1839302
2019
surface-science-reports
50
creator
asc
4030
https://www.ipcms.fr/wp-content/plugins/zotpress/
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[1]
T. Achard, J. Egly, M. Sigrist, A. Maisse-Francois, S. Bellemin-Laponnaz, Easy Ruthenium-Catalysed Oxidation of Primary Amines to Nitriles under Oxidant-Free Conditions, Chemistry-a European Journal 25 (2019) 13271–13274. https://doi.org/10.1002/chem.201902557.
[1]
D. Agathangelou, Y. El-Khoury, J. Brazard, O. Crégut, S. Haacke, G. Cerullo, J. Léonard, Towards broadband two-Dimensional electronic spectroscopy with similar to 8 fs phase-locked pulses at 400 nm, in: Cerullo, G and Ogilvie, J and Kartner, F and Khalil, M and Li, R (Ed.), XXI INTERNATIONAL CONFERENCE ON ULTRAFAST PHENOMENA 2018 (UP 2018), E D P SCIENCES, 2019. https://doi.org/10.1051/epjconf/201920503006.
[1]
D. Agathangelou, Y. Orozco-Gonzalez, M. del C.M. Perez, J. Brazard, H. Kandori, K.-H. Jung, J. Léonard, Jérémie, N. Ferre, M. Olivucci, S. Haacke, Anabaena Sensory Rhodopsin: Effect of point mutations on PSBR photo-isomerization speed, in: Cerullo, G and Ogilvie, J and Kartner, F and Khalil, M and Li, R (Ed.), XXI INTERNATIONAL CONFERENCE ON ULTRAFAST PHENOMENA 2018 (UP 2018), E D P SCIENCES, 2019. https://doi.org/10.1051/epjconf/201920510004.
[1]
P. Ai, M. Mauro, A.A. Danopoulos, A. Munoz-Castro, P. Braunstein, Dual Emission of a Cyclic Hexanuclear Gold(I) Complex. Interplay between Au-3 and Au-2 Ligand-Supported Luminophores, Journal of Physical Chemistry C 123 (2019) 915–921. https://doi.org/10.1021/acs.jpcc.8b10190.
[1]
A. Aliprandi, M. Eredia, C. Anichini, W. Baaziz, O. Ersen, A. Ciesielski, P. Samori, Persian waxing of graphite: towards green large-scale production of graphene, Chemical Communications 55 (2019) 5331–5334. https://doi.org/10.1039/c9cc01822k.
[1]
L. Álvarez-Miguel, I. Álvarez-Miguel, J.M. Martín-Álvarez, C.M. Álvarez, G. Rogez, R. García-Rodríguez, D. Miguel, Copper complexes for the promotion of iminopyridine ligands derived from β-alanine and self-aldol additions: relaxivity and cytotoxic properties, Dalton Transactions 48 (2019) 17544–17555. https://doi.org/10.1039/C9DT03822A.
[1]
C. Alvarino, B. Heinrich, B. Donnio, R. Deschenaux, B. Therrien, Supramolecular Arene-Ruthenium Metallacycle with Thermotropic Liquid -Crystalline Properties, Inorganic Chemistry 58 (2019) 9505–9512. https://doi.org/10.1021/acs.inorgchem.9b01532.
[1]
R. Arancon, M. Saab, A. Morvan, A. Bonduelle-Skrzypczak, A.-L. Taleb, A.-S. Gay, C. Legens, O. Ersen, K. Searles, V. Mougel, A. Fedorov, C. Coperet, P. Raybaud, Combined Experimental and Theoretical Molecular Approach of the Catalytically Active Hydrotreating MoS2 Phases Promoted by 3d Transition Metals, Journal of Physical Chemistry C 123 (2019) 24659–24669. https://doi.org/10.1021/acs.jpcc.9b08437.
[1]
A. Arias, G. Lochead, T.M. Wintermantel, S. Helmrich, S. Whitlock, Realization of a Rydberg-Dressed Ramsey Interferometer and Electrometer, Physical Review Letters 122 (2019) 053601. https://doi.org/10.1103/PhysRevLett.122.053601.
[1]
R. Arras, S. Cherifi-Hertel, Polarization Control of the Interface Ferromagnetic to Antiferromagnetic Phase Transition in Co/Pb(Zr,Ti)O-3, ACS Applied Materials & Interfaces 11 (2019) 34399–34407. https://doi.org/10.1021/acsami.9b08906.
[1]
Y. Bai, J. Qin, L. Shi, J. Zhang, M. Wang, Y. Zhan, H. Zou, S. Haacke, X. Hou, J. Zi, B. Hu, Amplified Spontaneous Emission Realized by Cogrowing Large/Small Grains with Self-Passivating Defects and Aligning Transition Dipoles, Advanced Optical Materials 7 (2019) 1900345. https://doi.org/10.1002/adom.201900345.
[1]
A. Balaji, M. Kostylev, M. Bailleul, Scattering of a magnetostatic surface spin wave from a one-dimensional step potential in a ferromagnetic film, Journal of Applied Physics 125 (2019) 163903. https://doi.org/10.1063/1.5091806.
[1]
R. Barhoumi, A. Amokrane, S. Klyatskaya, M. Boero, M. Ruben, J.-P. Bucher, Screening the 4f-electron spin of TbPc2 single-molecule magnets on metal substrates by ligand channeling, Nanoscale 11 (2019) 21167–21179. https://doi.org/10.1039/c9nr05873g.
[1]
L. Barloy, B. Heinrich, L. Douce, M. Henry, M. Scarpi-Luttenauer, N. Kyritsakas, P. Mobian, A robust Ti(iv)-based mesogen constructed around a TiO4N2 core, Dalton Transactions 48 (2019) 1960–1963. https://doi.org/10.1039/c8dt04972f.
[1]
M. Barthelemy, A. Maghraoui, G. Versini, M. Vomir, J.-Y. Bigot, Multiscale temporal probing of elemental ultrafast magnetization dynamics in permalloy using High order Harmonics, in: Cerullo, G and Ogilvie, J and Kartner, F and Khalil, M and Li, R (Ed.), XXI INTERNATIONAL CONFERENCE ON ULTRAFAST PHENOMENA 2018 (UP 2018), E D P SCIENCES, 2019. https://doi.org/10.1051/epjconf/201920502013.
[1]
T. Basu, C. Bloyet, F. Beaubras, V. Caignaert, O. Perez, J.-M. Rueff, A. Pautrat, B. Raveau, J.-F. Lohier, P.-A. Jaffrès, H. Couthon, G. Rogez, G. Taupier, H. Dorkenoo, Designing of a Magnetodielectric System in Hybrid Organic–Inorganic Framework, a Perovskite Layered Phosphonate MnO3PC6H4-m-Br⋅H2O, Advanced Functional Materials 29 (2019) 1901878. https://doi.org/10.1002/adfm.201901878.
[1]
D. Bechu, G. Rogez, M.W. Hosseini, S.A. Baudron, Tetrathiopyridyl-tetrathiafulvalene-based Cd(ii) coordination polymers: one ligand, one metal cation, many possibilities, New Journal of Chemistry 43 (2019) 14291–14298. https://doi.org/10.1039/c9nj03572a.
[1]
R. Bengas, H. Lahmar, K.M. Redha, L. Mentar, A. Azizi, G. Schmerber, A. Dinia, Electrochemical synthesis of n-type ZnS layers on p-Cu2O/n-ZnO heterojunctions with different deposition temperatures, RSC Advances 9 (2019) 29056–29069. https://doi.org/10.1039/c9ra04670d.
[1]
S. Berciaud, Quasi-two-dimensional electron–hole droplets, Nature Photonics 13 (2019) 225–226. https://doi.org/10.1038/s41566-019-0400-z.
[1]
M.M. Besli, C. Usubelli, M. Metzger, S. Hellstrom, S. Sainio, D. Nordlund, J. Christensen, G. Schneider, M.M. Doeff, S. Kuppan, Long-term chemothermal stability of delithiated NCA in polymer solid-state batteries, Journal of Materials Chemistry A 7 (2019) 27135–27147. https://doi.org/10.1039/c9ta11103d.
[1]
M. Biesuz, P. Bettotti, S. Signorini, M. Bortolotti, R. Campostrini, M. Bahri, O. Ersen, G. Speranza, A. Lale, S. Bernard, G.D. Soraru, First synthesis of silicon nanocrystals in amorphous silicon nitride from a preceramic polymer, Nanotechnology 30 (2019) 255601. https://doi.org/10.1088/1361-6528/ab0cc8.
[1]
D. Bissessar, J. Egly, T. Achard, P. Steffanut, S. Bellemin-Laponnaz, Catalyst-free hydrophosphination of alkenes in presence of 2-methyltetrahydrofuran: a green and easy access to a wide range of tertiary phosphines, RSC Advances 9 (2019) 27250–27256. https://doi.org/10.1039/c9ra04896k.
[1]
T. Botzung, D. Vodola, P. Naldesi, M. Muller, E. Ercolessi, G. Pupillo, Algebraic localization from power-law couplings in disordered quantum wires, Physical Review B 100 (2019) 155136. https://doi.org/10.1103/PhysRevB.100.155136.
[1]
K. Bouras, G. Schmerber, G. Ferblantier, D. Aureau, H. Park, W.K. Kim, H. Rinnert, A. Dinia, A. Slaoui, S. Colis, Cu(InGa)Se2 Solar Cell Efficiency Enhancement Using a Yb-Doped SnOx Photon Converting Layer, ACS Applied Energy Materials 2 (2019) 5094–5102. https://doi.org/10.1021/acsaem.9b00771.
[1]
K. Bouras, G. Schmerber, D. Aureau, H. Rinnert, J.-L. Rehspringer, D. Ihiawakrim, A. Dinia, A. Slaoui, S. Colis, Photon management properties of Yb-doped SnO2 nanoparticles synthesized by the sol-gel technique, Physical Chemistry Chemical Physics 21 (2019) 21407–21417. https://doi.org/10.1039/c9cp01993f.
[1]
S. Bouzida, E.B. Benamar, M. Battas, G. Schmerber, Z. Sekkat, A. Dinia, A. Slaoui, M. Abd-Lefdil, M. Regragut, EFFECT OF POTASSIUM CYANIDE ETCHING ON STRUCTURAL, OPTICAL AND ELECTRICAL PROPERTIES OF Cu2ZnSnS4 THIN FILMS DEPOSITED BY A MODIFIED SPRAY PROCESS, Surface Review and Letters 26 (2019) 1950053. https://doi.org/10.1142/S0218625X19500537.
[1]
M. Bowen, C. Back, Eric Beaurepaire a pioneer of ultrafast magnetism and organic spintronics passed away on April 24, 2018, Journal of Magnetism and Magnetic Materials 478 (2019) 279–280. https://doi.org/10.1016/j.jmmm.2018.11.064.
[1]
S. Carrara, M. Mauro, C.F. Hogan, Metallopolymers as Nanostructured Solid-State Platforms for Electrochemiluminescence Applications, ChemElectroChem 6 (2019) 5790–5796. https://doi.org/10.1002/celc.201901729.
[1]
A. Casset, J. Jouhannaud, A. Garofalo, C. Spiegelhalter, D.-V. Nguyen, D. Felder-Flesch, G. Pourroy, F. Pons, Macrophage functionality and homeostasis in response to oligoethyleneglycol-coated IONPs: Impact of a dendritic architecture, International Journal of Pharmaceutics 556 (2019) 287–300. https://doi.org/10.1016/j.ijpharm.2018.12.024.
[1]
Z. Chen, P. Gao, W. Wang, S. Klyatskaya, Z. Zhao-Karger, D. Wang, C. Kuebel, O. Fuhr, M. Fichtner, M. Ruben, A Lithium-Free Energy-Storage Device Based on an Alkyne-Substituted-Porphyrin Complex, ChemSusChem 12 (2019) 3737–3741. https://doi.org/10.1002/cssc.201901541.
[1]
Z. Chen, T. Lin, L. Zhang, L. Zhang, B. Xiang, H. Xu, F. Klappenberger, J.V. Barth, S. Klyatskaya, M. Ruben, Surface-Dependent Chemoselectivity in C-C Coupling Reactions, Angewandte Chemie-International Edition 58 (2019) 8356–8361. https://doi.org/10.1002/anie.201900636.
[1]
G. Cotin, C. Blanco-Andujar, D.-V. Nguyen, C. Affolter, S. Boutry, A. Boos, P. Ronot, B. Uring-Lambert, P. Choquet, P.E. Zorn, D. Mertz, S. Laurent, R.N. Muller, F. Meyer, D.F. Flesch, S. Bégin-Colin, Dendron based antifouling, MRI and magnetic hyperthermia properties of different shaped iron oxide nanoparticles, Nanotechnology 30 (2019) 374002. https://doi.org/10.1088/1361-6528/ab2998.
[1]
G. Cotin, F. Perton, C. Blanco-Andujar, B. Pichon, D. Mertz, S. Bégin-Colin, Design of Anisotropic Iron-Oxide-Based Nanoparticles for Magnetic Hyperthermia, in: R. Fratila, J. DeLaFuente (Eds.), NANOMATERIALS FOR MAGNETIC AND OPTICAL HYPERTHERMIA APPLICATIONS / Editd by R.M. Fratila & J.M. De La Fuente, 2019: pp. 41–60. 10.1016/B978-0-12-813928-8.00002-8.
[1]
G. Dahm, M. Bouche, C. Bailly, L. Karmazin, S. Bellemin-Laponnaz, Synthesis and structural characterization of benzyl-functionalized N-heterocyclic carbene platinum complexes: Dramatic substituent effect on anti-cancer activity, in: Journal of Organometallic Chemistry, 2019: p. 120908. https://doi.org/10.1016/j.jorganchem.2019.120908.
[1]
G.M.L. Dalmonico, E.O. Lopez, M.M. Longuinho, N.R. Checca, M. Farina, O. Ersen, A.M. Rossi, A.L. Rossi, Insight by Cryo-TEM into the growth and crystallization processes of calcium phosphate nanoparticles in aqueous medium, Materials Chemistry and Physics 237 (2019) 21862. https://doi.org/10.1016/j.matchemphys.2019.121862.
[1]
M. Darari, E. Domenichini, A. Frances-Monerris, C. Cebrian, K. Magra, M. Beley, M. Pastore, A. Monari, X. Assfeld, S. Haacke, P.C. Gros, Iron(ii) complexes with diazinyl-NHC ligands: impact of pi-deficiency of the azine core on photophysical properties, Dalton Transactions 48 (2019) 10915–10926. https://doi.org/10.1039/c9dt01731c.
[1]
A. Desmecht, F. Pennetreau, A. L’hoost, I. Nircha, B.P. Pichon, O. Riant, S. Hermans, Preparation of magnetically recoverable carbon nanotube-supported Pd(II) catalyst, in: Catalysis Today, 2019: pp. 24–29. https://doi.org/10.1016/j.cattod.2019.02.057.
[1]
A.A. Dev, R. Dey, F. Mugele, Behaviour of flexible superhydrophobic striped surfaces during (electro-)wetting of a sessile drop, Soft Matter 15 (2019) 9840–9848. https://doi.org/10.1039/c9sm01663e.
[1]
R. Díaz-Méndez, G. Pupillo, F. Mezzacapo, M. Wallin, J. Lidmar, E. Babaev, Phase-change switching in 2D via soft interactions, Soft Matter 3 (2019) 355–358. https://doi.org/10.1039/C8SM01738G.
[1]
M. Diebold, E. Christ, L. Biniek, L. Karmazin, B. Heinrich, C. Contal, S. Ghosh, P.J. Mesini, M. Brinkmann, Original polymorphism in a naphthalene bisimide pi-conjugated organogelator: a complex interplay between hydrogen bonding and heterocycle pi-stacking, Journal of Materials Chemistry C 7 (2019) 13120–13129. https://doi.org/10.1039/c9tc04402g.
[1]
M. Dolci, Y. Lei, L.-M. Lacroix, C. Kiefer, C. Leuvrey, S. Bégin-Colin, B.P. Pichon, Effect of Dipolar Interactions on the Assembly Process of Iron Oxide Nanoparticles Promoted by the CuAAC “Click” Chemistry Reaction, Journal of Physical Chemistry C 123 (2019) 27927–27936. https://doi.org/10.1021/acs.jpcc.9b08135.
[1]
M. Dolci, D. Toulemon, Z. Chaffar, J.-L. Bubendorff, F. Tielens, M. Calatayud, S. Zafeiratos, S. Bégin-Colin, B.P. Pichon, Nanoparticle Assembling through Click Chemistry Directed by Mixed SAMs for Magnetic Applications, ACS Appl. Nano Mater. 2 (2019) 554–565. https://doi.org/10.1021/acsanm.8b02152.
[1]
B. Doudin, N.T. Kemp, Ballistic Spin Transport, in: E. Tsymbal, I. Zutic (Eds.), SPINTRONICS HANDBOOK: SPIN TRANSPORT AND MAGNETISM: NANOSCALE SPINTRONICS AND APPLICATIONS, Vol. 3 , 2nd Ed. / Edited by I.Zutic, 2019: pp. 99–120.
[1]
C.A. Downing, T.J. Sturges, G. Weick, M. Stobinska, L. Martin-Moreno, Topological Phases of Polaritons in a Cavity Waveguide, Physical Review Letters 123 (2019) 217401. https://doi.org/10.1103/PhysRevLett.123.217401.
[1]
P. Dunne, J.M.D. Coey, Influence of a Magnetic Field on the Electrochemical Double Layer, Journal of Physical Chemistry C 123 (2019) 24181–24192. https://doi.org/10.1021/acs.jpcc.9b07534.
[1]
T.-Q. Duong, C. Massobrio, G. Ori, M. Boero, E. Martin, Thermal conductivity and transport modes in glassy GeTe4 by first-principles molecular dynamics, Physical Review Materials 3 (2019) 105401. https://doi.org/10.1103/PhysRevMaterials.3.105401.
[1]
J.R. Eone II, O.M. Bengone, C. Goyhenex, Unraveling Finite Size Effects on Magnetic Properties of Cobalt Nanoparticles, Journal of Physical Chemistry C 123 (2019) 4531–4539. https://doi.org/10.1021/acs.jpcc.8b11763.
[1]
P. Farger, C. Leuvrey, G. Rogez, M. Francois, P. Rabu, E. Delahay, Salts and Solvents Effect on the Crystal Structure of Imidazolium Dicarboxylate Salt Based Coordination Networks, Crystal Growth & Design 19 (2019) 4264–4272. https://doi.org/10.1021/acs.cgd.8b01725.
[1]
M. Faustini, M. Giraud, D. Jones, J. Roziere, M. Dupont, T.R. Porter, S. Nowak, M. Bahri, O. Ersen, C. Sanchez, C. Boissiere, C. Tard, J. Peron, Hierarchically Structured Ultraporous Iridium-Based Materials: A Novel Catalyst Architecture for Proton Exchange Membrane Water Electrolyzers, Advanced Energy Materials 9 (2019) 1802136. https://doi.org/10.1002/aenm.201802136.
[1]
Z. Ferjaoui, E.J. Al Dine, A. Kulmukhamedova, L. Bezdetnaya, C.S. Chan, R. Schneider, F. Mutelet, D. Mertz, S. Bégin-Colin, F. Quiles, E. Gaffet, H. Alem, Doxorubicin-Loaded Thermoresponsive Superparamagnetic Nanocarriers for Controlled Drug Delivery and Magnetic Hyperthermia Applications, ACS Applied Materials & Interfaces 11 (2019) 30610–30620. https://doi.org/10.1021/acsami.9b10444.