Publications 2026

1839302 2026 1 surface-science-reports 50 creator asc 26952 https://www.ipcms.fr/plugins/zotpress/
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[1]
L. Aliyeva, A. Guliyeva, C.A. Serra, F. Lemaire, M. Lenertz, A. Carvalho, F. Vigneron, M. Florent, H. Kerdjoujd, U. Hasanova, D. Chan-Seng, Tuning the specific surface area of pure monophasic hydroxyapatite nanoparticles synthesized by sol-gel method using a capillary-based microfluidic process, Powder Technology 476 (2026) 122359. https://doi.org/10.1016/j.powtec.2026.122359.
[1]
T.F. Allard, G. Weick, Reentrant localization transition in a dimerized quasiperiodic dipolar chain, Journal of Physics-Condensed Matter 38 (2026) 225401. https://doi.org/10.1088/1361-648X/ae695d.
[1]
H. Althubyani, D. Stoeffler, J. Bartringer, S. Roques, D. Ihiawakrim, A. Dinia, T. Fix, Investigation of CaZrO3-xSx oxysulfide perovskite thin films grown by pulsed laser deposition, Journal of Physics-Energy 8 (2026) 015034. https://doi.org/10.1088/2515-7655/ae52b5.
[1]
H. Althubyani, W. Couif, P. Pearson, A. Dinia, T. Fix, Environmental aging of CaZrO3-xSx oxychalcogenide perovskite thin films, EPJ Photovoltaics 17 (2026). https://doi.org/10.1051/epjpv/2026019.
[1]
D. Babanly, E. Orujlu, A. Dovlatov, J. Robert, F. Safarov, N. Parizel, B. Vileno, I. Amiraslanov, M. Babanly, P. Turek, MnTe-SnTe-Bi2Te3 pseudo-ternary system: Solid-phase equilibria diagram and magnetic properties of Mn0.55Sn0.45Bi10Te16 and Mn0.55Sn0.45Bi12Te19, Materials Chemistry and Physics 357 (2026) 132365. https://doi.org/10.1016/j.matchemphys.2026.132365.
[1]
B. Bakri, N. Crouseilles, P.-A. Hervieux, G. Manfredi, Wave-particle interactions in a spin polarized plasma, Physics of Plasmas 33 (2026) 022111. https://doi.org/10.1063/5.0312295.
[1]
L. Ballerini, M. Liu, L. Arrico, S. Voci, C. Gourlaouen, C. Daniel, V. Cesar, S. Bellemin-laponnaz, F. Zinna, L. Bouffier, F. Polo, L. Di Bari, N. Sojic, M. Mauro, Bright Circularly Polarized Electrochemiluminescence from Heterobinuclear IrIII-AuI Enantiomers, Angewandte Chemie-International Edition 65 (2026) e10787. https://doi.org/10.1002/anie.202510787.
[1]
L. Barloy, B. Heinrich, N. del Giudice, M. Scarpi-Luttenauer, L. Douce, P. Mobian, Ionic liquid crystals based on a triscatecholatotitanate(iv) complex associated with imidazolium counter-ions, Dalton Transactions 55 (2026) 11607–11617. https://doi.org/10.1039/d6dt00695g.
[1]
P. Chapel, Y. Wang, C. Leuvrey, M. Lenertz, N. Parizel, A. Beauvois, V. Briois, D. Ihiawakrim, J. Poulizac, V. Rouchon, P. Rabu, C. Taviot-Gueho, G. Rogez, Multistep microwave-assisted approach for the controlled insertion of Cu(ii) into Dion-Jacobson and Ruddlesden-Popper layered perovskites, Materials Chemistry Frontiers Early Access (2026). https://doi.org/10.1039/d6qm00623j.
[1]
H. Chen, A. Borzì, D. Janković, J.-G. Hartmann, P.-A. Hervieux, Full- and Low-Rank Exponential Euler Integrators for the Lindblad Equation, SIAM Journal on Scientific Computing 48 (2026) A1–A26. https://doi.org/10.1137/24M1690795.
[1]
R. Chico, M.J. Baena, C. Cuerva, R. Schmidt, B. Donnio, S. Coco, Ion transport in triphenylene metal-organic columnar mesophases, Journal of Materials Chemistry C 14 (2026) 3306. https://doi.org/10.1039/d5tc03933a.
[1]
C. Cretu, A.A. Andelescu, M. La Deda, G. Di Maio, A. Len, Z. Dudas, L. Spina, F. Ciuchi, G. De Luca, B. Donnio, A. Crispini, F. Scarpelli, E.I. Szerb, Exploring the self-assembling ability of cyclometallated Rh(iii) complexes with different N,N-chelating ligands in water, Dalton Transactions Early Access (2026). https://doi.org/10.1039/d6dt01255h.
[1]
Anthony. D’Aleo, A.K. Gupta, J. Gong, M. Kato, S. Tosun, L. Mager, J.C. Ribierre, Recent development of borondifluoride curcuminoid derivatives and their applications, CCS Chemistry Early Access (2026). https://doi.org/10.31635/ccschem.026.202607299.
[1]
C. Demangeat, R. Rullan, Y. Tang, B. Hu, A. D’Aleo, T. Le Bahers, M.E. Alikhani, A.-J. Attias, Dopant-tailored matrices: a crystal engineering strategy for organic room-temperature phosphorescent host-guest systems and beyond, Angewandte Chemie-International Edition Early Access (2026) 0:e8252460. https://doi.org/10.1002/anie.8252460.
[1]
L.E. Dickson, H. Cho, N. Ledos, V.-A. DiPalo, K. Udaya Mohanan, J.G. Manion, K. Narayanaswamy, S. Méry, N. Leclerc, C.-H. Kim, B.H. Lessard, Interfacial Siloxane Interactions to Enhance Semiconductor Ordering and Performance in Organic Thin-Film Transistors, ACS Applied Materials & Interfaces Early access (2026). https://doi.org/10.1021/acsami.6c01543.
[1]
D. Dubois, P. Guichard, R. Pasquier, Carbon nitride monolayer nanosheets: astrochemical insights into the fate of interstellar hydrogen, Physical Chemistry Chemical Physics Early Access (2026). https://doi.org/10.1039/d6cp00221h.
[1]
A. Durupt, C. Scarfiello, L. Schmidt, D.P. Minh, K. Soulantica, F. Meunier, O. Ersen, S. Zafeiratos, G. Clet, P. Serp, Reversible Strong Metal-Support Interactions in Co/TiO2 Catalysts Driven by CO2, ChemCatChem 18 (2026) e01392. https://doi.org/10.1002/cctc.202501392.
[1]
L. El Khabchi, L. Schlur, J. Robert, M. Lenertz, C. Leuvrey, G. Versini, F. Roulland, G. Chahine, N. Blanc, D. Preziosi, C. Lefevre, N. Viart, Strain-driven magnetic anisotropy and spin reorientation in epitaxial CoV2O4 spinel oxide thin films, Physical Review Materials 10 (2026) 014408. https://doi.org/10.1103/xzcv-shjr.
[1]
Y. Errouyessi, H. Lassri, S. Colis, R. Moubah, Magnetic behavior, spin transitions, and magnetocaloric effect in europium orthoferrite EuFeO3 nanoparticles synthesized by solid-state reaction, Inorganic Chemistry Communications 186 (2026) 116224. https://doi.org/10.1016/j.inoche.2026.116224.
[1]
M. Fausti, L. Arrico, A. Cesari, M. De Felice, M.A. Casulli, I. Taurino, T. Hashimoto, D. Pisignano, T. Biver, F.C. Zanacchi, L. Di Bari, A Eu(III) Supramolecular Emissive Label for Cyclodextrin-Based (Nano)Materials, ChemPhotoChem 10 (2026) e202500336. https://doi.org/10.1002/cptc.202500336.
[1]
M.A.G. Fernandez, M. Latrache, G. Lemercier, C. Allain, F. Allais, M. Abe, N. Hoffmann, Photochemistry of (-)-levoglucosenone: Norrish type I reaction and photoinduced electron transfer processes, ChemPhotoChem 10 (2026) e70171. https://doi.org/10.1002/cptc.70171.
[1]
J. Fiore, N. Sellati, M. Udina, L. Benfatto, Two-dimensional terahertz spectroscopy in electronic systems: A many-body diagrammatic approach, Physical Review B 113 (2026) 174524. https://doi.org/10.1103/8ffz-rtyf.
[1]
M. Flavenot, H. Sahib, J. Robert, M. Lenertz, G. Versini, L. Schlur, A. Gloter, N. Viart, D. Preziosi, Decoding Superconductivity in La3Ni2O7-δ Thin Films via Ozone-Driven Structure and Oxidation Tuning, Small Structures 7 (2026) 7:e70542. https://doi.org/10.1002/sstr.70542.
[1]
A. Fluck, V. Giuso, C.-H. Liu, C. Gourlaouen, C. Cebrian, F. Polo, H.-C. Su, A. Jouaiti, M. Mauro, Near infrared electroluminescence in light-emitting electrochemical cells from the binuclear copper(i) complexes bearing π-extended benzimidazole and benzothiazole ligands, Journal of Materials Chemistry C Early Access (2026). https://doi.org/10.1039/d6tc00899b.
[1]
J. Frey, S. Azar, S. Dagorne, S. Bellemin-Laponnaz, Bis(phenolate) n-heterocyclic carbene [OCO] pincer ligands: a unique family for the stabilization of transition metal centers and main group elements, ChemistryEurope 4 (2026) e202500283. https://doi.org/10.1002/ceur.202500283.
[1]
E. Gambari, H. Le Du, M. Lizee, A. Mukherjee, L. Limot, F. Scheurer, M. D’angelo, F. Debontridder, T. Cren, M. Herve, Electronic Signatures of the Multiple Moire Components in the Two-Dimensional CrCl3/Au Heterostructure Observed by Scanning Tunneling Microscopy and Spectroscopy, ACS Nano Early access (2026). https://doi.org/10.1021/acsnano.5c21391.
[1]
V. Girelli Consolaro, V. Rouchon, W. Baaziz, A. Hammoumi, T. Ferté, G. Pirngruber, M. Moreaud, O. Ersen, On the properties and origin of mesopore morphologies in dealuminated Faujasite Y zeolites, Nanoscale 18 (2026) 173–187. https://doi.org/10.1039/D5NR01457C.
[1]
V. Giuso, C. Gourlaouen, L. Arrico, L. Di Bari, M. Mauro, Millisecond-LongRed Phosphorescence in Chiral HeterolepticAg(I) Complexes Bearing Benzothiazole Ligands, Inorganic Chemistry 65 (2026) 18554−18562. https://doi.org/10.1021/acs.inorgchem.6c01416.
[1]
M. Guerra, I. Kim, S. Friedrich, P. Amaro, A. Andoche, G. Baptista, C. Bray, R. Cantor, D. Diercks, S.L. Fretwell, A. Gillespie, John.A. Hall, C.N. Harris, J.T. Harris, L.M. Hayen, P.A. Hervieux, P. Indelicato, G.B. Kim, K.G. Leach, A. Lennarz, V. Lordi, P. Machule, A. Marino, D. McKeen, X. Mougeot, D. Pinheiro, F. Ponce, C. Ruiz, A. Samanta, J.P. Santos, J. Smolsky, C. Stone-Whitehead, J. Templet, W. van de Pontseele, W.K. Warburton, B. Waters, J. Machado, BeEST Collaboration, Shakeup and shakeoff spectra in the electron capture decay of atomic 7Be, Physical Review C 114 (2026) 014624. https://doi.org/10.1103/knwn-47kl.
[1]
M.-X. Hao, Z.-L. Ou, H.-F. Wang, B. Xiao, K.-Q. Zhao, P. Hu, B.-Q. Wang, B. Donnio, Direct Synthesis of Fluorinated Polycyclic Aromatic Dioxanes: Mesomorphism, Luminescence, and Charge Transport, Organic Letters 28 (2026) 1995–1999. https://doi.org/10.1021/acs.orglett.5c05172.
[1]
X. Henning, L. Schlur, D. Stoeffler, M. Vomir, S. Colis, A. Dinia, M. Rastei, Surface photovoltage and open-circuit voltage spectroscopies of oxide heterostructures by atomic force microscopy under variable illumination, Physical Review Materials 10 (2026) 083802. https://doi.org/10.1103/pv1q-9yms.
[1]
K. Herasymenko, D. Walisinghe, M. Konno, V. Ledentu, M. Huix-Rotllant, X. Yang, N. Ferré, K. Inoue, M. Olivucci, S. Haacke, Effects of Counter Ion Protonation on the Ultrafast Excited State Dynamics in Archaerhodopsin-3, Biophysical Journal 125 (2026) 2416–2431. https://doi.org/https://doi.org/10.1016/j.bpj.2026.02.034.
[1]
M. Hrytsaienko, D.O. Siebadji Tchuimeni, M. Ziegler, O. Cregut, G. Schmidt, F. Bertram, J. Christen, S. Tamariz, R. Butte, N. Grandjean, P. Gilliot, M. Gallart, Subpicosecond thermalization of carriers in polar GaN/AlN quantum dots, Journal of Applied Physics 139 (2026) 085704. https://doi.org/10.1063/5.0309975.
[1]
C. Hu, X. Henning, D. Stoeffler, L. Schlur, G. Versini, C. Leuvrey, F. Roulland, U.-C. Chung, T. Fix, A. Dinia, M.V. Rastei, S. Colis, Impact of Bi Vacancies on the Polarization and Transport Properties of Bi2FeCrO6 Thin Films, ACS Applied Electronic Materials 8 (2026) 2364–2372. https://doi.org/10.1021/acsaelm.5c02590.
[1]
C. Hu, L. Schlur, G. Versini, T. Fix, A. Dinia, M.V. Rastei, S. Colis, Tailoring imprint in ferroelectric thin films through substrate work function, Applied Physics Letters 128 (2026) 252904. https://doi.org/10.1063/5.0335819.
[1]
R.A. Jalabert, Nonlocal effects in charge and energy transport with dissipative electrodes, Physical Review B 114 (2026) 045425. https://doi.org/10.1103/tnfs-694c.
[1]
D. Jankovic, R. Pasquier, J.-G. Hartmann, P.-A. Hervieux, Elucidating the physical and mathematical properties of the prouhet-thue-morse sequence in quantum computing, Annalen Der Physik 538 (2026) e00630. https://doi.org/10.1002/andp.202500630.
[1]
J. Jian, M.-M. Zhou, W.-H. Yu, X.-Y. Bai, K.-X. Zhao, K.-Q. Zhao, B. Donnio, From Targeted Synthesis to Serendipitous Discovery: Transforming Perfluorotoluene into Discotic Liquid Crystals and Dearomatized Spirofluorenes., The Journal of Organic Chemistry 91 (2026) 9341–9348. https://doi.org/10.1021/acs.joc.6c00735.
[1]
S. Jiang, F. Scheurer, Q. Sun, P. Ruffieux, X. Yao, A. Narita, K. Mullen, R. Fasel, T. Frederiksen, G. Schull, Length-IndependentQuantum transport through EngineeredBand states in graphene nanoribbon junctions, ACS Nano Early Access (2026). https://doi.org/10.1021/acsnano.6c08307.
[1]
Z.O. Kaplan, F. Kilicarslan, E. Keles, N. Seferoglu, M.W. Kiama, A. Barsella, Z. Seferoglu, Indole- and carbazole-functionalized dicyanomethyleneindan push-pull dyes. Part 1: Synthesis, cyanide sensing, photophysical and NLO properties, ChemistrySelect 11 (2026) e74146. https://doi.org/10.1002/slct.74146.
[1]
H. Kayas, Y. Unal, K. Erden, A. Barsella, O. Sahin, C. Dengiz, Substrate-controlled divergent reactivity of 2-alkynylindoles: [2+2] cycloaddition-retroelectrocyclization versus tricyanovinylation for the synthesis of nlophores, Journal of Organic Chemistry Early Access (2026). https://doi.org/10.1021/acs.joc.6c00004.
[1]
E. Keleş, A. Barsella, N. Seferoğlu, Z. Seferoğlu, B. Aydıner, Symmetrical D–π–A–π–D indanone dyes: a new design for nonlinear optics and cyanide detection, Beilstein Journal of Organic Chemistry 22 (2026) 131–142. https://doi.org/10.3762/bjoc.22.6.
[1]
D. Kim, M. Dherbecourt, S.R. Endo, G. Lee, A. Agrawal, S. Kim, W.-H. Wu, A.D. Mohite, M. Seo, D. Hagenmuller, J. Kono, Symmetry-controlled ultrastrong phonon-photon coupling in a terahertz cavity, Journal of Chemical Physics 164 (2026) 104201. https://doi.org/10.1063/5.0313120.
[1]
S.K. Kuppusamy, C. Pachl, Z. Jing, S. Paul, B. Heinrich, O. Fuhr, S. Klyatskaya, W. Wernsdorfer, A.K. Powell, K. Fink, M. Ruben, Ligand-field symmetry and magneto-optical correlations in a luminescent Dy(iii) single-molecule magnet, Dalton Transactions 55 (2026) 5448–5465. https://doi.org/10.1039/d6dt00081a.
[1]
E. Laurent, R.J.P. Roman, S. Miller, A.R. Moghe, E. Lorchat, S. Le Moal, E. Boer-Duchemin, L.F. Zagonel, S. Berciaud, E. Le Moal, Sub-diffraction-resolved spatial distribution of emitting excitons in scanning tunneling microscopy-induced luminescence of two-dimensional semiconductors via Richardson-Lucy deconvolution, Physical Review Applied 26 (2026) 014016. https://doi.org/10.1103/lwl7-zrk8.
[1]
B. Lee, B. Kim, P. Adrich, I. Belosevic, M. Chung, P. Comini, P. Crivelli, P. Debu, S. Geffroy, P. Guichard, P.-A. Hervieux, L. Hilico, P. Indelicato, S. Jonsell, S. Kim, E. Kim, N. Kuroda, L. Liszkay, D. Lunney, G. Manfredi, B. Mansoulie, M. Matusiak, V. Nesvizhevsky, F. Nez, K. Park, E. Perez, P. Perez, C. Regenfus, C. Roumegou, J. Rousse, F. Schmidt-Kaler, K. Szymczyk, T.A. Tanaka, B. Tuchming, D.P. van der Werf, D. Won, S. Wronka, P. Yzombard, Record accumulation of antiprotons in a Penning-Malmberg trap and their preparation for improved production of antihydrogen beams, Journal of Physics G-Nuclear and Particle Physics 53 (2026) 085002. https://doi.org/10.1088/1361-6471/ae7456.
[1]
C. Li, C. Ducottet, M. Moreaud, S. Desroziers, V. Girelli Consolaro, V. Rouchon, O. Ersen, Contrastive learning and physics oriented evaluation for advanced segmentation in electron tomography, Expert Systems with Applications 298 (2026) 129606. https://doi.org/10.1016/j.eswa.2025.129606.
[1]
R. Lopez-Martin, I. Makarchuk, F. Choueikani, S. Hettler, R. Arenal, J.A. De Toro, B.P. Pichon, Investigation of the chemical structure of core-shell Fe3O4@Ni1-xCo xFe2O4nanoparticles and its influence on their magnetic properties., Nanoscale Advances Early Access (2026). https://doi.org/10.1039/d6na00118a.
[1]
I. Lopez-sicilia, V. Girelli Consolaro, S. Marbach, N. Rahbany, G. Petit, O. Ersen, J.J. Giner-casares, A. Abou-hassan, Elucidating the role of surface ligands on the oxidative etching of au bipyramids during photothermia using liquid cell transmission electron microscopy, Advanced Functional Materials 36 (2026) e00034. https://doi.org/10.1002/adfm.202600034.
[1]
D. Lu, V. Giuso, A.G. Ricciardulli, K. Lu, G.-G. Wang, P. Samori, M. Mauro, A. Bianco, Color-tunable afterglow carbon dot@zeolite hybrids with efficient room temperature phosphorescence as anti-counterfeiting materials, Carbon 259 (2026) 121863. https://doi.org/10.1016/j.carbon.2026.121863.