Anthony D’ALEO

Anthony D'ALEO

Chargé de Recherche, Matériaux Organiques (DMO)anthony.daleo@ipcms.unistra.fr
Poste: +33(0)3 88 10 71 47Bureau: 2033

Parcours de recherche

After completing his studies at the University of Bordeaux I, Anthony completed his doctorate at the University of Amsterdam (UvA) under the supervision of Prof. Luisa De Cola. He thus defended his thesis entitled « From solution to solid state: energy- and electron-transfer in complex materials » in January 2006.

Anthony then joined ENS Lyon and the « chemistry for optics » group of Drs. Chantal Andraud and Olivier Maury for his first post-doctoral fellowship to study the 2-photon sensitization of the lanthanide complex. As a second post-doctoral training, from 2007 to 2009, Anthony worked on the photophysical characterization of lanthanide complexes for bio-imaging in the group of Prof. Kenneth N. Raymond at the University of California (Berkeley).

In November 2009, Anthony joined the CNRS at the “Centre Interdisciplinaire des Nanosciences de Marseille (CINaM)” in the team of Prof. Frédéric Fages to develop new near infrared emitters. At this time, he was interested in the mechanisms of fluorescence quenching within such NIR emitters. The development of such molecules allows him to work on light emitting diodes and to specialize his activity in the design and study of thermally activated delayed fluorescence molecules.

In 2016, he joined the CNRS-Ewha international Research Center (in Seoul, South Korea) as a CNRS / CINaM researcher to work in collaboration with Prof. Jeong Weon Wu on the effect of hyperbolic metamaterials on the photophysical properties of fluorescent molecules. In 2017, he was assigned to UMI 2B FUEL (in Seoul, South Korea) to build his group and work on the design, synthesis and characterization of organic molecules for LASERs. From January 2019, he is on leave from the CNRS within a start-up (KOALA Tech Inc) created by Prof. Chihaya Adachi. During this leave, he continued to specialize in the optical and electrical properties of organic LASERs.

Since April 2021, Anthony has joined the IPCMS within the DMO to develop his research themes around fluorescent p-conjugated organic molecules and in-depth study of their photophysical properties for applications mainly in organic electronics.

Parcours universitaire

Anthony did his study a the University of Bordeaux I

Recherches actuelles

All my activities are based on the design and synthesis of organic dyes for application spanning from organic light emitting diodes, organic laser diodes and epsilon-near-zero materials. I am seeking for new materials with tailored properties. In particular, the design of dyes allowing the control of the excited state’s nature allows to target specific applications.

Publications

[96] Z. Chen, S. Pascal, M. Daurat, L. Lichon, C. Nguyen,  A. Godefroy, D. Durand, L. M. A. Ali, N. Bettache, M. Gary-Bobo, P. Arnoux, J.-F. Longevial, A. D’Aléo, G. Marchand, D. Jacquemin, O. Siri ACS Appl. Mater. Interfaces, 2021, DOI: 10.1021/acsami.1c05933. Modified Indulines: From Dyestuffs to In Vivo Theranostic Agents

[95] U. Balijapalli, R. Nagata, N. Yamada, H. Nakanotani, M. Tanaka, A. D’Aléo, V. Placide, M. Mamada, Y. Tsuchiya, C. Adachi Angew. Chem. Int. Ed. 2021, 60, 15, 8477-8482. Highly Efficient Near-Infrared Electrofluorescence from a Thermally Activated Delayed Fluorescence Molecule;

[94] R. Aoki, R. Komatsu, K. Goushi, M. Mamada, S. Y. Ko, J. W. Wu, V. Placide, A. D’Aléo, and C. Adachi Adv. Opt. Mater. 2021, 2001947; Realizing Near-Infrared Laser Dyes through a Shift in Excited-State Absorption.

[93] C. Demangeat, Y. Dou, B. Hu, Y. Bretonniere, C. Andraud, A. D’Aléo, J. W. Wu, E. Kim, T. Le Bahers, A.-J. Attias Angew. Chem. Int. Ed. 2021, 60, 5, 2446-2454. σ‐Conjugation and H‐Bond‐Directed Supramolecular Self‐Assembly: Key Features for Efficient Long‐Lived Room Temperature Phosphorescent Organic Molecular Crystals.

[92] X. Tang, Y.-T. Lee, Z. Feng, S. Y. Ko, J. W. Wu, V. Placide, J.-C. Ribierre, A. D’Aléo, C. Adachi ACS Mater. Lett. 2020, 2, 1567-1574. Color-Tunable Low-Threshold Amplified Spontaneous Emission from Yellow to Near-Infrared (NIR) Based on Donor–Spacer–Acceptor–Spacer–Donor Linear Dyes.

[91] R. M. Pallares, M. Sturzbecher-Hoehne, N. H. Shivaram, J. P. Cryan, A. D’Aléo, R. J. Abergel J. Phys. Chem. Lett. 2020, 11, 15, 6063-6067, Two-Photon Antenna Sensitization of Curium: Evidencing Metal-Driven Effects on Absorption Cross Section in f-Element Complexes.

[90] M. Catherin, O. Uranga-Barandiaran, A. Brosseau, R. Métivier, G. Canard, A. D’Aléo, D. Casanova, F. Castet, E. Zaborova, F. Fages, F. Chem. Eur. J. 2020, 26, 17, 3818-3828. Exciton Interactions, Excimer Formation, and [2pi+2pi] Photodimerization in Nonconjugated Curcuminoid-BF2 Dimers.

[89] K. J. Lee, Y. M. Xiao, E. S. Kim, F. Mathevet, L. Mager, O. Cregut, F. Fages, J.-C. Ribierre, J. W. Wu, A. D’Aléo, ACS Photon 2019, 6, 11, 2649-2654. Donor-Acceptor Distance-Dependent Charge Transfer Dynamics Controlled by Metamaterial Structures.

[88] Y. U. Lee, O. P. M. Gaudin, K. J. Lee, E. Choi, V. Placide, K. Takaishi, T. Muto, P. André, A. Muranaka, M. Uchiyama, F. Mathevet, T. Aoyama, J. W. Wu, A. D’Aléo, J.-C. Ribierre ACS Photon 2019, 6, 7, 1681-1689. Organic Monolithic Natural Hyperbolic Material.

[87] M. Auffray, D. H. Kim, J. U. Kim, F. Bencheikh, D. Kreher, Q. Zhang, A. D’Aléo, J.-C. Ribierre, F. Mathevet, C. Adachi Chem Asian J. 2019, 14, 11, 1921-1925. Dithia[3.3]paracyclophane Core: A Versatile Platform for Triplet State Fine-Tuning and Through-Space TADF Emission

[86] O. A. Fedorova, N. E. Shepel, S. D. Tokarev, E. V., Lukovskaya, Y. A. Sotnikova, A. A. Moiseeva, A. D’Aléo, F. Fages, F. Maurel, Y. V. New J. Chem. 2018, 43, 6, 2817-2827. Intramolecular electron transfer in Cu(II) complexes with aryl-imidazo-1,10-phenanthroline derivatives: experimental and quantum chemical calculation studies

[85] A. Shahalizad, D. H. Kim, S. R. Bobbara, Y. Tsuchiya, A. D’Aléo, C. Andraud, J.-C. Ribierre, J.-M. Nunzi, C. Adachi, Appl. Phys. Lett. 2019, 114, 3, 033301. Enhanced near-infrared electroluminescence from a neodymium complex in organic light-emitting diodes with a solution-processed exciplex host.

[84] I. Bayach, A. D’Aléo, P. Trouillas J. Phys. Chem. A 2019, 123, 1, 194-201. Tuning Optical Properties of Chalcone Derivatives: Computational Study.

[83] J.-C. Ribierre, L. Zhao, X. Liu, E. Lacaze, B. Heinrich, S. Méry, P. Sleczkowski, Y. Xiao, F. Lafolet, D. Hashizume, T. Aoyama, M. Uchiyama, J. W. Wu, E. Zaborova, F. Fages, A. D’Aléo, F. Mathevet and C. Adachi J. Mater. Chem. C 2019, 7, 11, 3190-3198. A solvent-free and vacuum-free melt-processing method to fabricate organic semiconducting layers with large crystal size for organic electronic applications.

[82] A. D’Aléo, A. Saul, C. Attaccalite and F. Fages Mater. Chem. Frontiers 2019, 3, 1, 86-92. Influence of halogen substitution on aggregation-induced near infrared emission of borondifluoride complexes of 2’-hydroxychalcones

[81] O. Uranga-Barandiaran, M. Catherin, E. Zaborova, A. D’Aléo, F. Fages, F. Castet and D. Casanova Phys. Chem. Chem. Phys., 2018, 20, 24623-24632. Optical properties of quadrupolar and bi-quadrupolar dyes: intra and inter chromophoric interactions.

[80] H. Ye, D. H. Kim, X. Chen, A. S. D. Sandanayaka, J. U. Kim, E. Zaborova, G. Canard, Y. Tsuchiya, E. Y. Choi, J. W. Wu, F. Fages, J.-L. Bredas, A. D’Aléo, J.-C. Ribierre, and C. Adachi Chem Mater 2018, 30, 6702-6710. Near-Infrared Electroluminescence and Low Threshold Amplified Spontaneous Emission above 800 nm from a Thermally Activated Delayed Fluorescent Emitter.

[79] Y.U. Lee, E. Garoni, H. Kita, K. Kamada, B.H Woo, Y.C. Jun, S.M. Chae, H.J. Kim, K.J. Lee, S. Yoon, E. Choi, F. Mathevet, I. Ozerov, J.-C. Ribierre, J.W. Wu, A. D’Aléo, Adv. Opt. Mater. 2018, 6, 14, 1701400. Strong Nonlinear Optical Response in the Visible Spectral Range with EpsilonNearZero Organic Thin Films.

[78] F. Bocquet, L. Nony, F. Para, P. Luangprasert, J.-V. Naubron, C. Loppacher, T. Leoni, A. Thomas, A. Ranguis, A. D’Aléo, F. Fages, and C. Becker Phys. Rev. B 2018, 97, 235434. Noncontact AFM and differential reflectance spectroscopy joint analyses of bis-pyrenyl thin films on bulk insulators: Relationship between structural and optical properties.

[77]: M. Ponce-Vargas, B. Stefane, E. Zaborova, F. Fages, A. D’Aleo, D. Jacquemin, B. Le Guennic, B Dyes Pigments. 2018, 155, 59-67. Searching for new borondifluoride beta-diketonate complexes with enhanced absorption/emission properties using ab initio tools.

[76]: K. J. Lee, Y. U. Lee, F. Fages, J.-C. Ribierre, J. W. Wu and A. D’Aléo NanoLett. 2018, 18, 1476-1482. Blue-Shifting Intramolecular Charge Transfer Emission by Nonlocal Effect of Hyperbolic Metamaterials.

[75]: D.-H. Kim, A. D’Aléo, X.-K. Chen, A.S.D. Sandanayaka, D. Yao, L. Zhao, T. Komino, E. Zaborova, G. Canard, Y. Tsuchiya, E.Y. Choi, J.W. Wu, F. Fages, J.-L. Brédas, J.-C. Ribierre and C. Adachi Nature Photon. 2018, 12, 98-104. High-efficiency electroluminescence and amplified spontaneous emission from a thermally-activated delayed fluorescent near infrared emitter.

[74]: Y. Geng, A. D’Aléo, K. Inada, L.-S. Cui, J.U. Kim, H. Nakanotani, and C. Adachi Angew. Chem. Int. Ed. 2017, 56, 16536-16540. Donor–s–Acceptor Motifs: Thermally Activated Delayed Fluorescence Emitters with Dual Upconversion.

[73]: A. D’Aléo, M. H. Sazzad, D.-H. Kim, EY. Choi, J. W. Wu, G. Canard, F. Fages, J.-C. Ribierre and C. Adachi Chem. Commun. 2017, 53, 7003-7006. Boron difluoride hemicurcuminoid as an efficient far red to near-infrared emitter: toward OLEDs and laser dyes.

[72]: F. Archet, D. Yao, S. Chambon, M. Abbas, A. D’Aléo, G. Canard, M. Ponce-Vargas, E. Zaborova, B. Le Guennic, G. Wantz and F. Fages ACS Energy Lett., 2017, 2(6), 1303–1307. Synthesis of Bioinspired Curcuminoid Small Molecules for Solution-Processed Organic Solar Cells with High Open-Circuit Voltage.

[71]:    B. Štefane, F. Požgan, ES. Kim, EY. Choi, J.-C. Ribierre, J. W. Wu, M. Ponce-Vargas, B. Le Guennic, D. Jacquemin, G. Canard, E. Zaborova, F. Fages and A. D’Aléo Dyes Pigments 2017, 141, 38-47. Ethynylene-analogues of hemicurcuminoids: Synthesis and ground- and excited properties of their boron difluoride complexes.

[70]: A. D’Aléo, E. Zaborova, F. Fages Croatica Chem. Acta 2017, 90, 1-6. Effect of methoxy substitution on supramolecular arrangement of borondifluorides of 2′-​hydroxy chalcones and their solid-​state NIR fluorescence.

[69]: A. Shahalizad, A. D’Aléo, C. Andraud, M. H. Sazzad, D.-H. Kim, Y. Tsuchiya, J.-C. Ribierre, J.-M. Nunzi and C. Adachi Org. Electron. 2017, 44, 50-58. Near infrared electroluminescence from Nd(TTA)(3) phen in solution-processed small molecule organic light-emitting diodes.

[68]: T. Lelaidier, T. Leoni, A. Ranguis, A. D’Aléo, F. Fages and C. Becker J. Phys. Chem. C 2017, 121(13), 7214-7220. Adsorption and Growth of Bis-pyrene Molecular Layers on Au(111) Studied by STM.

[67]: D. Gao, C. Azarias, A. D’Aléo, M. Giorgi, O. Siri, T. S. Balaban, D. Jacquemin and G. Canard Eur. J. Inorg. Chem. 2017, (4), 780-788. Synthesis and Characterization of Ruffled Phosphorus meso-Ester Corroles.

[66]: G. Canard, M. Ponce-Vargas, D. Jacquemin, B. Le Guennic, A. Felouat,  M. Rivoal,  E. Zaborova, A. D’Aléo and F. Fages RSC Adv. 2017, (7), 10132-10142. Influence of the electron donor groups on the optical and electrochemical properties of borondifluoride complexes of curcuminoid derivatives: a joint theoretical and experimental study

[65]: X. He, L. Norel, Y.-M. Hervault, R. Métivier, A. D’Aléo, O. Maury, and S. Rigaut Inorg. Chem. 2016, 55(24), 12635–12643. Modulation of Eu(III) and Yb(III) Luminescence Using a DTE Photochromic Ligand.

[64]: K. J. Lee, J. H. Woo, Y. Xiao, L. M. Mazur, E. Kim, A.-J. Attias, K. Matczyszyn, M. Samoc, B. Heinrich,S. Mery,F. Fages,L. Mager,A. D’Aléo,J. W. Wu, F. Mathevet, P. André and J.-C. Ribierre RSC Adv. 2016, (6), 57811-57819. Structure-charge transfer property relationship in self-assembled discotic liquid-crystalline donor-acceptor dyad and triad thin films.

[63]: Y. Sotnikova, E. Lukovskaya, A. Bobylyova, Y. Fedorov, V. Novikov, A. Peregudov, A. Anisimov, A. D’Aléo, Frédéric Fages, O. Fedorova Inorg. Chim. Acta 2016, 445(24), 103-109. Cation-dependent structural diversity of zinc(II), calcium(II) mono- and binuclear complexes of aryl-imidazo-1,10-phenanthroline derivatives.

[62]: P.-H. Lanoë, B. Mettra, Y. Y. Liao,N. Calin, A. D’Aléo, T. Namikawa, K. Kamada, F. Fages, C. Monnereau and C. Andraud ChemPhysChem 2016, 17(14), 2128–2136. A physico-chemical study of boron b-diketonate complexes with intense two-photon induced fluorescence in solution and in the solid state

[61]: M. Stürzbecher-Hoehne, P. Yang, A. D’Aléo and R. J. Abergel Dalton Trans. 2016, 45, 9912-9919. Intramolecular sensitization of americium luminescence in solution: Shining light on short-lived forbidden 5f transitions.

[60]: K. J. Lee, J. H. Woo, E. Kim, Y. Xiao, X. Su,L. Mazur, A.-J. Attias, F. Fages, O. Cregut, A. Barsella, F. Mathevet, L. Mager, J. W. Wu, A. D’Aléo, J.-C. Ribierre Phys. Chem. Chem. Phys. 2016, 18, 7875-7887. Electronic Energy and Electron Transfer Processes in Photoexcited Donor-Acceptor Dyad and Triad Molecular Systems Based on Triphenylene and Perylene Bisimide Units.

[59]: T. Lelaidier, T. Lünskens, A. von Weber, T. Leoni, A. Ranguis , A. D’Aléo, F. Fages, A. Kartouzian, C. Becker, U. Heiz Phys. Chem. Chem. Phys. 2016, 18(7), 5299-5305. Optical and morphological properties of thin films of bis-pyrenyl π-conjugated molecules.

[58]: K. Kamada, T. Namikawa, S. Senatore, C. Matthews, P.-F. Lenne, O. Maury, C. Andraud, M. Ponce-Vargas, B. Le Guennic, D. Jacquemin, P. Agbo, D. D. An, S. S. Gauny, X. Liu, R. J. Abergel, F. Fages, A. D’Aléo Chem. Eur. J. 2016, 22(15), 5219–5232. Two-photon absorption and brightness optimization of curcuminoid borondifluoride complexes.

[57]: E. Kim, A. Felouat, E. Zaborova, J.-C. Ribierre, J. W. Wu, S. Senatore, C. Matthews, P.-F. Lenne, C. Baffert, A. Karapetyan, M. Giorgi, D. Jacquemin, M. Ponce-Vargas, B. Le Guennic, F. Fages, A. D’Aléo Org. Biomol. Chem. 2016, 14; 1311-1324.Borondifluoride complexes of hemicurcuminoids as bio-inspired push-pull dyes for bioimaging.

[56]: M. Rivoal, E. Zaborova, G. Canard, A. D’Aléo, F. Fages New. J. Chem. 2016, 40; 1297-1305. Synthesis, Electrochemical and Photophysical Studies of the Borondifluoride Complex of a meta-Linked Biscurcuminoid.

[55]: L. J. Daumann, D. S. Tatum, C. M. Andolina, J. I. Pacold, A. D’Aléo, G.-L. Law, J. Xu, K. N. Raymond Inorg. Chem. 2016, 55(1), 114-124. Effects of Ligand Geometry on the Photophysical Properties of Photoluminescent Eu(III) and Sm(III) 1-Hydroxypyridin-2-one Complexes in Aqueous Solution

[54]: A. Bourdolle, A. D’Aléo, C. Philippot, P. L. Baldeck, Y. Guyot, F. Dubois, A. Ibanez, C. Andraud, S. Brasselet, O. Maury Chem. Phys. Chem. 2016, , 17; 128-135. NIR-to-NIR Two Photon Scanning Laser Microscopy Imaging of Single Nanoparticule Doped by Yb(III) Complexes.

[53]: C. Constantinescu, A. K. Diallo, A. D’Aléo, F. Fages, C. Videlot-Ackermann, P. Delaporte and A.-P. Alloncle Appl. Surf. Sci. 2015, 336, 133–137. Laser-induced forward transfer of a bis-pyrene compound for OTFTs.

[52]: C. Constantinescua, A. K. Diallo, A. D’Aléo, F. Fages, P. Rotaru, C. Videlot-Ackermann, P. Delaporte, A.-P. Alloncle Synth. Met. 2015, 209, 29-33. Thermal behaviour and thin film properties of a bis-pyrene compound for organic thin film transistor applications.

[51]: A. D’Aléo, E. G. Moore, J. Xu, L. J. Daumann, K. N. Raymond Inorg. Chem. 2015, 54, 6807-6820. Optimization of the Sensitization Process and Stability of Octadentate Eu(III) 1,2-HOPO Complexes.

[50]: A. Felouat, A. D’Aleo, A. Charaf-Eddin, D. Jacquemin, B. Le Guennic, E. Kim, K. Lee, J. H. Woo, J.-C. Ribierre, J. W. Wu, F. Fages J. Phys. Chem. A 2015, 119(24), 6283-6295. Tuning the Direction of Intramolecular Charge Transfer and the Nature of the Fluorescent State in a T-Shaped Molecular Dyad.

[49]: A. D’Aléo, V. Heresanu, M. Giorgi, F. Fages Tetrahedron 2015, 71, 2255-2259. Tuning solid state emission properties of pyrene-containing chalcone derivatives.

[48]: G. Canard, D. Gao, A. D’Aléo, M. Giorgi, F.-X. Dang, T. S. Balaban Chem. Eur. J. 2015, 21(21), 7760-7771. Meso-Ester Corroles.

[47]: A. D’Aléo, A. Felouat, F. Fages Adv. Nat. Sci.: Nanosci. Nanotechnol. 2015, 6, 1, 015009. Boron difluoride complexes of 2’-hydroxychalcones and curcuminoids as fluorescent dyes for photonic applications.

[46]: A. D’Aléo, F. Fages Display and Imaging 2014, 2, 1, 149-174. Boron Complexes as Solid-State Fluorophores.

[45]: A. D’Aléo, F. Fages Nonlinear Optics, Quantum Optics 2014, 45, 4, 293-306. Photophysical study of Boron difluoride complex of 5-hydroxyflavone derivative.

[44]: H. Audi, Z. Chen, A. Charaf-Eddin, A. D’Aléo, G. Canard, D. Jacquemin and O. Siri Chem. Commun. 2014, 50, 15140-15143. Extendable nickel complex tapes that reach into NIR absorptions.

[43]: P. Alemany, A. D’Aléo, M. Giorgi, E. Canadell, F. Fages Crystal Growth Des. 2014, 14, 3700-3703, C−H···BF2O2 Interactions in Crystals: A Case for Boron Hydrogen Bonding?

[42]: A. D’Aléo, V. Heresanu, M. Giorgi, B. Le Guennic, D. Jacquemin, F. Fages J. Phys. Chem. C 2014, 118, 11906-11918, NIR Emission in Borondifluoride Complexes of 2’-Hydroxychalcone Derivatives Containing an Acetonaphthone Ring.

[41]: A. D’Aléo, A. Felouat, V. Heresanu, A. Ranguis, D. Chaudanson, A. Karapetyan, M. Giorgi, F. Fages J. Mater. Chem. C 2014, 2, 5208-5215. Two-Photon Excited Fluorescence of BF2 Complexes of Curcumin Analogues: Toward NIR-to-NIR Fluorescent Organic Nanoparticles.

[40]: E. Biver, M. Berta, A. D’Aléo, T. Phan, S. Maria, F. Fages, D. Gigmes, M. Sentis, P. Delaporte ACS App. Mater. Interfaces 2014, 6, 41-48. Influence of Pyrene Grafting on PMMA Nanosecond Laser Ablation at 248 nm.

[39]: E. Dumont, G. Pompidor, A. D’Aléo, J. Vicat, L. Toupet, R. Kahn, E. Girard, O. Maury, N. Giraud PCCP 2013, 15, 18235-18242. Exploration of the Supramolecular Interactions Involving Tris-Dipicolinate Lanthanide Complexes in Protein Crystals by a Combined Biostructural, Computational and NMR study.

[38]: A. D’Aléo, E. Dumont, O. Maury, N. Giraud Magn. Reson. Chem. 2013, 14, 3361-3367. A multi-dimensional approach to the analysis of chemical shift titration experiments in the frame of a multiple reaction scheme.

[37]: A. Bourdolle, M. Allali, A. D’Aléo, P. L. Baldeck, K. Kamada, J. A. G. Williams, H. Le Bozec, C. Andraud, O. Maury ChemPhysChem 2013, 51, 641-648. Influence of the metal ion on the two-photon absorption properties of lanthanide complexes including NIR emitters.

[36]: M. Berta, E. Biver, S. Maria, T. N. T. Phan, A. D’Aléo, P. Delaporte, F. Fages, D. Bertin, D. Gigmes, Appl. Surface Sci. 2013, 282, 880-886. Nanosecond laser-induced periodic surface structuring of cross-linked azo-polymer films.

[35]: A. Felouat, A. D’Aléo, F. Fages J. Org. Chem. 2013, 78(9), 4446-4455. Synthesis and Photophysical Properties of Difluoroboron Complexes of Curcuminoid Derivatives Bearing Different Terminal Aromatic Units and a meso-Aryl Ring.

[34]: S. Chambon, A. D’Aléo, C. Baffert, G. Wantz, F. Fages Chem Commun. 2013, 49, 3555-3557. Solution-processed bulk heterojunction solar cells based on BF2-hydroxychalcone complexes.

[33]: A. D’Aléo, F. Fages Photochem. Photobiol. Sci. 2013, 12, 500-510. Boron difluoride complexes of 3-hydroxyflavone derivatives : Efficient bioinspired dyes for solution and solid-state emission.

[32]: O. Maury, A. D’Aléo, A. Picot, M. Allali, S. Brasselet, P.L. Baldeck, S. Parola, C. Andraud J. Lumin. 2013, 133, 175-179. Two-photon excited luminescence of lanthanide complex in bulk sol-gel matrix.

[31]: A. D’Aléo, D. Gachet, V. Heresanu, M. Giorgi, F. Fages Chem. Eur. J. 2012, 18(40), 12764-12772. Efficient NIR Light Emission in Solid-State Borondifluoride Complexes of 2’-Hydroxychalcone Derivatives.

[30]: A. D’Aléo, A. Bourdolle, S. Brustlein, T. Fauquier, A. Grichine, A. Duperray, P. L. Baldeck, C. Andraud, S. Brasselet, O. Maury Angew. Chem. Int. Ed. 2012, 51(27), 6622-6625. Ytterbium based Bioprobes for NIR-to-NIR Two Photon Scanning Laser Microscopy Imaging.

[29]: A. D’Aléo, L. Ouahab, C. Andraud,F. Pointillart, O. Maury Coord. Chem. Rev. 2012, 256, 1604-1620. Charge Transfer Excited States Sensitization of Lanthanide Emitting from the Visible to the Near-Infra-red.

[28]: M. Sturzbecher-Hoehne, C. Ng Pak Leung, A. D’Aléo, B. Kullgren, A.-L. Prigent, D. K. Shuh, K. N. Raymond, R. J. Abergel; Dalton Trans. 2011, 40, 8340-8346. 3,4,3-LI(1,2-HOPO): In Vitro Formation of Highly Stable Lanthanide Complexes Translates into Efficient In Vivo Decorporation.

[27]: E. G. Moore, J. Xu, S. Dodani, C. J. Jocher, A. D’Aléo, M. Seitz, and K. N. Raymond; Inorg. Chem. 2010, 49(9), 4156-4166. 3,2-HOPO Complexes of Near Infra-Red (NIR) Emitting Lanthanides: Efficient Sensitization of Yb(III) and Nd(III) in Aqueous Solution.

[26]: A. D’Aléo, M. Allali, A. Picot, P. L. Baldeck, L. Toupet, C. Andraud and O. Maury, C. R. Chimie 2010, 13, 681-690. Sensitization of Eu(III) luminescence donor-phenylethynyl-functionalized DTPA and DO3A macrocycles.

[25]: R. J. Abergel, A. D’Aléo, C. Ng Pak Leung, D. K. Shuh, K. N. Raymond; Inorg. Chem. 2009, 48(23), 10868-10870. Using the Antenna Effect as a Spectroscopic Tool; Photophysics and Solution Thermodynamics of the Luminescent Hydroxypyridonate Complex [EuIII(3,4,3LI(1,2-HOPO))]

[24]: A. D’Aléo, J. Xu, K. Do, G. Muller, K. N. Raymond; Helv. Chim. Acta, 2009, 92(11), 2439-2460. A [Cyclentetrakis(methylene)]tetrakis[2-hydroxybenzamide] Ligand That Complexes and Sensitizes Lanthanide(III) Ions

[23]: E. G. Moore, A. D’Aléo, J. Xu, K. N. Raymond; Aust. J. Chem.2009, 62, 1300-1307.

Eu(III) Complexes of Octadentate 1-Hydroxy-2-pyridinones:  Stability and Improved Photophysical Performance

[22]: A. D’Aléo, E. G. Moore, G. Szigethy, J. Xu, K. N. Raymond; Inorg Chem. 2009, 48 (19), 9316–9324. Aryl bridged 1-Hydroxypyridin-2-one: Effect of the bridge on the Eu(III) sensitization process.

[21]: A. D’Aléo, E. Cecchetto, L. De Cola, R. M. Williams; Sensor, 2009, 9(5), 3604-3626.

Metal Ion Enhanced Charge Transfer in a Terpyridine-bis-Pyrene System

[20]: G. Kervern, A. D’Aléo, L. Toupet, O. Maury, L. Emsley, and G. Pintacuda; Angew. Chem. Int. Ed., 2009, 48, 3082-3086. Crystal structure determination of powdered paramagnetic lanthanide complexes by proton NMR.

[19]: A. D’Aléo, A. Picot, P. L. Baldeck, C. Andraud, O. Maury; Inorg. Chem. 2008, 47, 10269-10279. Luminescence of Functionalized-Tris Dipicolinate Lanthanide Complexes. Part 2: Optimization of the Two-Photon Cross-Sections.

[18]: A. D’Aléo, A. Picot, A. Beeby, J. A. G. Williams, B. Le Guennic, C. Andraud, O. Maury; Inorg. Chem. 2008, 47, 10258-10268. Efficient sensitization process of europium, ytterbium and neodymium through charge-transfer excited state.

[17]: A. D’Aléo, J. Xu, E. G. Moore, C. J. Jocher, K. N. Raymond; Inorg. Chem., 2008, 47(14), 6109-6111. Aryl bridged 1-Hydroxypyridin-2-one : Sensitizer Ligands for Eu(III).

[16]: G. Pompidor, A. D’Aléo, N. Giraud, J. Vicat, L. Toupet, L. Emsley, R. Kahn, O. Maury; Angew. Chem. Int. Ed., 2008, 47(18), 3388-3391. Strong Supramolecular Interactions Between Tris-dipicolinate Lanthanide Complexes and Arginine Amino Acid: Application to Protein Crystallography.

[15]: A. Picot, A. D’Aléo, P. L. Baldeck, A. Grishine, A. Duperray, C. Andraud, O. Maury; J. Am. Chem. Soc., 2008, 130(5), 1532-1533. Long-Lived Two Photon Excited Luminescence of Water Soluble EuIII complexes;

[14]: A. D’Aléo, L. Toupet, S. Rigaut, C. Andraud, O. Maury; Opt. Mater. 2008, 30, 1682-1688.Guanidinium as powerful cation for the design of lanthanate for tris-Dipicolinate cristalline materials: Synthesis, structure and photophysical properties.

[13]: V. Legrand, F. Aubert, A. D’Aléo, P. Rabiller and O. Maury Acta Cryst. E 2008, E64, m1280–m1281. Tricaesium tris(pyridine-2,6-dicarboxylato-κ3O2,N,O6)lutetium(III) octahydrate.

[12]: A. D’Aléo, G. Pompidor, B. Elena, J. Vicat, P. L. Baldeck, L. Toupet, R. Kahn, C. Andraud, O. Maury; ChemPhysChem. 2007, 8, 2125-2132. (avec couverture du journal) Lanthanide Containing Biological and Bio-inspired Materials for Nonlinear Biphotonic Microscopy.

[11]: A. D’Aléo, J.-L. Pozzo, K. Heuzé, F. Vögtle, F. Fages; Tetrahedron. 2007, 63, 7482-7488. Benzyl and t-butyl carbamate derivatives of 1,w– amino acids as simple yet efficient gelators.

[10]: A. Fahmi, S.P. Barragan, A. D’Aléo, R.M. Williams, J. Van Heyst, L. De Cola, F. Vögtle; Mater. Chem. Phys. 2007, 103, 361-363. Aggregation of oligothio dendrimer-semi-capped nanoparticles on solid surfaces: Droplets and “Doughnuts”.

[9]: A. Fahmi, A. D’Aléo, R. M. Williams, L. De Cola, N. Gindy, F. Vögtle; Langmuir. 2007, 23, 7831-7835. Converting Self-Assembled Nanoparticle/Dendrimer Nanodroplets into Horse-shoe-like Nanostructures by Thermal Annealing.

[8]: A. D’Aléo, R. M. Williams, Y. Chriqui, V. M. Iyer, P. Belser, F. Vergeer, V. Ruiz, P. R. Unwin, and L. De Cola; Open Inorg. Chem. J. 2007, 1, 1-9. Electrochemical and photophysical properties of ruthenium (II) bipyridyl complexes with pendant alkanethiol chains in solution and anchored to metal surfaces.

[7]: V. M. Iyer, H. Stoeckli-Evans, A. D’Aléo, L. De Cola, P. Belser; Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 2005, 61(Pt 4), o259-61. Packing effects in 4,4′-bis(4-hydroxybutyl)-2,2′-bipyridine and 4,4′-bis(4-bromobutyl)-2,2′-bipyridine.

[6]: A. D’Aléo, S. Welter, E. Cecchetto, L. De Cola; Pure Appl. Chem. 2005, 77(6), 1035-1050. Electronic Energy Transfer in Dinuclear complexes containing meta substituted phenylene units.

[5]: A. D’Aléo, R. M. Williams, F. Osswald, P. Edamana, U. Hahn, J. van Heyst, F. D. Tichelaar, F. Vögtle, L. De Cola; Adv. Funct. Mater. 2004, 14(12), 1167-1177. Oligothia Dendrimers For The Controlled Formation Of Gold Nanoparticles.

[4]: A. D’Aléo, J.-L. Pozzo, F. Fages, M. Schmutz, G. Mieden-Gundert, F. Vögtle, V. Caplar, M. Zinic, Chem. Com. 2004, 2, 190-191. 11-Aminoundecanoic acid: a versatile unit for the generation of low molecular weight gelators for water and organic solvents.

[3]: M. Lescanne, P. Grondin, A. D’Aléo, F. Fages, J.-L. Pozzo, O. Monval-Mondain, P. Reinheimer, A. Colin, Langmuir 2004, 20(8), 3032-3041. Thixotropic Organogels Based on a Simple n-Hydroxyalkyl Amide: Rheological and aging properties.

[2]: S. Leroy-Lhez, C. Belin, A. D’Aléo, R. M. Williams, L. De Cola, F. Fages, Supramol. Chem. 2003, 15(7-8), 627-637. Extending Excited-State Lifetimes by Interchromophoric Triplet-state Equilibration in a Pyrene-Ru(II)diimine Dyad System.

[1]: W. M. Müller, U. Müller, G. Mieden-Gundert, F. Vögtle, M. Lescanne, K. Heuzé, A. D’Aléo, F. Fages, Eur. J. Org. Chem. 2002, 17, 2891-2893. Salts of 4-substituted dipicolinic acid derivatives- very low molecular mass gelators of aqueous DMSO.