1839302
DEB5KWFS
2022
surface-science-reports
50
creator
asc
16596
https://www.ipcms.fr/wp-content/plugins/zotpress/
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[1]
C. Antuna-Horlein, F. Wu, C. Deraedt, C. Bouillet, J.-P. Djukic, Cobalt Nanoparticles Formed upon Reaction of Cp*Co(III) Metallacycles with Na[BHEt3] Show Catalytic Activity in the Hydrosilylation of Aryl Ketones, Aldehydes and Nitriles, European Journal of Inorganic Chemistry (2022) e202200563. https://doi.org/10.1002/ejic.202200563.
[1]
A.T.F. Batista, C. Chizallet, F. Diehl, A.-L. Taleb, A.-S. Gay, O. Ersen, P. Raybaud, Evaluating acid and metallic site proximity in Pt/gamma-Al2O3-Cl bifunctional catalysts through an atomic scale geometrical model., Nanoscale 14 (2022) 8753–8765. https://doi.org/10.1039/d2nr00261b.
[1]
B. Chowrira, L. Kandpal, M. Lamblin, F. Ngassam, C.-A. Kouakou, T. Zafar, D. Mertz, B. Vileno, C. Kieber, G. Versini, B. Gobaut, L. Joly, T. Ferté, E. Monteblanco, A. Bahouka, R. Bernard, S. Mohapatra, H. Prima Garcia, S. Elidrissi, M. Gavara, E. Sternitzky, V. Da Costa, M. Hehn, F. Montaigne, F. Choueikani, P. Ohresser, D. Lacour, W. Weber, S. Boukari, M. Alouani, M. Bowen, Quantum Advantage in a Molecular Spintronic Engine that Harvests Thermal Fluctuation Energy., Advanced Materials Early access (2022) e2206688–e2206688. https://doi.org/10.1002/adma.202206688.
[1]
G. Cotin, B. Heinrich, F. Perton, C. Kiefer, G. Francius, D. Mertz, B. Freis, B. Pichon, J.-M. Strub, S. Cianférani, N. Ortiz Peña, D. Ihiawakrim, D. Portehault, O. Ersen, A. Khammari, M. Picher, F. Banhart, C. Sanchez, S. Bégin-Colin, A Confinement-Driven Nucleation Mechanism of Metal Oxide Nanoparticles Obtained via Thermal Decomposition in Organic Media, Small (2022) 2200414. https://doi.org/10.1002/smll.202200414.
[1]
B. Croes, I. Gaponenko, C. Voulot, O. Grégut, K.D. Dorkenoo, F. Cheynis, S. Curiotto, P. Müller, F. Leroy, K. Cordero-Edwards, P. Paruch, S. Cherifi-Hertel, Automatic Ferroelectric Domain Pattern Recognition Based on the Analysis of Localized Nonlinear Optical Responses Assisted by Machine Learning, Advanced Physics Research n/a (2022) 2200037. https://doi.org/https://doi.org/10.1002/apxr.202200037.
[1]
G.M.L. Dalmonico, D. Ihiawakrim, N. Ortiz, A.G. Barreto, C.F.C. Marcellos, M. Farina, O. Ersen, A.L. Rossi, Live Visualization of the Nucleation and Growth of Needle-Like Hydroxyapatite Crystals in Solution by In Situ TEM, Crystal Growth & Design 22 (2022) 4828–4837. https://doi.org/10.1021/acs.cgd.2c00296.
[1]
O. Darouich, W. Baaziz, D. Ihiawakrim, C. Hirlimann, D. Spehner, P. Schultz, H. Poncet, V. Rouchon, S. Labidi, C. Petit, P. Levitz, O. Ersen, 3D multiscale analysis of the hierarchical porosity in Coscinodiscus sp. diatoms using a combination of tomographic techniques, Nanoscale Advances 4 (2022) 1587–1598. https://doi.org/10.1039/d1na00691f.
[1]
M.L. De Marco, W. Baaziz, S. Sharna, F. Devred, C. Poleunis, A. Chevillot-Biraud, S. Nowak, R. Haddad, M. Odziomek, C. Boissiere, D.P. Debecker, O. Ersen, J. Peron, M. Faustini, High-Entropy-Alloy Nanocrystal Based Macro- and Mesoporous Materials., ACS Nano Early Access (2022). https://doi.org/10.1021/acsnano.2c05465.
[1]
A. Demchenko, S. Homkar, C. Bouillet, C.T. Lefèvre, F. Roulland, D. Preziosi, G. Versini, C. Leuvrey, P. Boullay, X. Devaux, N. Viart, Unveiling unconventional ferroelectric switching in multiferroic Ga-0.6 Fe1.4O3 thin films through multiscale electron microscopy investigations, Acta Materialia 240 (2022) 118337. https://doi.org/10.1016/j.actamat.2022.118337.
[1]
I. Gaponenko, S. Cherifi-Hertel, U. Acevedo-Salas, N. Bassiri-Gharb, P. Paruch, Correlative imaging of ferroelectric domain walls, Scientific Reports 12 (2022) 165. https://doi.org/10.1038/s41598-021-04166-y.
[1]
C. Goyhenex, Rationalization of the sub-surface segregation in nanoalloys of weakly miscible metals., Nanoscale Early access (2022). https://doi.org/10.1039/d2nr04364e.
[1]
N.Z. Hagström, M. Schneider, N. Kerber, A. Yaroslavtsev, E. Burgos Parra, M. Beg, M. Lang, C.M. Gunther, B. Seng, F. Kammerbauer, H. Popescu, M. Pancaldi, K. Neeraj, D. Polley, R. Jangid, S.B. Hrkac, S.K.K. Patel, S. Ovcharenko, D. Turenne, D. Ksenzov, C. Boeglin, M. Baidakova, C. von Korff Schmising, M. Borchert, B. Vodungbo, K. Chen, C. Luo, F. Radu, L. Muller, M. Martinez Florez, A. Philippi-Kobs, M. Riepp, W. Roseker, G. Grubel, R. Carley, J. Schlappa, B.E. Van Kuiken, R. Gort, L. Mercadier, N. Agarwal, L. Le Guyader, G. Mercurio, M. Teichmann, J.T. Delitz, A. Reich, C. Broers, D. Hickin, C. Deiter, J. Moore, D. Rompotis, J. Wang, D. Kane, S. Venkatesan, J. Meier, F. Pallas, T. Jezynski, M. Lederer, D. Boukhelef, J. Szuba, K. Wrona, S. Hauf, J. Zhu, M. Bergemann, E. Kamil, T. Kluyver, R. Rosca, M. Spirzewski, M. Kuster, M. Turcato, D. Lomidze, A. Samartsev, J. Engelke, M. Porro, S. Maffessanti, K. Hansen, F. Erdinger, P. Fischer, C. Fiorini, A. Castoldi, M. Manghisoni, C.B. Wunderer, E.E. Fullerton, O.G. Shpyrko, C. Gutt, C. Sanchez-Hanke, H.A. Durr, E. Iacocca, H.T. Nembach, M.W. Keller, J.M. Shaw, T.J. Silva, R. Kukreja, H. Fangohr, S. Eisebitt, M. Klaui, N. Jaouen, A. Scherz, S. Bonetti, E. Jal, Megahertz-rate ultrafast X-ray scattering and holographic imaging at the European XFEL., Journal of Synchrotron Radiation 29 (2022) 1454–1464. https://doi.org/10.1107/S1600577522008414.
[1]
M.Z. Hussain, Z. Yang, B. van der Linden, W.R. Heinz, M. Bahri, O. Ersen, Q. Jia, R.A. Fischer, Y. Zhu, Y. Xia, MOF-Derived Multi-heterostructured Composites for Enhanced Photocatalytic Hydrogen Evolution: Deciphering the Roles of Different Components, Energy & Fuels Early access (2022). https://doi.org/10.1021/acs.energyfuels.2c02319.
[1]
L. Joly, F. Scheurer, P. Ohresser, B. Kengni-Zanguim, J.-F. Dayen, P. Seneor, B. Dlubak, F. Godel, D. Halley, X-ray magnetic dichroism and tunnel magneto-resistance study of the magnetic phase in epitaxial CrVO x nanoclusters, Journal of Physics-Condensed Matter 34 (2022) 175801. https://doi.org/10.1088/1361-648X/ac4f5e.
[1]
O. Laghzali, G.S. Nayak, F. Mouillard, P. Masson, G. Pourroy, H. Palkowski, A. Carradò, Designing maxillofacial prostheses for bone reconstruction: an overview, Emerging Materials Research 11 (2022) 1–9. https://doi.org/10.1680/jemmr.21.00138.
[1]
M. Lemare, H. Puja, S.R. David, S. Mathieu, D. Ihiawakrim, V.A. Geoffroy, C. Rigouin, Engineering siderophore production in Pseudomonas to improve asbestos weathering, Microbial Biotechnology 15 (2022) 2351–2363. https://doi.org/10.1111/1751-7915.14099.
[1]
A. Lipatov, P. Chaudhary, Z. Guan, H. Lu, G. Li, O. Crégut, K.D. Dorkenoo, R. Proksch, S. Cherifi-Hertel, D.-F. Shao, E.Y. Tsymbal, J. Iniguez, A. Sinitskii, A. Gruverman, Direct observation of ferroelectricity in two-dimensional MoS2, NPJ 2D Materials and Applications 6 (2022) 18. https://doi.org/10.1038/s41699-022-00298-5.
[1]
Z. Liu, Y. Hu, W. Zheng, C. Wang, W. Baaziz, F. Richard, O. Ersen, M. Bonn, H. Wang I., A. Narita, A. Ciesielski, K. Muellen, P. Samori, Untying the Bundles of Solution-Synthesized Graphene Nanoribbons for Highly Capacitive Micro-Supercapacitors, Advanced Functional Materials 32 (2022) 2109543. https://doi.org/10.1002/adfm.202109543.
[1]
W. Liu, F. Morfin, K. Provost, M. Bahri, W. Baaziz, O. Ersen, L. Piccolo, C. Zlotea, Unveiling the Ir single atoms as selective active species for the partial hydrogenation of butadiene by operando XAS, Nanoscale 14 (2022) 7641–7649. https://doi.org/10.1039/d2nr00994c.
[1]
M.M. Longuinho, V. Ramnarain, N.O. Pena, D. Ihiawakrim, R. Soria-Martinez, M. Farina, O. Ersen, A.L. Rossi, The influence of l-aspartic acid on calcium carbonate nucleation and growth revealed by in situ liquid phase TEM, CrystEngComm 24 (2022) 2602–2614. https://doi.org/10.1039/d2ce00117a.
[1]
B. Ma, W. Baaziz, L. Mazerolles, O. Ersen, B. Sahut, C. Sanchez, S. Delalande, D. Portehault, Liquid Processing of Bismuth-Silica Nanoparticle/Aluminum Matrix Nanocomposites for Heat Storage Applications, ACS Applied Nano Materials 5 (2022) 1917–1924. https://doi.org/10.1021/acsanm.1c03534.
[1]
S. Mohapatra, S. Cherifi-Hertel, S.K. Kuppusamy, G. Schmerber, J. Arabski, B. Gobaut, W. Weber, M. Bowen, V. Da Costa, S. Boukari, Organic ferroelectric croconic acid: a concise survey from bulk single crystals to thin films, Journal of Materials Chemistry C 10 (2022) 8142–8167. https://doi.org/10.1039/D1TC05310H.
[1]
A.N. Morozovska, E.A. Eliseev, S. Cherifi-Hertel, D.R. Evans, R. Hertel, Electric field control of labyrinth domain structures in core-shell ferroelectric nanoparticles, Physical Review B 106 (2022) 144104. https://doi.org/10.1103/PhysRevB.106.144104.
[1]
G.S. Nayak, A. Carradò, P. Masson, G. Pourroy, F. Mouillard, V. Migonney, C. Falentin-Daudre, C. Pereira, H. Palkowski, Trends in Metal-Based Composite Biomaterials for Hard Tissue Applications, JOM 74 (2022) 102–125. https://doi.org/10.1007/s11837-021-04992-5.
[1]
A. Palazzolo, C. Poucin, A.P. Freitas, A. Ropp, C. Bouillet, O. Ersen, S. Carenco, The delicate balance of phase speciation in bimetallic nickel cobalt nanoparticles., Nanoscale 14 (2022) 7547. https://doi.org/10.1039/d2nr00917j.
[1]
H. Pasco, L. de Viguerie, M. Faustini, C. Coelho-Diogo, O. Ersen, C. Gervais, F. Gobeaux, D. Ihiawakrim, M. Jaber, P. Walter, C. Sanchez, Shedding Light on Functional Hybrid Nanocomposites 19th Century Paint Medium, Advanced Functional Materials 32 (2022) 2106346. https://doi.org/https://doi.org/10.1002/adfm.202106346.
[1]
F. Payet, C. Bouillet, F. Leroux, C. Leuvrey, P. Rabu, F. Schosseler, C. Taviot-Guého, G. Rogez, Fast and efficient shear-force assisted production of covalently functionalized oxide nanosheets, Journal of Colloid and Interface Science 607 (2022) 621–632. https://doi.org/10.1016/j.jcis.2021.08.213.
[1]
N.O. Pena, D. Ihiawakrim, S. Cretu, G. Cotin, C. Kiefer, S. Bégin-Colin, C. Sanchez, D. Portehault, O. Ersen, In situ liquid transmission electron microscopy reveals self-assembly-driven nucleation in radiolytic synthesis of iron oxide nanoparticles in organic media, Nanoscale 14 (2022) 10950–10957. https://doi.org/10.1039/d2nr01511k.
[1]
R.J. Pena Roman, D. Pommier, R. Bretel, L.E.P. Lopez, E. Lorchat, J. Chaste, A. Ouerghi, S. Le Moal, E. Boer-Duchemin, G. Dujardin, A.G. Borisov, L.F. Zagonel, G. Schull, S. Berciaud, E. Le Moal, Electroluminescence of monolayer WS2 in a scanning tunneling microscope: Effect of bias polarity on spectral and angular distribution of emitted light, Physical Review B 106 (2022) 085419. https://doi.org/10.1103/PhysRevB.106.085419.
[1]
R.J. Peña Román, R. Bretel, D. Pommier, L.E. Parra López, E. Lorchat, E. Boer-Duchemin, G. Dujardin, A.G. Borisov, L.F. Zagonel, G. Schull, S. Berciaud, E. Le Moal, Tip-Induced and Electrical Control of the Photoluminescence Yield of Monolayer WS2, Nano Lett. 22 (2022) 9244–9251. https://doi.org/10.1021/acs.nanolett.2c02142.
[1]
C. Pereira, J.-S. Baumann, P. Masson, G. Pourroy, A. Carradò, V. Migonney, C. Falentin-Daudre, Double Functionalization for the Design of Innovative Craniofacial Prostheses, JOM 74 (2022) 87–95. https://doi.org/10.1007/s11837-021-04997-0.
[1]
C. Pereira, C.S. Da Moura, A. Carradò, C. Falentin-Daudre, Ultraviolet irradiation modification of poly(methyl methacrylate) titanium grafted surface for biological purpose, Colloids and Surfaces A-Physicochemical and Engineering Aspects 655 (2022) 130295. https://doi.org/10.1016/j.colsurfa.2022.130295.
[1]
M. Picher, S.K. Sinha, T. LaGrange, F. Banhart, Analytics at the nanometer and nanosecond scales by short electron pulses in an electron microscope, ChemTexts 8 (2022) 18. https://doi.org/10.1007/s40828-022-00169-y.
[1]
V. Ramnarain, T. Georges, N. Ortiz Pena, D. Ihiawakrim, M. Longuinho, H. Bulou, C. Gervais, C. Sanchez, T. Azais, O. Ersen, Monitoring of CaCO3 Nanoscale Structuration through Real-Time Liquid Phase Transmission Electron Microscopy and Hyperpolarized NMR, Journal of the American Chemical Society 144 (2022) 15236–15251. https://doi.org/10.1021/jacs.2c05731.
[1]
A. Roslawska, T. Neuman, B. Doppagne, A.G. Borisov, M. Romeo, F. Scheurer, J. Aizpurua, G. Schull, p Mapping Lamb, Stark, and Purcell Effects at a Chromophore-Picocavity Junction with Hyper-Resolved Fluorescence Microscopy, Physical Review X 12 (2022) 011012. https://doi.org/10.1103/PhysRevX.12.011012.
[1]
K. Sartori, D. Ihiawakrim, C. Lefèvre, S. Reguer, C. Mocuta, S. Bégin-Colin, F. Choueikani, B.P. Pichon, A detailed investigation of the core@shell structure of exchanged coupled magnetic nanoparticles after performing solvent annealing, Materials Advances Early access (2022). https://doi.org/10.1039/d2ma00629d.
[1]
E. Soszka, M. Jedrzejczyk, C. Lefèvre, D. Ihiawakrim, N. Keller, A.M. Ruppert, TiO2-supported Co catalysts for the hydrogenation of gamma-valerolactone to 2-methyltetrahydrofuran: influence of the support, Catalysis Science & Technology Early Access (2022). https://doi.org/10.1039/d2cy01044e.
[1]
L. Truong-Phuoc, C. Duong-Viet, G. Tuci, A. Rossin, J.-M. Nhut, W. Baaziz, O. Ersen, M. Arab, A. Jourdan, G. Giambastiani, C. Pham-Huu, Graphite Felt-Sandwiched Ni/SiC Catalysts for the Induction Versus Joule-Heated Sabatier Reaction: Assessing the Catalyst Temperature at the Nanoscale, ACS Sustainable Chemistry & Engineering 10 (2022) 622–632. https://doi.org/10.1021/acssuschemeng.1c07217.
[1]
K. Vasilev, B. Doppagne, T. Neuman, A. Roslawska, H. Bulou, A. Boeglin, F. Scheurer, G. Schull, Internal Stark effect of single-molecule fluorescence, Nature Communications 13 (2022) 677. https://doi.org/10.1038/s41467-022-28241-8.
[1]
L. Wang, V.A. Saveleva, M.J. Eslamibidgoli, D. Antipin, C. Bouillet, I. Biswas, A.S. Gago, S.S. Hosseiny, P. Gazdzicki, M.H. Eikerling, E.R. Savinova, K.A. Friedrich, Deciphering the Exceptional Performance of NiFe Hydroxide for the Oxygen Evolution Reaction in an Anion Exchange Membrane Electrolyzer, ACS Applied Energy Materials 5 (2022) 2221–2230. https://doi.org/10.1021/acsaem.1c03761.
[1]
Q. Wang, S. Santos, C.A. Urbina-Blanco, W. Zhou, Y. Yang, M. Marinova, S. Heyte, T.-R. Joelle, O. Ersen, W. Baaziz, O. Safonova V., M. Saeys, V.V. Ordomsky, Ru(III) single site solid micellar catalyst for selective aqueous phase hydrogenation of carbonyl groups in biomass-derived compounds, Applied Catalysis B-Environmental 300 (2022) 120730. https://doi.org/10.1016/j.apcatb.2021.120730.
[1]
D.S. Wang, T. Neuman, S.F. Yelin, J. Flick, Cavity-Modified Unimolecular Dissociation Reactions via Intramolecular Vibrational Energy Redistribution., Journal of Physical Chemistry Letters 13 (2022) 3317–3324. https://doi.org/10.1021/acs.jpclett.2c00558.
[1]
C. Weymann, S. Cherifi-Hertel, C. Lichtensteiger, I. Gaponenko, K.D. Dorkenoo, A.B. Naden, P. Paruch, Non-Ising domain walls in $c$-phase ferroelectric lead titanate thin films, Physical Review B 106 (2022) L241404. https://doi.org/10.1103/PhysRevB.106.L241404.