Parcours de recherche
Depuis déc. 2003 : Chercheur CNRS, IPCMS
Matériaux hybrides multifonctionnels, synthèses, propriétés magnétiques et optiques
Nov. 2002-nov. 2003 : stage post-doctoral, Dipartimento di Chimica “G. Ciamician”, Gruppo di Fotochimica e Chimica Supramolecolare, Universita di Bologna, Italie
Etudes photochimiques de “machines moléculaires”
Resp. : Vincenzo Balzani, Alberto Credi, Maria-Teresa Gandolfi
Sept. 1999-oct. 2002 : doctorat, Laboratoire de Chimie Inorganique, Institut de Chimie Moléculaire et des Matériaux d’Orsay
Synthèse et études de systèmes moléculaires magnétiques : molécules à haut spin et anisotropie magnétique. Synthèse de systèmes polymétalliques, études de caractéristiques spectroscopiques et magnétiques. Étude de l’anisotropie magnétique de complexes de NiII
Directeur de thèse : Talal Mallah
Parcours universitaire
2014 : Habilitation à diriger des recherches (soutenue le 1er juillet 2014)
“Des briques moléculaires aux matériaux hybrides multifonctionnels”
Jury : B. Doudin (rapporteur), M. Drillon, F. Leroux (rapporteur), Y. Journaux (rapporteur), M. Maglione, P. Rabu (garant), C. Sanchez (président)
2002 : Thèse de doctorat en Chimie Inorganique (soutenue le 21 octobre 2002)
“Modulation des propriétés électroniques et de l’anisotropie magnétique de complexes mono et polynucléaires: influence des ligands pontants et périphériques”
Jury : D. Astruc (rapporteur), M. Drillon (rapporteur), D. Gatteschi, J.-J. Girerd (président), M. Julve, T. Mallah (directeur de thèse)
1999 : DEA de Chimie Inorganique
Universités Paris XI, Paris VI et Versailles St-Quentin, ESPCI et ENSCP
1998 : Agrégation de Sciences Physiques option Chimie
Liens intéressants
Recherches actuelles
- Matériaux hybrides lamellaires (multi)fonctionnels :
Hydroxydes Simples Lamellaires
Oxydes lamellaires - Nouvelles méthodes de fonctionnalisation de matériaux lamellaires :
Préfonctionalisation
Chimie micro-onde
Chimie in situ (réactions confinées dans l’espace interlamellaire) - Exfoliation et réassemblage dirigé
- Chimie de coordination
- Propriétés magnétiques de composés hybrides et moléculaires
Projets en cours
2021-2025: Projet ITI QMat
“Confined synthetic approaches to layered multifunctional heterostructures and 2D magnets” (2Dconfined)
2019-2022: Projet IDEX “Attractivité”
“Functionalized oxide nanosheets : new platforms for directed assembly of multifunctional hybrid materials and films”
2019-2023: Projet ANR
“Structured CAtalysts in Layered HYdroxide materials for selective CO2 electroreduction reaction” (CALHYCO2). Coordinatrice : Sylvie Chardon (DCM, Grenoble), autre partenaire : Christine Mousty (ICCF, Clermont-Ferrand)
Principales collaborations
François Schosseler, Institut Charles Sadron, Strasbourg
Sylvie Choua, Sylvie Ferlay, Marine Desage-El Murr, Romain Ruppert, Institut de Chimie de Strasbourg
Thomas Ebbesen, Institut de Science et d’Ingénierie Supramoléculaires, Strasbourg
Sylvie Chardon, Cyrille Costentin, Département de Chimie Moléculaire, Grenoble
Pierre Bonnet, Fabrice Leroux, Christine Mousty, Vanessa Prévot, Christine Taviot-Guého, Institut de Chimie de Clermont-Ferrand
Clément Sanchez, Laboratoire de Chimie de la Matière Condensée, Paris
Nicolas Barrier, Alain Pautrat, Olivier Pérez, Jean-Michel Rueff, Laboratoire Cristallographie et Matériaux, Caen
Paul-Alain Jaffrès, Laboratoire Chimie Electrochimie Moléculaires et Chimie Analytique, Brest
Emilie Delahaye, Laboratoire de Chimie de Coordination, Toulouse
Vadapalli Chandrasekhar, Tata Institute of Fundamental Research, Hyderabad, Inde
Publications
[1]
Y. Wang, C. Leuvrey, E. Delahaye, F. Leroux, P. Rabu, C. Taviot-Gueho, G. Rogez, Tuning the organization of the interlayer organic moiety in a hybrid layered perovskite, Journal of Solid State Chemistry. 269 (2019) 532–539. https://doi.org/10.1016/j.jssc.2018.10.034.
[1]
Y. Wang, M. Nikolopoulou, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Microwave-assisted functionalization of the Aurivillius phase Bi2SrTa2O9: diol grafting and amine insertion vs. alcohol grafting, Chemical Science. 9 (2018) 7104–7114. https://doi.org/10.1039/c8sc01754a.
[1]
Y. Wang, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Post-Synthesis Modification of the Aurivillius Phase Bi2SrTa2O9 via In Situ Microwave-Assisted “Click Reaction,” Inorganic Chemistry. 55 (2016) 9790–9797. https://doi.org/10.1021/acs.inorgchem.6b01600.
[1]
Y. Wang, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Efficient Microwave-Assisted Functionalization of the Aurivillius-Phase Bi2SrTa2O9, Inorganic Chemistry. 55 (2016) 4039–4046. https://doi.org/10.1021/acs.inorgchem.6b00338.
[1]
H. Ullah, N. Batisse, K. Guerin, G. Rogez, P. Bonnet, Synthesis of NiF2 and NiF2 center dot 4H(2)O Nanoparticles by Microemulsion and Their Self-Assembly, Langmuir. 36 (2020) 8461–8475. https://doi.org/10.1021/acs.langmuir.0c00889.
[1]
A. Thomas, E. Devaux, K. Nagarajan, G. Rogez, M. Seidel, F. Richard, C. Genet, M. Drillon, T.W. Ebbesen, Large Enhancement of Ferromagnetism under a Collective Strong Coupling of YBCO Nanoparticles, Nano Letters. 21 (2021) 4365–4370. https://doi.org/10.1021/acs.nanolett.1c00973.
[1]
E. Terazzi, T.B. Jensen, B. Donnio, K. Buchwalder, C. Bourgogne, G. Rogez, B. Heinrich, J.-L. Gallani, C. Piguet, Control of the transition temperatures of metallomesogens by specific interface design: application to Mn-12 single molecule magnets, Dalton Transactions. 40 (2011) 12028–12032. https://doi.org/10.1039/c1dt10908a.
[1]
E. Terazzi, G. Rogez, J.L. Gallani, B. Donnio, Supramolecular Organization and Magnetic Properties of Mesogen-Hybridized Mixed-Valent Manganese Single Molecule Magnets (Mn8Mn4O12)-Mn-III-O-IV(L-x,L-y,L-z-CB)(16)(H2O)(4), Journal of the American Chemical Society. 135 (2013) 2708–2722. https://doi.org/10.1021/ja311190a.
[1]
A. Tarhini, J. Aguirre-Araque, M. Guyot, C. Costentin, G. Rogez, S. Chardon-Noblat, V. Prevot, C. Mousty, Behavior of Iron Tetraphenylsulfonato Porphyrin Intercalated into LDH and LSH as Materials for Electrocatalytic Applications, Electrocatalysis. 14 (2022) 111–120. https://doi.org/10.1007/s12678-022-00778-8.
[1]
N. Suaud, G. Rogez, J.-N. Rebilly, M.-A. Bouammali, N. Guihery, A.-L. Barra, T. Mallah, Playing with Magnetic Anisotropy in Hexacoordinated Mononuclear Ni(II) Complexes, An Interplay Between Symmetry and Geometry, Applied Magnetic Resonance. (2020). https://doi.org/10.1007/s00723-020-01228-8.
[1]
A.R. Stefankiewicz, G. Rogez, J. Harrowfield, A.N. Sobolev, A. Madalan, J. Huuskonen, K. Rissanen, J.-M. Lehn, Self-ordering of metallogrid complexes via directed hydrogen-bonding, Dalton Transactions. 41 (2012) 13848–13855. https://doi.org/10.1039/c2dt31384g.
[1]
S. Si, A. Taubert, A. Mantion, G. Rogez, P. Rabu, Peptide-intercalated layered metal hydroxides: effect of peptide chain length and side chain functionality on structural, optical and magnetic properties, Chemical Science. 3 (2012) 1945–1957. https://doi.org/10.1039/c2sc01087a.
[1]
R. Sen, D. Saha, D. Mal, P. Brandao, G. Rogez, Z. Lin, Synthesis, Structural Aspects and Catalytic Performance of a Tetrahedral Cobalt Phosphonate Framework, European Journal of Inorganic Chemistry. 2013 (2013) 5020–5026. https://doi.org/10.1002/ejic.201300639.
[1]
R. Sen, D. Mal, P. Brandao, G. Rogez, Z. Lin, Synthesis, characterization and observation of structural diversities in a series of transition metal based furan dicarboxylic acid systems, CrystEngComm. 15 (2013) 2113–2119. https://doi.org/10.1039/c3ce26306a.
[1]
R. Sen, D. Saha, D. Mal, P. Brandao, G. Rogez, Z. Lin, A 2D -> 3D Polycatenated Metal-Organic Framework: Synthesis, Structure, Magnetic and Catalytic Study, European Journal of Inorganic Chemistry. (2013) 3076–3081. https://doi.org/10.1002/ejic.201300123.
[1]
B. Schneiderova, J. Demel, J. Plestil, P. Janda, J. Bohuslav, D. Ihiawakrim, O. Ersen, G. Rogez, K. Lang, Nickel hydroxide ultrathin nanosheets as building blocks for electrochemically active layers, Journal of Materials Chemistry A. 1 (2013) 11429–11437. https://doi.org/10.1039/c3ta12129a.
[1]
D. Sarma, P. Mahata, S. Natarajan, P. Panissod, G. Rogez, M. Drillon, Synthesis, Structure, and Magnetic Properties of a New Eight-Connected Metal-Organic Framework (MOF) based on Co-4 Clusters, Inorganic Chemistry. 51 (2012) 4495–4501. https://doi.org/10.1021/ic2020989.
[1]
G. Rogez, C. Massobrio, P. Rabu, M. Drillon, Layered hydroxide hybrid nanostructures: a route to multifunctionality, Chemical Society Reviews. 40 (2011) 1031–1058. https://doi.org/10.1039/c0cs00159g.
[1]
M. Roger, C. Bloyet, Q. Evrard, H. Couthon-Gourves, M. Berchel, J.-M. Rueff, O. Perez, G. Rogez, P.-A. Jaffres, Rigid phosphonic acid for the construction of crystalline organic-inorganic hybrid materials, Phosphorus Sulfur and Silicon and the Related Elements. 191 (2016) 1482–1484. https://doi.org/10.1080/10426507.2016.1212048.
[1]
P. Rabu, E. Delahaye, G. Rogez, Hybrid interfaces in layered hydroxides: magnetic and multifunctional superstructures by design, Nanotechnology Reviews. 4 (2015) 557–580. https://doi.org/10.1515/ntrev-2015-0017.
[1]
Y. Prado, L. Lisnard, D. Heurtaux, G. Rogez, A. Gloter, O. Stephan, N. Dia, E. Riviere, L. Catala, T. Mallah, Tailored coordination nanoparticles: assessing the magnetic single-domain critical size, Chemical Communications. 47 (2011) 1051–1053. https://doi.org/10.1039/c0cc03382k.
[1]
Y. Prado, N. Dia, L. Lisnard, G. Rogez, F. Brisset, L. Catala, T. Mallah, Tuning the magnetic anisotropy in coordination nanoparticles: random distribution versus core-shell architecture, Chemical Communications. 48 (2012) 11455–11457. https://doi.org/10.1039/c2cc35929d.
[1]
Y. Prado, S. Mazerat, E. Riviere, G. Rogez, A. Gloter, O. Stephan, L. Catala, T. Mallah, Magnetization Reversal in (CsNiCrIII)-Cr-II(CN)(6) Coordination Nanoparticles: Unravelling Surface Anisotropy and Dipolar Interaction Effects, Advanced Functional Materials. 24 (2014) 5402–5411. https://doi.org/10.1002/adfm.201400741.
[1]
D. Pogozhev, S.A. Baudron, G. Rogez, M.W. Hosseini, From discrete tricyanovinylene appended 7-azaindole copper(II) paddlewheel to an infinite ID network: Synthesis, crystal structure and magnetic properties, Polyhedron. 52 (2013) 1329–1335. https://doi.org/10.1016/j.poly.2012.06.009.
[1]
F. Payet, C. Bouillet, F. Leroux, C. Leuvrey, P. Rabu, F. Schosseler, C. Taviot-Guého, G. Rogez, Fast and efficient shear-force assisted production of covalently functionalized oxide nanosheets, Journal of Colloid and Interface Science. 607 (2022) 621–632. https://doi.org/10.1016/j.jcis.2021.08.213.
[1]
O. Palamarciuc, E. Delahaye, P. Rabu, G. Rogez, Microwave-assisted post-synthesis modification of layered simple hydroxides, New Journal of Chemistry. 38 (2014) 2016–2023. https://doi.org/10.1039/C3NJ01231J.
[1]
A. Nano, L. Brelot, G. Rogez, A. Maisse-Francois, S. Bellemin-Laponnaz, Ditopic bis(oxazolines): Synthesis and structural studies of zinc(II), copper(II) and nickel(II) complexes, Inorganica Chimica Acta. 376 (2011) 285–289. https://doi.org/10.1016/j.ica.2011.06.029.
[1]
T. Miyamachi, M. Gruber, V. Davesne, M. Bowen, S. Boukari, L. Joly, F. Scheurer, G. Rogez, T.K. Yamada, P. Ohresser, E. Beaurepaire, W. Wulfhekel, Robust spin crossover and memristance across a single molecule, Nature Communications. 3 (2012) 938. https://doi.org/10.1038/ncomms1940.
[1]
L. Mathivathanan, G. Rogez, N. Ben Amor, V. Robert, R.G. Raptis, A.K. Boudalis, Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles, Chemistry-a European Journal. 26 (2020) 1–17. https://doi.org/10.1002/chem.202001028.
[1]
A. Massard, G. Rogez, P. Braunstein, Synthesis and characterization of a new nonanuclear Ni(II) cluster from a pyridyl-alcohol ligand, Dalton Transactions. 43 (2014) 42–46. https://doi.org/10.1039/c3dt52744a.
[1]
A.M. Madalan, X.-Y. Cao, G. Rogez, J.-M. Lehn, Ferromagnetic Coupling in Copper(II) [2 x 2] Grid-like Complexes, Inorganic Chemistry. 53 (2014) 4275–4277. https://doi.org/10.1021/ic500285m.
[1]
M. Lang, E. Delahaye, D. Foix, D. Ihiawakrim, O. Ersen, C. Leuvrey, J.-M. Greneche, G. Rogez, P. Rabu, Pseudomorphic Transformation of Layered Simple Hydroxides into Prussian Blue Analogue Nanoplatelets, European Journal of Inorganic Chemistry. (2016) 2030–2038. https://doi.org/10.1002/ejic.201501338.
[1]
M.A.A. Kerroum, C. Iacovita, W. Baaziz, D. Ihiawakrim, G. Rogez, M. Benaissa, C.M. Lucaciu, O. Ersen, Quantitative Analysis of the Specific Absorption Rate Dependence on the Magnetic Field Strength in ZnxFe3-xO4 Nanoparticles, International Journal of Molecular Sciences. 21 (2020) 7775. https://doi.org/10.3390/ijms21207775.
[1]
S. Kartal, G. Rogez, J. Robert, B. Heinrich, A.K. Boudalis, A Magnetocaloric Glass from an Ionic-Liquid Gadolinium Complex, ChemPhysChem. 23 (2022) e202200213. https://doi.org/https://doi.org/10.1002/cphc.202200213.
[1]
B. Joarder, A.K. Chaudhari, G. Rogez, S.K. Ghosh, A carboxylate-based dinuclear dysprosium(III) cluster exhibiting slow magnetic relaxation behaviour, Dalton Transactions. 41 (2012) 7695–7699. https://doi.org/10.1039/c2dt30643c.
[1]
N. Hugot, M. Roger, J.-M. Rueff, J. Cardin, O. Perez, V. Caignaert, B. Raveau, G. Rogez, P.-A. Jaffres, Copper-Fluorenephosphonate Cu(PO3-C13H9)center dot H2O: A Layered Antiferromagnetic Hybrid, European Journal of Inorganic Chemistry. (2016) 266–271. https://doi.org/10.1002/ejic.201501041.
[1]
S. Hameury, L. Kayser, R. Pattacini, G. Rogez, W. Wernsdorfer, P. Braunstein, Synthesis of cubane-type Ni(II) complexes from pyridyl-alcohol ligands; their single-molecule magnet behaviour, Dalton Transactions. 42 (2013) 5013–5024. https://doi.org/10.1039/c3dt32869d.
[1]
M. Guyot, M.-N. Lalloz, J.S. Aguirre-Araque, G. Rogez, C. Costentin, S. Chardon-Noblat, Rhenium Carbonyl Molecular Catalysts for CO2 Electroreduction: Effects on Catalysis of Bipyridine Substituents Mimicking Anchorage Functions to Modify Electrodes, Inorganic Chemistry. 61 (2022) 16072–16080. https://doi.org/10.1021/acs.inorgchem.2c02473.
[1]
J. Goura, G. Rogez, E. Rivière, V. Chandrasekhar, Hexanuclear, Heterometallic, Ni3Ln3 Complexes Possessing O-Capped Homo- and Heterometallic Structural Subunits: SMM Behavior of the Dysprosium Analogue, Inorganic Chemistry. 53 (2014) 7815–7823. https://doi.org/10.1021/ic403090z.
[1]
P. Farger, C. Leuvrey, G. Rogez, M. Francois, P. Rabu, E. Delahay, Salts and Solvents Effect on the Crystal Structure of Imidazolium Dicarboxylate Salt Based Coordination Networks, Crystal Growth & Design. 19 (2019) 4264–4272. https://doi.org/10.1021/acs.cgd.8b01725.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, J. Rocha, D. Ananias, P. Rabu, E. Delahaye, Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry, Beilstein Journal of Nanotechnology. 9 (2018) 2775–2787. https://doi.org/10.3762/bjnano.9.259.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, P. Rabu, E. Delahaye, Elaboration of Luminescent and Magnetic Hybrid Networks Based on Lanthanide Ions and Imidazolium Dicarboxylate Salts: Influence of the Synthesis Conditions, Magnetochemistry. 3 (2017) 1. https://doi.org/10.3390/magnetochemistry3010001.
[1]
P. Farger, R. Guillot, F. Leroux, N. Parizel, M. Gallart, P. Gilliot, G. Rogez, E. Delahaye, P. Rabu, Imidazolium Dicarboxylate Based Metal-Organic Frameworks Obtained by Solvo-Ionothermal Reaction, European Journal of Inorganic Chemistry. (2015) 5342–5350. https://doi.org/10.1002/ejic.201500825.
[1]
S. Eyele-Mezui, P. Vialat, C. Higy, R. Bourzami, C. Leuvrey, N. Parizel, P. Turek, P. Rabu, G. Rogez, C. Mousty, Electrocatalytic Properties of Metal Phthalocyanine Tetrasulfonate Intercalated in Metal Layered Simple Hydroxides (Metal: Co, Cu, and Zn), Journal of Physical Chemistry C. 119 (2015) 13335–13342. https://doi.org/10.1021/acs.jpcc.5b02985.
[1]
S. Eyele-Mezui, E. Delahaye, G. Rogez, P. Rabu, Functional Hybrid Materials Based on Layered Simple Hydroxide Hosts and Dicarboxylate Schiff Base Metal Complex Guests, European Journal of Inorganic Chemistry. (2012) 5225–5238. https://doi.org/10.1002/ejic.201200695.
[1]
Q. Evrard, C. Leuvrey, P. Farger, E. Delahaye, P. Rabu, G. Taupier, K.D. Dorkenoo, J.-M. Rueff, N. Barrier, O. Perez, G. Rogez, Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu-2(OH)(3)(C12H25SO4), Crystal Growth & Design. 18 (2018) 1809–1817. https://doi.org/10.1021/acs.cgd.7601692.
[1]
Q. Evrard, Z. Chaker, M. Roger, C.M. Sevrain, E. Delahaye, M. Gallart, P. Gilliot, C. Leuvrey, J.-M. Rueff, P. Rabu, C. Massobrio, M. Boero, A. Pautrat, P.-A. Jaffrès, G. Ori, G. Rogez, Layered Simple Hydroxides Functionalized by Fluorene-Phosphonic Acids: Synthesis, Interface Theoretical Insights, and Magnetoelectric Effect, Advanced Functional Materials. 27 (2017) 1703576. https://doi.org/10.1002/adfm.201703576.
[1]
H. El Moll, A. Dolbecq, J. Marrot, G. Rousseau, M. Haouas, F. Taulelle, G. Rogez, W. Wernsdorfer, B. Keita, P. Mialane, A Stable Hybrid Bisphosphonate Polyoxometalate Single-Molecule Magnet, Chemistry-a European Journal. 18 (2012) 3845–3849. https://doi.org/10.1002/chem.201200140.
[1]
M. Dolai, H.A. Molla, G. Rogez, M. Ali, Two [Mn-3(mu(3)-O)(7+) based Single Chain Magnets with different solvent ligation, Polyhedron. 127 (2017) 248–256. https://doi.org/10.1016/j.poly.2017.01.043.
[1]
M. Dolai, T. Mistri, S. Biswas, G. Rogez, M. Ali, Solvent-Dependent Oxime-Azide and Oxime-Nitrile Coupling: Crystallographic and Catalytic Studies, ChemPlusChem. 79 (2014) 1649–1656. https://doi.org/10.1002/cplu.201402178.