Guillaume ROGEZ

Guillaume ROGEZ

Directeur de Recherche, Inorganic Materials Chemistry (DCMI)guillaume.rogez@ipcms.unistra.fr
Station: +33(0)3 88 10 72 95, +33(0)3 88 10 71 96Office: 3006
See personal page

Research background

Since Dec. 2003 : CNRS Researcher, IPCMS
Multifunctional Hybrid Materials, syntheses, optical and magnetic properties

Nov. 2002-Nov. 2003 : Post-doctoral internship, Dipartimento di Chimica “G. Ciamician”, Gruppo di Fotochimica e Chimica Supramolecolare, Universita di Bologna, Italy
Photochemical studies of “molecular machines”
Supervisors : Vincenzo Balzani, Alberto Credi, Maria-Teresa Gandolfi

Sept. 1999-Oct. 2002 : PhD, Laboratoire de Chimie Inorganique, Institut de Chimie Moléculaire et des Matériaux d’Orsay
Syntheses and studies of magnetic molecular systems : high-spin molecules and magnetic anisotropy. Synthesis of polymetallic systems, spectroscopic and magnetic characterizations. Study of the magnetic anisotropy of NiII complexes.
PhD supervisor : Talal Mallah

Academic background

2014 : Habilitation (defended on July 1st 2014)
“From molecular bricks to multifunctional hybrid materials”
Jury : B. Doudin (rapporteur), M. Drillon, F. Leroux (rapporteur), Y. Journaux (rapporteur), M. Maglione, P. Rabu (garant), C. Sanchez (president)

2002 : PhD in Inorganic Chemistry (defended on October 21st 2002)
“Modulation of the electronic properties and of the magnetic anisotropy of mono and polynuclear complexes : influence of bridging and peripheral ligands”
Jury : D. Astruc (rapporteur), M. Drillon (rapporteur), D. Gatteschi, J.-J. Girerd (president), M. Julve, T. Mallah (PhD supervisor)

1999 : Master in Inorganic Chemistry
Universities Paris XI, Paris VI and Versailles St-Quentin, ESPCI and ENSCP

1998 : “Agrégation” in Physics, major in Chemistry

Interesting links

Division Chimie du Solide de la Société Chimique de France
Association Française de Magnétisme Moléculaire
Association Française de Magnétisme Moléculaire
Réseau francophone de magnétométrie
Groupe Français d’Etude des Composés d’Insertion

Current researches

  • (Multi)functional layered hybrid materials :
    Layered Simple Hydroxides
    Layered oxides
  • New methods to functionalize layered materials :
    Pre-functionalization
    Microwave-assisted chemistry
    In situ reactions (confined in the interlayer spacing)
  • Exfoliation and directed reassembly
  • Coordination chemistry
  • Magnetic properties of hybrid and molecular compounds

Ongoing projects

2021-2024 : ITI QMat
“Confined synthetic approaches to layered multifunctional heterostructures and 2D magnets” (2Dconfined)

2019-2021 : IDEX “Attractivité”
“Functionalized oxide nanosheets : new platforms for directed assembly of multifunctional hybrid materials and films”

2019-2023 : ANR
“Structured CAtalysts in Layered HYdroxide materials for selective CO2 electroreduction reaction” (CALHYCO2). Coordinator : Sylvie Chardon (DCM, Grenoble), other partner : Christine Mousty (ICCF, Clermont-Ferrand)

Principal collaborations

François Schosseler, Institut Charles Sadron, Strasbourg

Sylvie Choua, Sylvie Ferlay, Marine Desage-El Murr, Romain Ruppert, Institut de Chimie de Strasbourg

Thomas Ebbesen, Institut de Science et d’Ingénierie Supramoléculaires, Strasbourg

Sylvie Chardon, Cyrille Costentin, Département de Chimie Moléculaire, Grenoble

Pierre Bonnet, Fabrice Leroux, Christine Mousty, Vanessa Prévot, Christine Taviot-Guého, Institut de Chimie de Clermont-Ferrand

Nicolas Barrier, Alain Pautrat, Olivier Pérez, Jean-Michel Rueff, Laboratoire Cristallographie et Matériaux, Caen

Paul-Alain Jaffrès, Laboratoire Chimie Electrochimie Moléculaires et Chimie Analytique, Brest

Emilie Delahaye, Laboratoire de Chimie de Coordination, Toulouse

Vadapalli Chandrasekhar, Tata Institute of Fundamental Research, Hyderabad, Inde

Publications

[1]
N. Benamara, M. Diop, C. Leuvrey, M. Lenertz, P. Gilliot, M. Gallart, H. Bolvin, F. Setifi, G. Rogez, P. Rabu, E. Delahaye, Octahedral Hexachloro Environment of Dy3+ with Slow Magnetic Relaxation and Luminescent Properties, European Journal of Inorganic Chemistry. early (2021). https://doi.org/10.1002/ejic.202100143.
[1]
H. Ullah, N. Batisse, K. Guerin, G. Rogez, P. Bonnet, Synthesis of NiF2 and NiF2 center dot 4H(2)O Nanoparticles by Microemulsion and Their Self-Assembly, Langmuir. 36 (2020) 8461–8475. https://doi.org/10.1021/acs.langmuir.0c00889.
[1]
N. Suaud, G. Rogez, J.-N. Rebilly, M.-A. Bouammali, N. Guihery, A.-L. Barra, T. Mallah, Playing with Magnetic Anisotropy in Hexacoordinated Mononuclear Ni(II) Complexes, An Interplay Between Symmetry and Geometry, Applied Magnetic Resonance. (2020). https://doi.org/10.1007/s00723-020-01228-8.
[1]
L. Mathivathanan, G. Rogez, N. Ben Amor, V. Robert, R.G. Raptis, A.K. Boudalis, Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles, Chemistry-a European Journal. 26 (2020) 1–17. https://doi.org/10.1002/chem.202001028.
[1]
M.A.A. Kerroum, C. Iacovita, W. Baaziz, D. Ihiawakrim, G. Rogez, M. Benaissa, C.M. Lucaciu, O. Ersen, Quantitative Analysis of the Specific Absorption Rate Dependence on the Magnetic Field Strength in ZnxFe3-xO4 Nanoparticles, International Journal of Molecular Sciences. 21 (2020) 7775. https://doi.org/10.3390/ijms21207775.
[1]
Y. Wang, C. Leuvrey, E. Delahaye, F. Leroux, P. Rabu, C. Taviot-Gueho, G. Rogez, Tuning the organization of the interlayer organic moiety in a hybrid layered perovskite, Journal of Solid State Chemistry. 269 (2019) 532–539. https://doi.org/10.1016/j.jssc.2018.10.034.
[1]
P. Farger, C. Leuvrey, G. Rogez, M. Francois, P. Rabu, E. Delahay, Salts and Solvents Effect on the Crystal Structure of Imidazolium Dicarboxylate Salt Based Coordination Networks, Crystal Growth & Design. 19 (2019) 4264–4272. https://doi.org/10.1021/acs.cgd.8b01725.
[1]
Y. Wang, M. Nikolopoulou, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Microwave-assisted functionalization of the Aurivillius phase Bi2SrTa2O9: diol grafting and amine insertion vs. alcohol grafting, Chemical Science. 9 (2018) 7104–7114. https://doi.org/10.1039/c8sc01754a.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, J. Rocha, D. Ananias, P. Rabu, E. Delahaye, Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry, Beilstein Journal of Nanotechnology. 9 (2018) 2775–2787. https://doi.org/10.3762/bjnano.9.259.
[1]
Q. Evrard, C. Leuvrey, P. Farger, E. Delahaye, P. Rabu, G. Taupier, K.D. Dorkenoo, J.-M. Rueff, N. Barrier, O. Perez, G. Rogez, Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu-2(OH)(3)(C12H25SO4), Crystal Growth & Design. 18 (2018) 1809–1817. https://doi.org/10.1021/acs.cgd.7601692.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, P. Rabu, E. Delahaye, Elaboration of Luminescent and Magnetic Hybrid Networks Based on Lanthanide Ions and Imidazolium Dicarboxylate Salts: Influence of the Synthesis Conditions, Magnetochemistry. 3 (2017) 1. https://doi.org/10.3390/magnetochemistry3010001.
[1]
Q. Evrard, Z. Chaker, M. Roger, C.M. Sevrain, E. Delahaye, M. Gallart, P. Gilliot, C. Leuvrey, J.-M. Rueff, P. Rabu, C. Massobrio, M. Boero, A. Pautrat, P.-A. Jaffrès, G. Ori, G. Rogez, Layered Simple Hydroxides Functionalized by Fluorene-Phosphonic Acids: Synthesis, Interface Theoretical Insights, and Magnetoelectric Effect, Advanced Functional Materials. 27 (2017) 1703576. https://doi.org/10.1002/adfm.201703576.
[1]
M. Dolai, H.A. Molla, G. Rogez, M. Ali, Two [Mn-3(mu(3)-O)(7+) based Single Chain Magnets with different solvent ligation, Polyhedron. 127 (2017) 248–256. https://doi.org/10.1016/j.poly.2017.01.043.
[1]
Y. Wang, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Post-Synthesis Modification of the Aurivillius Phase Bi2SrTa2O9 via In Situ Microwave-Assisted “Click Reaction,” Inorganic Chemistry. 55 (2016) 9790–9797. https://doi.org/10.1021/acs.inorgchem.6b01600.
[1]
Y. Wang, E. Delahaye, C. Leuvrey, F. Leroux, P. Rabu, G. Rogez, Efficient Microwave-Assisted Functionalization of the Aurivillius-Phase Bi2SrTa2O9, Inorganic Chemistry. 55 (2016) 4039–4046. https://doi.org/10.1021/acs.inorgchem.6b00338.
[1]
M. Roger, C. Bloyet, Q. Evrard, H. Couthon-Gourves, M. Berchel, J.-M. Rueff, O. Perez, G. Rogez, P.-A. Jaffres, Rigid phosphonic acid for the construction of crystalline organic-inorganic hybrid materials, Phosphorus Sulfur and Silicon and the Related Elements. 191 (2016) 1482–1484. https://doi.org/10.1080/10426507.2016.1212048.
[1]
M. Lang, E. Delahaye, D. Foix, D. Ihiawakrim, O. Ersen, C. Leuvrey, J.-M. Greneche, G. Rogez, P. Rabu, Pseudomorphic Transformation of Layered Simple Hydroxides into Prussian Blue Analogue Nanoplatelets, European Journal of Inorganic Chemistry. (2016) 2030–2038. https://doi.org/10.1002/ejic.201501338.
[1]
N. Hugot, M. Roger, J.-M. Rueff, J. Cardin, O. Perez, V. Caignaert, B. Raveau, G. Rogez, P.-A. Jaffres, Copper-Fluorenephosphonate Cu(PO3-C13H9)center dot H2O: A Layered Antiferromagnetic Hybrid, European Journal of Inorganic Chemistry. (2016) 266–271. https://doi.org/10.1002/ejic.201501041.