Guillaume ROGEZ

Guillaume ROGEZ

Senior Researcher, Inorganic Materials Chemistry (DCMI)Guillaume.Rogez@ipcms.unistra.fr
Phone: +33(0)3 88 10 72 95, +33(0)3 88 10 71 96Office: 2012

Research background

Since Dec. 2003 : CNRS Researcher, IPCMS
Multifunctional Hybrid Materials, syntheses, optical and magnetic properties

Nov. 2002-Nov. 2003 : Post-doctoral internship, Dipartimento di Chimica “G. Ciamician”, Gruppo di Fotochimica e Chimica Supramolecolare, Universita di Bologna, Italy
Photochemical studies of “molecular machines”
Supervisors : Vincenzo Balzani, Alberto Credi, Maria-Teresa Gandolfi

Sept. 1999-Oct. 2002 : PhD, Laboratoire de Chimie Inorganique, Institut de Chimie Moléculaire et des Matériaux d’Orsay
Syntheses and studies of magnetic molecular systems : high-spin molecules and magnetic anisotropy. Synthesis of polymetallic systems, spectroscopic and magnetic characterizations. Study of the magnetic anisotropy of NiII complexes.
PhD supervisor : Talal Mallah

Academic background

2014 : Habilitation (defended on July 1st 2014)
“From molecular bricks to multifunctional hybrid materials”
Jury : B. Doudin (rapporteur), M. Drillon, F. Leroux (rapporteur), Y. Journaux (rapporteur), M. Maglione, P. Rabu (garant), C. Sanchez (president)

2002 : PhD in Inorganic Chemistry (defended on October 21st 2002)
“Modulation of the electronic properties and of the magnetic anisotropy of mono and polynuclear complexes : influence of bridging and peripheral ligands”
Jury : D. Astruc (rapporteur), M. Drillon (rapporteur), D. Gatteschi, J.-J. Girerd (president), M. Julve, T. Mallah (PhD supervisor)

1999 : Master in Inorganic Chemistry
Universities Paris XI, Paris VI and Versailles St-Quentin, ESPCI and ENSCP

1998 : “Agrégation” in Physics, major in Chemistry

Interesting links

Division Chimie du Solide de la Société Chimique de France
Association Française de Magnétisme Moléculaire
Association Française de Magnétisme Moléculaire
Réseau francophone de magnétométrie
Groupe Français d’Etude des Composés d’Insertion

Current researches

  • (Multi)functional layered hybrid materials :
    Layered Simple Hydroxides
    Layered oxides
  • New methods to functionalize layered materials :
    Pre-functionalization
    Microwave-assisted chemistry
    In situ reactions (confined in the interlayer spacing)
  • Exfoliation and directed reassembly
  • Coordination chemistry
  • Magnetic properties of hybrid and molecular compounds

Ongoing projects

2021-2025: ITI QMat
“Confined synthetic approaches to layered multifunctional heterostructures and 2D magnets” (2Dconfined)

2019-2022: IDEX “Attractivité”
“Functionalized oxide nanosheets : new platforms for directed assembly of multifunctional hybrid materials and films”

2019-2023: ANR
“Structured CAtalysts in Layered HYdroxide materials for selective CO2 electroreduction reaction” (CALHYCO2). Coordinator : Sylvie Chardon (DCM, Grenoble), other partner : Christine Mousty (ICCF, Clermont-Ferrand)

Principal collaborations

François Schosseler, Institut Charles Sadron, Strasbourg

Sylvie Choua, Sylvie Ferlay, Marine Desage-El Murr, Romain Ruppert, Institut de Chimie de Strasbourg

Thomas Ebbesen, Institut de Science et d’Ingénierie Supramoléculaires, Strasbourg

Sylvie Chardon, Cyrille Costentin, Département de Chimie Moléculaire, Grenoble

Pierre Bonnet, Fabrice Leroux, Christine Mousty, Vanessa Prévot, Christine Taviot-Guého, Institut de Chimie de Clermont-Ferrand

Clément Sanchez, Laboratoire de Chimie de la Matière Condensée, Paris

Nicolas Barrier, Alain Pautrat, Olivier Pérez, Jean-Michel Rueff, Laboratoire Cristallographie et Matériaux, Caen

Paul-Alain Jaffrès, Laboratoire Chimie Electrochimie Moléculaires et Chimie Analytique, Brest

Emilie Delahaye, Laboratoire de Chimie de Coordination, Toulouse

Vadapalli Chandrasekhar, Tata Institute of Fundamental Research, Hyderabad, Inde

Publications

Full publication list (PDF)Télécharger
[1]
Y. Wang, C. Leuvrey, E. Delahaye, F. Leroux, P. Rabu, C. Taviot-Gueho, G. Rogez, Tuning the organization of the interlayer organic moiety in a hybrid layered perovskite, Journal of Solid State Chemistry 269 (2019) 532–539. https://doi.org/10.1016/j.jssc.2018.10.034.
[1]
Y. Wang, M. Nikolopoulou, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Microwave-assisted functionalization of the Aurivillius phase Bi2SrTa2O9: diol grafting and amine insertion vs. alcohol grafting, Chemical Science 9 (2018) 7104–7114. https://doi.org/10.1039/c8sc01754a.
[1]
Y. Wang, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Post-Synthesis Modification of the Aurivillius Phase Bi2SrTa2O9 via In Situ Microwave-Assisted “Click Reaction,” Inorganic Chemistry 55 (2016) 9790–9797. https://doi.org/10.1021/acs.inorgchem.6b01600.
[1]
Y. Wang, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Efficient Microwave-Assisted Functionalization of the Aurivillius-Phase Bi2SrTa2O9, Inorganic Chemistry 55 (2016) 4039–4046. https://doi.org/10.1021/acs.inorgchem.6b00338.
[1]
H. Ullah, N. Batisse, K. Guerin, G. Rogez, P. Bonnet, Synthesis of NiF2 and NiF2 center dot 4H(2)O Nanoparticles by Microemulsion and Their Self-Assembly, Langmuir 36 (2020) 8461–8475. https://doi.org/10.1021/acs.langmuir.0c00889.
[1]
A. Thomas, E. Devaux, K. Nagarajan, G. Rogez, M. Seidel, F. Richard, C. Genet, M. Drillon, T.W. Ebbesen, Large Enhancement of Ferromagnetism under a Collective Strong Coupling of YBCO Nanoparticles, Nano Letters 21 (2021) 4365–4370. https://doi.org/10.1021/acs.nanolett.1c00973.
[1]
E. Terazzi, T.B. Jensen, B. Donnio, K. Buchwalder, C. Bourgogne, G. Rogez, B. Heinrich, J.-L. Gallani, C. Piguet, Control of the transition temperatures of metallomesogens by specific interface design: application to Mn-12 single molecule magnets, Dalton Transactions 40 (2011) 12028–12032. https://doi.org/10.1039/c1dt10908a.
[1]
E. Terazzi, G. Rogez, J.L. Gallani, B. Donnio, Supramolecular Organization and Magnetic Properties of Mesogen-Hybridized Mixed-Valent Manganese Single Molecule Magnets (Mn8Mn4O12)-Mn-III-O-IV(L-x,L-y,L-z-CB)(16)(H2O)(4), Journal of the American Chemical Society 135 (2013) 2708–2722. https://doi.org/10.1021/ja311190a.
[1]
A. Tarhini, J. Aguirre-Araque, M. Guyot, C. Costentin, G. Rogez, S. Chardon-Noblat, V. Prevot, C. Mousty, Behavior of Iron Tetraphenylsulfonato Porphyrin Intercalated into LDH and LSH as Materials for Electrocatalytic Applications, Electrocatalysis 14 (2022) 111–120. https://doi.org/10.1007/s12678-022-00778-8.
[1]
N. Suaud, G. Rogez, J.-N. Rebilly, M.-A. Bouammali, N. Guihery, A.-L. Barra, T. Mallah, Playing with Magnetic Anisotropy in Hexacoordinated Mononuclear Ni(II) Complexes, An Interplay Between Symmetry and Geometry, Applied Magnetic Resonance (2020). https://doi.org/10.1007/s00723-020-01228-8.
[1]
A.R. Stefankiewicz, G. Rogez, J. Harrowfield, A.N. Sobolev, A. Madalan, J. Huuskonen, K. Rissanen, J.-M. Lehn, Self-ordering of metallogrid complexes via directed hydrogen-bonding, Dalton Transactions 41 (2012) 13848–13855. https://doi.org/10.1039/c2dt31384g.
[1]
S. Si, A. Taubert, A. Mantion, G. Rogez, P. Rabu, Peptide-intercalated layered metal hydroxides: effect of peptide chain length and side chain functionality on structural, optical and magnetic properties, Chemical Science 3 (2012) 1945–1957. https://doi.org/10.1039/c2sc01087a.
[1]
R. Sen, D. Saha, D. Mal, P. Brandao, G. Rogez, Z. Lin, Synthesis, Structural Aspects and Catalytic Performance of a Tetrahedral Cobalt Phosphonate Framework, European Journal of Inorganic Chemistry 2013 (2013) 5020–5026. https://doi.org/10.1002/ejic.201300639.
[1]
R. Sen, D. Mal, P. Brandao, G. Rogez, Z. Lin, Synthesis, characterization and observation of structural diversities in a series of transition metal based furan dicarboxylic acid systems, CrystEngComm 15 (2013) 2113–2119. https://doi.org/10.1039/c3ce26306a.
[1]
R. Sen, D. Saha, D. Mal, P. Brandao, G. Rogez, Z. Lin, A 2D -> 3D Polycatenated Metal-Organic Framework: Synthesis, Structure, Magnetic and Catalytic Study, European Journal of Inorganic Chemistry (2013) 3076–3081. https://doi.org/10.1002/ejic.201300123.
[1]
B. Schneiderova, J. Demel, J. Plestil, P. Janda, J. Bohuslav, D. Ihiawakrim, O. Ersen, G. Rogez, K. Lang, Nickel hydroxide ultrathin nanosheets as building blocks for electrochemically active layers, Journal of Materials Chemistry A 1 (2013) 11429–11437. https://doi.org/10.1039/c3ta12129a.
[1]
D. Sarma, P. Mahata, S. Natarajan, P. Panissod, G. Rogez, M. Drillon, Synthesis, Structure, and Magnetic Properties of a New Eight-Connected Metal-Organic Framework (MOF) based on Co-4 Clusters, Inorganic Chemistry 51 (2012) 4495–4501. https://doi.org/10.1021/ic2020989.
[1]
G. Rogez, C. Massobrio, P. Rabu, M. Drillon, Layered hydroxide hybrid nanostructures: a route to multifunctionality, Chemical Society Reviews 40 (2011) 1031–1058. https://doi.org/10.1039/c0cs00159g.
[1]
M. Roger, C. Bloyet, Q. Evrard, H. Couthon-Gourves, M. Berchel, J.-M. Rueff, O. Perez, G. Rogez, P.-A. Jaffres, Rigid phosphonic acid for the construction of crystalline organic-inorganic hybrid materials, Phosphorus Sulfur and Silicon and the Related Elements 191 (2016) 1482–1484. https://doi.org/10.1080/10426507.2016.1212048.
[1]
P. Rabu, E. Delahaye, G. Rogez, Hybrid interfaces in layered hydroxides: magnetic and multifunctional superstructures by design, Nanotechnology Reviews 4 (2015) 557–580. https://doi.org/10.1515/ntrev-2015-0017.
[1]
Y. Prado, L. Lisnard, D. Heurtaux, G. Rogez, A. Gloter, O. Stephan, N. Dia, E. Riviere, L. Catala, T. Mallah, Tailored coordination nanoparticles: assessing the magnetic single-domain critical size, Chemical Communications 47 (2011) 1051–1053. https://doi.org/10.1039/c0cc03382k.
[1]
Y. Prado, N. Dia, L. Lisnard, G. Rogez, F. Brisset, L. Catala, T. Mallah, Tuning the magnetic anisotropy in coordination nanoparticles: random distribution versus core-shell architecture, Chemical Communications 48 (2012) 11455–11457. https://doi.org/10.1039/c2cc35929d.
[1]
Y. Prado, S. Mazerat, E. Riviere, G. Rogez, A. Gloter, O. Stephan, L. Catala, T. Mallah, Magnetization Reversal in (CsNiCrIII)-Cr-II(CN)(6) Coordination Nanoparticles: Unravelling Surface Anisotropy and Dipolar Interaction Effects, Advanced Functional Materials 24 (2014) 5402–5411. https://doi.org/10.1002/adfm.201400741.
[1]
D. Pogozhev, S.A. Baudron, G. Rogez, M.W. Hosseini, From discrete tricyanovinylene appended 7-azaindole copper(II) paddlewheel to an infinite ID network: Synthesis, crystal structure and magnetic properties, Polyhedron 52 (2013) 1329–1335. https://doi.org/10.1016/j.poly.2012.06.009.
[1]
F. Payet, C. Bouillet, F. Leroux, C. Leuvrey, P. Rabu, F. Schosseler, C. Taviot-Guého, G. Rogez, Fast and efficient shear-force assisted production of covalently functionalized oxide nanosheets, Journal of Colloid and Interface Science 607 (2022) 621–632. https://doi.org/10.1016/j.jcis.2021.08.213.
[1]
O. Palamarciuc, E. Delahaye, P. Rabu, G. Rogez, Microwave-assisted post-synthesis modification of layered simple hydroxides, New Journal of Chemistry 38 (2014) 2016–2023. https://doi.org/10.1039/C3NJ01231J.
[1]
A. Pakalniškis, G. Niaura, R. Ramanauskas, D. Karpinsky, G. Rogez, M. Lenertz, J. Robert, P. Rabu, S.-W. Chen, T.C.-K. Yang, R. Skaudžius, A. Kareiva, Temperature-driven magnetic and structural transitions in multiferroic Lu(1-x)ScxFeO3, Journal of Alloys and Compounds 972 (2024) 172805. https://doi.org/https://doi.org/10.1016/j.jallcom.2023.172805.
[1]
A. Nano, L. Brelot, G. Rogez, A. Maisse-Francois, S. Bellemin-Laponnaz, Ditopic bis(oxazolines): Synthesis and structural studies of zinc(II), copper(II) and nickel(II) complexes, Inorganica Chimica Acta 376 (2011) 285–289. https://doi.org/10.1016/j.ica.2011.06.029.
[1]
T. Miyamachi, M. Gruber, V. Davesne, M. Bowen, S. Boukari, L. Joly, F. Scheurer, G. Rogez, T.K. Yamada, P. Ohresser, E. Beaurepaire, W. Wulfhekel, Robust spin crossover and memristance across a single molecule, Nature Communications 3 (2012) 938. https://doi.org/10.1038/ncomms1940.
[1]
L. Mathivathanan, G. Rogez, N. Ben Amor, V. Robert, R.G. Raptis, A.K. Boudalis, Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles, Chemistry-a European Journal 26 (2020) 1–17. https://doi.org/10.1002/chem.202001028.
[1]
A. Massard, G. Rogez, P. Braunstein, Synthesis and characterization of a new nonanuclear Ni(II) cluster from a pyridyl-alcohol ligand, Dalton Transactions 43 (2014) 42–46. https://doi.org/10.1039/c3dt52744a.
[1]
A.M. Madalan, X.-Y. Cao, G. Rogez, J.-M. Lehn, Ferromagnetic Coupling in Copper(II) [2 x 2] Grid-like Complexes, Inorganic Chemistry 53 (2014) 4275–4277. https://doi.org/10.1021/ic500285m.
[1]
G. Letheux, P. Ganesan, F. Veillon, J. Varignon, O. Perez, J. Cardin, C. Labbe, G. Rogez, M. Ligeour, P.-A. Jaffres, J.-M. Rueff, A new series of magnetic and luminescent layered hybrid materials obtained from thianthrene phosphonic acid: M(H2O)PO3-S2C12H7 (M = Cu, Zn) and M(H2O)2(PO2OH-S2C12H7)2 (M = Mn, Co)., Dalton Transactions Early Access (2023). https://doi.org/10.1039/d3dt03153e.
[1]
M. Lang, E. Delahaye, D. Foix, D. Ihiawakrim, O. Ersen, C. Leuvrey, J.-M. Greneche, G. Rogez, P. Rabu, Pseudomorphic Transformation of Layered Simple Hydroxides into Prussian Blue Analogue Nanoplatelets, European Journal of Inorganic Chemistry (2016) 2030–2038. https://doi.org/10.1002/ejic.201501338.
[1]
V. Kumar, Q. Evrard, C. Leuvrey, M. Lenertz, Y. Garcia, P. Rabu, G. Rogez, Incorporation of Photo- and Thermoresponsive N-Salicylidene Aniline Derivatives into Cobalt and Zinc Layered Hydroxides., Inorganic Chemistry 62 (2023) 21101–21114. https://doi.org/10.1021/acs.inorgchem.3c03013.
[1]
M.A.A. Kerroum, C. Iacovita, W. Baaziz, D. Ihiawakrim, G. Rogez, M. Benaissa, C.M. Lucaciu, O. Ersen, Quantitative Analysis of the Specific Absorption Rate Dependence on the Magnetic Field Strength in ZnxFe3-xO4 Nanoparticles, International Journal of Molecular Sciences 21 (2020) 7775. https://doi.org/10.3390/ijms21207775.
[1]
S. Kartal, G. Rogez, J. Robert, B. Heinrich, A.K. Boudalis, A Magnetocaloric Glass from an Ionic-Liquid Gadolinium Complex, ChemPhysChem 23 (2022) e202200213. https://doi.org/https://doi.org/10.1002/cphc.202200213.
[1]
B. Joarder, A.K. Chaudhari, G. Rogez, S.K. Ghosh, A carboxylate-based dinuclear dysprosium(III) cluster exhibiting slow magnetic relaxation behaviour, Dalton Transactions 41 (2012) 7695–7699. https://doi.org/10.1039/c2dt30643c.
[1]
N. Hugot, M. Roger, J.-M. Rueff, J. Cardin, O. Perez, V. Caignaert, B. Raveau, G. Rogez, P.-A. Jaffres, Copper-Fluorenephosphonate Cu(PO3-C13H9)center dot H2O: A Layered Antiferromagnetic Hybrid, European Journal of Inorganic Chemistry (2016) 266–271. https://doi.org/10.1002/ejic.201501041.
[1]
S. Hameury, L. Kayser, R. Pattacini, G. Rogez, W. Wernsdorfer, P. Braunstein, Synthesis of cubane-type Ni(II) complexes from pyridyl-alcohol ligands; their single-molecule magnet behaviour, Dalton Transactions 42 (2013) 5013–5024. https://doi.org/10.1039/c3dt32869d.
[1]
M. Guyot, M.-N. Lalloz, J.S. Aguirre-Araque, G. Rogez, C. Costentin, S. Chardon-Noblat, Rhenium Carbonyl Molecular Catalysts for CO2 Electroreduction: Effects on Catalysis of Bipyridine Substituents Mimicking Anchorage Functions to Modify Electrodes, Inorganic Chemistry 61 (2022) 16072–16080. https://doi.org/10.1021/acs.inorgchem.2c02473.
[1]
J. Goura, G. Rogez, E. Rivière, V. Chandrasekhar, Hexanuclear, Heterometallic, Ni3Ln3 Complexes Possessing O-Capped Homo- and Heterometallic Structural Subunits: SMM Behavior of the Dysprosium Analogue, Inorganic Chemistry 53 (2014) 7815–7823. https://doi.org/10.1021/ic403090z.
[1]
P. Farger, C. Leuvrey, G. Rogez, M. Francois, P. Rabu, E. Delahay, Salts and Solvents Effect on the Crystal Structure of Imidazolium Dicarboxylate Salt Based Coordination Networks, Crystal Growth & Design 19 (2019) 4264–4272. https://doi.org/10.1021/acs.cgd.8b01725.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, J. Rocha, D. Ananias, P. Rabu, E. Delahaye, Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry, Beilstein Journal of Nanotechnology 9 (2018) 2775–2787. https://doi.org/10.3762/bjnano.9.259.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, P. Rabu, E. Delahaye, Elaboration of Luminescent and Magnetic Hybrid Networks Based on Lanthanide Ions and Imidazolium Dicarboxylate Salts: Influence of the Synthesis Conditions, Magnetochemistry 3 (2017) 1. https://doi.org/10.3390/magnetochemistry3010001.
[1]
P. Farger, R. Guillot, F. Leroux, N. Parizel, M. Gallart, P. Gilliot, G. Rogez, E. Delahaye, P. Rabu, Imidazolium Dicarboxylate Based Metal-Organic Frameworks Obtained by Solvo-Ionothermal Reaction, European Journal of Inorganic Chemistry (2015) 5342–5350. https://doi.org/10.1002/ejic.201500825.
[1]
S. Eyele-Mezui, P. Vialat, C. Higy, R. Bourzami, C. Leuvrey, N. Parizel, P. Turek, P. Rabu, G. Rogez, C. Mousty, Electrocatalytic Properties of Metal Phthalocyanine Tetrasulfonate Intercalated in Metal Layered Simple Hydroxides (Metal: Co, Cu, and Zn), Journal of Physical Chemistry C 119 (2015) 13335–13342. https://doi.org/10.1021/acs.jpcc.5b02985.
[1]
S. Eyele-Mezui, E. Delahaye, G. Rogez, P. Rabu, Functional Hybrid Materials Based on Layered Simple Hydroxide Hosts and Dicarboxylate Schiff Base Metal Complex Guests, European Journal of Inorganic Chemistry (2012) 5225–5238. https://doi.org/10.1002/ejic.201200695.
[1]
Q. Evrard, C. Leuvrey, P. Farger, E. Delahaye, P. Rabu, G. Taupier, K.D. Dorkenoo, J.-M. Rueff, N. Barrier, O. Perez, G. Rogez, Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu-2(OH)(3)(C12H25SO4), Crystal Growth & Design 18 (2018) 1809–1817. https://doi.org/10.1021/acs.cgd.7601692.
[1]
Q. Evrard, Z. Chaker, M. Roger, C.M. Sevrain, E. Delahaye, M. Gallart, P. Gilliot, C. Leuvrey, J.-M. Rueff, P. Rabu, C. Massobrio, M. Boero, A. Pautrat, P.-A. Jaffrès, G. Ori, G. Rogez, Layered Simple Hydroxides Functionalized by Fluorene-Phosphonic Acids: Synthesis, Interface Theoretical Insights, and Magnetoelectric Effect, Advanced Functional Materials 27 (2017) 1703576. https://doi.org/10.1002/adfm.201703576.