Ivan Khariushin (ICS, postdoctorant équipe SAMS)

Résumé: The proposed project addresses the bottlenecks of quantum state initialization and coherence by developing optically addressable, photogenerated high spin states. By coupling organic chromophores with paramagnetic transition metal and lanthanide centers or with stable organic radicals, this project aim to study Enhanced Intersystem Crossing (EISC) to achieve non-thermal spin hyperpolarization upon pulsed optical excitation. The use of a modular assembly strategy, which combines covalent and supramolecular linkers, allows systematical design and investigation of spin properties-structure realtionships in such systems »