Motivation
Le travail de recherche de l’équipe concerne essentiellement l’étude des propriétés optiques non linéaires (ONL) quadratiques de composés organiques, de la molécule simple aux systèmes plus complexes (polymères fonctionnalisés, matériaux hybrides organiques/inorganiques). Nos travaux expérimentaux vont des aspects fondamentaux de compréhension des mécanismes à l’origine des propriétés optiques non linéaires des systèmes étudiés jusqu’à leur application dans la création de dispositifs intégrés. Les travaux de nature pluridisciplinaire sont menés en collaboration étroite avec des théoriciens pour les aspects fondamentaux, des équipes de chimistes pour la synthèse de composés originaux ainsi qu’avec des biologistes pour l’imagerie multiphotonique.
ACTIVITES
Dichroisme circulaire
Guides d’onde auto-inscrites
Micro-usinage laser
Microscopie en generation de second harmonique
Publications récentes :
[1]
M. Yahya, N. Seferoglu, G. Kaplan, Y. Nural, A. Barsella, Z. Seferoglu, Synthesis, nonlinear optical properties, photophysical, and theoretical studies of azo dye bearing coumarin-thiophene, Journal of Molecular Structure. 1273 (2023) 134257. https://doi.org/10.1016/j.molstruc.2022.134257.
[1]
F. Mammadova, F.C. Inyurt, A. Barsella, C. Dengiz, Cyano-rich donor-acceptor-donor-type NLOphores containing dialkylated triazene and aniline groups*, Dyes and Pigments. 209 (2023) 110894. https://doi.org/10.1016/j.dyepig.2022.110894.
[1]
U. Acevedo-Salas, B. Croes, Y. Zhang, O. Crégut, K.D. Dorkenoo, B. Kirbus, E. Singh, H. Beccard, M. Rusing, L.M. Eng, R. Hertel, E.A. Eliseev, A.N. Morozovska, S. Cherifi-Hertel, Impact of 3D Curvature on the Polarization Orientation in Non-Ising Domain Walls., Nano Letters. 23 (2023) 795–803. https://doi.org/10.1021/acs.nanolett.2c03579.
[1]
C. Weymann, S. Cherifi-Hertel, C. Lichtensteiger, I. Gaponenko, K.D. Dorkenoo, A.B. Naden, P. Paruch, Non-Ising domain walls in $c$-phase ferroelectric lead titanate thin films, Physical Review B. 106 (2022) L241404. https://doi.org/10.1103/PhysRevB.106.L241404.
[1]
E.V. Verbitskiy, P. le Poul, F. Bures, S. Achelle, A. Barsella, Y.A. Kvashnin, G.L. Rusinov, V.N. Charushin, Push-Pull Derivatives Based on 2,4’-Biphenylene Linker with Quinoxaline, [1,2,5]Oxadiazolo[3,4-B]Pyrazine and [1,2,5]Thiadiazolo[3,4-B]Pyrazine Electron Withdrawing Parts., Molecules. 27 (2022) 4250. https://doi.org/10.3390/molecules27134250.
[1]
J. Shaya, G. Correia, B. Heinrich, J.-C. Ribierre, K. Polychronopoulou, L. Mager, S. Méry, Functionalization of Biphenylcarbazole (CBP) with Siloxane-Hybrid Chains for Solvent-Free Liquid Materials, Molecules. 27 (2022) 89. https://doi.org/10.3390/molecules27010089.
[1]
M.D. Pichois, X. Henning, M.A. Hurier, M. Vomir, A. Barsella, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photovoltaic and photothermal effects induced by visible laser radiation in atomic force microscopy probes., Ultramicroscopy. 241 (2022) 113601. https://doi.org/10.1016/j.ultramic.2022.113601.
[1]
A. Lipatov, P. Chaudhary, Z. Guan, H. Lu, G. Li, O. Crégut, K.D. Dorkenoo, R. Proksch, S. Cherifi-Hertel, D.-F. Shao, E.Y. Tsymbal, J. Iniguez, A. Sinitskii, A. Gruverman, Direct observation of ferroelectricity in two-dimensional MoS2, NPJ 2D Materials and Applications. 6 (2022) 18. https://doi.org/10.1038/s41699-022-00298-5.
[1]
B. Croes, I. Gaponenko, C. Voulot, O. Grégut, K.D. Dorkenoo, F. Cheynis, S. Curiotto, P. Müller, F. Leroy, K. Cordero-Edwards, P. Paruch, S. Cherifi-Hertel, Automatic Ferroelectric Domain Pattern Recognition Based on the Analysis of Localized Nonlinear Optical Responses Assisted by Machine Learning, Advanced Physics Research. n/a (2022) 2200037. https://doi.org/https://doi.org/10.1002/apxr.202200037.
[1]
M. Yahya, N. Seferoglu, A. Barsella, S. Achelle, Z. Seferoglu, Amino-substituted-1,1-dicyano-2,4-diaryl-1,3-butadiene chromophores: Synthesis and photophysical properties, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy. 248 (2021) 119178. https://doi.org/10.1016/j.saa.2020.119178.
[1]
M. Vignolo, G. Bovone, M. Capra, F. Loria, C. Bernini, B. Vileno, L. Mager, B. Donnio, M. Rastei V., J.-L. Gallani, Magnetism: Another Idiosyncrasy of Boron?, European Journal of Inorganic Chemistry. (2021) 1224–1229. https://doi.org/10.1002/ejic.202001075.
[1]
E.V. Verbitskiy, S. Achelle, F. Bures, P. le Poul, A. Barsella, Y.A. Kvashnin, G.L. Rusinov, F. Robin-le Guen, O.N. Chupakhin, V.N. Charushin, Synthesis, photophysical and nonlinear optical properties of [1,2,5] oxadiazolo[3,4-b]pyrazine-based linear push-pull systems, Journal of Photochemistry and Photobiology A-Chemistry. 404 (2021) 112900. https://doi.org/10.1016/j.jphotochem.2020.112900.
[1]
M.D. Pichois, M.A. Hurier, M. Vomir, A. Barsella, B. Donnio, J.-L. Gallani, M.V. Rastei, Photothermal Plasmonic Actuation of Micromechanical Cantilever Beams, Physical Review Applied. 15 (2021) 034020. https://doi.org/10.1103/PhysRevApplied.15.034020.
[1]
A. Ozarslan, D. Cakmaz, F. Erol, H. Senoz, N. Seferoglu, A. Barsella, Z. Seferoglu, Synthesis and investigation of photophysical, NLO and thermal properties of D-pi-A-pi-D dyes, Journal of Molecular Structure. 1229 (2021) 129583. https://doi.org/10.1016/j.molstruc.2020.129583.
[1]
R.J. Durand, S. Achelle, F. Robin-Le Guen, E. Caytan, N. Le Poul, A. Barsella, P. Guevara Level, D. Jacquemin, S. Gauthier, Investigation of second-order nonlinear optical responses in a series of V-shaped binuclear platinum(ii) complexes, Dalton Transactions. 50 (2021) 4623–4633. https://doi.org/10.1039/d1dt00151e.
[1]
B. Croes, F. Cheynis, Y. Zhang, C. Voulot, K.D. Dorkenoo, S. Cherifi-Hertel, C. Mocuta, M. Texier, T. Cornelius, O. Thomas, M.-I. Richard, P. Müller, S. Curiotto, F. Leroy, Ferroelectric nanodomains in epitaxial GeTe thin films, Physical Review Materials. 5 (2021) 124415. https://doi.org/10.1103/PhysRevMaterials.5.124415.
[1]
K.-R. Choi, D.H. Kim, Y.U. Lee, V. Placide, S. Huynh, D. Yao, G. Canard, E. Zaborova, F. Mathevet, L. Mager, B. Heinrich, J.-C. Ribierre, J.W. Wu, F. Fages, A. D’Aleo, Effect of the electron donating group on the excited-state electronic nature and epsilon-near-zero properties of curcuminoid-borondifluoride dyes, RSC Advances. 11 (2021) 38247–38257. https://doi.org/10.1039/d1ra08025c.
[1]
S. Cherifi-Hertel, C. Voulot, U. Acevedo-Salas, Y. Zhang, O. Crégut, K.D. Dorkenoo, R. Hertel, Shedding light on non-Ising polar domain walls: Insight from second harmonic generation microscopy and polarimetry analysis, Journal of Applied Physics. 129 (2021) 081101. https://doi.org/10.1063/5.0037286.
[1]
S. Achelle, E.V. Verbitskiy, M. Feckova, F. Bures, A. Barsella, F. Robin-le Guen, V-Shaped Methylpyrimidinium Chromophores for Nonlinear Optics, ChemPlusChem. 86 (2021) 758–762. https://doi.org/10.1002/cplu.202100081.
[1]
A.U. Putra, D. Cakmaz, N. Seferoglu, A. Barsella, Z. Seferoglu, Styryl-based new organic chromophores bearing free amino and azomethine groups: synthesis, photophysical, NLO, and thermal properties, Beilstein Journal of Organic Chemistry. 16 (2020) 2282–2296. https://doi.org/10.3762/bjoc.16.189.
[1]
T.N. Moshkina, P. Le Poul, A. Barsella, O. Pytela, F. Bures, F. Robin-Le Guen, S. Achelle, E.V. Nosova, G.N. Lipunova, V.N. Charushin, Electron-Withdrawing Substituted Quinazoline Push-Pull Chromophores: Synthesis, Electrochemical, Photophysical and Second-Order Nonlinear Optical Properties, European Journal of Organic Chemistry. (2020) 5445–5454. https://doi.org/10.1002/ejoc.202000870.
[1]
E. Keles, M. Yahya, E. Aktan, B. Aydiner, N. Seferoglu, A. Barsella, Z. Seferoglu, Indole based push-pull dyes bearing azo and dimethine: Synthesis, spectroscopic, NLO, anion affinity properties and thermal characterization, Journal of Photochemistry and Photobiology A-Chemistry. 402 (2020) 112818. https://doi.org/10.1016/j.jphotochem.2020.112818.
[1]
P. Gosset, G. Taupier, O. Crégut, J. Brazard, Y. Mely, K.-D. Dorkenoo, J. Léonard, P. Didier, Excited-State Proton Transfer in Oxyluciferin and Its Analogues, Journal of Physical Chemistry Letters. 11 (2020) 3653–3659. https://doi.org/10.1021/acs.jpclett.0c00839.
[1]
A. Barsella, M.A. Hurier, M.D. Pichois, M. Vomir, H. Hasan, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photonic Excitation of a Micromechanical Cantilever in Electrostatic Fields, Physical Review Letters. 125 (2020) 254301. https://doi.org/10.1103/PhysRevLett.125.254301.
Emission laser auto-doublée dans un système organique
Etude des propriétés ONL de molécules à transfert de charge
