl-oxide%20layer%20degrades%2C%20leading%20to%20enhanced%20CO%20conversion%20up%20to%20similar%20to%20950%20degrees%20C%20followed%20by%20partial%20deactivation%20at%20higher%20temperatures%20due%20to%20extensive%20sintering.%20These%20results%20provide%20direct%20nanoscale%20evidence%20of%20how%20a%20natural%20Fe%5C%2FAl-rich%20interfacial%20layer%20governs%20the%20stability%2C%20sintering%20pathways%20and%20performance%20of%20bio-silica-supported%20Pt%20catalysts%20under%20severe%20CO%20oxidation%20conditions%2C%20outlining%20a%20general%20mechanism%20for%20the%20thermal%20stability%20and%20deactivation%20of%20bio-derived%20hierarchical%20silica%20supports%20in%20high-temperature%20oxidation%20catalysis.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.26599%5C%2FNR.2026.94908808%22%2C%22citationKey%22%3A%22WOS%3A001868476200001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.26599%5C%2FNR.2026.94908808%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221998-0124%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226739WBV7%22%2C%22DEB5KWFS%22%2C%22PLGT4TIP%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A05%3A38Z%22%7D%7D%2C%7B%22key%22%3A%22MBKKS2UV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Demangeat%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20Demangeat%2C%20R.%20Rullan%2C%20Y.%20Tang%2C%20B.%20Hu%2C%20A.%20D%26%23x2019%3BAleo%2C%20T.%20Le%20Bahers%2C%20M.E.%20Alikhani%2C%20A.-J.%20Attias%2C%20Dopant-tailored%20matrices%3A%20a%20crystal%20engineering%20strategy%20for%20organic%20room-temperature%20phosphorescent%20host-guest%20systems%20and%20beyond%2C%20Angewandte%20Chemie-International%20Edition%20Early%20Access%20%282026%29%200%3Ae8252460.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.8252460%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.8252460%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Dopant-tailored%20matrices%3A%20a%20crystal%20engineering%20strategy%20for%20organic%20room-temperature%20phosphorescent%20host-guest%20systems%20and%20beyond%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Catherine%22%2C%22lastName%22%3A%22Demangeat%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Raphael%22%2C%22lastName%22%3A%22Rullan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yipeng%22%2C%22lastName%22%3A%22Tang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bin%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony%22%2C%22lastName%22%3A%22D%27Aleo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tangui%22%2C%22lastName%22%3A%22Le%20Bahers%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohammad%20Esmail%22%2C%22lastName%22%3A%22Alikhani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andre-Jean%22%2C%22lastName%22%3A%22Attias%22%7D%5D%2C%22abstractNote%22%3A%22Host-guest%20doping%20of%20molecular%20crystals%20is%20a%20powerful%20strategy%20to%20tune%20optoelectronic%20properties%2C%20yet%20achieving%20precise%20host-dopant%20compatibility%20and%20beneficial%20synergy%20without%20introducing%20detrimental%20effects%20caused%20by%20dopant-induced%20disorders%20remains%20challenging.%20Here%2C%20a%20new%20crystal%20engineering%20strategy%20is%20introduced%20in%20which%20host%20matrices%20are%20rationally%20designed%20to%20accommodate%20a%20predefined%20class%20of%20dopants%20and%20promote%20favorable%20host-guest%20interactions.%20This%20tailored-dopant%20matrix%20concept%20is%20demonstrated%20for%20dopant-induced%20organic%20room-temperature%20phosphorescence%20%28RTP%29%20using%20carbazole-based%20matrices%20and%20benzoindole-based%20dopants%2C%20a%20prototypical%20RTP%20system.%20Guided%20by%20the%20hypothesis%20that%20a%20herringbone%20packing%20of%20carbazole%20units%20promotes%20synergistic%20structural%20interactions%20with%20the%20dopant%2C%20a%20multiscale%20theoretical%20methodology%20is%20first%20developed%20to%20elucidate%20the%20intermolecular%20interactions%20stabilizing%20this%20motif%20in%20pristine%20carbazole-based%20crystals.%20These%20insights%20enable%20the%20design%20and%20synthesis%20of%20new%20host%20architectures%20exhibiting%20the%20targeted%20packing%20arrangement.%20Ultimately%2C%20the%20resulting%20single-crystalline%20host-guest%20materials%20exhibit%20long-lived%20organic%20RTP%2C%20with%20phosphorescence%20lifetimes%20of%20several%20hundred%20milliseconds.%20This%20work%20could%20establish%20dopant-tailored%20crystal%20engineering%20as%20a%20potential%20new%20paradigm%20for%20designing%20functional%20doped%20organic%20semiconductor%20crystals%20with%20tailored%20optoelectronic%20properties.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fanie.8252460%22%2C%22citationKey%22%3A%22WOS%3A001847210900001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.8252460%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221433-7851%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22499C62Y9%22%2C%22HMIN5U62%22%2C%22VYTETDZF%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A37%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22UN3FNVQT%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dherb%5Cu00e9court%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.%20Dherb%26%23xE9%3Bcourt%2C%20J.%20Bellessa%2C%20C.%20Symonds%2C%20G.%20Weick%2C%20D.%20Hagenmuller%2C%20Spontaneous%20raman%20scattering%20under%20vibrational%20strong%20coupling%3A%20The%20critical%20role%20of%20polariton%20spatial%20mode%20coherence%2C%20Physical%20Review%20Letters%20137%20%282026%29%20116901.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fm138-4w64%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fm138-4w64%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Spontaneous%20raman%20scattering%20under%20vibrational%20strong%20coupling%3A%20The%20critical%20role%20of%20polariton%20spatial%20mode%20coherence%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Dherb%5Cu00e9court%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joel%22%2C%22lastName%22%3A%22Bellessa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clementine%22%2C%22lastName%22%3A%22Symonds%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Weick%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Hagenmuller%22%7D%5D%2C%22abstractNote%22%3A%22Resonant%20coupling%20of%20a%20vibration%20to%20a%20cavity%20mode%20has%20been%20reported%20to%20dramatically%20modify%20spontaneous%20Raman%20scattering%2C%20but%20subsequent%20studies%20have%20produced%20conflicting%20results.%20In%20this%20Letter%2C%20we%20develop%20a%20microscopic%20quantum%20framework%20that%20captures%20the%20spatial%20structure%20of%20polaritonic%20modes.%20In%20a%20homogeneously%20filled%20cavity%2C%20spatial%20overlap%20between%20polaritons%20and%20cavity%20resonances%20enforces%20selection%20rules%20that%20suppress%20the%20initially%20reported%20polaritonic%20Raman%20peaks%2C%20consistent%20with%20most%20experiments.%20In%20contrast%2C%20for%20a%20quasi-two-dimensional%20%282D%29%20molecular%20layer%2C%20these%20rules%20are%20lifted%2C%20yielding%20Raman%20peaks%20at%20the%20polariton%20energies.%20Our%20Letter%20clarifies%20that%20the%20Raman%20response%20under%20vibrational%20strong%20coupling%20is%20determined%20by%20cavity-vibration%20spatial%20mode%20overlap%20and%20offers%20a%20framework%20for%20Raman%20studies%20of%20strongly%20coupled%20quasi-2D%20systems.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Fm138-4w64%22%2C%22citationKey%22%3A%22WOS%3A001879394700005%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2Fm138-4w64%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220031-9007%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22EPW69HFA%22%2C%22PLGT4TIP%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A06%3A02Z%22%7D%7D%2C%7B%22key%22%3A%22TSM5E4NK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dickson%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BL.E.%20Dickson%2C%20H.%20Cho%2C%20N.%20Ledos%2C%20V.-A.%20DiPalo%2C%20K.%20Udaya%20Mohanan%2C%20J.G.%20Manion%2C%20K.%20Narayanaswamy%2C%20S.%20M%26%23xE9%3Bry%2C%20N.%20Leclerc%2C%20C.-H.%20Kim%2C%20B.H.%20Lessard%2C%20Interfacial%20Siloxane%20Interactions%20to%20Enhance%20Semiconductor%20Ordering%20and%20Performance%20in%20Organic%20Thin-Film%20Transistors%2C%20ACS%20Applied%20Materials%20%26amp%3B%20Interfaces%20Early%20access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.6c01543%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.6c01543%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Interfacial%20Siloxane%20Interactions%20to%20Enhance%20Semiconductor%20Ordering%20and%20Performance%20in%20Organic%20Thin-Film%20Transistors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laura%20E.%22%2C%22lastName%22%3A%22Dickson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hyungjun%22%2C%22lastName%22%3A%22Cho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Ledos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vittoria-Ann%22%2C%22lastName%22%3A%22DiPalo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kannan%22%2C%22lastName%22%3A%22Udaya%20Mohanan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joseph%20G.%22%2C%22lastName%22%3A%22Manion%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kamatham%22%2C%22lastName%22%3A%22Narayanaswamy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22St%5Cu00e9phane%22%2C%22lastName%22%3A%22M%5Cu00e9ry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Leclerc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chang-Hyun%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20H.%22%2C%22lastName%22%3A%22Lessard%22%7D%5D%2C%22abstractNote%22%3A%22Achieving%20low-power%2C%20high-mobility%20organic%20thin-film%20transistors%20requires%20control%20over%20the%20buried%20interface%20between%20the%20semiconductor%20and%20the%20dielectric%20layers.%20Here%2C%20we%20demonstrate%20that%20siloxane-based%20molecular%20design%20provides%20a%20powerful%20means%20of%20engineering%20interfacial%20compatibility%20and%20charge%20transport.%20By%20integrating%20siloxane-functionalized%20diketopyrrolopyrrole%20%28DPP%29%20semiconductors%20with%20a%20PDMS-based%20polyionic%20liquid%20%28PIL%29%20dielectric%2C%20we%20show%20that%20siloxane-siloxane%20interactions%20promote%20enhanced%20molecular%20ordering%2C%20increased%20crystal%20coherence%2C%20and%20improved%20charge-carrier%20mobility%20of%20the%20semiconductor.%20Grazing-incidence%20wide-angle%20X-ray%20scattering%20and%20Raman%20morphological%20analyses%20indicate%20that%20interfacial%20interactions%20drive%20coherent%20stacking%20and%20reduce%20the%20level%20of%20disorder%20at%20the%20interface.%20This%20interfacial%20design%20strategy%20offers%20a%20general%20approach%20to%20tuning%20interfaces%20through%20conjugated%20polymer%5C%2Fdielectric%20systems%2C%20offering%20insight%20into%20strategies%20for%20the%20development%20of%20low-voltage%2C%20high-performance%20organic%20electronics.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facsami.6c01543%22%2C%22citationKey%22%3A%22dicksonInterfacialSiloxaneInteractions2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.6c01543%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221944-8244%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22VYTETDZF%22%5D%2C%22dateModified%22%3A%222026-04-23T14%3A56%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22JT36BBQS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dubois%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BD.%20Dubois%2C%20P.%20Guichard%2C%20R.%20Pasquier%2C%20Carbon%20nitride%20monolayer%20nanosheets%3A%20astrochemical%20insights%20into%20the%20fate%20of%20interstellar%20hydrogen%2C%20Physical%20Chemistry%20Chemical%20Physics%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6cp00221h%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6cp00221h%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Carbon%20nitride%20monolayer%20nanosheets%3A%20astrochemical%20insights%20into%20the%20fate%20of%20interstellar%20hydrogen%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Dubois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Guichard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Remi%22%2C%22lastName%22%3A%22Pasquier%22%7D%5D%2C%22abstractNote%22%3A%22Ubiquitously%20found%20in%20the%20Universe%2C%20atomic%20hydrogen%20represents%20up%20to%2070%25%20of%20the%20neutral%20gas%20composition%20of%20the%20Milky%20Way.%20As%20an%20adatom%2C%20hydrogen%20can%20physisorb%20or%20chemisorb%20onto%20interstellar%20dust%20grains%20and%20icy%20mantles%2C%20thereby%20contributing%20to%20the%20formation%20of%20H2%20and%2C%20potentially%2C%20to%20the%20synthesis%20of%20more%20complex%20hydrogenated%20species.%20In%20addition%2C%20structures%20with%20relatively%20large%20specific%20surface%20areas%20-%20such%20as%20silicates%2C%20amorphous%20carbon%2C%20graphene%20sheets%2C%20or%20water%20ice%20-%20host%20heterogeneous%20chemistry%20that%20is%20thought%20to%20facilitate%20the%20emergence%20of%20complex%20organic%20matter%20in%20astrophysical%20environments.%20Although%20the%20fundamental%20physical%20and%20chemical%20processes%20occurring%20at%20dust%5C%2Fgas%20interfaces%20are%20well%20characterized%2C%20current%20understanding%20of%20dust%20properties%20governing%20the%20formation%20of%20H2%20and%20complex%20molecules%20remains%20incomplete.%20In%20this%20context%2C%20we%20introduce%20graphitic-like%20two-dimensional%20carbon%20nitride%20monolayer%20structures%20%282D-CN%29%20as%20a%20putative%20molecular%20family%20of%20potential%20relevance%20to%20astro-chemistry.%20The%20physicochemical%20and%20electronic%20properties%20of%20these%20materials%20have%20been%20extensively%20examined%20in%20recent%20years%20for%20industrial%20and%20technological%20applications.%20Here%2C%20we%20propose%20that%20their%20importance%20may%20likewise%20extend%20to%20interstellar%20and%20circumstellar%20environments.%20To%20explore%20this%20possibility%2C%20we%20employed%20density%20functional%20theory%20%28DFT%29%20calculations%20to%20investigate%20the%20characteristics%20and%20extent%20of%20H%20adsorption%20onto%20C2N1%2C%20C3N1%2C%20C3N2%2C%20C3N4%2C%20C4N3%2C%20C6N6%2C%20C6N8%2C%20C9N4%2C%20and%20C9N7%20monolayer%20nanosheets.%20We%20identify%20multiple%20adsorption%20sites%20over%20C-C%20bonds%2C%20above%20C%20and%20N%20atoms%2C%20and%20hollow%20%28macropore%29%20locations%20at%20which%20energetically%20favorable%20binding%20of%20atomic%20hydrogen%20could%20occur%20in%20the%20interstellar%20medium%20%28ISM%29.%20From%20an%20astrochemical%20perspective%2C%20these%202D-CN%20structures%2C%20if%20formed%2C%20could%20therefore%20contribute%20to%20the%20physicochemical%20processing%20and%20evolution%20of%20hydrogen%20in%20the%20ISM.%20As%20such%2C%20given%20their%20structural%20similarities%20to%20prebiotic%20nitrogen-bearing%20frameworks%20%28many%20found%20in%20meteoritic%20samples%20and%20organic%20aerosols%29%2C%202D-CN%20molecules%20may%20emerge%20as%20promising%20candidates%20for%20exploring%20the%20complex%20interstellar%20chemistry%20of%20astrophysically%20relevant%20molecules.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd6cp00221h%22%2C%22citationKey%22%3A%22WOS%3A001747747100001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd6cp00221h%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221463-9076%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%2C%22J5UPAUC3%22%5D%2C%22dateModified%22%3A%222026-06-09T12%3A06%3A05Z%22%7D%7D%2C%7B%22key%22%3A%229585AFYV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Durupt%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BA.%20Durupt%2C%20C.%20Scarfiello%2C%20L.%20Schmidt%2C%20D.P.%20Minh%2C%20K.%20Soulantica%2C%20F.%20Meunier%2C%20O.%20Ersen%2C%20S.%20Zafeiratos%2C%20G.%20Clet%2C%20P.%20Serp%2C%20Reversible%20Strong%20Metal-Support%20Interactions%20in%20Co%5C%2FTiO2%20Catalysts%20Driven%20by%20CO2%2C%20ChemCatChem%2018%20%282026%29%20e01392.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcctc.202501392%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcctc.202501392%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Reversible%20Strong%20Metal-Support%20Interactions%20in%20Co%5C%2FTiO2%20Catalysts%20Driven%20by%20CO2%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aurelien%22%2C%22lastName%22%3A%22Durupt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Canio%22%2C%22lastName%22%3A%22Scarfiello%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leon%22%2C%22lastName%22%3A%22Schmidt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Doan%20Pham%22%2C%22lastName%22%3A%22Minh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katerina%22%2C%22lastName%22%3A%22Soulantica%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frederic%22%2C%22lastName%22%3A%22Meunier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Spyridon%22%2C%22lastName%22%3A%22Zafeiratos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Clet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Serp%22%7D%5D%2C%22abstractNote%22%3A%22Strong%20metal-support%20interactions%20can%20significantly%20influence%20catalytic%20performance.%20On%20titania%20supports%2C%20these%20interactions%20often%20involve%20the%20formation%20of%20a%20substoichiometric%20TiOX%20overlayer%20during%20high-temperature%20reduction%2C%20which%20can%20be%20reversed%20by%20treatments%20under%20dioxygen.%20Under%20CO2%20hydrogenation%20conditions%2C%20where%20water%20is%20produced%2C%20complete%20removal%20of%20the%20TiOX%20overlayer%20has%20been%20reported%2C%20raising%20questions%20about%20its%20stability%20in%20the%20presence%20of%20a%20mild%20oxidant%20such%20as%20CO2.%20In%20this%20study%2C%20in%20situ%20and%20operando%20techniques%20were%20employed%20to%20examine%20the%20effect%20of%20varying%20conditions%20on%20both%20the%20titania%20overlayer%20and%20cobalt%20species%20in%20a%20Co%5C%2FTiO2%20catalyst.%20After%20reduction%20at%20350%20degrees%20C%2C%20the%20overlayer%20consisted%20of%20stoichiometric%20anatase%20TiO2%2C%20while%20cobalt%20remained%20partially%20reduced.%20Exposure%20to%20CO2%5C%2FH2%20at%20220%20degrees%20C%20enabled%20complete%20cobalt%20reduction%20without%20affecting%20the%20TiO2%20overlayer.%20In%20contrast%2C%20pure%20CO2%20at%20220%20degrees%20C%20caused%20overlayer%20removal%20and%20full%20cobalt%20oxidation.%20The%20impact%20of%20this%20CO2-mediated%20reversibility%20on%20CO2%20hydrogenation%20was%20also%20evaluated.%20Although%20steady-state%20activity%20was%20largely%20unaffected%2C%20the%20transient%20regime%20showed%20substantial%20changes%20in%20selectivity%20and%20behavior.%20These%20results%20demonstrate%20that%20different%20treatments%20can%20strongly%20influence%20both%20the%20stability%20and%20reactivity%20of%20Co%5C%2FTiO2%20catalysts%2C%20highlighting%20the%20importance%20of%20dynamic%20SMSI%20effects%20in%20CO2%20hydrogenation.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fcctc.202501392%22%2C%22citationKey%22%3A%22duruptReversibleStrongMetalSupport2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcctc.202501392%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221867-3880%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226739WBV7%22%2C%22DEB5KWFS%22%5D%2C%22dateModified%22%3A%222026-02-23T08%3A57%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22RPI3PWP5%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22El%20Khabchi%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BL.%20El%20Khabchi%2C%20L.%20Schlur%2C%20J.%20Robert%2C%20M.%20Lenertz%2C%20C.%20Leuvrey%2C%20G.%20Versini%2C%20F.%20Roulland%2C%20G.%20Chahine%2C%20N.%20Blanc%2C%20D.%20Preziosi%2C%20C.%20Lefevre%2C%20N.%20Viart%2C%20Strain-driven%20magnetic%20anisotropy%20and%20spin%20reorientation%20in%20epitaxial%20CoV2O4%20spinel%20oxide%20thin%20films%2C%20Physical%20Review%20Materials%2010%20%282026%29%20014408.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fxzcv-shjr%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fxzcv-shjr%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Strain-driven%20magnetic%20anisotropy%20and%20spin%20reorientation%20in%20epitaxial%20CoV2O4%20spinel%20oxide%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lamiae%22%2C%22lastName%22%3A%22El%20Khabchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilbert%22%2C%22lastName%22%3A%22Chahine%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nils%22%2C%22lastName%22%3A%22Blanc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lefevre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22CoV2O4%20%28CVO%29%20stands%20out%20among%20spinel%20vanadates%20for%20its%20ultrashort%20V-V%20distances%2C%20placing%20it%20at%20the%20brink%20of%20itinerant%20electron%20behavior-an%20ideal%20playground%20for%20strain%20engineering.%20In%20this%20work%2C%20we%20exploit%20this%20sensitivity%20by%20growing%20high-quality%20epitaxial%20CVO%20thin%20films%20on%20SrTiO3%20%28001%29%20and%20MgO%20%28001%29%2C%20inducing%20compressive%20and%20tensile%20strain%2C%20respectively.%20Using%20pulsed%20laser%20deposition%20under%20ultralow%20oxygen%20pressure%2C%20we%20achieve%20high%20crystalline%20quality%20and%20strain-controlled%20tetragonal%20distortions%3A%20c%20%26gt%3B%20a%20under%20compression%20%28STO%29%20and%20c%20%26lt%3B%20a%20under%20tension%20%28MgO%29.%20Resonant%20elastic%20x-ray%20scattering%20confirms%20a%20normal%20spinel%20structure%2C%20with%20cobalt%20occupying%20tetrahedral%20sites%20and%20vanadium%20octahedral%20ones.%20Both%20strain%20types%20reduce%20charge%20transport%2C%20driving%20the%20system%20into%20a%20highly%20resistive%20state.%20Magnetic%20measurements%20reveal%20strain-driven%20anisotropy%20switching%3A%20STO%20films%20transition%20from%20out-of-plane%20to%20in-plane%20easy%20axis%20below%2090%20K%2C%20while%20MgO%20films%20flip%20from%20in-plane%20to%20out-of-plane%20below%2045%20K.%20These%20results%20highlight%20CVO%26%23039%3Bs%20exceptional%20responsiveness%20to%20lattice%20strain%2C%20unlocking%20a%20path%20to%20finely%20tunable%20electronic%20and%20magnetic%20properties.%20With%20its%20strong%20spin-lattice%20coupling%20and%20potential%20in%20spin%20Hall%20magnetoresistance%2C%20strained%20CVO%20emerges%20as%20a%20compelling%20platform%20for%20next-generation%20low-power%20spintronic%20devices.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Fxzcv-shjr%22%2C%22citationKey%22%3A%22elkhabchiStraindrivenMagneticAnisotropy2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fxzcv-shjr%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222475-9953%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22CHW2VGSR%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222026-03-12T15%3A50%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22L8T9BVSZ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Errouyessi%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BY.%20Errouyessi%2C%20H.%20Lassri%2C%20S.%20Colis%2C%20R.%20Moubah%2C%20Magnetic%20behavior%2C%20spin%20transitions%2C%20and%20magnetocaloric%20effect%20in%20europium%20orthoferrite%20EuFeO3%20nanoparticles%20synthesized%20by%20solid-state%20reaction%2C%20Inorganic%20Chemistry%20Communications%20186%20%282026%29%20116224.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.inoche.2026.116224%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.inoche.2026.116224%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetic%20behavior%2C%20spin%20transitions%2C%20and%20magnetocaloric%20effect%20in%20europium%20orthoferrite%20EuFeO3%20nanoparticles%20synthesized%20by%20solid-state%20reaction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Errouyessi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Lassri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Colis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Moubah%22%7D%5D%2C%22abstractNote%22%3A%22We%20present%20a%20comprehensive%20investigation%20of%20the%20structural%2C%20magnetic%20and%20magnetocaloric%20properties%20of%20europium%20orthoferrite%20EuFeO3%20nanoparticles.%20X-ray%20diffraction%20analysis%20confirms%20that%20the%20compound%20crystallizes%20in%20a%20singlephase%20orthorhombic%20perovskite%20structure%20belonging%20to%20the%20Pbnm%20space%20group.%20The%20sample%20exhibits%20an%20average%20crystallite%20size%20of%2043.6%20nm.%20Europium%20orthoferrite%20exhibits%20an%20antiferromagnetic%20ordering%20of%20Fe3%2B%20spins%2C%20accompanied%20by%20a%20weak%20ferromagnetic%20component%20induced%20by%20the%20Dzyaloshinskii-Moriya%20%28DM%29%20interaction.%20Such%20an%20interaction%20induces%20a%20slight%20deviation%20from%20the%20ideal%20antiparallel%20alignment%20of%20magnetic%20moments%20within%20the%20antiferromagnetic%20sublattices%2C%20giving%20rise%20to%20a%20spin-flop%20transition%20%28SFT%29%20and%20a%20small%20residual%20ferromagnetic%20moment.%20Special%20attention%20has%20been%20devoted%20to%20the%20spin-reorientation%20%28SR%29%20transitions%2C%20analyzed%20through%20the%20magnetocaloric%20effect%20%28MCE%29%20as%20a%20highly%20sensitive%20probe.%20The%20temperature%20evolution%20of%20the%20magnetic%20entropy%20change-Delta%20SM%20exhibits%20positive%20maximum%20values%20corresponding%20to%20a%20normal%20MCE%20near%20the%20two%20SR%20temperatures%2C%20TSR1%20%3D%2030K%20and%20TSR2%20%3D%20180K%2C%20whereas%20a%20negative%20MCE%20%28negative-Delta%20SM%20values%29%20emerges%20around%20T%20%3D%2060%20K.%20Such%20findings%20confirm%20the%20occurrence%20of%20a%20SR%20transition%20with%20a%20metamagnetic%20signature%2C%20emphasizing%20the%20complex%20magnetic%20nature%20inherent%20in%20this%20orthoferrite%20system.%20Analyses%20of%20the%20temperature%20dependence%20of%20the%20critical%20exponent%20n%28T%29%20under%20various%20applied%20magnetic%20fields%20further%20validates%20the%20observed%20transitions%20and%20provides%20deep%20insight%20into%20their%20intrinsic%20nature.%20Moreover%2C%20the%20construction%20of%20a%20universal%20phenomenological%20curve%2C%20achieved%20by%20normalizing%20each%20isofield-Delta%20SM%28T%29%20curve%2C%20offers%20additional%20confirmation%20of%20the%20type%20and%20order%20of%20these%20magnetic%20transitions.%20Overall%2C%20these%20results%20highlight%20the%20important%20role%20of%20the%20Dzyaloshinskii-Moriya%20interaction%20in%20stabilizing%20weak%20ferromagnetism%20in%20EuFeO3%2C%20while%20demonstrating%20the%20reliability%20and%20sensitivity%20of%20the%20magnetocaloric%20approach%20as%20a%20powerful%20method%20for%20probing%20subtle%20SR%20and%20metamagnetic%20phenomena%20in%20rare-earth%20orthoferrites.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.inoche.2026.116224%22%2C%22citationKey%22%3A%22errouyessiMagneticBehaviorSpin2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.inoche.2026.116224%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221387-7003%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222026-03-12T15%3A50%3A46Z%22%7D%7D%2C%7B%22key%22%3A%22HUUP7RSW%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fausti%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.%20Fausti%2C%20L.%20Arrico%2C%20A.%20Cesari%2C%20M.%20De%20Felice%2C%20M.A.%20Casulli%2C%20I.%20Taurino%2C%20T.%20Hashimoto%2C%20D.%20Pisignano%2C%20T.%20Biver%2C%20F.C.%20Zanacchi%2C%20L.%20Di%20Bari%2C%20A%20Eu%28III%29%20Supramolecular%20Emissive%20Label%20for%20Cyclodextrin-Based%20%28Nano%29Materials%2C%20ChemPhotoChem%2010%20%282026%29%20e202500336.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.202500336%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.202500336%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20Eu%28III%29%20Supramolecular%20Emissive%20Label%20for%20Cyclodextrin-Based%20%28Nano%29Materials%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mattia%22%2C%22lastName%22%3A%22Fausti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Arrico%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrea%22%2C%22lastName%22%3A%22Cesari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martina%22%2C%22lastName%22%3A%22De%20Felice%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Antonietta%22%2C%22lastName%22%3A%22Casulli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Irene%22%2C%22lastName%22%3A%22Taurino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takeshi%22%2C%22lastName%22%3A%22Hashimoto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dario%22%2C%22lastName%22%3A%22Pisignano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tarita%22%2C%22lastName%22%3A%22Biver%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesca%20Cella%22%2C%22lastName%22%3A%22Zanacchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Di%20Bari%22%7D%5D%2C%22abstractNote%22%3A%22The%20determination%20of%20the%20biodistribution%20of%20cyclodextrin-based%20%28nano%29materials%20represents%20a%20critical%20point%20for%20their%20development%20and%20in%20vivo%20use%20as%20drug%20carriers%20and%20gene-delivery%20systems.%20In%20this%20work%2C%20we%20report%20the%20design%20and%20preparation%20of%20a%20Eu%28III%29-based%20emissive%20probe%20based%20on%20a%20new%20adamantyl-appended%20beta-diketone.%20This%20probe%20has%20favorable%20emission%20and%20structural%20features%2C%20as%20it%20is%20endowed%20with%20a%20long%20lifetime%20%28280%20%26amp%3B%20micro%3Bs%29.%20Also%2C%20it%20is%20able%20to%20form%20a%20stable%20supramolecular%20inclusion%20complex%20with%20virtually%20any%20cyclodextrin-based%20systems.%20With%20such%20an%20emissive%20probe%2C%20time-resolved%20fluorescence%20imaging%20techniques%20could%20be%20exploited%20to%20obtain%20images%20with%20higher%20contrast%20and%20hence%20enhanced%20quality%2C%20allowing%20one%20to%20follow%20the%20fate%20of%20cyclodextrin-based%20delivery%20systems%20in%20complex%20biological%20media%2C%20such%20as%20cells%20and%20tissues.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fcptc.202500336%22%2C%22citationKey%22%3A%22faustiEuIIISupramolecularEmissive2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.202500336%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222367-0932%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222026-04-23T14%3A55%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22WCM7SKYG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fernandez%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.A.G.%20Fernandez%2C%20M.%20Latrache%2C%20G.%20Lemercier%2C%20C.%20Allain%2C%20F.%20Allais%2C%20M.%20Abe%2C%20N.%20Hoffmann%2C%20Photochemistry%20of%20%28-%29-levoglucosenone%3A%20Norrish%20type%20I%20reaction%20and%20photoinduced%20electron%20transfer%20processes%2C%20ChemPhotoChem%2010%20%282026%29%20e70171.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.70171%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.70171%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Photochemistry%20of%20%28-%29-levoglucosenone%3A%20Norrish%20type%20I%20reaction%20and%20photoinduced%20electron%20transfer%20processes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%20Andres%20Gomez%22%2C%22lastName%22%3A%22Fernandez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohammed%22%2C%22lastName%22%3A%22Latrache%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Lemercier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clemence%22%2C%22lastName%22%3A%22Allain%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florent%22%2C%22lastName%22%3A%22Allais%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Manabu%22%2C%22lastName%22%3A%22Abe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Norbert%22%2C%22lastName%22%3A%22Hoffmann%22%7D%5D%2C%22abstractNote%22%3A%22Photochemical%20reactions%20of%20levoglucosenone%20%28LGO%29%20considerably%20extend%20its%20potential%20as%20a%20synthon%20in%20organic%20synthesis.%20At%20the%20photochemical%20excited%20state%2C%20LGO%20undergoes%20a%20reaction%20that%20resembles%20Norrish%20type%20I%20reactions.%20Ketene%20intermediates%20are%20formed%20and%20trapped%20with%20alcohols%20or%20amines.%20A%20variety%20of%20alkenes%20with%20interesting%20substitution%20patterns%20are%20thus%20obtained.%20The%20reaction%20mechanism%20has%20been%20determined%20and%20compared%20to%20the%20classical%20mechanism%20of%20the%20Norrish%20type%20I%20reaction%20of%20Cyrene.%20The%20triplet%20energies%20of%20both%20compounds%20have%20also%20been%20determined%20by%20phosphorescence%20at%20low%20temperature.%20In%20the%20case%20of%20photochemically%20excited%20LGO%2C%20electron%20transfer%20from%20tertiary%20aromatic%20amines%20is%20possible.%20Such%20a%20photochemical%20electron%20transfer%20can%20also%20be%20induced%20by%20sensitization%20involving%20triplet%20energy%20transfer%20from%20a%20sensitizer%20to%20LGO.%20These%20processes%20are%20competitive%20with%20the%20efficient%20Norrish%20type%20I%20reactions.%20In%20such%20reactions%2C%20the%20bicyclic%20structure%20of%20LGO%20is%20conserved%2C%20and%20aniline%20derivatives%20are%20stereospecifically%20added.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fcptc.70171%22%2C%22citationKey%22%3A%22WOS%3A001764954300001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fcptc.70171%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222367-0932%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%2C%22J5UPAUC3%22%5D%2C%22dateModified%22%3A%222026-06-09T12%3A03%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22ZPVI9ZS2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fiore%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Fiore%2C%20N.%20Sellati%2C%20M.%20Udina%2C%20L.%20Benfatto%2C%20Two-dimensional%20terahertz%20spectroscopy%20in%20electronic%20systems%3A%20A%20many-body%20diagrammatic%20approach%2C%20Physical%20Review%20B%20113%20%282026%29%20174524.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2F8ffz-rtyf%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2F8ffz-rtyf%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Two-dimensional%20terahertz%20spectroscopy%20in%20electronic%20systems%3A%20A%20many-body%20diagrammatic%20approach%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacopo%22%2C%22lastName%22%3A%22Fiore%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Niccolo%22%2C%22lastName%22%3A%22Sellati%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mattia%22%2C%22lastName%22%3A%22Udina%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lara%22%2C%22lastName%22%3A%22Benfatto%22%7D%5D%2C%22abstractNote%22%3A%22The%20term%20%5Cu201ctwo-dimensional%20coherent%20spectroscopy%5Cu201d%20%282DCS%29%20usually%20refers%20to%20experimental%20setups%20where%20a%20coherently%20generated%20electric%20field%20in%20a%20sample%20is%20recorded%20over%20many%20runs%20as%20a%20function%20of%20two%20time%20variables%3A%20the%20delay%20tau%20between%20two%20consequent%20excitation%20pulses%20and%20the%20time%20t%20over%20which%20the%20signal%20is%20emitted.%20Even%20if%20its%20implementation%20in%20the%20femtosecond%20time%20domain%20for%20investigation%20of%20vibrational%20molecular%20states%20was%20developed%20more%20than%20two%20decades%20ago%2C%20its%20experimental%20development%20in%20the%20terahertz%20domain%20with%20application%20to%20interacting%20electronic%20systems%20is%20still%20in%20its%20infancy.%20The%20present%20work%20aims%20at%20providing%20a%20theoretical%20framework%20for%20the%20description%20and%20interpretation%20of%202DCS%20by%20using%20the%20same%20many-body%20language%20based%20on%20a%20perturbative%20diagrammatic%20expansion%20that%20has%20been%20largely%20developed%20and%20applied%20in%20the%20literature%20to%20linear%20spectroscopy.%20By%20focusing%20on%20the%20case%20of%20centrosymmetric%20systems%2C%20we%20show%20how%20the%20problem%20of%20the%20theoretical%20interpretation%20of%20the%202D%20maps%20can%20be%20recast%20in%20the%20solution%20of%20two%20different%20but%20complementary%20problems.%20The%20first%20one%20is%20the%20evaluation%20of%20a%20third-order%20response%20function%20to%20the%20gauge%20field%2C%20whose%20derivation%20in%20the%20velocity%20gauge%20leads%20to%20a%20semianalytical%20expression%20for%20the%20computation%20of%20the%202D%20maps%20in%20the%20case%20of%20simple%20band%20dispersions%20and%20a%20Gaussianlike%20pulse%20envelope.%20This%20has%20the%20twofold%20advantage%20of%20reducing%20considerably%20the%20computational%20complexity%20and%20to%20guide%20the%20assignment%20of%20the%20spectral%20features%20to%20microscopic%20processes%2C%20as%20we%20demonstrate%20explicitly%20for%20a%20toy%20model%20of%20electrons%20in%20a%20semiconductinglike%20band%20structure.%20The%20second%20one%20is%20a%20careful%20description%20of%20multiwave%20propagation%20effects%20inside%20the%20material%2C%20that%20for%20bulk%20systems%20can%20completely%20screen%20the%20intrinsic%20properties%20of%20the%20nonlinear%20response%2C%20as%20we%20show%20for%20the%20case%20of%20soft%20superconducting%20Josephson%20plasmons.%20Our%20results%20provide%20a%20theoretical%20foundation%20prone%20to%20further%20extension%20to%20several%20interacting%20systems%20and%20offer%20a%20flexible%20method%20for%20modeling%20realistically%20the%20nonlinear%20responses%20across%20arbitrary%20spectral%20widths%20of%20the%20driving%20fields.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2F8ffz-rtyf%22%2C%22citationKey%22%3A%22WOS%3A001778786000001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2F8ffz-rtyf%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222469-9950%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22EPW69HFA%22%2C%22QD76RV9Q%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-06-26T12%3A37%3A12Z%22%7D%7D%2C%7B%22key%22%3A%22CB84VURK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Flavenot%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.%20Flavenot%2C%20H.%20Sahib%2C%20J.%20Robert%2C%20M.%20Lenertz%2C%20G.%20Versini%2C%20L.%20Schlur%2C%20A.%20Gloter%2C%20N.%20Viart%2C%20D.%20Preziosi%2C%20Decoding%20Superconductivity%20in%20La3Ni2O7-%26%23x3B4%3B%20Thin%20Films%20via%20Ozone-Driven%20Structure%20and%20Oxidation%20Tuning%2C%20Small%20Structures%207%20%282026%29%207%3Ae70542.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsstr.70542%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsstr.70542%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Decoding%20Superconductivity%20in%20La3Ni2O7-%5Cu03b4%20Thin%20Films%20via%20Ozone-Driven%20Structure%20and%20Oxidation%20Tuning%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathieu%22%2C%22lastName%22%3A%22Flavenot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hoshang%22%2C%22lastName%22%3A%22Sahib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Gloter%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%5D%2C%22abstractNote%22%3A%22The%20discovery%20of%20superconductivity%20in%20bulk%20Ruddlesden-Popper%20La3Ni2O7%28LNO327%29%20under%20high%20hydrostatic%20pressure%20has%20redefined%20the%20recent%20experimental%20consensus%20that%20nickelate%20superconductivity%20is%20restricted%20to%20systems%20with%20a%203d%209%20electronic%20configuration%20and%20square-planar%20coordination.%20However%2C%20the%20structural%20and%20electronic%20prerequisites%20for%20stabilizing%20superconductivity%2C%20whether%20under%20pressure%20or%20at%20ambient%20conditions%20in%20the%20case%20of%20thin%20films%2C%20remain%20poorly%20understood%2C%20largely%20due%20to%20the%20metastable%20nature%20of%20the%20LNO327%20phase.%20Here%2C%20we%20present%20a%20detailed%20structural%20study%20of%20epitaxial%20La3Ni2O7-delta%20thin%20films%20by%20using%20scanning%20transmission%20electron%20microscopy%20%28STEM%29%20combined%20with%20electron%20energy%20loss%20spectroscopy%20%28EELS%29.%20Grown%20via%20pulsed%20laser%20deposition%20onto%20SrLaAlO4%20substrates%2C%20those%20films%20exhibit%20distinct%20superconducting%20properties%20as%20a%20function%20of%20the%20different%20post-annealing%20conditions%20used.%20By%20correlating%20the%20rich%20landscape%20of%20stacking%20polymorphs%20with%20transport%20behavior%2C%20this%20work%20establishes%20a%20framework%20for%20understanding%20the%20metastable%20superconducting%20phase%20in%20bilayer%20nickelate%20thin%20films.%20In%20particular%2C%20we%20found%20that%20the%20LNO-1313%20stacking%20polymorph%20does%20not%20support%20superconductivity%2C%20suggesting%20it%20is%20not%20a%20superconducting%20phase.%20Our%20findings%20underscore%20the%20critical%20role%20of%20homogeneity%20in%20oxygen%20stoichiometry%2C%20epitaxial%20strain%20and%20structural%20motif%20in%20stabilizing%20superconductivity%2C%20offering%20a%20clear%20pathway%20for%20designing%20ambient-pressure%20superconducting%20nickelates.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fsstr.70542%22%2C%22citationKey%22%3A%22flavenotDecodingSuperconductivityLa3Ni2O7%5Cu03b42026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsstr.70542%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222688-4062%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22CHW2VGSR%22%2C%22HMIN5U62%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A38%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22F25J9I7Q%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Fluck%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BA.%20Fluck%2C%20V.%20Giuso%2C%20C.-H.%20Liu%2C%20C.%20Gourlaouen%2C%20C.%20Cebrian%2C%20F.%20Polo%2C%20H.-C.%20Su%2C%20A.%20Jouaiti%2C%20M.%20Mauro%2C%20Near%20infrared%20electroluminescence%20in%20light-emitting%20electrochemical%20cells%20from%20the%20binuclear%20copper%28i%29%20complexes%20bearing%20%26%23x3C0%3B-extended%20benzimidazole%20and%20benzothiazole%20ligands%2C%20Journal%20of%20Materials%20Chemistry%20C%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6tc00899b%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6tc00899b%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Near%20infrared%20electroluminescence%20in%20light-emitting%20electrochemical%20cells%20from%20the%20binuclear%20copper%28i%29%20complexes%20bearing%20%5Cu03c0-extended%20benzimidazole%20and%20benzothiazole%20ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Audrey%22%2C%22lastName%22%3A%22Fluck%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Giuso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chun-Hsi%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristina%22%2C%22lastName%22%3A%22Cebrian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hai-Ching%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelaziz%22%2C%22lastName%22%3A%22Jouaiti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22The%20design%20of%20compounds%20that%20efficiently%20emit%20into%20the%20deep-red%20to%20near-infrared%20%28NIR%29%20region%20is%20highly%20challenging%2C%20yet%20they%20can%20play%20pivotal%20roles%20in%20optoelectronic%20devices%20for%20phototherapy%2C%20encryption%20and%20telecommunication%20technology.%20To%20date%2C%20examples%20of%20NIR-emissive%20earth-abundant%20Cu%28i%29%20complexes%20are%20still%20very%20rare%20in%20literature.%20Herein%2C%20a%20series%20of%20binuclear%20heteroleptic%20Cu%28i%29%20complexes%2C%20namely%2C%20Cu1-Cu4%2C%20is%20presented%20and%20thoroughly%20characterized%20by%20chemical%20and%20time-resolved%20optical%20spectroscopies%20as%20well%20as%20single-crystal%20X-ray%20diffraction%20analysis.%20The%20optical%20and%20electronic%20properties%20are%20further%20elucidated%20with%20time-dependent%20density%20functional%20theory%20%28TD-DFT%29%20computations%20that%20confirm%20the%20nature%20of%20the%20transitions%20and%20excited%20states%20involved.%20It%20is%20shown%20that%20the%20introduction%20of%20sulphur%20and%20nitrogen%20heteroatoms%20in%20the%20peripheral%20pi-accepting%20coordinating%20scaffolds%2C%20such%20as%20%28substituted%29%20benzimidazoles%20and%20benzothiazole%2C%20along%20with%20the%20thiazolo%5B5%2C4-d%5Dthiazole%20bridging%20unit%2C%20results%20in%20deep-red%20to%20NIR%20emissive%20complexes%20both%20in%20CH2Cl2%20solution%20and%20in%20the%20solid%20state%2C%20with%20long-lived%20emission%20profiles%20centred%20at%20lambda%28em%29%20%3D%20734-776%20nm%20and%20644-757%20nm%2C%20respectively%2C%20attributable%20to%20an%20emissive%20excited%20state%20with%20admixed%20%28MLCT%29-M-3%5C%2F%28LLCT%29-L-3%20character.%20Finally%2C%20the%20derivatives%20Cu1%20and%20Cu4%20are%20tested%20as%20electroluminescent%20materials%20in%20light-emitting%20electrochemical%20cells%20%28LECs%29.%20The%20former%20displays%20deep-red%20electroluminescence%20%28EL%29%2C%20with%20lambda%28EL%29%20%3D%20686-697%20nm%20and%20an%20external%20quantum%20efficiency%20%28EQE%29%20up%20to%200.5%25%2C%20while%20the%20latter%20remarkably%20achieves%20NIR%20EL%20with%20lambda%28EL%29%20%5Cu00bf%20770%20nm%20in%20combination%20with%20high%20spectral%20stability.%20Overall%2C%20the%20presented%20results%20demonstrate%20that%20Cu%28i%29%20complexes%20represent%20a%20valid%20alternative%20to%20precious%20metals%20for%20NIR%20EL%20devices.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd6tc00899b%22%2C%22citationKey%22%3A%22WOS%3A001788060900001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd6tc00899b%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222050-7526%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22QD76RV9Q%22%5D%2C%22dateModified%22%3A%222026-06-26T12%3A38%3A17Z%22%7D%7D%2C%7B%22key%22%3A%22NE56LBN6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Frey%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Frey%2C%20S.%20Azar%2C%20S.%20Dagorne%2C%20S.%20Bellemin-Laponnaz%2C%20Bis%28phenolate%29%20n-heterocyclic%20carbene%20%5BOCO%5D%20pincer%20ligands%3A%20a%20unique%20family%20for%20the%20stabilization%20of%20transition%20metal%20centers%20and%20main%20group%20elements%2C%20ChemistryEurope%204%20%282026%29%20e202500283.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fceur.202500283%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fceur.202500283%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Bis%28phenolate%29%20n-heterocyclic%20carbene%20%5BOCO%5D%20pincer%20ligands%3A%20a%20unique%20family%20for%20the%20stabilization%20of%20transition%20metal%20centers%20and%20main%20group%20elements%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Frey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soussana%22%2C%22lastName%22%3A%22Azar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Samuel%22%2C%22lastName%22%3A%22Dagorne%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22The%20present%20contribution%20comprehensively%20reviews%20the%20coordination%20chemistry%20of%20N-heterocyclic%20carbene%20%28NHC%29%20bis-phenolate%20tridentate%20ligand%20of%20the%20type%20%5BOCO%5D%20to%20various%20metal%20and%20heteroatom%20centers.%20The%20structural%20features%20of%20the%20resulting%20robust%20%5BOCO%5DM%20chelates%20are%20discussed%20along%20with%20their%20unique%20and%20specific%20properties%2C%20including%20emerging%20redox%20and%20optical%20properties%20of%20such%20complexes.%20Thanks%20to%20their%20stability%20and%20electronic%20features%2C%20this%20class%20of%20robust%20metal%20chelates%20has%20already%20been%20exploited%20for%20various%20catalytic%20applications%2C%20most%20notably%20the%20controlled%20polymerization%20of%20polar%20cyclic%20monomers%20and%20olefins%2C%20N2%20reduction%20and%20photoinduced%20catalysis.%20In%20addition%2C%20some%20%5BOCO%5DM%20complexes%20have%20also%20been%20shown%20to%20stoichiometrically%20activate%5C%2Ffunctionalize%20small%20molecules%20such%20as%20O2%20and%20NH3.%20All%20these%20aspects%2C%20some%20of%20them%20just%20emerging%2C%20are%20discussed%20herein%20along%20with%20future%20research%20opportunities%20on%20%5BOCO%5DM%20chelates.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fceur.202500283%22%2C%22citationKey%22%3A%22WOS%3A001816309100001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fceur.202500283%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222751-4765%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22499C62Y9%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A38%3A38Z%22%7D%7D%2C%7B%22key%22%3A%22C3MC93BH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Gambari%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Gambari%2C%20H.%20Le%20Du%2C%20M.%20Lizee%2C%20A.%20Mukherjee%2C%20L.%20Limot%2C%20F.%20Scheurer%2C%20M.%20D%26%23x2019%3Bangelo%2C%20F.%20Debontridder%2C%20T.%20Cren%2C%20M.%20Herve%2C%20Electronic%20Signatures%20of%20the%20Multiple%20Moire%20Components%20in%20the%20Two-Dimensional%20CrCl3%5C%2FAu%20Heterostructure%20Observed%20by%20Scanning%20Tunneling%20Microscopy%20and%20Spectroscopy%2C%20ACS%20Nano%20Early%20access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.5c21391%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.5c21391%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electronic%20Signatures%20of%20the%20Multiple%20Moire%20Components%20in%20the%20Two-Dimensional%20CrCl3%5C%2FAu%20Heterostructure%20Observed%20by%20Scanning%20Tunneling%20Microscopy%20and%20Spectroscopy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eugenio%22%2C%22lastName%22%3A%22Gambari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hugo%22%2C%22lastName%22%3A%22Le%20Du%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathieu%22%2C%22lastName%22%3A%22Lizee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arindam%22%2C%22lastName%22%3A%22Mukherjee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Limot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Scheurer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marie%22%2C%22lastName%22%3A%22D%27angelo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Debontridder%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tristan%22%2C%22lastName%22%3A%22Cren%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marie%22%2C%22lastName%22%3A%22Herve%22%7D%5D%2C%22abstractNote%22%3A%22Moire%20patterns%20are%20a%20central%20motif%20in%20van%20der%20Waals%20heterostructures%20arising%20from%20the%20superposition%20of%20two-dimensional%20%282D%29%20incommensurate%20lattices.%20These%20patterns%20reveal%20a%20wealth%20of%20correlated%20effects%2C%20influencing%20electronic%2C%20magnetic%2C%20and%20structural%20phenomena.%20While%20diffraction%20techniques%20typically%20resolve%20multiple%20moire%20wave%20vectors%20corresponding%20to%20the%20incommensurate%20nature%20of%20the%20underlying%20lattices%2C%20Scanning%20Tunneling%20Microscopy%20%28STM%29%20often%20reveals%20only%20a%20dominant%20superperiod.%20In%20this%20work%2C%20we%20address%20this%20apparent%20discrepancy%20through%20an%20STM%20study%20of%20a%20twisted%20monolayer%20of%20CrCl3%20on%20Au%28111%29.%20We%20observe%20the%20coexistence%20of%20several%20Fourier%20components%20of%20moire%20patterns%20at%20a%20fixed%20twist%20angle%2C%20whose%20relative%20intensity%20depends%20on%20the%20tunneling%20bias.%20Fourier%20analysis%20of%20STM%20data%20uncovers%20hidden%20higher-order%20moire%20components%20not%20visible%20in%20STM%20topographic%20images%2C%20while%20spectroscopy%20maps%20reveal%20that%20the%20spectral%20weight%20of%20each%20pattern%20varies%20with%20electron%20energy.%20Our%20results%20establish%20that%20STM%20selectively%20probes%20in%20the%20same%20area%20distinct%20quasiperiodic%20modulations%20depending%20on%20electronic%20confinement%2C%20providing%20a%20unified%20framework%20that%20reconciles%20real-space%20and%20reciprocal-space%20observations%20of%20complex%20moire%20superstructures.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facsnano.5c21391%22%2C%22citationKey%22%3A%22gambariElectronicSignaturesMultiple2026May20Epub2026May20%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsnano.5c21391%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%229USMFXMV%22%2C%22DEB5KWFS%22%2C%22J5UPAUC3%22%5D%2C%22dateModified%22%3A%222026-08-28T09%3A27%3A36Z%22%7D%7D%2C%7B%22key%22%3A%228JLM25AY%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ghobar%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.%20Ghobar%2C%20C.B.%20Karroum%2C%20M.%20Liparo%2C%20A.R.E.%20Prinsloo%2C%20C.J.%20Sheppard%2C%20G.%20Simon%2C%20J.%20Robert%2C%20N.L.%20Breton%2C%20A.%20Fessant%2C%20J.-P.%20Jay%2C%20D.T.%20Dekadjevi%2C%20D.%20Spenato%2C%20Low-damping%20spin%20dynamics%20in%20thin%20sputtered%20FeGa%20films%20for%20strain-mediated%20spintronics%2C%20Applied%20Physics%20Letters%20129%20%282026%29%20082402.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0343561%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0343561%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Low-damping%20spin%20dynamics%20in%20thin%20sputtered%20FeGa%20films%20for%20strain-mediated%20spintronics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Madeleine%22%2C%22lastName%22%3A%22Ghobar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cynthia%20Bou%22%2C%22lastName%22%3A%22Karroum%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthieu%22%2C%22lastName%22%3A%22Liparo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aletta%20R.%20E.%22%2C%22lastName%22%3A%22Prinsloo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charles%20J.%22%2C%22lastName%22%3A%22Sheppard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gaelle%22%2C%22lastName%22%3A%22Simon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nolwenn%20Le%22%2C%22lastName%22%3A%22Breton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alain%22%2C%22lastName%22%3A%22Fessant%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Philippe%22%2C%22lastName%22%3A%22Jay%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%20T.%22%2C%22lastName%22%3A%22Dekadjevi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Spenato%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20on%20the%20dynamic%20and%20quasistatic%20magnetic%20properties%20of%20ultrathin%20sputtered%20Ta%5C%2FFe81Ga19%5C%2Fglass%20thin%20films%20without%20buffer%20layers%20or%20post-deposition%20annealing.%20Ferromagnetic%20resonance%20measurements%20reveal%20a%20narrow%20peak-to-peak%20linewidth%20of%2010.3%20%2B%5C%2F-%200.3%20mT%20at%209.86%20GHz%2C%20corresponding%20to%20an%20upper-bound%20Gilbert%20damping%20parameter%20of%202.5%20%26amp%3B%20times%3B10%28-2%29.%20These%20films%20also%20exhibit%20low%20coercivity%20in%20the%20range%20of%203-6%20mT%2C%20confirming%20their%20soft%20magnetic%20character.%20Angular-dependent%20measurements%20indicate%20a%20predominantly%20twofold%20symmetry%20in%20the%20resonance%20field%2C%20while%20magnetization%20reversal%20displays%20a%20fourfold%20behavior.%20The%20origin%20of%20this%20discrepancy%20between%20dynamic%20and%20quasistatic%20anisotropies%20remains%20unclear%20and%20calls%20for%20further%20investigation.%20These%20results%20establish%20sputtered%20FeGa%20as%20a%20promising%20rare-earth-free%20magnetostrictive%20material%20combining%20strong%20magnetoelastic%20coupling%20with%20low-loss%20spin%20dynamics.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0343561%22%2C%22citationKey%22%3A%22ghobarLowdampingSpinDynamics2026%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F5.0343561%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220003-6951%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22PLGT4TIP%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A06%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22UU5IDKGX%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Girelli%20Consolaro%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BV.%20Girelli%20Consolaro%2C%20V.%20Rouchon%2C%20W.%20Baaziz%2C%20A.%20Hammoumi%2C%20T.%20Fert%26%23xE9%3B%2C%20G.%20Pirngruber%2C%20M.%20Moreaud%2C%20O.%20Ersen%2C%20On%20the%20properties%20and%20origin%20of%20mesopore%20morphologies%20in%20dealuminated%20Faujasite%20Y%20zeolites%2C%20Nanoscale%2018%20%282026%29%20173%26%23x2013%3B187.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD5NR01457C%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD5NR01457C%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22On%20the%20properties%20and%20origin%20of%20mesopore%20morphologies%20in%20dealuminated%20Faujasite%20Y%20zeolites%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valentina%22%2C%22lastName%22%3A%22Girelli%20Consolaro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Virgile%22%2C%22lastName%22%3A%22Rouchon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adam%22%2C%22lastName%22%3A%22Hammoumi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tom%22%2C%22lastName%22%3A%22Fert%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gerhard%22%2C%22lastName%22%3A%22Pirngruber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Moreaud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%5D%2C%22abstractNote%22%3A%22Faujasite%20Y%20zeolites%20%28FAU-Y%29%20represent%20one%20of%20the%20most%20important%20categories%20of%20heterogeneous%20catalysts.%20They%20are%20historically%20known%20for%20their%20crucial%20role%20in%20the%20refining%20industry%2C%20and%20they%20have%20growing%20potential%20for%20upgrading%20bio-based%20products%20today.%20However%2C%20the%20thermal%20stability%2C%20acidity%2C%20and%20molecular%20transport%20properties%20of%20the%20synthesized%20zeolite%20are%20not%20ideal%20for%20the%20intended%20process%20conditions%2C%20activity%2C%20selectivity%20and%20catalyst%20deactivation.%20Consequently%2C%20post-synthesis%20physical%5Cu2013chemical%20treatments%2C%20such%20as%20dealuminating%20treatments%2C%20are%20usually%20employed%20to%20design%20a%20more%20efficient%20material%20that%20combines%20stronger%20acidity%2C%20better%20stability%2C%20and%20hierarchical%20porosity.%20This%20material%20is%20referred%20to%20as%20Ultrastable%20Y%20%28USY%29%20zeolite.%20Nevertheless%2C%20the%20precise%20mechanisms%20of%20mesopore%20network%20formation%20and%20its%20relationship%20with%20the%20crystal%20structure%20and%20morphology%20remain%20poorly%20understood.%20Our%20research%20investigates%20the%20evolution%20of%20the%20porous%20system%20induced%20by%20the%20dealumination%20in%20FAU-Y%20zeolites.%20Here%2C%20we%20propose%20a%20classification%2C%20quantification%2C%20morphological%20description%20and%20formation%20scheme%20of%20the%20mesopores%20with%20an%20unprecedented%20level%20of%20detail%2C%20that%20is%20based%20on%20electron%20tomography%20data%20from%20the%20main%20steps%20of%20the%20dealumination%20process.%20Four%20main%20groups%20of%20pores%20are%20identified%3A%20%281%29%20closed%2C%20isolated%20mesopores%20with%20more%20spherical%20shapes%20and%20diameters%20of%207%5Cu20138%20nm%3B%20%282%29%20open%20intracrystalline%20channeling%20mesopores%20that%20often%20run%20along%20crystallographic%20orientations%2C%20vary%20in%20diameter%2C%20and%20whose%20morphology%20recall%20a%20mechanism%20of%20isolated%20mesopore%20coalescence%3B%20%283%29%20intercrystalline%20mesopores%20with%20irregular%20shapes%20detected%20at%20the%20boundaries%20of%20twinned%20crystals%2C%20and%20%284%29%20surface%20roughness.%20We%20finally%20observe%20that%20the%20localization%20and%20development%20of%20mesopores%20are%20associated%20with%20structural%20defects%2C%20such%20as%20stacking%20faults%20and%20twinning.%20These%20results%20allow%20us%20to%20consider%20a%20nucleation%5C%2Fdiffusion%20mechanism%20for%20the%20mesoporous%20network%20within%20zeolite%20Y%20during%20dealumination%20and%20provide%20guidelines%20for%20identifying%20new%20pathways%20to%20optimize%20hierarchical%20zeolites.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2FD5NR01457C%22%2C%22citationKey%22%3A%22girelliconsolaroPropertiesOriginMesopore2026%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2FD5NR01457C%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%226739WBV7%22%2C%22DEB5KWFS%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222026-02-17T14%3A46%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22Y93D568B%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Giuso%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BV.%20Giuso%2C%20C.%20Gourlaouen%2C%20L.%20Arrico%2C%20L.%20Di%20Bari%2C%20M.%20Mauro%2C%20Millisecond-LongRed%20Phosphorescence%20in%20Chiral%20HeterolepticAg%28I%29%20Complexes%20Bearing%20Benzothiazole%20Ligands%2C%20Inorganic%20Chemistry%2065%20%282026%29%2018554%26%23x2212%3B18562.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6c01416%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6c01416%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Millisecond-LongRed%20Phosphorescence%20in%20Chiral%20HeterolepticAg%28I%29%20Complexes%20Bearing%20Benzothiazole%20Ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Giuso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Arrico%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lorenzo%22%2C%22lastName%22%3A%22Di%20Bari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22Six%20orange-red%20phosphorescent%20chiral%20Ag%28I%29%20complexes%20of%20general%20structure%20%5BAg%28N1%26lt%3B%5E%26gt%3BN2%29%28P%26lt%3B%5E%26gt%3BP%29%5DPF6%2C%20where%20N1%26lt%3B%5E%26gt%3BN2%20is%20a%20pyridyl-%20or%20quinolyl-functionalized%20benzo%5Bd%5Dthiazole%20and%20P%26lt%3B%5E%26gt%3BP%20is%20an%20enantiopure%20diphosphine%20of%20the%20BINAP%20family%20with%20axial%20chirality%2C%20are%20herein%20presented.%20The%20novel%20complexes%20have%20been%20extensively%20characterized%20from%20a%20chemical%2C%20structural%2C%20and%20photophysical%20point%20of%20view%2C%20resulting%20in%20a%20family%20of%20chiral%20Ag%28I%29%20coordination%20compounds%20with%20red%20photoluminescence.%20Their%20emissive%20properties%20can%20be%20attributed%20to%20ligand-centered%20triplet%20manifold%20excited%20states%20localized%20on%20the%20benzothiazole%20ligand%20%283LCbtz%29.%20Low%20photoluminescence%20quantum%20yield%20%28PLQY%29%20values%20are%20recorded%20in%20solution%2C%20as%20is%20typical%20of%20Ag%28I%29%20derivatives%2C%20whereas%20a%20remarkable%20switch-on%20of%20the%20emission%20is%20observed%20in%20the%20solid%20state%2C%20with%20samples%20of%20quinolyl-benzothiazole%20xylBINAP%20complexes%20R-3%20and%20S-3%20displaying%20PLQY%20as%20high%20as%2050%25%20and%20excited-state%20lifetimes%20in%20the%20millisecond%20range.%20Electron%20circular%20dichroism%20%28ECD%29%20spectra%20show%20strong%20activity%20in%20both%20solution%20and%20solid%20state%20as%20thin%20films%20for%20all%20the%20complexes.%20Time-dependent%20density%20functional%20theory%20%28TD-DFT%29%20calculations%20confirm%20the%20strong%20LCbtz%20nature%20of%20the%20major%20absorbing%20singlet%20and%20emissive%20triplet%20states%20and%20provide%20an%20argument%20behind%20the%20absence%20of%20circularly%20polarized%20luminescence%20%28CPL%29%20in%20these%20samples.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.6c01416%22%2C%22citationKey%22%3A%22giusoMillisecondLongRedPhosphorescenceChiral2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.6c01416%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220020-1669%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22499C62Y9%22%2C%22HMIN5U62%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A38%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22EPRPP4X3%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Giuso%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BV.%20Giuso%2C%20J.-Y.%20Zhuang%2C%20C.%20Gourlaouen%2C%20C.%20Cebrian%2C%20H.-C.%20Su%2C%20M.%20Mauro%2C%20Heteroleptic%20ag%28I%29%20complexes%20bearing%20benzothiazole%20and%20benzoxazole%20ligands%20for%20orange-red%20light-emitting%20electrochemical%20cells%2C%20Advanced%20Optical%20Materials%20Early%20access%20%282026%29%20e71836.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.71836%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadom.71836%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Heteroleptic%20ag%28I%29%20complexes%20bearing%20benzothiazole%20and%20benzoxazole%20ligands%20for%20orange-red%20light-emitting%20electrochemical%20cells%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Giuso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jing-%20Yuan%22%2C%22lastName%22%3A%22Zhuang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristina%22%2C%22lastName%22%3A%22Cebrian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hai-%20Ching%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22Optoelectronic%20devices%20based%20on%20metal%20complexes%20alternative%20to%20platinum%20group%20metals%20are%20highly%20sought%2C%20yet%20their%20design%20remains%20very%20challenging.%20In%20this%20framework%2C%20electroactive%20silver%20complexes%20have%20been%20largely%20overlooked%20to%20date.%20Herein%2C%20a%20family%20of%20orange%20phosphorescent%20mononuclear%20cationic%20Ag%28I%29%20complexes%20of%20general%20structure%20%5BAg%28N1%5Cu00a1%20%5Cu0302%5Cu00bfN2%29%28P%5Cu00a1%20%5Cu0302%5Cu00bfP%29%5DPF6%2C%20where%20N1%5Cu00a1%20%5Cu0302%5Cu00bfN2%20is%20a%20%28o-methyl%29pyridyl-%2C%20quinolyl-%20or%20pyrazyl-%20functionalized%20benzo%28x%29azole%20%28x%20%3D%20thio-%20or%20ox-%29%20and%20P%5Cu00a1%20%5Cu0302%5Cu00bfP%20is%20either%20DPEphos%20or%20Xantphos%2C%20is%20unraveled.%20The%20complexes%20display%20emission%20arising%20from%20a%20triplet%20ligand%20centered%20%283LC%29%20excited%20state%20located%20on%20the%20N1%5Cu00a1%20%5Cu0302%5Cu00bfN2%20ligand.%20Interestingly%2C%20the%20compounds%20display%20high%20photoluminescence%20quantum%20yield%20%28PLQY%29%20in%20solid%20state%20and%2C%20for%20derivative%203b%2C%20a%20value%20as%20high%20as%2014%25%20was%20recorded%20in%20CH2Cl2%20solution.%20Their%20use%20as%20electroactive%20materials%20in%20LECs%20is%20also%20demonstrated%2C%20with%20complexes%201b%20and%203b%20providing%20devices%20with%20peak%20external%20quantum%20efficiencies%20%28EQE%29%20as%20high%20as%203.5%20and%202.5%25%20respectively%20in%20the%20orange-red%20region%20of%20the%20visible%20spectrum%2C%20enhanced%20carrier%20balance%2C%20and%20limited%20temporal%20variation%20of%20the%20electroluminescence%20%28EL%29%20profile.%20The%20photophysical%20investigation%20of%20these%20complexes%20is%20further%20accompanied%20by%20%28time-dependent%29%20density%20functional%20theory%20%28TD-DFT%29%20calculations%2C%20which%20unravel%20multiple%20scenarios%20behind%20the%20exciton-assisted%20non-radiative%20quenching%20pathways%20typical%20of%20these%20Ag%28I%29%20complexes.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fadom.71836%22%2C%22citationKey%22%3A%22WOS%3A001883005100001%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadom.71836%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222195-1071%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22PLGT4TIP%22%5D%2C%22dateModified%22%3A%222026-10-22T12%3A06%3A55Z%22%7D%7D%2C%7B%22key%22%3A%2235CQ8432%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guerra%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.%20Guerra%2C%20I.%20Kim%2C%20S.%20Friedrich%2C%20P.%20Amaro%2C%20A.%20Andoche%2C%20G.%20Baptista%2C%20C.%20Bray%2C%20R.%20Cantor%2C%20D.%20Diercks%2C%20S.L.%20Fretwell%2C%20A.%20Gillespie%2C%20John.A.%20Hall%2C%20C.N.%20Harris%2C%20J.T.%20Harris%2C%20L.M.%20Hayen%2C%20P.A.%20Hervieux%2C%20P.%20Indelicato%2C%20G.B.%20Kim%2C%20K.G.%20Leach%2C%20A.%20Lennarz%2C%20V.%20Lordi%2C%20P.%20Machule%2C%20A.%20Marino%2C%20D.%20McKeen%2C%20X.%20Mougeot%2C%20D.%20Pinheiro%2C%20F.%20Ponce%2C%20C.%20Ruiz%2C%20A.%20Samanta%2C%20J.P.%20Santos%2C%20J.%20Smolsky%2C%20C.%20Stone-Whitehead%2C%20J.%20Templet%2C%20W.%20van%20de%20Pontseele%2C%20W.K.%20Warburton%2C%20B.%20Waters%2C%20J.%20Machado%2C%20BeEST%20Collaboration%2C%20Shakeup%20and%20shakeoff%20spectra%20in%20the%20electron%20capture%20decay%20of%20atomic%207Be%2C%20Physical%20Review%20C%20114%20%282026%29%20014624.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fknwn-47kl%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fknwn-47kl%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Shakeup%20and%20shakeoff%20spectra%20in%20the%20electron%20capture%20decay%20of%20atomic%207Be%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mauro%22%2C%22lastName%22%3A%22Guerra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Inwook%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephan%22%2C%22lastName%22%3A%22Friedrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pedro%22%2C%22lastName%22%3A%22Amaro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adrien%22%2C%22lastName%22%3A%22Andoche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Goncalo%22%2C%22lastName%22%3A%22Baptista%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Connor%22%2C%22lastName%22%3A%22Bray%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Robin%22%2C%22lastName%22%3A%22Cantor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Diercks%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Spencer%20L.%22%2C%22lastName%22%3A%22Fretwell%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abigail%22%2C%22lastName%22%3A%22Gillespie%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22John.%20A.%22%2C%22lastName%22%3A%22Hall%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cameron%20N.%22%2C%22lastName%22%3A%22Harris%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jackson%20T.%22%2C%22lastName%22%3A%22Harris%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Leendert%20M.%22%2C%22lastName%22%3A%22Hayen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul%20Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul%22%2C%22lastName%22%3A%22Indelicato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geon%20Bo%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kyle%20G.%22%2C%22lastName%22%3A%22Leach%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Annika%22%2C%22lastName%22%3A%22Lennarz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincenzo%22%2C%22lastName%22%3A%22Lordi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peter%22%2C%22lastName%22%3A%22Machule%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrew%22%2C%22lastName%22%3A%22Marino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22McKeen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Mougeot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Pinheiro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francisco%22%2C%22lastName%22%3A%22Ponce%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chris%22%2C%22lastName%22%3A%22Ruiz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amit%22%2C%22lastName%22%3A%22Samanta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jose%20Paulo%22%2C%22lastName%22%3A%22Santos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joseph%22%2C%22lastName%22%3A%22Smolsky%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Caitlyn%22%2C%22lastName%22%3A%22Stone-Whitehead%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joseph%22%2C%22lastName%22%3A%22Templet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wouter%22%2C%22lastName%22%3A%22van%20de%20Pontseele%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22William%20K.%22%2C%22lastName%22%3A%22Warburton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Waters%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jorge%22%2C%22lastName%22%3A%22Machado%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22BeEST%20Collaboration%22%7D%5D%2C%22abstractNote%22%3A%22The%20most%20stringent%20laboratory-based%20experimental%20limits%20on%20the%20existence%20of%20submegaelectronvolt%20sterile%20neutrinos%20are%20currently%20set%20by%20decay%20spectroscopy%20of%20radioactive%207Be%20embedded%20into%20superconducting%20sensors.%20The%20systematic%20uncertainties%20are%20dominated%20by%20the%20modeling%20of%20the%20electron%20shakeup%20and%20shakeoff%20spectra%20that%20are%20not%20based%20on%20state-of-the-art%20atomic%20theory%20and%20do%20not%20include%20electron%20correlations%20or%20relativistic%20effects.%20We%20have%20used%20the%20multiconfiguration%20Dirac-Fock%20formalism%20to%20obtain%20correlated%20wave%20functions%20ab%20initio%20and%20compute%20all%20single%20and%20double%20shake%20processes%20in%20the%20electron%20capture%20decay%20of%20atomic%207Be.%20The%20simulations%20can%20explain%20some%20but%20not%20all%20of%20the%20observed%20spectral%20features%2C%20likely%20because%20the%20wave%20functions%20are%20modified%20by%20the%20Ta%20sensor%20material%20that%20the%207Be%20is%20embedded%20into.%20The%20new%20models%20also%20show%20that%20the%20L%5C%2FK%20electron%20capture%20ratio%20of%207Be%20in%20Ta%20has%20previously%20been%20slightly%20underestimated%20revising%20the%20previous%20value%20of%200.070%287%29%20to%20a%20new%20value%20of%200.0756%2820%29.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Fknwn-47kl%22%2C%22citationKey%22%3A%22guerraShakeupShakeoffSpectra2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fknwn-47kl%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222469-9985%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%2288PVNMDA%22%2C%22CHW2VGSR%22%2C%22HMIN5U62%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A39%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22FBLYHB9D%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hao%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.-X.%20Hao%2C%20Z.-L.%20Ou%2C%20H.-F.%20Wang%2C%20B.%20Xiao%2C%20K.-Q.%20Zhao%2C%20P.%20Hu%2C%20B.-Q.%20Wang%2C%20B.%20Donnio%2C%20Direct%20Synthesis%20of%20Fluorinated%20Polycyclic%20Aromatic%20Dioxanes%3A%20Mesomorphism%2C%20Luminescence%2C%20and%20Charge%20Transport%2C%20Organic%20Letters%2028%20%282026%29%201995%26%23x2013%3B1999.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.orglett.5c05172%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.orglett.5c05172%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Direct%20Synthesis%20of%20Fluorinated%20Polycyclic%20Aromatic%20Dioxanes%3A%20Mesomorphism%2C%20Luminescence%2C%20and%20Charge%20Transport%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Meng-Xiang%22%2C%22lastName%22%3A%22Hao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zi-Ling%22%2C%22lastName%22%3A%22Ou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hai-Feng%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bo%22%2C%22lastName%22%3A%22Xiao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ping%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bi-Qin%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20a%20straightforward%20synthesis%20of%20new%20Janus-fluorinated%20dioxa-bridged%20tetracene%20and%20pentacene%20liquid%20crystals.%20These%20materials%20self-assemble%20into%20stable%20columnar%20mesophases%20driven%20by%20noncovalent%20perfluoroarene-arene%20interactions%20that%20promote%20effective%20intermolecular%20pi-stacking.%20The%20degree%20of%20fluorination%20on%20the%20aromatic%20core%20plays%20a%20pivotal%20role%20in%20the%20induction%20of%20mesomorphism%3A%20substitution%20with%20two%20fluorine%20atoms%20is%20insufficient%20to%20induce%20mesomorphism%2C%20whereas%20homologous%20derivatives%20bearing%20four%20or%20six%20fluorine%20atoms%20readily%20self-organize%20into%20mesophases.%20They%20display%20luminescence%20with%20an%20absolute%20quantum%20yield%20of%204%25%20in%20the%20thin%20film.%20These%20molecules%20also%20exhibit%20an%20electron%20mobility%20rate%20in%20the%2010-2-10-3%20cm2%20V-1%20s-1%20range%2C%20well%20within%20the%20values%20needed%20for%20molecular-based%20devices.%20The%20synthetic%20strategy%20described%20here%20presents%20great%20potential%20for%20the%20construction%20of%20novel%20fluorine-containing%20molecular%20materials%20of%20interest%20for%20applications%20in%20organic%20electronics.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.orglett.5c05172%22%2C%22citationKey%22%3A%22haoDirectSynthesisFluorinated2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.orglett.5c05172%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221523-7060%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222026-02-19T13%3A21%3A09Z%22%7D%7D%2C%7B%22key%22%3A%22AM4W7ZYD%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Henning%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BX.%20Henning%2C%20L.%20Schlur%2C%20D.%20Stoeffler%2C%20M.%20Vomir%2C%20S.%20Colis%2C%20A.%20Dinia%2C%20M.%20Rastei%2C%20Surface%20photovoltage%20and%20open-circuit%20voltage%20spectroscopies%20of%20oxide%20heterostructures%20by%20atomic%20force%20microscopy%20under%20variable%20illumination%2C%20Physical%20Review%20Materials%2010%20%282026%29%20083802.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fpv1q-9yms%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fpv1q-9yms%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Surface%20photovoltage%20and%20open-circuit%20voltage%20spectroscopies%20of%20oxide%20heterostructures%20by%20atomic%20force%20microscopy%20under%20variable%20illumination%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Henning%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Stoeffler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%22%2C%22lastName%22%3A%22Vomir%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silviu%22%2C%22lastName%22%3A%22Colis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%22%2C%22lastName%22%3A%22Rastei%22%7D%5D%2C%22abstractNote%22%3A%22Photoelectron%20excitations%20in%20oxide%20heterostructures%20routinely%20elicit%20both%20surface%20photovoltage%20and%20open-circuit%20voltage.%20Surface%20photovoltage%20measurements%20are%20hence%20often%20used%20as%20a%20proxy%20to%20gauge%20open-circuit%20voltage%20response.%20Here%2C%20we%20present%20a%20method%20for%20studying%20photovoltaic%20effects%20in%20oxide%20heterostructures%20by%20concurrently%20measuring%2C%20with%20an%20atomic%20force%20microscope%2C%20surface%20photovoltage%20%28OVSPV%29%20and%20open-circuit%20voltage%20%28VOC%29%20while%20varying%20illumination%20wavelength%20and%20intensity.%20This%20combined%20method%20is%20applied%20at%20super-%20and%20subband-gap%20illumination%20wavelengths%20on%20Bi2FeCrO6%5C%2FNb-SrTiO3%20heterostructures%20annealed%20under%20various%20oxidative%20and%20reductive%20conditions.%20The%20results%20show%20that%20OVSPV%20consistently%20reflects%20interfacial%20photocarrier%20generation%2C%20whereas%20VOC%20is%20more%20governed%20by%20photocarrier%20transport%2C%20sensitive%20to%20recombination.%20It%20is%20also%20shown%20that%20deep%20oxygen-vacancy%20levels%20act%20as%20recombination%20centers%2C%20whereas%20shallow%20cation-vacancy%20levels%20impact%20depletion%20region%20width.%20Experimental%20observations%20are%20consistent%20with%20DFT%20density%20of%20states%20of%20crystals%20containing%20isolated%20and%20coupled%20vacancies.%20Together%2C%20OVSPV%20and%20VOC%20spectroscopies-applied%20across%20multiple%20excitation%20energies%20and%20intensities-offer%20valuable%20insights%20into%20mechanisms%20governing%20photon-induced%20electrical%20power%20generation%20in%20photovoltaic%20oxide%20heterostructures.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Fpv1q-9yms%22%2C%22citationKey%22%3A%22WOS%3A001847563300006%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Fpv1q-9yms%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222475-9953%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22499C62Y9%22%2C%22CF4ZI7HM%22%2C%22CHW2VGSR%22%2C%22GA3EX26X%22%2C%22HMIN5U62%22%2C%22IEGKATUQ%22%2C%22JZU5CN8N%22%2C%22SB8Q592R%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A40%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22G6FH7U2A%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Herasymenko%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BK.%20Herasymenko%2C%20D.%20Walisinghe%2C%20M.%20Konno%2C%20V.%20Ledentu%2C%20M.%20Huix-Rotllant%2C%20X.%20Yang%2C%20N.%20Ferr%26%23xE9%3B%2C%20K.%20Inoue%2C%20M.%20Olivucci%2C%20S.%20Haacke%2C%20Effects%20of%20Counter%20Ion%20Protonation%20on%20the%20Ultrafast%20Excited%20State%20Dynamics%20in%20Archaerhodopsin-3%2C%20Biophysical%20Journal%20125%20%282026%29%202416%26%23x2013%3B2431.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bpj.2026.02.034%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bpj.2026.02.034%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Effects%20of%20Counter%20Ion%20Protonation%20on%20the%20Ultrafast%20Excited%20State%20Dynamics%20in%20Archaerhodopsin-3%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krystyna%22%2C%22lastName%22%3A%22Herasymenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Danushka%22%2C%22lastName%22%3A%22Walisinghe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Masae%22%2C%22lastName%22%3A%22Konno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Ledentu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Miquel%22%2C%22lastName%22%3A%22Huix-Rotllant%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xuchun%22%2C%22lastName%22%3A%22Yang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Ferr%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Keiichi%22%2C%22lastName%22%3A%22Inoue%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimo%22%2C%22lastName%22%3A%22Olivucci%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Haacke%22%7D%5D%2C%22abstractNote%22%3A%22Archaerhodopsin-3%20%28AR-3%29%20and%20its%20mutants%20have%20attracted%20a%20large%20attention%20for%20applications%20in%20optogenetics%20since%20they%20display%20a%20voltage-sensitive%2C%20near-infrared%20fluorescence.%20Recent%20quantum%20chemistry%20modelling%20of%20the%20electrostatic%20interactions%20between%20the%20protein%20environment%20and%20the%20protonated%20Schiff%20base%20retinal%20%28PSBR%29%20gave%20a%20detailed%20insight%20about%20the%20origin%20of%20a%20mutation-induced%20excited%20state%20barrier%2C%20which%20hinders%20the%20usual%20sub-picosecond%20photo-isomerization%2C%20and%20increases%20the%20fluorescence%20quantum%20yield%20%28%5Cu03a6f%29.%20However%2C%20despite%20the%20large%20range%20of%20mutations%20tested%2C%20the%5Cu03a6f%20rarely%20exceeds%201%20%25%2C%20which%20is%20in%20large%20contrast%20to%20the%20sole%20naturally%20fluorescent%20retinal%20protein%20NeoRhodopsin%20%28NeoR%29%20%28%5Cu03a6f%20%3D%2020%25%29.%20In%20order%20to%20obtain%20a%20deeper%20insight%20into%20the%20electrostatic%20PSBR%20%5Cu2013%20protein%20interactions%20of%20wild-type%20%28wt%29%20AR-3%2C%20the%20present%20contribution%20sets%20out%20to%20identify%20the%20pKa%20values%20of%20the%20neighbouring%20aspartic%20acids%20D95%20and%20D222%2C%20and%20hence%20their%20pH-dependent%20protonation%20states.%20This%20is%20done%20by%20a%20combined%20experimental%20and%20theoretical%20approach%2C%20which%20investigates%20the%20pH-dependent%20absorption%20spectra%2C%20isomer%20compositions%20and%20excited%20state%20lifetimes%20in%20wt%20AR-3%2C%20recombinantly%20expressed%20in%20E.%20coli.%20The%20mutant%20D95N%20with%20a%20neutral%20asparagine%20residue%20at%20position%2095%20is%20also%20studied%20as%20a%20reference%20system.%20We%20show%20that%20wt%20AR-3%20displays%20two%20pKa%20values%20at%201.5%5Cu00b1%200.2%20and%202.5%5Cu00b1%200.2%2C%20which%20are%20related%20to%20the%20protonation%20of%20D222%20and%20D95%2C%20respectively.%20One%20major%20argument%20for%20this%20assignment%20is%20the%20fact%20that%20the%20isomer%20composition%20and%20spectroscopic%20properties%20are%20the%20%5Cnsame%20for%20wt%20AR-3%20at%20pH%202%20and%20for%20the%20D95N%20mutant.%20Two%20different%20simulation%20approaches%20are%20used%20to%20describe%20the%20pH%20and%20mutation-induced%20effects%2C%20providing%20very%20good%20quantitative%20agreement%20in%20most%20cases.%20The%20benefits%20and%20limitations%20of%20each%20method%20are%20discussed%20in%20detail.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bpj.2026.02.034%22%2C%22citationKey%22%3A%22herasymenkoEffectsCounterIon2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0006349526001566%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220006-3495%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2295EJ8IDX%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222026-06-15T07%3A43%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22EKBKKYPT%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hrytsaienko%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BM.%20Hrytsaienko%2C%20D.O.%20Siebadji%20Tchuimeni%2C%20M.%20Ziegler%2C%20O.%20Cregut%2C%20G.%20Schmidt%2C%20F.%20Bertram%2C%20J.%20Christen%2C%20S.%20Tamariz%2C%20R.%20Butte%2C%20N.%20Grandjean%2C%20P.%20Gilliot%2C%20M.%20Gallart%2C%20Subpicosecond%20thermalization%20of%20carriers%20in%20polar%20GaN%5C%2FAlN%20quantum%20dots%2C%20Journal%20of%20Applied%20Physics%20139%20%282026%29%20085704.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0309975%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0309975%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Subpicosecond%20thermalization%20of%20carriers%20in%20polar%20GaN%5C%2FAlN%20quantum%20dots%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hrytsaienko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%20O.%22%2C%22lastName%22%3A%22Siebadji%20Tchuimeni%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Ziegler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22O.%22%2C%22lastName%22%3A%22Cregut%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Schmidt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Bertram%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Christen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Tamariz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Butte%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Grandjean%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Gilliot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Gallart%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigate%20at%20room%20temperature%20the%20thermalization%20and%20recombination%20dynamics%20of%20near-resonantly%20photogenerated%20carriers%20in%20c-plane%20GaN%5C%2FAlN%20wurtzite%20quantum%20dots%20%28QDs%29%20using%20time-resolved%20photoluminescence%20and%20non-degenerate%20pump-probe%20differential%20transmission.%20Owing%20to%20a%20continuous%20gradient%20in%20dot%20height%2C%20the%20QD%20ensemble%20exhibits%20a%20broad%20emission%20range%20from%203.5%20to%204.5%20eV.%20Time-resolved%20photoluminescence%20reveals%20two%20distinct%20recombination%20lifetimes%20associated%20with%20two%20families%20of%20QDs%20with%20different%20morphologies%2C%20whose%20emission%20energies%20are%20governed%20by%20the%20interplay%20between%20the%20quantum-confined%20Stark%20effect%20and%20lateral%20confinement.%20Pump-probe%20measurements%20evidence%20an%20ultrafast%20carrier%20thermalization%20with%20subpicosecond%20rise%20times%20on%20the%20order%20of%20200%20fs%2C%20significantly%20shorter%20than%20in%20other%20epitaxial%20III-V%20QD%20systems.%20At%20longer%20delays%2C%20the%20relaxation%20dynamics%20is%20non-exponential%20and%20strongly%20dependent%20on%20both%20carrier%20density%20and%20probe%20energy.%20It%20is%20reproduced%20by%20a%20phenomenological%20model%20based%20on%20multi-carrier%20scattering%20processes%2C%20whose%20efficiency%20progressively%20vanishes%20as%20the%20probe%20energy%20approaches%20the%20luminescence%20maximum%2C%20where%20interband%20recombination%20dominates.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0309975%22%2C%22citationKey%22%3A%22hrytsaienkoSubpicosecondThermalizationCarriers2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0309975%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220021-8979%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22HVHG5Z72%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222026-04-23T13%3A54%3A31Z%22%7D%7D%2C%7B%22key%22%3A%222IK27Q43%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hu%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20Hu%2C%20X.%20Henning%2C%20D.%20Stoeffler%2C%20L.%20Schlur%2C%20G.%20Versini%2C%20C.%20Leuvrey%2C%20F.%20Roulland%2C%20U.-C.%20Chung%2C%20T.%20Fix%2C%20A.%20Dinia%2C%20M.V.%20Rastei%2C%20S.%20Colis%2C%20Impact%20of%20Bi%20Vacancies%20on%20the%20Polarization%20and%20Transport%20Properties%20of%20Bi2FeCrO6%20Thin%20Films%2C%20ACS%20Applied%20Electronic%20Materials%208%20%282026%29%202364%26%23x2013%3B2372.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.5c02590%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.5c02590%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Impact%20of%20Bi%20Vacancies%20on%20the%20Polarization%20and%20Transport%20Properties%20of%20Bi2FeCrO6%20Thin%20Films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chenyue%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Henning%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Stoeffler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22U-Chan%22%2C%22lastName%22%3A%22Chung%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%20V.%22%2C%22lastName%22%3A%22Rastei%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silviu%22%2C%22lastName%22%3A%22Colis%22%7D%5D%2C%22abstractNote%22%3A%22Among%20ferroelectric%20oxides%2C%20Bi2FeCrO6%20%28BFCO%29%20stands%20out%20due%20to%20its%20high%20polarization%20and%20relatively%20low%20bandgap%20of%201.5%20eV%2C%20which%20make%20it%20promising%20for%20optoelectronic%20applications%20based%20on%20visible-light%20absorption.%20Its%20properties%20such%20as%20bandgap%20width%2C%20polarization%20switching%20bias%2C%20and%20imprint%20of%20the%20ferroelectric%20hysteresis%20loop%20can%20be%20largely%20modulated%20by%20inducing%20different%20types%20of%20defects%20in%20the%20structure%20such%20as%20Fe%20%28Cr%29%20antisite%20defects%20or%20oxygen%20vacancies.%20In%20this%20work%2C%20we%20demonstrate%20that%20Bi%20vacancies%20can%20also%20play%20a%20key%20role%20in%20the%20properties%20of%20epitaxial%20BFCO%20thin%20films%20grown%20by%20pulsed%20laser%20deposition.%20Notably%2C%20we%20show%20that%20increasing%20the%20deposition%20temperature%20enhances%20the%20concentration%20of%20Bi%20vacancies%2C%20which%2C%20in%20turn%2C%20significantly%20impacts%20both%20the%20transport%20and%20ferroelectric%20properties.%20The%20film%20shows%20a%20p-type%20character%2C%20which%20is%20consistent%20with%20density%20functional%20theory%20%28DFT%29%20calculations%20on%20BFCO%20containing%20Bi%20vacancies.%20In%20extreme%20cases%2C%20the%20lack%20of%20Bi%20can%20lead%20to%20nonmiscible%20highly%20Bi-deficient%20phases%20with%20high%20conductivities%20that%20prevent%20the%20establishment%20of%20an%20electric%20field%20across%20the%20film%2C%20thereby%20hindering%20its%20polarization%20control.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facsaelm.5c02590%22%2C%22citationKey%22%3A%22huImpactBiVacancies2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.5c02590%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22GA3EX26X%22%2C%22IEGKATUQ%22%2C%22SB8Q592R%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-04-23T13%3A52%3A23Z%22%7D%7D%2C%7B%22key%22%3A%22IQQSN5L5%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hu%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20Hu%2C%20L.%20Schlur%2C%20G.%20Versini%2C%20T.%20Fix%2C%20A.%20Dinia%2C%20M.V.%20Rastei%2C%20S.%20Colis%2C%20Tailoring%20imprint%20in%20ferroelectric%20thin%20films%20through%20substrate%20work%20function%2C%20Applied%20Physics%20Letters%20128%20%282026%29%20252904.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0335819%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0335819%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tailoring%20imprint%20in%20ferroelectric%20thin%20films%20through%20substrate%20work%20function%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chenyue%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%20V.%22%2C%22lastName%22%3A%22Rastei%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silviu%22%2C%22lastName%22%3A%22Colis%22%7D%5D%2C%22abstractNote%22%3A%22The%20imprint%20effect%2C%20one%20of%20the%20most%20critical%20parameters%20in%20ferroelectrics%2C%20manifests%20as%20an%20asymmetry%20in%20polarization%20reversal.%20The%20precise%20control%20of%20imprint%20is%20essential%20for%20reliable%20implementations%20of%20ferroelectric%20materials%20in%20many%20applications.%20In%20this%20study%2C%20we%20demonstrate%20that%20imprint%20can%20be%20tuned%20in%20Bi2FeCrO6%20%28BFCO%29%20thin%20films%20by%20changing%20the%20nature%20of%20the%20underlying%20layer.%20Specifically%2C%20BFCO%28111%29%20films%20deposited%20on%20Nb-doped%20SrTiO3%20%28Nb%3ASTO%29%20and%20SrRuO3%20%28SRO%29%20exhibit%20distinct%20imprint%20characteristics.%20Piezoresponse%20force%20microscopy%20reveals%20a%20consistent%20imprint%20difference%20of%20about%201%20V%20between%20BFCO%5C%2FNb%3ASTO%20and%20BFCO%5C%2FSRO%2C%20which%20correlates%20with%20the%20work%20function%20difference%20between%20the%20two%20substrates.%20These%20findings%20underscore%20a%20generalizable%20mechanism%20for%20imprint%20control%20in%20ferroelectric%20heterostructures%20and%20hold%20particular%20relevance%20for%20applications%20demanding%20fine%20polarization%20management.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0335819%22%2C%22citationKey%22%3A%22huTailoringImprintFerroelectric2026%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F5.0335819%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220003-6951%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22CF4ZI7HM%22%2C%22CHW2VGSR%22%2C%22IEGKATUQ%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222026-07-09T14%3A37%3A20Z%22%7D%7D%2C%7B%22key%22%3A%224N2M463Y%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jalabert%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BR.A.%20Jalabert%2C%20Nonlocal%20effects%20in%20charge%20and%20energy%20transport%20with%20dissipative%20electrodes%2C%20Physical%20Review%20B%20114%20%282026%29%20045425.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Ftnfs-694c%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Ftnfs-694c%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nonlocal%20effects%20in%20charge%20and%20energy%20transport%20with%20dissipative%20electrodes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rodolfo%20A.%22%2C%22lastName%22%3A%22Jalabert%22%7D%5D%2C%22abstractNote%22%3A%22Recent%20advances%20in%20nanothermometry%20have%20led%20to%20an%20extension%20of%20the%20Landauer-B%20%26amp%3B%20uuml%3Bttiker%20scattering%20theory%20to%20include%20the%20nonlocal%20dissipation%20associated%20with%20charge%20transport.%20Such%20a%20program%20is%20implemented%20by%20describing%20the%20inelastic%20scattering%20in%20the%20connecting%20electrodes%20within%20an%20electrostatically%20self-consistent%20scheme.%20The%20restriction%20to%20quasi-one-dimensional%20geometries%2C%20weak%20excitation%2C%20and%20low%20temperature%20allows%20us%20to%20obtain%20general%20expressions%20of%20the%20current%20density%20and%20the%20dissipated%20power%2C%20valid%20in%20different%20regimes%2C%20for%20the%20cases%20of%20an%20energy-independent%20mean%20free%20path%20or%20an%20energy-independent%20relaxation%20rate.%20In%20particular%2C%20the%20dissipation%20asymmetry%20at%20both%20sides%20of%20a%20nanodevice%20and%20the%20conditions%20for%20observing%20heating%20spots%20with%20a%20local%20maximum%20of%20the%20dissipated%20power%20are%20formulated%20in%20terms%20of%20the%20key%20parameters%20that%20define%20the%20nanodevice%20and%20its%20environment.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2Ftnfs-694c%22%2C%22citationKey%22%3A%22jalabertNonlocalEffectsCharge2026%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2Ftnfs-694c%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222469-9950%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%22EPW69HFA%22%2C%22HMIN5U62%22%2C%22UVN4N32C%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A40%3A20Z%22%7D%7D%2C%7B%22key%22%3A%229NACPCCP%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jankovic%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BD.%20Jankovic%2C%20R.%20Pasquier%2C%20J.-G.%20Hartmann%2C%20P.-A.%20Hervieux%2C%20Elucidating%20the%20physical%20and%20mathematical%20properties%20of%20the%20prouhet-thue-morse%20sequence%20in%20quantum%20computing%2C%20Annalen%20Der%20Physik%20538%20%282026%29%20e00630.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fandp.202500630%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fandp.202500630%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Elucidating%20the%20physical%20and%20mathematical%20properties%20of%20the%20prouhet-thue-morse%20sequence%20in%20quantum%20computing%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Denis%22%2C%22lastName%22%3A%22Jankovic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Remi%22%2C%22lastName%22%3A%22Pasquier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Gabriel%22%2C%22lastName%22%3A%22Hartmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%5D%2C%22abstractNote%22%3A%22This%20study%20explores%20the%20applications%20of%20the%20Prouhet-Thue-Morse%20%28PTM%29%20sequence%20in%20quantum%20computing%2C%20highlighting%20its%20mathematical%20elegance%20and%20practical%20relevance.%20We%20demonstrate%20the%20critical%20role%20of%20the%20PTM%20sequence%20in%20quantum%20error%20correction%2C%20in%20noise-resistant%20quantum%20memories%2C%20and%20in%20providing%20insights%20into%20quantum%20chaos.%20Notably%2C%20we%20demonstrate%20how%20the%20PTM%20sequence%20naturally%20appears%20in%20Ising%20X-X%20interacting%20systems%2C%20leading%20to%20a%20proposed%20robust%20encoding%20of%20quantum%20memories%20in%20such%20systems.%20Furthermore%2C%20connections%20to%20number%20theory%2C%20including%20the%20Riemann%20zeta%20function%2C%20bridge%20quantum%20computing%20with%20pure%20mathematics.%20Our%20findings%20emphasize%20the%20PTM%20sequence%26%23039%3Bs%20importance%20in%20understanding%20the%20mathematical%20structure%20of%20quantum%20computing%20systems%20and%20the%20development%20of%20the%20full%20potential%20of%20quantum%20technologies%20and%20invite%20further%20interdisciplinary%20research.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fandp.202500630%22%2C%22citationKey%22%3A%22WOS%3A001752517700013%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fandp.202500630%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220003-3804%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%2C%22J5UPAUC3%22%5D%2C%22dateModified%22%3A%222026-06-09T12%3A01%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22Z67SFDGN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jian%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Jian%2C%20M.-M.%20Zhou%2C%20W.-H.%20Yu%2C%20X.-Y.%20Bai%2C%20K.-X.%20Zhao%2C%20K.-Q.%20Zhao%2C%20B.%20Donnio%2C%20From%20Targeted%20Synthesis%20to%20Serendipitous%20Discovery%3A%20Transforming%20Perfluorotoluene%20into%20Discotic%20Liquid%20Crystals%20and%20Dearomatized%20Spirofluorenes.%2C%20The%20Journal%20of%20Organic%20Chemistry%2091%20%282026%29%209341%26%23x2013%3B9348.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-DOIURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.joc.6c00735%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.joc.6c00735%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22From%20Targeted%20Synthesis%20to%20Serendipitous%20Discovery%3A%20Transforming%20Perfluorotoluene%20into%20Discotic%20Liquid%20Crystals%20and%20Dearomatized%20Spirofluorenes.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiao%22%2C%22lastName%22%3A%22Jian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ming-Mei%22%2C%22lastName%22%3A%22Zhou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wen-Hao%22%2C%22lastName%22%3A%22Yu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiao-Yan%22%2C%22lastName%22%3A%22Bai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Xiao%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22This%20study%20develops%20a%20one-pot%20synthetic%20system%20that%20concurrently%20produces%20two%20classes%20of%20functional%20materials%20via%20a%20previously%20unobserved%20transformation%20of%20perfluorotoluene%20under%20nucleophilic%20conditions.%20Building%20on%20prior%20work%20with%20fluorinated%20discotic%20systems%2C%20the%20reaction%20of%202%2C2%26%23039%3B-dilithio-1%2C1%26%23039%3B-biaryls%20with%20perfluorotoluene%20%28C6F5-CF3%29%20furnishes%20trifluoromethylated%20trifluorotriphenylene%20derivatives%20%28TPFn%2C%20n%20%3D%201-4%2C%206%2C%208%2C%2010%2C%208%5C%2F2%29%20alongside%20structurally%20distinct%20dearomatized%20spirofluorene%20analogues%20%28TPFn-1%29.%20The%20formation%20of%20the%20spirofluorene%20compounds%20points%20to%20a%20competing%20pathway%20beyond%20classical%20aryl%20nucleophilic%20substitution.%20Based%20on%20structural%20evidence%2C%20a%20dearomatization%20process%20involving%20cleavage%20of%20four%20C-F%20bonds%20%28one%20from%20the%20pentafluorophenyl%20ring%20and%20three%20from%20the%20CF3%20group%29%20and%20subsequent%20formation%20of%20new%20C-C%20bonds%20is%20proposed%20to%20account%20for%20the%20formation%20of%20the%20spiro-fused%20architecture.%20This%20side%20reaction%20sheds%20light%20on%20the%20moderate%20yields%20of%20the%20target%20TPFn%20series%20and%20highlights%20the%20complex%20reactivity%20of%20perfluorotoluene%20with%202%2C2%26%23039%3B-dilithio-1%2C1%26%23039%3B-biaryls.%20All%20TPFn%20compounds%20form%20thermally%20stable%20hexagonal%20columnar%20%28Colhex%29%20mesophases%20with%20large%20liquid-crystalline%20ranges%2C%20along%20with%20a%20strong%20modulation%20of%20the%20clearing%20temperatures%20with%20alkoxy%20chain%20lengths.%20Despite%20the%20presence%20of%20the%20bulky%20lateral%20CF3%20group%2C%20the%20transition%20temperatures%20are%20surprisingly%20not%20greatly%20affected%20when%20compared%20to%20previously%20synthesized%204F-TPn%20homologous%20compounds%20%28with%20no%20CF3%20groups%29.%20Structural%20analysis%2C%20supported%20by%20X-ray%20crystallography%20of%20ditert-butyl%20model%20compound%20%28tBuTPF%29%2C%20validates%20the%20molecular%20design%20and%20packing.%20This%20work%20thus%20provides%20a%20practical%20one-pot%20route%20to%20potentially%20fluorinated%20discotic%20semiconductors%20while%20revealing%20a%20competing%20transformation%20that%20advances%20the%20understanding%20of%20polyfluorinated%20arene%20chemistry%20and%20offers%20access%20to%20novel%20spiro-fused%20molecular%20architectures.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.joc.6c00735%22%2C%22citationKey%22%3A%22jianTargetedSynthesisSerendipitous2026Jun29Epub2026Jun29%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.joc.6c00735%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221520-6904%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222026-07-15T10%3A43%3A35Z%22%7D%7D%2C%7B%22key%22%3A%22QA7EEDVU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jiang%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BS.%20Jiang%2C%20F.%20Scheurer%2C%20Q.%20Sun%2C%20P.%20Ruffieux%2C%20X.%20Yao%2C%20A.%20Narita%2C%20K.%20Mullen%2C%20R.%20Fasel%2C%20T.%20Frederiksen%2C%20G.%20Schull%2C%20Length-IndependentQuantum%20transport%20through%20EngineeredBand%20states%20in%20graphene%20nanoribbon%20junctions%2C%20ACS%20Nano%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.6c08307%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.6c08307%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Length-IndependentQuantum%20transport%20through%20EngineeredBand%20states%20in%20graphene%20nanoribbon%20junctions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Song%22%2C%22lastName%22%3A%22Jiang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Scheurer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Qiang%22%2C%22lastName%22%3A%22Sun%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pascal%22%2C%22lastName%22%3A%22Ruffieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xuelin%22%2C%22lastName%22%3A%22Yao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Akimitsu%22%2C%22lastName%22%3A%22Narita%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Klaus%22%2C%22lastName%22%3A%22Mullen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roman%22%2C%22lastName%22%3A%22Fasel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Frederiksen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Schull%22%7D%5D%2C%22abstractNote%22%3A%22In%20molecular%20electronics%2C%20the%20development%20of%20molecular%20wires%20capable%20of%20carrying%20high%20electrical%20current%20with%20minimal%20loss%20remains%20a%20central%20challenge%2C%20despite%20extensive%20efforts%20in%20both%20solution-phase%20and%20ultrahigh-vacuum%20synthesis.%20Graphene%20nanoribbons%20%28GNRs%29%20with%20their%20structural%20robustness%20and%20tunable%20electronic%20properties%20have%20emerged%20as%20promising%20candidates.%20In%20particular%2C%20topologically%20engineered%20GNRs%20with%20atomically%20precise%20edge%20modifications%20offer%20new%20routes%20for%20efficient%20charge%20transport.%20Here%2C%20we%20systematically%20investigate%20the%20transport%20properties%20of%20a%20staggered%2C%20edge-extended%20GNR%20based%20on%20a%207-AGNR%20backbone%2C%20denoted%20as%207-AGNR-S%281%2C3%29%2C%20using%20low-temperature%20scanning%20tunneling%20microscopy%20liftoff%20experiments.%20Under%20favorable%20junction%20conditions%2C%20the%20conductance%20remains%20nearly%20constant%20during%20tip%20retraction%20over%20junction%20lengths%20exceeding%2010%20nm%2C%20mediated%20by%20the%20low-energy%20bands%20arising%20from%20the%20coupled%20topological%20zero-energy%20edge%20states.%20Additionally%2C%20we%20developed%20a%20detailed%20model%20of%20the%20liftoff%20process%20and%20simulated%20charge%20transport%2C%20revealing%20the%20roles%20of%20delocalized%20valence%20band%20states%20and%20showing%20how%20local%20potential%20variations%20at%20the%20electrode%20interfaces%20can%20modulate%20molecular-level%20alignment%20and%20conductance.%20Our%20findings%20underscore%20the%20importance%20of%20interface%20engineering%20in%20the%20design%20of%20high-performance%20molecular%20electronic%20devices.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facsnano.6c08307%22%2C%22citationKey%22%3A%22WOS%3A001853654700001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.6c08307%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%221936-0851%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%229USMFXMV%22%2C%22DEB5KWFS%22%2C%22SDQDQW25%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A40%3A36Z%22%7D%7D%2C%7B%22key%22%3A%224SZUMAI6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kaplan%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BZ.O.%20Kaplan%2C%20F.%20Kilicarslan%2C%20E.%20Keles%2C%20N.%20Seferoglu%2C%20M.W.%20Kiama%2C%20A.%20Barsella%2C%20Z.%20Seferoglu%2C%20Indole-%20and%20carbazole-functionalized%20dicyanomethyleneindan%20push-pull%20dyes.%20Part%201%3A%20Synthesis%2C%20cyanide%20sensing%2C%20photophysical%20and%20NLO%20properties%2C%20ChemistrySelect%2011%20%282026%29%20e74146.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fslct.74146%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fslct.74146%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Indole-%20and%20carbazole-functionalized%20dicyanomethyleneindan%20push-pull%20dyes.%20Part%201%3A%20Synthesis%2C%20cyanide%20sensing%2C%20photophysical%20and%20NLO%20properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zahide%20Oztas%22%2C%22lastName%22%3A%22Kaplan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Furkan%22%2C%22lastName%22%3A%22Kilicarslan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ergin%22%2C%22lastName%22%3A%22Keles%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nurgul%22%2C%22lastName%22%3A%22Seferoglu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marion%20Wanjiru%22%2C%22lastName%22%3A%22Kiama%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Barsella%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zeynel%22%2C%22lastName%22%3A%22Seferoglu%22%7D%5D%2C%22abstractNote%22%3A%22The%201-Indanylidenemalononitrile-based%20donor-pi-acceptor%20chromophores%20are%20attractive%20platforms%20for%20the%20design%20of%20optical%20materials%2C%20cyanide-responsive%20probes%2C%20and%20second-order%20nonlinear%20optical%20systems.%20Herein%2C%20we%20compare%20indole%20and%20carbazole%20donor%20units%20on%20a%20common%20dicyanomethyleneindan%20acceptor%20scaffold%20and%20evaluate%20their%20photophysical%20behavior%2C%20cyanide%20sensing%2C%20cellulose-supported%20solid-state%20sensing%20performance%2C%20and%20second-order%20nonlinear%20optical%20%28NLO%29%20properties.%20The%20chromophores%20were%20synthesized%20by%20Knoevenagel-type%20condensation%2C%20characterized%20by%20Fourier-transform%20infrared%20spectroscopy%20%28FT-IR%29%2C%20nuclear%20magnetic%20resonance%20%28NMR%29%20spectroscopy%2C%20and%20high-resolution%20mass%20spectrometry%20%28HRMS%29%2C%20and%20investigated%20by%20ultraviolet-visible%20%28UV-vis%29%20absorption%20spectroscopy%2C%20fluorescence%20spectroscopy%2C%20tetrabutylammonium%20cyanide%20%28TBACN%29%20titration%2C%20electric-field-induced%20second-harmonic%20generation%20%28EFISH%29%20measurements%2C%20density%20functional%20theory%20%28DFT%29%2C%20and%20time-dependent%20density%20functional%20theory%20%28TD-DFT%29%20calculations.%20Both%20compounds%20exhibited%20solvent-sensitive%20ICT%20behavior%20and%20selective%20responses%20toward%20CN-%20in%20DMSO%2C%20with%20LOD%20values%20of%200.21%20and%200.24%20%26amp%3B%20micro%3BM%20for%20compounds%202%20and%203%2C%20respectively.%20The%20cyanide-induced%20optical%20response%2C%20Job%26%23039%3Bs%20plot%20analysis%2C%20and%201H%20NMR%20titration%20were%20consistent%20with%20a%201%3A1%20stoichiometry%20for%20a%20Michael-type%20nucleophilic%20addition%20process%20that%20disrupts%20the%20donor-acceptor%20conjugated%20pathway.%20Compound%202%20was%20further%20transferred%20to%20a%20cellulose-based%20textile%20substrate%20and%20produced%20visible%20colorimetric%20and%20fluorescence%20responses%20toward%20CN-%20in%20the%20solid%20state.%20EFISH%20measurements%20and%20theoretical%20calculations%20confirmed%20measurable%20second-order%20NLO%20activity%2C%20with%20the%20carbazole%20derivative%20showing%20the%20highest%20response.%20Overall%2C%20the%20results%20demonstrate%20that%20donor%20variation%20on%20the%20dicyanomethyleneindan%20scaffold%20is%20an%20effective%20strategy%20for%20ICT%20tuning%2C%20cyanide%20reactivity%2C%20textile%20applicability%2C%20and%20NLO%20performance%20within%20a%20single%20push-pull%20chromophore%20family.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fslct.74146%22%2C%22citationKey%22%3A%22WOS%3A001847066500001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fslct.74146%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%222365-6549%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22499C62Y9%22%2C%22CHW2VGSR%22%2C%22HMIN5U62%22%2C%22WWGPR7DV%22%5D%2C%22dateModified%22%3A%222026-08-31T13%3A40%3A58Z%22%7D%7D%2C%7B%22key%22%3A%227Q638CQ7%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kayas%20et%20al.%22%2C%22parsedDate%22%3A%222026%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B%5B1%5D%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BH.%20Kayas%2C%20Y.%20Unal%2C%20K.%20Erden%2C%20A.%20Barsella%2C%20O.%20Sahin%2C%20C.%20Dengiz%2C%20Substrate-controlled%20divergent%20reactivity%20of%202-alkynylindoles%3A%20%5B2%2B2%5D%20cycloaddition-retroelectrocyclization%20versus%20tricyanovinylation%20for%20the%20synthesis%20of%20nlophores%2C%20Journal%20of%20Organic%20Chemistry%20Early%20Access%20%282026%29.%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.joc.6c00004%26%23039%3B%26gt%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.joc.6c00004%26lt%3B%5C%2Fa%26gt%3B.%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Substrate-controlled%20divergent%20reactivity%20of%202-alkynylindoles%3A%20%5B2%2B2%5D%20cycloaddition-retroelectrocyclization%20versus%20tricyanovinylation%20for%20the%20synthesis%20of%20nlophores%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hazal%22%2C%22lastName%22%3A%22Kayas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yagmur%22%2C%22lastName%22%3A%22Unal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kubra%22%2C%22lastName%22%3A%22Erden%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Barsella%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Onur%22%2C%22lastName%22%3A%22Sahin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cagatay%22%2C%22lastName%22%3A%22Dengiz%22%7D%5D%2C%22abstractNote%22%3A%22This%20study%20provides%20insight%20into%20the%20donor%20characteristics%20of%20the%20indole%20framework%20and%20allows%20a%20comparison%20between%20its%20C-2%20and%20C-3%20positions.%20Ten%20electron-rich%20alkynes%20incorporating%20an%20indole%20core%20were%20synthesized%20via%20the%20Sonogashira%20cross-coupling%20reaction.%20Structural%20variations%20within%20these%20substrates%20led%20to%20two%20distinct%20reaction%20pathways%20for%20the%20formation%20of%20cyano-containing%20conjugated%20systems%2C%20yielding%20eight%20tricyanovinylation%20and%20two%20%5B2%20%2B%202%5D%20cycloaddition-retroelectrocyclization%20%28CA-RE%29%20products.%20The%20tricyanovinylation%20products%20formed%20with%20tetracyanoethylene%20%28TCNE%29%20were%20obtained%20in%2040-82%25%20yields%2C%20whereas%20the%20chromophores%20produced%20through%20the%20%5B2%20%2B%202%5D%20CA-RE%20pathway%20arising%20from%20alkyne%20activation%20were%20isolated%20in%2030-63%25%20yields.%20They%20display%20pronounced%20intramolecular%20charge%20transfer%20%28ICT%29%2C%20with%20lambda%20max%20values%20ranging%20from%20494%20to%20504%20nm%20for%20the%20tricyanovinylation%20products%2C%20while%20the%20two%20%5B2%20%2B%202%5D%20CA-RE%20chromophores%20absorb%20at%20471%20and%20495%20nm.%20The%20observed%20ICT%20bands%20are%20supported%20by%20UV%5C%2Fvis%20studies%20by%20positive%20solvatochromism%20and%20protonation%20experiments.%20To%20clarify%20the%20relationship%20between%20NLO%20response%20and%20ICT%20properties%2C%20the%20dipole%20moment%2C%20band%20gap%2C%20electronegativity%2C%20average%20global%20hardness-softness%2C%20average%20polarizability%2C%20and%20first%20hyperpolarizability%20parameters%20were%20evaluated%20using%20computational%20methods.%20In%20addition%20to%20theoretical%20DFT%20calculations%2C%20the%20EFISHG%20technique%20was%20employed%20to%20investigate%20the%20NLO%20properties.%20The%20experimental%20mu%20beta%20values%20of%20the%20selected%20molecules%20range%20from%20150%20to%20560%20%26amp%3B%20times%3B%2010-48%20esu.%22%2C%22date%22%3A%222026%22%2C%22section%22%3A%22%22%2C%22partNumber%22%3A%22%22%2C%22partTitle%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.joc.6c00004%22%2C%22citationKey%22%3A%22WOS%3A001792690400001%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.joc.6c00004%22%2C%22PMID%22%3A%22%22%2C%22PMCID%22%3A%22%22%2C%22ISSN%22%3A%220022-3263%22%2C%22language%22%3A%22English%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22QD76RV9Q%22%2C%22WWGPR7DV%22%5D%2C%22dateModified%22%3A%222026-06-26T12%3A40%3A32Z%22%7D%7D%5D%7D
[1]
L. Aliyeva, A. Guliyeva, C.A. Serra, F. Lemaire, M. Lenertz, A. Carvalho, F. Vigneron, M. Florent, H. Kerdjoujd, U. Hasanova, D. Chan-Seng, Tuning the specific surface area of pure monophasic hydroxyapatite nanoparticles synthesized by sol-gel method using a capillary-based microfluidic process, Powder Technology 476 (2026) 122359. https://doi.org/10.1016/j.powtec.2026.122359.
[1]
T.F. Allard, G. Weick, Reentrant localization transition in a dimerized quasiperiodic dipolar chain, Journal of Physics-Condensed Matter 38 (2026) 225401. https://doi.org/10.1088/1361-648X/ae695d.
[1]
H. Althubyani, D. Stoeffler, J. Bartringer, S. Roques, D. Ihiawakrim, A. Dinia, T. Fix, Investigation of CaZrO3-xSx oxysulfide perovskite thin films grown by pulsed laser deposition, Journal of Physics-Energy 8 (2026) 015034. https://doi.org/10.1088/2515-7655/ae52b5.
[1]
H. Althubyani, W. Couif, P. Pearson, A. Dinia, T. Fix, Environmental aging of CaZrO3-xSx oxychalcogenide perovskite thin films, EPJ Photovoltaics 17 (2026). https://doi.org/10.1051/epjpv/2026019.
[1]
D. Babanly, E. Orujlu, A. Dovlatov, J. Robert, F. Safarov, N. Parizel, B. Vileno, I. Amiraslanov, M. Babanly, P. Turek, MnTe-SnTe-Bi2Te3 pseudo-ternary system: Solid-phase equilibria diagram and magnetic properties of Mn0.55Sn0.45Bi10Te16 and Mn0.55Sn0.45Bi12Te19, Materials Chemistry and Physics 357 (2026) 132365. https://doi.org/10.1016/j.matchemphys.2026.132365.
[1]
B. Bakri, N. Crouseilles, P.-A. Hervieux, G. Manfredi, Wave-particle interactions in a spin polarized plasma, Physics of Plasmas 33 (2026) 022111. https://doi.org/10.1063/5.0312295.
[1]
B. Bakri, G. Manfredi, P.-A. Hervieux, Ultrafast electron-magnon interactions in a spin-polarized electron gas, in: J. Wegrowe, H. Jaffres (Eds.), Spintronics and Nanomagnetism, The International Society for Optics and Photonics; European Optical Society; Photonics21, 2026. https://doi.org/10.1117/12.3102051.
[1]
L. Ballerini, M. Liu, L. Arrico, S. Voci, C. Gourlaouen, C. Daniel, V. Cesar, S. Bellemin-laponnaz, F. Zinna, L. Bouffier, F. Polo, L. Di Bari, N. Sojic, M. Mauro, Bright Circularly Polarized Electrochemiluminescence from Heterobinuclear IrIII-AuI Enantiomers, Angewandte Chemie-International Edition 65 (2026) e10787. https://doi.org/10.1002/anie.202510787.
[1]
L. Barloy, B. Heinrich, N. del Giudice, M. Scarpi-Luttenauer, L. Douce, P. Mobian, Ionic liquid crystals based on a triscatecholatotitanate(iv) complex associated with imidazolium counter-ions, Dalton Transactions 55 (2026) 11607–11617. https://doi.org/10.1039/d6dt00695g.
[1]
J. Bartsch, A. Borzi, P.-A. Hervieux, G. Manfredi, Faster-than-adiabatic cooling of non-neutral plasmas, Physical Review E 114 (2026) 035208. https://doi.org/10.1103/yn72-3qrw.
[1]
F. Busato, M. De Felice, F. Petri, M. Fausti, B. Bruschi, P. Lenzi, F. Cella Zanacchi, D. Pisignano, L. Di Bari, L. Arrico, A bioconjugable eu(III)-based luminescent probe for multicolor and time-gated immunofluorescence, Chemical & Biomedical Imaging Early access (2026). https://doi.org/10.1021/cbmi.6c00148.
[1]
P. Chapel, Y. Wang, C. Leuvrey, M. Lenertz, N. Parizel, A. Beauvois, V. Briois, D. Ihiawakrim, J. Poulizac, V. Rouchon, P. Rabu, C. Taviot-Gueho, G. Rogez, Multistep microwave-assisted approach for the controlled insertion of Cu(ii) into Dion-Jacobson and Ruddlesden-Popper layered perovskites, Materials Chemistry Frontiers Early Access (2026). https://doi.org/10.1039/d6qm00623j.
[1]
H. Chen, A. Borzì, D. Janković, J.-G. Hartmann, P.-A. Hervieux, Full- and Low-Rank Exponential Euler Integrators for the Lindblad Equation, SIAM Journal on Scientific Computing 48 (2026) A1–A26. https://doi.org/10.1137/24M1690795.
[1]
R. Chico, M.J. Baena, C. Cuerva, R. Schmidt, B. Donnio, S. Coco, Ion transport in triphenylene metal-organic columnar mesophases, Journal of Materials Chemistry C 14 (2026) 3306. https://doi.org/10.1039/d5tc03933a.
[1]
J.S. Cordova, A. Friedel, Q. Rossi, J. Robert, Y. Henry, P. Pirro, S. Petit-Watelot, S. Andrieu, M. Bailleul, Spin polarization of the electric current in half-metallic Co2MnSi Heusler thin films, Physical Review B 114 (2026) 094436. https://doi.org/10.1103/w93y-w66w.
[1]
C. Cretu, A.A. Andelescu, M. La Deda, G. Di Maio, A. Len, Z. Dudas, L. Spina, F. Ciuchi, G. De Luca, B. Donnio, A. Crispini, F. Scarpelli, E.I. Szerb, Exploring the self-assembling ability of cyclometallated Rh(iii) complexes with different N,N-chelating ligands in water, Dalton Transactions Early Access (2026). https://doi.org/10.1039/d6dt01255h.
[1]
Anthony. D’Aleo, A.K. Gupta, J. Gong, M. Kato, S. Tosun, L. Mager, J.C. Ribierre, Recent development of borondifluoride curcuminoid derivatives and their applications, CCS Chemistry Early Access (2026). https://doi.org/10.31635/ccschem.026.202607299.
[1]
A. D’Aleo, G. Michaluszko, A. Coron, D.-H. Kim, A. Gary, D. Valverde, E. Zaborova, E. Couzigné, L. Engel, L. Mager, G. Canard, C. Adachi, Y. Olivier, J.-C. Ribierre, Donor-strength-driven evolution from charge-transfer to polymethine excited states in CurcBF2Derivatives, Advanced Optical Materials Early access (2026) e71896. https://doi.org/10.1002/adom.71896.
[1]
O. Darouich, D. Ihiawakrim, S. Labidi, O. Ersen, W. Baaziz, Microstructural evolution and sintering of Pt nanoclusters on diatomite under CO oxidation conditions: An operando and 3D TEM study, Nano Research 19 (2026) 94908808. https://doi.org/10.26599/NR.2026.94908808.
[1]
C. Demangeat, R. Rullan, Y. Tang, B. Hu, A. D’Aleo, T. Le Bahers, M.E. Alikhani, A.-J. Attias, Dopant-tailored matrices: a crystal engineering strategy for organic room-temperature phosphorescent host-guest systems and beyond, Angewandte Chemie-International Edition Early Access (2026) 0:e8252460. https://doi.org/10.1002/anie.8252460.
[1]
M. Dherbécourt, J. Bellessa, C. Symonds, G. Weick, D. Hagenmuller, Spontaneous raman scattering under vibrational strong coupling: The critical role of polariton spatial mode coherence, Physical Review Letters 137 (2026) 116901. https://doi.org/10.1103/m138-4w64.
[1]
L.E. Dickson, H. Cho, N. Ledos, V.-A. DiPalo, K. Udaya Mohanan, J.G. Manion, K. Narayanaswamy, S. Méry, N. Leclerc, C.-H. Kim, B.H. Lessard, Interfacial Siloxane Interactions to Enhance Semiconductor Ordering and Performance in Organic Thin-Film Transistors, ACS Applied Materials & Interfaces Early access (2026). https://doi.org/10.1021/acsami.6c01543.
[1]
D. Dubois, P. Guichard, R. Pasquier, Carbon nitride monolayer nanosheets: astrochemical insights into the fate of interstellar hydrogen, Physical Chemistry Chemical Physics Early Access (2026). https://doi.org/10.1039/d6cp00221h.
[1]
A. Durupt, C. Scarfiello, L. Schmidt, D.P. Minh, K. Soulantica, F. Meunier, O. Ersen, S. Zafeiratos, G. Clet, P. Serp, Reversible Strong Metal-Support Interactions in Co/TiO2 Catalysts Driven by CO2, ChemCatChem 18 (2026) e01392. https://doi.org/10.1002/cctc.202501392.
[1]
L. El Khabchi, L. Schlur, J. Robert, M. Lenertz, C. Leuvrey, G. Versini, F. Roulland, G. Chahine, N. Blanc, D. Preziosi, C. Lefevre, N. Viart, Strain-driven magnetic anisotropy and spin reorientation in epitaxial CoV2O4 spinel oxide thin films, Physical Review Materials 10 (2026) 014408. https://doi.org/10.1103/xzcv-shjr.
[1]
Y. Errouyessi, H. Lassri, S. Colis, R. Moubah, Magnetic behavior, spin transitions, and magnetocaloric effect in europium orthoferrite EuFeO3 nanoparticles synthesized by solid-state reaction, Inorganic Chemistry Communications 186 (2026) 116224. https://doi.org/10.1016/j.inoche.2026.116224.
[1]
M. Fausti, L. Arrico, A. Cesari, M. De Felice, M.A. Casulli, I. Taurino, T. Hashimoto, D. Pisignano, T. Biver, F.C. Zanacchi, L. Di Bari, A Eu(III) Supramolecular Emissive Label for Cyclodextrin-Based (Nano)Materials, ChemPhotoChem 10 (2026) e202500336. https://doi.org/10.1002/cptc.202500336.
[1]
M.A.G. Fernandez, M. Latrache, G. Lemercier, C. Allain, F. Allais, M. Abe, N. Hoffmann, Photochemistry of (-)-levoglucosenone: Norrish type I reaction and photoinduced electron transfer processes, ChemPhotoChem 10 (2026) e70171. https://doi.org/10.1002/cptc.70171.
[1]
J. Fiore, N. Sellati, M. Udina, L. Benfatto, Two-dimensional terahertz spectroscopy in electronic systems: A many-body diagrammatic approach, Physical Review B 113 (2026) 174524. https://doi.org/10.1103/8ffz-rtyf.
[1]
M. Flavenot, H. Sahib, J. Robert, M. Lenertz, G. Versini, L. Schlur, A. Gloter, N. Viart, D. Preziosi, Decoding Superconductivity in La3Ni2O7-δ Thin Films via Ozone-Driven Structure and Oxidation Tuning, Small Structures 7 (2026) 7:e70542. https://doi.org/10.1002/sstr.70542.
[1]
A. Fluck, V. Giuso, C.-H. Liu, C. Gourlaouen, C. Cebrian, F. Polo, H.-C. Su, A. Jouaiti, M. Mauro, Near infrared electroluminescence in light-emitting electrochemical cells from the binuclear copper(i) complexes bearing π-extended benzimidazole and benzothiazole ligands, Journal of Materials Chemistry C Early Access (2026). https://doi.org/10.1039/d6tc00899b.
[1]
J. Frey, S. Azar, S. Dagorne, S. Bellemin-Laponnaz, Bis(phenolate) n-heterocyclic carbene [OCO] pincer ligands: a unique family for the stabilization of transition metal centers and main group elements, ChemistryEurope 4 (2026) e202500283. https://doi.org/10.1002/ceur.202500283.
[1]
E. Gambari, H. Le Du, M. Lizee, A. Mukherjee, L. Limot, F. Scheurer, M. D’angelo, F. Debontridder, T. Cren, M. Herve, Electronic Signatures of the Multiple Moire Components in the Two-Dimensional CrCl3/Au Heterostructure Observed by Scanning Tunneling Microscopy and Spectroscopy, ACS Nano Early access (2026). https://doi.org/10.1021/acsnano.5c21391.
[1]
M. Ghobar, C.B. Karroum, M. Liparo, A.R.E. Prinsloo, C.J. Sheppard, G. Simon, J. Robert, N.L. Breton, A. Fessant, J.-P. Jay, D.T. Dekadjevi, D. Spenato, Low-damping spin dynamics in thin sputtered FeGa films for strain-mediated spintronics, Applied Physics Letters 129 (2026) 082402. https://doi.org/10.1063/5.0343561.
[1]
V. Girelli Consolaro, V. Rouchon, W. Baaziz, A. Hammoumi, T. Ferté, G. Pirngruber, M. Moreaud, O. Ersen, On the properties and origin of mesopore morphologies in dealuminated Faujasite Y zeolites, Nanoscale 18 (2026) 173–187. https://doi.org/10.1039/D5NR01457C.
[1]
V. Giuso, C. Gourlaouen, L. Arrico, L. Di Bari, M. Mauro, Millisecond-LongRed Phosphorescence in Chiral HeterolepticAg(I) Complexes Bearing Benzothiazole Ligands, Inorganic Chemistry 65 (2026) 18554−18562. https://doi.org/10.1021/acs.inorgchem.6c01416.
[1]
V. Giuso, J.-Y. Zhuang, C. Gourlaouen, C. Cebrian, H.-C. Su, M. Mauro, Heteroleptic ag(I) complexes bearing benzothiazole and benzoxazole ligands for orange-red light-emitting electrochemical cells, Advanced Optical Materials Early access (2026) e71836. https://doi.org/10.1002/adom.71836.
[1]
M. Guerra, I. Kim, S. Friedrich, P. Amaro, A. Andoche, G. Baptista, C. Bray, R. Cantor, D. Diercks, S.L. Fretwell, A. Gillespie, John.A. Hall, C.N. Harris, J.T. Harris, L.M. Hayen, P.A. Hervieux, P. Indelicato, G.B. Kim, K.G. Leach, A. Lennarz, V. Lordi, P. Machule, A. Marino, D. McKeen, X. Mougeot, D. Pinheiro, F. Ponce, C. Ruiz, A. Samanta, J.P. Santos, J. Smolsky, C. Stone-Whitehead, J. Templet, W. van de Pontseele, W.K. Warburton, B. Waters, J. Machado, BeEST Collaboration, Shakeup and shakeoff spectra in the electron capture decay of atomic 7Be, Physical Review C 114 (2026) 014624. https://doi.org/10.1103/knwn-47kl.
[1]
M.-X. Hao, Z.-L. Ou, H.-F. Wang, B. Xiao, K.-Q. Zhao, P. Hu, B.-Q. Wang, B. Donnio, Direct Synthesis of Fluorinated Polycyclic Aromatic Dioxanes: Mesomorphism, Luminescence, and Charge Transport, Organic Letters 28 (2026) 1995–1999. https://doi.org/10.1021/acs.orglett.5c05172.
[1]
X. Henning, L. Schlur, D. Stoeffler, M. Vomir, S. Colis, A. Dinia, M. Rastei, Surface photovoltage and open-circuit voltage spectroscopies of oxide heterostructures by atomic force microscopy under variable illumination, Physical Review Materials 10 (2026) 083802. https://doi.org/10.1103/pv1q-9yms.
[1]
K. Herasymenko, D. Walisinghe, M. Konno, V. Ledentu, M. Huix-Rotllant, X. Yang, N. Ferré, K. Inoue, M. Olivucci, S. Haacke, Effects of Counter Ion Protonation on the Ultrafast Excited State Dynamics in Archaerhodopsin-3, Biophysical Journal 125 (2026) 2416–2431. https://doi.org/https://doi.org/10.1016/j.bpj.2026.02.034.
[1]
M. Hrytsaienko, D.O. Siebadji Tchuimeni, M. Ziegler, O. Cregut, G. Schmidt, F. Bertram, J. Christen, S. Tamariz, R. Butte, N. Grandjean, P. Gilliot, M. Gallart, Subpicosecond thermalization of carriers in polar GaN/AlN quantum dots, Journal of Applied Physics 139 (2026) 085704. https://doi.org/10.1063/5.0309975.
[1]
C. Hu, X. Henning, D. Stoeffler, L. Schlur, G. Versini, C. Leuvrey, F. Roulland, U.-C. Chung, T. Fix, A. Dinia, M.V. Rastei, S. Colis, Impact of Bi Vacancies on the Polarization and Transport Properties of Bi2FeCrO6 Thin Films, ACS Applied Electronic Materials 8 (2026) 2364–2372. https://doi.org/10.1021/acsaelm.5c02590.
[1]
C. Hu, L. Schlur, G. Versini, T. Fix, A. Dinia, M.V. Rastei, S. Colis, Tailoring imprint in ferroelectric thin films through substrate work function, Applied Physics Letters 128 (2026) 252904. https://doi.org/10.1063/5.0335819.
[1]
R.A. Jalabert, Nonlocal effects in charge and energy transport with dissipative electrodes, Physical Review B 114 (2026) 045425. https://doi.org/10.1103/tnfs-694c.
[1]
D. Jankovic, R. Pasquier, J.-G. Hartmann, P.-A. Hervieux, Elucidating the physical and mathematical properties of the prouhet-thue-morse sequence in quantum computing, Annalen Der Physik 538 (2026) e00630. https://doi.org/10.1002/andp.202500630.
[1]
J. Jian, M.-M. Zhou, W.-H. Yu, X.-Y. Bai, K.-X. Zhao, K.-Q. Zhao, B. Donnio, From Targeted Synthesis to Serendipitous Discovery: Transforming Perfluorotoluene into Discotic Liquid Crystals and Dearomatized Spirofluorenes., The Journal of Organic Chemistry 91 (2026) 9341–9348. https://doi.org/10.1021/acs.joc.6c00735.
[1]
S. Jiang, F. Scheurer, Q. Sun, P. Ruffieux, X. Yao, A. Narita, K. Mullen, R. Fasel, T. Frederiksen, G. Schull, Length-IndependentQuantum transport through EngineeredBand states in graphene nanoribbon junctions, ACS Nano Early Access (2026). https://doi.org/10.1021/acsnano.6c08307.
[1]
Z.O. Kaplan, F. Kilicarslan, E. Keles, N. Seferoglu, M.W. Kiama, A. Barsella, Z. Seferoglu, Indole- and carbazole-functionalized dicyanomethyleneindan push-pull dyes. Part 1: Synthesis, cyanide sensing, photophysical and NLO properties, ChemistrySelect 11 (2026) e74146. https://doi.org/10.1002/slct.74146.
[1]
H. Kayas, Y. Unal, K. Erden, A. Barsella, O. Sahin, C. Dengiz, Substrate-controlled divergent reactivity of 2-alkynylindoles: [2+2] cycloaddition-retroelectrocyclization versus tricyanovinylation for the synthesis of nlophores, Journal of Organic Chemistry Early Access (2026). https://doi.org/10.1021/acs.joc.6c00004.