Microscopie Nonlineaire et Structuration des Materiaux Organiques (NOMPOM)

Motivation

Le travail de recherche de l’équipe concerne essentiellement l’étude des propriétés optiques non linéaires (ONL) quadratiques de composés organiques, de la molécule simple aux systèmes plus complexes (polymères fonctionnalisés, matériaux hybrides organiques/inorganiques). Nos travaux expérimentaux vont des aspects fondamentaux de compréhension des mécanismes à l’origine des propriétés optiques non linéaires des systèmes étudiés jusqu’à leur application dans la création de dispositifs intégrés. Les travaux de nature pluridisciplinaire sont menés en collaboration étroite avec des théoriciens pour les aspects fondamentaux, des équipes de chimistes pour la synthèse de composés originaux ainsi qu’avec des biologistes pour l’imagerie multiphotonique.

ACTIVITES

Emission laser auto-doublée dans un système organique

Etude des propriétés ONL de molécules à transfert de charge

Matériaux organiques pour l’électro-optique

Dichroisme circulaire

Guides d’onde auto-inscrites

Micro-usinage laser

Microscopie en generation de second harmonique

Membres de l’équipe :

Maître de conférences, Optique Ultra-rapide et Nanophotonique (DON)Alberto.Barsella@ipcms.unistra.fr
Tél: +33(0)3 88 10 72 26Bureau: 2051
Voir la page personnelle
Professeur, Optique Ultra-rapide et Nanophotonique (DON)kdorkeno@ipcms.unistra.fr
Tél: /Bureau: 2402
Doctorant, Optique Ultra-rapide et Nanophotonique (DON)aaron.terpstra@ipcms.unistra.fr
Tél: +33(0)3 88 10 70 91Bureau: 1030
Chargé de Recherche, Optique Ultra-rapide et Nanophotonique (DON)Loic.Mager@ipcms.unistra.fr
Tél: /Bureau: 2051

Publications récentes :

[1]
M. Yahya, E. Keles, R. Metin, B. Aydiner, N. Seferoglu, A. Barsella, E. Sahin, Y. Sakalli, Z. Seferoglu, A new indanone based dyes bearing dicyanomethylene and salicylidene moieties for selective detection cyanide anion and aromatic amines, Journal of Photochemistry and Photobiology A-Chemistry 462 (2025) 116176. https://doi.org/10.1016/j.jphotochem.2024.116176.
[1]
I. Savas, M.E. Celik, A. Barsella, C. Dengiz, Carbamate-Functionalized NLOphores via a Formal [2+2] Cycloaddition-Retroelectrocyclization Strategy., Chemistry-a European Journal (2025) e202404778–e202404778. https://doi.org/10.1002/chem.202404778.
[1]
R. Metin, E. Keles, E. Aktan, A. Barsella, Z. Seferoglu, Synthesis of fluorescent dicyanomethylenevinyl-1,3-dicoumarin compounds with donor-acceptor-pi-donor (D-A-pi-D) system and investigation of their photophysical, NLO, and chemosensor properties: Part 1., Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy 330 (2025) 125619–125619. https://doi.org/10.1016/j.saa.2024.125619.
[1]
I. Nadinov, O. Kovalenko, J.-L. Rehspringer, L. Mager, Functionalization of micro-size garnet at the end of optical fiber for magneto-optical applications, Optics Express 32 (2024) 7651–7658. https://doi.org/10.1364/OE.503864.
[1]
M.S. Islam, R.K. Chowdhury, M. Barthelemy, L. Moczko, P. Hébraud, S. Berciaud, A. Barsella, F. Fras, Large-Scale Statistical Analysis of Defect Emission in hBN: Revealing Spectral Families and Influence of Flake Morphology, ACS Nano 18 (2024) 20980–20989. https://doi.org/10.1021/acsnano.3c10403.
[1]
K. Erden, D. Soyler, A. Barsella, O. Şahin, S. Soylemez, C. Dengiz, Synthesis and Optical Characterization of Hydrazone-Substituted Push–Pull-Type NLOphores, J. Org. Chem. 89 (2024) 13192–13207. https://doi.org/10.1021/acs.joc.4c01328.
[1]
M. Yahya, N. Seferoglu, G. Kaplan, Y. Nural, A. Barsella, Z. Seferoglu, Synthesis, nonlinear optical properties, photophysical, and theoretical studies of azo dye bearing coumarin-thiophene, Journal of Molecular Structure 1273 (2023) 134257. https://doi.org/10.1016/j.molstruc.2022.134257.
[1]
J. Shaya, J.-C. Ribierre, G. Correia, Y.J. Dappe, F. Mathevet, L. Mager, B. Heinrich, S. Méry, Control of the Organization of 4,4’-bis(carbazole)-1,1’-biphenyl (CBP) Molecular Materials through Siloxane Functionalization., Molecules 28 (2023) 2038. https://doi.org/10.3390/molecules28052038.
[1]
F. Mammadova, F.C. Inyurt, A. Barsella, C. Dengiz, Cyano-rich donor-acceptor-donor-type NLOphores containing dialkylated triazene and aniline groups*, Dyes and Pigments 209 (2023) 110894. https://doi.org/10.1016/j.dyepig.2022.110894.
[1]
U. Acevedo-Salas, B. Croes, Y. Zhang, O. Crégut, K.D. Dorkenoo, B. Kirbus, E. Singh, H. Beccard, M. Rusing, L.M. Eng, R. Hertel, E.A. Eliseev, A.N. Morozovska, S. Cherifi-Hertel, Impact of 3D Curvature on the Polarization Orientation in Non-Ising Domain Walls., Nano Letters 23 (2023) 795–803. https://doi.org/10.1021/acs.nanolett.2c03579.
[1]
C. Weymann, S. Cherifi-Hertel, C. Lichtensteiger, I. Gaponenko, K.D. Dorkenoo, A.B. Naden, P. Paruch, Non-Ising domain walls in $c$-phase ferroelectric lead titanate thin films, Physical Review B 106 (2022) L241404. https://doi.org/10.1103/PhysRevB.106.L241404.
[1]
E.V. Verbitskiy, P. le Poul, F. Bures, S. Achelle, A. Barsella, Y.A. Kvashnin, G.L. Rusinov, V.N. Charushin, Push-Pull Derivatives Based on 2,4’-Biphenylene Linker with Quinoxaline, [1,2,5]Oxadiazolo[3,4-B]Pyrazine and [1,2,5]Thiadiazolo[3,4-B]Pyrazine Electron Withdrawing Parts., Molecules 27 (2022) 4250. https://doi.org/10.3390/molecules27134250.
[1]
J. Shaya, G. Correia, B. Heinrich, J.-C. Ribierre, K. Polychronopoulou, L. Mager, S. Méry, Functionalization of Biphenylcarbazole (CBP) with Siloxane-Hybrid Chains for Solvent-Free Liquid Materials, Molecules 27 (2022) 89. https://doi.org/10.3390/molecules27010089.
[1]
M.D. Pichois, X. Henning, M.A. Hurier, M. Vomir, A. Barsella, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photovoltaic and photothermal effects induced by visible laser radiation in atomic force microscopy probes., Ultramicroscopy 241 (2022) 113601. https://doi.org/10.1016/j.ultramic.2022.113601.
[1]
A. Lipatov, P. Chaudhary, Z. Guan, H. Lu, G. Li, O. Crégut, K.D. Dorkenoo, R. Proksch, S. Cherifi-Hertel, D.-F. Shao, E.Y. Tsymbal, J. Iniguez, A. Sinitskii, A. Gruverman, Direct observation of ferroelectricity in two-dimensional MoS2, NPJ 2D Materials and Applications 6 (2022) 18. https://doi.org/10.1038/s41699-022-00298-5.
[1]
B. Croes, I. Gaponenko, C. Voulot, O. Grégut, K.D. Dorkenoo, F. Cheynis, S. Curiotto, P. Müller, F. Leroy, K. Cordero-Edwards, P. Paruch, S. Cherifi-Hertel, Automatic Ferroelectric Domain Pattern Recognition Based on the Analysis of Localized Nonlinear Optical Responses Assisted by Machine Learning, Advanced Physics Research n/a (2022) 2200037. https://doi.org/https://doi.org/10.1002/apxr.202200037.
[1]
M. Yahya, N. Seferoglu, A. Barsella, S. Achelle, Z. Seferoglu, Amino-substituted-1,1-dicyano-2,4-diaryl-1,3-butadiene chromophores: Synthesis and photophysical properties, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy 248 (2021) 119178. https://doi.org/10.1016/j.saa.2020.119178.
[1]
M. Vignolo, G. Bovone, M. Capra, F. Loria, C. Bernini, B. Vileno, L. Mager, B. Donnio, M. Rastei V., J.-L. Gallani, Magnetism: Another Idiosyncrasy of Boron?, European Journal of Inorganic Chemistry (2021) 1224–1229. https://doi.org/10.1002/ejic.202001075.
[1]
E.V. Verbitskiy, S. Achelle, F. Bures, P. le Poul, A. Barsella, Y.A. Kvashnin, G.L. Rusinov, F. Robin-le Guen, O.N. Chupakhin, V.N. Charushin, Synthesis, photophysical and nonlinear optical properties of [1,2,5] oxadiazolo[3,4-b]pyrazine-based linear push-pull systems, Journal of Photochemistry and Photobiology A-Chemistry 404 (2021) 112900. https://doi.org/10.1016/j.jphotochem.2020.112900.
[1]
M.D. Pichois, M.A. Hurier, M. Vomir, A. Barsella, B. Donnio, J.-L. Gallani, M.V. Rastei, Photothermal Plasmonic Actuation of Micromechanical Cantilever Beams, Physical Review Applied 15 (2021) 034020. https://doi.org/10.1103/PhysRevApplied.15.034020.
[1]
A. Ozarslan, D. Cakmaz, F. Erol, H. Senoz, N. Seferoglu, A. Barsella, Z. Seferoglu, Synthesis and investigation of photophysical, NLO and thermal properties of D-pi-A-pi-D dyes, Journal of Molecular Structure 1229 (2021) 129583. https://doi.org/10.1016/j.molstruc.2020.129583.
[1]
R.J. Durand, S. Achelle, F. Robin-Le Guen, E. Caytan, N. Le Poul, A. Barsella, P. Guevara Level, D. Jacquemin, S. Gauthier, Investigation of second-order nonlinear optical responses in a series of V-shaped binuclear platinum(ii) complexes, Dalton Transactions 50 (2021) 4623–4633. https://doi.org/10.1039/d1dt00151e.
[1]
B. Croes, F. Cheynis, Y. Zhang, C. Voulot, K.D. Dorkenoo, S. Cherifi-Hertel, C. Mocuta, M. Texier, T. Cornelius, O. Thomas, M.-I. Richard, P. Müller, S. Curiotto, F. Leroy, Ferroelectric nanodomains in epitaxial GeTe thin films, Physical Review Materials 5 (2021) 124415. https://doi.org/10.1103/PhysRevMaterials.5.124415.
[1]
K.-R. Choi, D.H. Kim, Y.U. Lee, V. Placide, S. Huynh, D. Yao, G. Canard, E. Zaborova, F. Mathevet, L. Mager, B. Heinrich, J.-C. Ribierre, J.W. Wu, F. Fages, A. D’Aleo, Effect of the electron donating group on the excited-state electronic nature and epsilon-near-zero properties of curcuminoid-borondifluoride dyes, RSC Advances 11 (2021) 38247–38257. https://doi.org/10.1039/d1ra08025c.
[1]
S. Cherifi-Hertel, C. Voulot, U. Acevedo-Salas, Y. Zhang, O. Crégut, K.D. Dorkenoo, R. Hertel, Shedding light on non-Ising polar domain walls: Insight from second harmonic generation microscopy and polarimetry analysis, Journal of Applied Physics 129 (2021) 081101. https://doi.org/10.1063/5.0037286.
[1]
S. Achelle, E.V. Verbitskiy, M. Feckova, F. Bures, A. Barsella, F. Robin-le Guen, V-Shaped Methylpyrimidinium Chromophores for Nonlinear Optics, ChemPlusChem 86 (2021) 758–762. https://doi.org/10.1002/cplu.202100081.
[1]
A.U. Putra, D. Cakmaz, N. Seferoglu, A. Barsella, Z. Seferoglu, Styryl-based new organic chromophores bearing free amino and azomethine groups: synthesis, photophysical, NLO, and thermal properties, Beilstein Journal of Organic Chemistry 16 (2020) 2282–2296. https://doi.org/10.3762/bjoc.16.189.
[1]
T.N. Moshkina, P. Le Poul, A. Barsella, O. Pytela, F. Bures, F. Robin-Le Guen, S. Achelle, E.V. Nosova, G.N. Lipunova, V.N. Charushin, Electron-Withdrawing Substituted Quinazoline Push-Pull Chromophores: Synthesis, Electrochemical, Photophysical and Second-Order Nonlinear Optical Properties, European Journal of Organic Chemistry (2020) 5445–5454. https://doi.org/10.1002/ejoc.202000870.
[1]
E. Keles, M. Yahya, E. Aktan, B. Aydiner, N. Seferoglu, A. Barsella, Z. Seferoglu, Indole based push-pull dyes bearing azo and dimethine: Synthesis, spectroscopic, NLO, anion affinity properties and thermal characterization, Journal of  Photochemistry and Photobiology A-Chemistry 402 (2020) 112818. https://doi.org/10.1016/j.jphotochem.2020.112818.
[1]
P. Gosset, G. Taupier, O. Crégut, J. Brazard, Y. Mely, K.-D. Dorkenoo, J. Léonard, P. Didier, Excited-State Proton Transfer in Oxyluciferin and Its Analogues, Journal of Physical Chemistry Letters 11 (2020) 3653–3659. https://doi.org/10.1021/acs.jpclett.0c00839.
[1]
A. Barsella, M.A. Hurier, M.D. Pichois, M. Vomir, H. Hasan, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photonic Excitation of a Micromechanical Cantilever in Electrostatic Fields, Physical Review Letters 125 (2020) 254301. https://doi.org/10.1103/PhysRevLett.125.254301.

Emission laser auto-doublée dans un système organique

Etude des propriétés ONL de molécules à transfert de charge

Matériaux organiques pour l’électro-optique