Nonlinear Microscopy and Patterning of Organic Materials (NOMPOM)

Motivation

Our research is focused on the study of the non linear optical (NLO) properties of organic compounds, from simple molecules to more complex systems (functionalized polymers, organic/inorganic hybrid materials). Our experimental work starts from the fundamental aspects of understanding the mechanisms involved in the NLO properties of such systems up to their applications in the production of integrated optical devices. These interdisciplinary studies are developed in collaboration with theoreticians for the fundamental aspects, chemists for the synthesis of new molecules and biologists for multiphoton microscopy techniques.

Research Activities

Self-doubled laser emission from an organic system

NLO properties of charge transfer molecules

New organics material for electro-optics

Circular dichroism

Self-inscribed waveguides

Laser micromachining

Second-harmonic generation microscopy

Team Members :

Assistant professor, Ultrafast Optics and Nanophotonics (DON)Alberto.Barsella@ipcms.unistra.fr
Phone: +33(0)3 88 10 70 90Office: 2051
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Professor, Ultrafast Optics and Nanophotonics (DON)kdorkeno@ipcms.unistra.fr
Phone: +33(0)3 88 10 71 17, +33(0)3 88 10 71 18Office: 2402
PhD student, Ultrafast Optics and Nanophotonics (DON)aaron.terpstra@ipcms.unistra.fr
Phone: +33(0)3 88 10 70 91Office: 1030
Researcher, Ultrafast Optics and Nanophotonics (DON)Loic.Mager@ipcms.unistra.fr
Phone: +33(0)3 88 10 70 90Office: 2051

Recent publications :

[1]
M. Yahya, N. Seferoglu, G. Kaplan, Y. Nural, A. Barsella, Z. Seferoglu, Synthesis, nonlinear optical properties, photophysical, and theoretical studies of azo dye bearing coumarin-thiophene, Journal of Molecular Structure 1273 (2023) 134257. https://doi.org/10.1016/j.molstruc.2022.134257.
[1]
J. Shaya, J.-C. Ribierre, G. Correia, Y.J. Dappe, F. Mathevet, L. Mager, B. Heinrich, S. Méry, Control of the Organization of 4,4’-bis(carbazole)-1,1’-biphenyl (CBP) Molecular Materials through Siloxane Functionalization., Molecules 28 (2023) 2038. https://doi.org/10.3390/molecules28052038.
[1]
F. Mammadova, F.C. Inyurt, A. Barsella, C. Dengiz, Cyano-rich donor-acceptor-donor-type NLOphores containing dialkylated triazene and aniline groups*, Dyes and Pigments 209 (2023) 110894. https://doi.org/10.1016/j.dyepig.2022.110894.
[1]
U. Acevedo-Salas, B. Croes, Y. Zhang, O. Crégut, K.D. Dorkenoo, B. Kirbus, E. Singh, H. Beccard, M. Rusing, L.M. Eng, R. Hertel, E.A. Eliseev, A.N. Morozovska, S. Cherifi-Hertel, Impact of 3D Curvature on the Polarization Orientation in Non-Ising Domain Walls., Nano Letters 23 (2023) 795–803. https://doi.org/10.1021/acs.nanolett.2c03579.
[1]
C. Weymann, S. Cherifi-Hertel, C. Lichtensteiger, I. Gaponenko, K.D. Dorkenoo, A.B. Naden, P. Paruch, Non-Ising domain walls in $c$-phase ferroelectric lead titanate thin films, Physical Review B 106 (2022) L241404. https://doi.org/10.1103/PhysRevB.106.L241404.
[1]
E.V. Verbitskiy, P. le Poul, F. Bures, S. Achelle, A. Barsella, Y.A. Kvashnin, G.L. Rusinov, V.N. Charushin, Push-Pull Derivatives Based on 2,4’-Biphenylene Linker with Quinoxaline, [1,2,5]Oxadiazolo[3,4-B]Pyrazine and [1,2,5]Thiadiazolo[3,4-B]Pyrazine Electron Withdrawing Parts., Molecules 27 (2022) 4250. https://doi.org/10.3390/molecules27134250.
[1]
J. Shaya, G. Correia, B. Heinrich, J.-C. Ribierre, K. Polychronopoulou, L. Mager, S. Méry, Functionalization of Biphenylcarbazole (CBP) with Siloxane-Hybrid Chains for Solvent-Free Liquid Materials, Molecules 27 (2022) 89. https://doi.org/10.3390/molecules27010089.
[1]
M.D. Pichois, X. Henning, M.A. Hurier, M. Vomir, A. Barsella, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photovoltaic and photothermal effects induced by visible laser radiation in atomic force microscopy probes., Ultramicroscopy 241 (2022) 113601. https://doi.org/10.1016/j.ultramic.2022.113601.
[1]
A. Lipatov, P. Chaudhary, Z. Guan, H. Lu, G. Li, O. Crégut, K.D. Dorkenoo, R. Proksch, S. Cherifi-Hertel, D.-F. Shao, E.Y. Tsymbal, J. Iniguez, A. Sinitskii, A. Gruverman, Direct observation of ferroelectricity in two-dimensional MoS2, NPJ 2D Materials and Applications 6 (2022) 18. https://doi.org/10.1038/s41699-022-00298-5.
[1]
B. Croes, I. Gaponenko, C. Voulot, O. Grégut, K.D. Dorkenoo, F. Cheynis, S. Curiotto, P. Müller, F. Leroy, K. Cordero-Edwards, P. Paruch, S. Cherifi-Hertel, Automatic Ferroelectric Domain Pattern Recognition Based on the Analysis of Localized Nonlinear Optical Responses Assisted by Machine Learning, Advanced Physics Research n/a (2022) 2200037. https://doi.org/https://doi.org/10.1002/apxr.202200037.
[1]
M. Yahya, N. Seferoglu, A. Barsella, S. Achelle, Z. Seferoglu, Amino-substituted-1,1-dicyano-2,4-diaryl-1,3-butadiene chromophores: Synthesis and photophysical properties, Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy 248 (2021) 119178. https://doi.org/10.1016/j.saa.2020.119178.
[1]
M. Vignolo, G. Bovone, M. Capra, F. Loria, C. Bernini, B. Vileno, L. Mager, B. Donnio, M. Rastei V., J.-L. Gallani, Magnetism: Another Idiosyncrasy of Boron?, European Journal of Inorganic Chemistry (2021) 1224–1229. https://doi.org/10.1002/ejic.202001075.
[1]
E.V. Verbitskiy, S. Achelle, F. Bures, P. le Poul, A. Barsella, Y.A. Kvashnin, G.L. Rusinov, F. Robin-le Guen, O.N. Chupakhin, V.N. Charushin, Synthesis, photophysical and nonlinear optical properties of [1,2,5] oxadiazolo[3,4-b]pyrazine-based linear push-pull systems, Journal of Photochemistry and Photobiology A-Chemistry 404 (2021) 112900. https://doi.org/10.1016/j.jphotochem.2020.112900.
[1]
M.D. Pichois, M.A. Hurier, M. Vomir, A. Barsella, B. Donnio, J.-L. Gallani, M.V. Rastei, Photothermal Plasmonic Actuation of Micromechanical Cantilever Beams, Physical Review Applied 15 (2021) 034020. https://doi.org/10.1103/PhysRevApplied.15.034020.
[1]
A. Ozarslan, D. Cakmaz, F. Erol, H. Senoz, N. Seferoglu, A. Barsella, Z. Seferoglu, Synthesis and investigation of photophysical, NLO and thermal properties of D-pi-A-pi-D dyes, Journal of Molecular Structure 1229 (2021) 129583. https://doi.org/10.1016/j.molstruc.2020.129583.
[1]
R.J. Durand, S. Achelle, F. Robin-Le Guen, E. Caytan, N. Le Poul, A. Barsella, P. Guevara Level, D. Jacquemin, S. Gauthier, Investigation of second-order nonlinear optical responses in a series of V-shaped binuclear platinum(ii) complexes, Dalton Transactions 50 (2021) 4623–4633. https://doi.org/10.1039/d1dt00151e.
[1]
B. Croes, F. Cheynis, Y. Zhang, C. Voulot, K.D. Dorkenoo, S. Cherifi-Hertel, C. Mocuta, M. Texier, T. Cornelius, O. Thomas, M.-I. Richard, P. Müller, S. Curiotto, F. Leroy, Ferroelectric nanodomains in epitaxial GeTe thin films, Physical Review Materials 5 (2021) 124415. https://doi.org/10.1103/PhysRevMaterials.5.124415.
[1]
K.-R. Choi, D.H. Kim, Y.U. Lee, V. Placide, S. Huynh, D. Yao, G. Canard, E. Zaborova, F. Mathevet, L. Mager, B. Heinrich, J.-C. Ribierre, J.W. Wu, F. Fages, A. D’Aleo, Effect of the electron donating group on the excited-state electronic nature and epsilon-near-zero properties of curcuminoid-borondifluoride dyes, RSC Advances 11 (2021) 38247–38257. https://doi.org/10.1039/d1ra08025c.
[1]
S. Cherifi-Hertel, C. Voulot, U. Acevedo-Salas, Y. Zhang, O. Crégut, K.D. Dorkenoo, R. Hertel, Shedding light on non-Ising polar domain walls: Insight from second harmonic generation microscopy and polarimetry analysis, Journal of Applied Physics 129 (2021) 081101. https://doi.org/10.1063/5.0037286.
[1]
S. Achelle, E.V. Verbitskiy, M. Feckova, F. Bures, A. Barsella, F. Robin-le Guen, V-Shaped Methylpyrimidinium Chromophores for Nonlinear Optics, ChemPlusChem 86 (2021) 758–762. https://doi.org/10.1002/cplu.202100081.
[1]
A.U. Putra, D. Cakmaz, N. Seferoglu, A. Barsella, Z. Seferoglu, Styryl-based new organic chromophores bearing free amino and azomethine groups: synthesis, photophysical, NLO, and thermal properties, Beilstein Journal of Organic Chemistry 16 (2020) 2282–2296. https://doi.org/10.3762/bjoc.16.189.
[1]
T.N. Moshkina, P. Le Poul, A. Barsella, O. Pytela, F. Bures, F. Robin-Le Guen, S. Achelle, E.V. Nosova, G.N. Lipunova, V.N. Charushin, Electron-Withdrawing Substituted Quinazoline Push-Pull Chromophores: Synthesis, Electrochemical, Photophysical and Second-Order Nonlinear Optical Properties, European Journal of Organic Chemistry (2020) 5445–5454. https://doi.org/10.1002/ejoc.202000870.
[1]
E. Keles, M. Yahya, E. Aktan, B. Aydiner, N. Seferoglu, A. Barsella, Z. Seferoglu, Indole based push-pull dyes bearing azo and dimethine: Synthesis, spectroscopic, NLO, anion affinity properties and thermal characterization, Journal of  Photochemistry and Photobiology A-Chemistry 402 (2020) 112818. https://doi.org/10.1016/j.jphotochem.2020.112818.
[1]
P. Gosset, G. Taupier, O. Crégut, J. Brazard, Y. Mely, K.-D. Dorkenoo, J. Léonard, P. Didier, Excited-State Proton Transfer in Oxyluciferin and Its Analogues, Journal of Physical Chemistry Letters 11 (2020) 3653–3659. https://doi.org/10.1021/acs.jpclett.0c00839.
[1]
A. Barsella, M.A. Hurier, M.D. Pichois, M. Vomir, H. Hasan, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photonic Excitation of a Micromechanical Cantilever in Electrostatic Fields, Physical Review Letters 125 (2020) 254301. https://doi.org/10.1103/PhysRevLett.125.254301.

Self-doubled laser emission from an organic system

NLO properties of charge transfer molecules

New organics material for electro-optics