1839302
2020
surface-science-reports
50
creator
asc
4024
https://www.ipcms.fr/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-cb3f310f8e73619cbeee8721e4c3e9fb%22%2C%22meta%22%3A%7B%22request_last%22%3A200%2C%22request_next%22%3A50%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22RQMITG74%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Achard%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Achard%2C%20L.%20Egger%2C%20C.%20Tortoreto%2C%20L.%20Gu%26%23xE9%3Bn%26%23xE9%3Be%2C%20J.%20Lacour%2C%20Preparation%20and%20Structural%20Characterization%20of%20%5BCpRu%281%2C10-phenanthroline%29%28CH3CN%29%5D%5BX%5D%20and%20Precursor%20Complexes%20%28X%3DPF6%2C%20BArF%2C%20TRISPHAT-N%29%2C%20Helvetica%20Chimica%20Acta%20103%20%282020%29%20e2000190.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fhlca.202000190%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fhlca.202000190%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Preparation%20and%20Structural%20Characterization%20of%20%5BCpRu%281%2C10-phenanthroline%29%28CH3CN%29%5D%5BX%5D%20and%20Precursor%20Complexes%20%28X%3DPF6%2C%20BArF%2C%20TRISPHAT-N%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Achard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L%5Cu00e9o%22%2C%22lastName%22%3A%22Egger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cecilia%22%2C%22lastName%22%3A%22Tortoreto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laure%22%2C%22lastName%22%3A%22Gu%5Cu00e9n%5Cu00e9e%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J%5Cu00e9r%5Cu00f4me%22%2C%22lastName%22%3A%22Lacour%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20Cationic%20%5BRu%28%5Cu03b75-C5H5%29%28CH3CN%293%5D%2B%20complex%2C%20tris%28acetonitrile%29%28cyclopentadienyl%29ruthenium%28II%29%2C%20gives%20rise%20to%20a%20very%20rich%20organometallic%20chemistry.%20Combined%20with%20diimine%20ligands%2C%20and%201%2C10-phenanthroline%20in%20particular%2C%20this%20system%20efficiently%20catalyzes%20diazo%20decomposition%20processes%20to%20generate%20metal-carbenes%20which%20undergo%20a%20series%20of%20original%20transformations%20in%20the%20presence%20of%20Lewis%20basic%20substrates.%20Herein%2C%20syntheses%20and%20characterizations%20of%20%5BCpRu%28Phen%29%28L%29%5D%20complexes%20with%20%28large%29%20lipophilic%20non-coordinating%20%28PF6%5Cu2212%20and%20BArF%5Cu2212%29%20and%20coordinating%20TRISPHAT-N%5Cu2212%20anions%20are%20reported.%20Complex%20%5BCpRu%28%5Cu03b76-naphthalene%29%5D%5BBArF%5D%20%28%5B1%5D%5BBArF%5D%29%20is%20readily%20accessible%2C%20in%20high%20yield%2C%20by%20direct%20counterion%20exchange%20between%20%5B1%5D%5BPF6%5D%20and%20sodium%20tetrakis%5B3%2C5-bis%28trifluoromethyl%29phenyl%5Dborate%20%28NaBArF%29%20salts.%20Ligand%20exchange%20of%20%5B1%5D%5BBArF%5D%20in%20acetonitrile%20generated%20stable%20%5BRu%28%5Cu03b75-C5H5%29%28CH3CN%293%5D%5BBArF%5D%20%28%5B2%5D%5BBArF%5D%29%20complex%20in%20high%20yield.%20Then%2C%20the%20desired%20%5BCpRu%28Phen%29%28CH3CN%29%5D%20%28%5B3%5D%29%20complexes%20were%20obtained%20from%20either%20the%20%5B1%5D%20or%20%5B2%5D%20complex%20in%20the%20presence%20of%20the%201%2C10-phenanthroline%20as%20ligand.%20For%20characterization%20and%20comparison%20purposes%2C%20the%20anionic%20hemilabile%20ligand%20TRISPHAT%5Cu2212N%20%28TTN%29%20was%20introduced%20on%20the%20ruthenium%20center%2C%20from%20the%20complex%20%5B3%5D%5BPF6%5D%2C%20to%20quantitatively%20generate%20the%20desired%20complex%20%5BCpRu%28Phen%29%28TTN%29%5D%20%28%5B4%5D%29%20by%20displacement%20of%20the%20remaining%20acetonitrile%20ligand%20and%20of%20the%20PF6%5Cu2212%20anion.%20Solid%20state%20structures%20of%20complexes%20%5B1%5D%5BBArF%5D%2C%20%5B2%5D%5BBArF%5D%2C%20%5B3%5D%5BBArF%5D%2C%20%5B3%5D%5BPF6%5D%20and%20%5B4%5D%20were%20determined%20by%20X-ray%20diffraction%20studies%20and%20are%20discussed%20herein.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fhlca.202000190%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fonlinelibrary.wiley.com%5C%2Fdoi%5C%2Fabs%5C%2F10.1002%5C%2Fhlca.202000190%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222022-02-08T08%3A30%3A29Z%22%7D%7D%2C%7B%22key%22%3A%228HY269TK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Aggar%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20Aggar%2C%20D.%20Bradai%2C%20Y.I.%20Bourezg%2C%20M.%20Abdesselam%2C%20A.C.%20Chami%2C%20C.%20Mocuta%2C%20D.%20Thiaudiere%2C%20C.%20Speisser%2C%20D.%20Muller%2C%20C.%20Bouillet%2C%20F.%20Le%20Normand%2C%20GaN%20nanocrystals%20obtained%20by%20Ga%20and%20N%20implantations%20and%20thermal%20treatment%20under%20N-2%20into%20SiO2%5C%2FSi%20and%20SiNx%5C%2FSi%20wafers%2C%20Nuclear%20Instruments%20%26amp%3B%20Methods%20in%20Physics%20Research%20Section%20B-Beam%20Interactions%20with%20Materials%20and%20Atoms%20485%20%282020%29%2057%26%23x2013%3B67.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.nimb.2020.10.012%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.nimb.2020.10.012%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22GaN%20nanocrystals%20obtained%20by%20Ga%20and%20N%20implantations%20and%20thermal%20treatment%20under%20N-2%20into%20SiO2%5C%2FSi%20and%20SiNx%5C%2FSi%20wafers%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Aggar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Bradai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%20I.%22%2C%22lastName%22%3A%22Bourezg%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Abdesselam%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20C.%22%2C%22lastName%22%3A%22Chami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Mocuta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Thiaudiere%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Speisser%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Muller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Le%20Normand%22%7D%5D%2C%22abstractNote%22%3A%22The%20formation%20of%20GaN%20nanocrystals%20in%20SiO2%5C%2FSi%20and%20SiNx%5C%2FSi%20dielectric%20layers%20implanted%20with%20Ga%20%2B%20and%20N%20%2B%20ions%2C%20followed%20by%20annealing%20at%20950%20degrees%20C%20for%2060-120%20min%20in%20N-2%2C%20has%20been%20studied%20by%20high%20resolution%20transmission%20electron%20microscopy%20%28HRTEM%29%2C%20synchrotron%20radiation%20X-ray%20diffraction%20%28XRD%29%2C%20X-ray%20absorption%20fine%20structure%20%28XAFS%29%20technique%20at%20the%20Ga%20K-edge%2C%20as%20well%20as%20by%20Rutherford%20Backscattering%20spectrometry%20%28RBS%29%2C%20X-Ray%20photoelectron%20spectroscopy%20%28XPS%29%2C%20Raman%20spectroscopy%20%28RS%29%20and%20Scanning%20electron%20microscopy%20%28SEM%29.%20The%20effect%20of%20the%20dielectric%20matrix%2C%20of%20the%20gas%20annealing%20environment%20%28N-2%29%20and%20of%20the%20annealing%20time%20at%20950%20degrees%20C%20have%20been%20inves-tigated.%20GaN%20nanocrystals%20implanted%20near%20the%20surface%20are%20observed%20in%20SiO2%5C%2FSi%20only.%20The%20hexagonal%20wurtzite%20crystalline%20structure%20was%20confirmed%20by%20HRTEM%2C%20XRD%20and%20Raman%20spectroscopy.%20However%2C%20the%20synthesis%20process%20is%20multiphasic%20as%20elemental%20Ga-0%20nanoparticles%20at%20larger%20depths%20and%20Ga2O3%20rods%20%28similar%20to%20200-300%20nm%29%20on%20the%20surface%20were%20formed%20in%20addition%20to%20implanted%20h-GaN%2C%20as%20shown%20by%20TEM%2C%20XAFS%2C%20SEM%2C%20XPS%20and%20Raman%20spectroscopy.%20Moreover%2C%20Ga%20atoms%20are%20always%20remaining%20on%20some%20vacant%20Si%20sites%20in%20the%20SiO2%20matrix.%20The%20local%20environment%20around%20Ga%20is%20quite%20different%20in%20the%20SiNx%20matrix%2C%20as%20seen%20by%20XAFS.%20This%20difference%20can%20be%20explained%20by%20the%20gallium%20and%20nitrogen%20diffusions%20which%20are%20much%20faster%20in%20the%20case%20of%20the%20SiO2%20matrix%2C%20as%20shown%20by%20RBS%20profiles.%20Results%20are%20discussed%20in%20close%20comparison%20with%20existing%20literature.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.nimb.2020.10.012%22%2C%22ISSN%22%3A%220168-583X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.nimb.2020.10.012%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222021-02-17T16%3A03%3A12Z%22%7D%7D%2C%7B%22key%22%3A%22TXBD3C67%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Andelescu%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.-A.%20Andelescu%2C%20B.%20Heinrich%2C%20M.A.%20Spirache%2C%20E.%20Voirin%2C%20M.%20La%20Deda%2C%20G.%20Di%20Maio%2C%20E.I.%20Szerb%2C%20B.%20Donnio%2C%20O.%20Costisor%2C%20Playing%20with%20Pt-II%20and%20Zn-II%20Coordination%20to%20Obtain%20Luminescent%20Metallomesogens%2C%20Chemistry-a%20European%20Journal%2026%20%282020%29%204850%26%23x2013%3B4860.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202000124%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202000124%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Playing%20with%20Pt-II%20and%20Zn-II%20Coordination%20to%20Obtain%20Luminescent%20Metallomesogens%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adelina-Antonia%22%2C%22lastName%22%3A%22Andelescu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Angela%22%2C%22lastName%22%3A%22Spirache%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emilie%22%2C%22lastName%22%3A%22Voirin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimo%22%2C%22lastName%22%3A%22La%20Deda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giuseppe%22%2C%22lastName%22%3A%22Di%20Maio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elisabeta%20I.%22%2C%22lastName%22%3A%22Szerb%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Otilia%22%2C%22lastName%22%3A%22Costisor%22%7D%5D%2C%22abstractNote%22%3A%22Blue-green%20luminescent%20terpyridine-containing%20Pt-II%20and%20Zn-II%20complexes%20are%20reported.%20Equipped%20with%20lipophilic%20gallate%20units%2C%20which%20act%20as%20monodentate%20ancillary%20coordinating%20ligands%20and%5C%2For%20as%20anions%2C%20they%20display%20low-temperature%20mesomorphic%20properties%20%28lamello-columnar%20and%20hexagonal%20mesophases%20for%20Pt-II%20and%20Zn-II%20complexes%2C%20respectively%29.%20The%20mesomorphic%20properties%20were%20investigated%20by%20polarised%20optical%20microscopy%2C%20differential%20scanning%20calorimetry%2C%20thermogravimetric%20analysis%20and%20X-ray%20scattering%20of%20bulk%20materials%20and%20oriented%20thin%20films.%20The%20model%20of%20self-assembly%20into%20the%20lamello-columnar%20phase%20of%20the%20Pt-II%20complex%20has%20been%20described%20in%20detail.%20The%20optical%20properties%20of%20the%20complexes%20were%20investigated%20in%20the%20liquid%20and%20condensed%20liquid%20crystalline%20states%2C%20highlighting%20the%20delicate%20balance%20between%20the%20role%20of%20the%20metal%20in%20determining%20the%20type%20of%20excited%20state%20responsible%20for%20the%20emission%2C%20and%20the%20role%20of%20the%20ancillary%20ligand%20in%20driving%20intermolecular%20interactions%20for%20proper%20mesophase%20formation.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchem.202000124%22%2C%22ISSN%22%3A%220947-6539%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchem.202000124%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22BMA9GKQT%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A31%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22URNTZSGD%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Anefnaf%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Anefnaf%2C%20S.%20Aazou%2C%20G.%20Schmerber%2C%20S.%20Refki%2C%20N.%20Zimmermann%2C%20T.%20Heiser%2C%20G.%20Ferblantier%2C%20A.%20Slaoui%2C%20A.%20Dinia%2C%20M.%20Abd-Lefdil%2C%20Z.%20Sekkat%2C%20Polyethylenimine-Ethoxylated%20Interfacial%20Layer%20for%20Efficient%20Electron%20Collection%20in%20SnO2-Based%20Inverted%20Organic%20Solar%20Cells%2C%20Crystals%2010%20%282020%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fcryst10090731%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fcryst10090731%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Polyethylenimine-Ethoxylated%20Interfacial%20Layer%20for%20Efficient%20Electron%20Collection%20in%20SnO2-Based%20Inverted%20Organic%20Solar%20Cells%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ikram%22%2C%22lastName%22%3A%22Anefnaf%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Safae%22%2C%22lastName%22%3A%22Aazou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guy%22%2C%22lastName%22%3A%22Schmerber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Siham%22%2C%22lastName%22%3A%22Refki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Zimmermann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Heiser%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G%5Cu00e9rald%22%2C%22lastName%22%3A%22Ferblantier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelilah%22%2C%22lastName%22%3A%22Slaoui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohammed%22%2C%22lastName%22%3A%22Abd-Lefdil%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zouheir%22%2C%22lastName%22%3A%22Sekkat%22%7D%5D%2C%22abstractNote%22%3A%22In%20this%20work%2C%20we%20studied%20inverted%20organic%20solar%20cells%20based%20on%20bulk%20heterojunction%20using%20poly%283-hexylthiophene-2%2C5-diyl%29%3A%5B6%2C6%5D-phenyl-C71-butyric%20acid%20methyl%20ester%20%28P3HT%3APCBM%29%20as%20an%20active%20layer%20and%20a%20novel%20cathode%20buffer%20bilayer%20consisting%20of%20tin%20dioxide%20%28SnO2%29%20combined%20with%20polyethylenimine-ethoxylated%20%28PEIE%29%20to%20overcome%20the%20limitations%20of%20the%20single%20cathode%20buffer%20layer.%20The%20combination%20of%20SnO2%20with%20PEIE%20is%20a%20promising%20approach%20that%20improves%20the%20charge%20carrier%20collection%20and%20reduces%20the%20recombination.%20The%20efficient%20device%2C%20which%20is%20prepared%20with%20a%20cathode%20buffer%20bilayer%20of%2020%20nm%20SnO2%20combined%20with%2010%20nm%20PEIE%2C%20achieved%20Jsc%20%3D%207.86%20mA%5C%2Fcm2%2C%20Voc%20%3D%20574%20mV%20and%20PCE%20%3D%202.84%25.%20The%20obtained%20results%20exceed%20the%20performances%20of%20reference%20solar%20cell%20using%20only%20a%20single%20cathode%20layer%20of%20either%20SnO2%20or%20PEIE.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3390%5C%2Fcryst10090731%22%2C%22ISSN%22%3A%222073-4352%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fcryst10090731%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222020-09-18T13%3A40%3A27Z%22%7D%7D%2C%7B%22key%22%3A%22XXRENUEQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Anefnaf%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Anefnaf%2C%20S.%20Aazou%2C%20G.%20Schmerber%2C%20A.%20Dinia%2C%20Z.%20Sekkat%2C%20Study%20the%20effect%20of%20fullerene%20derivatives%20ratio%20on%20P3HT-based%20inverted%20organic%20solar%20cells%2C%20in%3A%20Z.H.%20Kafafi%2C%20P.A.%20Lane%2C%20K.%20Lee%2C%20H.W.%20Ade%2C%20Y.-L.%20%28Lynn%29%20Loo%20%28Eds.%29%2C%20Organic%2C%20Hybrid%2C%20and%20Perovskite%20Photovoltaics%20XXI%2C%20SPIE%2C%202020%3A%20pp.%2057%26%23x2013%3B66.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1117%5C%2F12.2568790%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1117%5C%2F12.2568790%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Study%20the%20effect%20of%20fullerene%20derivatives%20ratio%20on%20P3HT-based%20inverted%20organic%20solar%20cells%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I.%22%2C%22lastName%22%3A%22Anefnaf%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Aazou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guy%22%2C%22lastName%22%3A%22Schmerber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Z.%22%2C%22lastName%22%3A%22Sekkat%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22Zakya%20H.%22%2C%22lastName%22%3A%22Kafafi%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22Paul%20A.%22%2C%22lastName%22%3A%22Lane%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22Kwanghee%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22Harald%20W.%22%2C%22lastName%22%3A%22Ade%22%7D%2C%7B%22creatorType%22%3A%22editor%22%2C%22firstName%22%3A%22Yueh-Lin%20%28Lynn%29%22%2C%22lastName%22%3A%22Loo%22%7D%5D%2C%22abstractNote%22%3A%22The%20inverted%20organic%20solar%20cell%20devices%20%28iOSCs%29%20were%20fabricated%20with%20different%20weight%20ratios%201%3A0.6%2C%201%3A0.8%2C%20and%201%3A1%20of%20P3HT%20and%20PCBM%2C%20respectively.%20The%20photo-physical%20properties%20of%20these%20devices%20with%20varying%20weight%20ratios%20are%20investigated.%20We%20find%20that%20the%20absorption%20spectra%20revealed%20a%20decrease%20in%20the%20intensities%20with%20increasing%20the%20fullerene%20ratio%20and%20the%20peaks%20were%20blue%20shifted.%20Thin%20films%20morphology%20is%20evaluated%20by%20atomic%20force%20microscopy%20%28AFM%29.%20The%20PL%20quenching%20suggests%20that%20the%20transfer%20of%20photo-induced%20electrons%20from%20P3HT%20to%20PCBM%20increases%20hugely%20with%20an%20increase%20in%20the%20amount%20of%20PCBM.%20Raman%20spectroscopy%20for%20devices%20shows%20a%20strong%20reduction%20in%20the%20crystallinity%20by%20increasing%20the%20ratio%20of%20fullerene%20within%20the%20blend.%20The%20J-V%20measurements%20for%20all%20devices%20were%20performed%20under%20the%20illumination%20of%20simulated%20AM%201.5%20sunlight%20at%20100%20mW%5C%2Fcm2.%20External%20quantum%20efficiency%20%28EQE%29%20and%20Internal%20quantum%20efficiency%20%28IQE%29%20measurements%20are%20also%20performed%20for%20the%20best%20device.%20The%20best%20performance%20was%20recorded%20for%20the%20device%20with%201%3A1%20weight%20ratio%20of%20P3HT%20and%20PCBM%20give%20Power%20Conversion%20Efficiency%20%28PCE%29%20of%203.67%25%2C%20in%20contrast%20to%203.36%25%20for%20%281%3A0.8%29%20and%202.51%25%20for%201%3A0.6%20devices.%22%2C%22date%22%3A%222020%22%2C%22proceedingsTitle%22%3A%22Organic%2C%20Hybrid%2C%20and%20Perovskite%20Photovoltaics%20XXI%22%2C%22conferenceName%22%3A%22Organic%2C%20Hybrid%2C%20and%20Perovskite%20Photovoltaics%20XXI%2C%20Online%2C%2024%20ao%5Cu00fbt-%204%20septembre%202020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1117%5C%2F12.2568790%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1117%5C%2F12.2568790%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-01-25T14%3A03%3A48Z%22%7D%7D%2C%7B%22key%22%3A%224747CR37%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Avedissian%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Avedissian%2C%20J.%20Arabski%2C%20J.A.%20Wytko%2C%20J.%20Weiss%2C%20C.%20M%26%23xE9%3Bny%2C%20Probing%20the%20Growth%20of%20Organic%20Molecular%20Films%20Embedded%20between%20Cobalt%20and%20Iron%20Electrodes%3A%20Ferromagnetic%20Nuclear%20Resonance%20Approach%2C%20Advanced%20Functional%20Materials%202005605%20%282020%29%201%26%23x2013%3B6.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadfm.202005605%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadfm.202005605%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Probing%20the%20Growth%20of%20Organic%20Molecular%20Films%20Embedded%20between%20Cobalt%20and%20Iron%20Electrodes%3A%20Ferromagnetic%20Nuclear%20Resonance%20Approach%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Garen%22%2C%22lastName%22%3A%22Avedissian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacek%22%2C%22lastName%22%3A%22Arabski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jennifer%20A.%22%2C%22lastName%22%3A%22Wytko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean%22%2C%22lastName%22%3A%22Weiss%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%5D%2C%22abstractNote%22%3A%22Physical%20properties%20of%20magnetic%20nanostructures%20and%20devices%20strongly%20depend%20on%20the%20morphological%20characteristics%20of%20their%20various%20components.%20This%20is%20especially%20true%20and%20becomes%20particularly%20complex%20in%20hybrid%20nanostructures%2C%20where%20soft%20organic%20molecules%20are%20at%20the%20vicinity%20of%20ferromagnetic%20metallic%20films.%20The%20supramolecular%20architecture%20of%20molecular%20films%20embedded%20between%20Fe%20and%20Co%20layers%20is%20investigated%20by%20ferromagnetic%20nuclear%20resonance%20%28FNR%29.%20With%20such%20sample%20architecture%2C%20the%20presence%20of%20pin%20holes%20in%20the%20organic%20layers%20is%20detected%20by%20FNR%20contributions%20in%20a%20specific%20spectral%20range.%20The%20methodology%20that%20is%20developed%20allows%20the%20probing%20of%20the%20continuity%20and%20the%20packing%20of%20zinc%20tetraphenyl%20porphyrin%20%28ZnTPP%29%20molecular%20films%20between%20the%20Co%20and%20Fe%20films.%20The%20experimental%20results%20suggest%20that%2C%20regardless%20of%20the%20nature%20of%20the%20ferromagnetic%20underlayer%2C%20at%20least%2015%20monolayers%20of%20ZnTPP%20are%20necessary%20to%20form%20continuous%20and%20pin-hole%20free%20molecular%20films.%20In%20addition%2C%20quantitative%20analyses%20show%20that%20ZnTPP%20layers%20exhibit%20distinct%20morphologies%20that%20are%20dependent%20on%20the%20nature%20of%20the%20ferromagnetic%20metallic%20underlayer.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadfm.202005605%22%2C%22ISSN%22%3A%221616-301X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadfm.202005605%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22TR4ZUX8B%22%5D%2C%22dateModified%22%3A%222021-11-17T14%3A54%3A35Z%22%7D%7D%2C%7B%22key%22%3A%22VD38SCIN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Avedissian%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Avedissian%2C%20J.%20Arabski%2C%20J.A.%20Wytko%2C%20J.%20Weiss%2C%20C.%20M%26%23xE9%3Bny%2C%20Revealing%20the%20morphology%20and%20the%20magnetic%20properties%20of%20single%20buried%20cobalt-ZnTPP%20hybrid%20interfaces%20by%20ferromagnetic%20nuclear%20resonance%20spectroscopy%2C%20Physical%20Review%20B%20102%20%282020%29%20184114.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.102.184114%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.102.184114%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Revealing%20the%20morphology%20and%20the%20magnetic%20properties%20of%20single%20buried%20cobalt-ZnTPP%20hybrid%20interfaces%20by%20ferromagnetic%20nuclear%20resonance%20spectroscopy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Garen%22%2C%22lastName%22%3A%22Avedissian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacek%22%2C%22lastName%22%3A%22Arabski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jennifer%20A.%22%2C%22lastName%22%3A%22Wytko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean%22%2C%22lastName%22%3A%22Weiss%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%5D%2C%22abstractNote%22%3A%22The%20deeply%20buried%2C%20yet%20most%20important%20part%20of%20any%20spintronic%20device%20is%20the%20interface.%20This%20is%20even%20more%20interesting%20and%20much%20more%20complex%20when%20soft%2C%20light%20materials%20like%20organic%20molecules%20are%20in%20contact%20with%20an%20inorganic%20metallic%20electrode.%20Hence%2C%20exceptional%20care%20is%20required%20to%20better%20understand%20the%20phenomena%20driven%20by%20this%20type%20of%20organic%5C%2Finorganic%20interfaces.%20To%20this%20end%2C%20ferromagnetic%20nuclear%20resonance%20%28FNR%29%20spectroscopy%20studies%20were%20performed%20to%20investigate%20the%20morphology%20and%20the%20magnetic%20properties%20of%20the%20hybrid%20organic-inorganic%20interfaces%20when%20zinc%20tetraphenyl%20porphyrin%20%28ZnTPP%29%20molecules%20are%20at%20the%20vicinity%20of%20ferromagnetic%20metallic%20cobalt%20%28Co%29%20layers.%20The%20FNR%20experimental%20results%20show%20that%20when%20ZnTPP%20is%20deposited%20on%20top%20of%20Co%20the%20resulting%20interface%20is%20smoother%20and%20sharper%20compared%20to%20the%20more%20extended%20interface%20obtained%20when%20Co%20is%20deposited%20on%20top%20of%20ZnTPP.%20The%20shape%20of%20the%20spectra%20suggests%20that%20no%20chemical%20bonds%20take%20place%20between%20the%20interfacial%20Co%20atoms%20and%20the%20ZnTPP%20molecules%20and%20that%20interactions%20at%20the%20interfaces%20are%20governed%20by%20weak%20van%20der%20Waals%20forces.%20Finally%2C%20FNR%20also%20showed%20that%20the%20magnetic%20anisotropy%20at%20the%20Co-ZnTPP%20hybrid%20interfaces%20is%20reduced%20compared%20to%20the%20magnetic%20anisotropy%20of%20the%20Co%20atoms%20inside%20the%20Co%20films.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.102.184114%22%2C%22ISSN%22%3A%222469-9950%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevB.102.184114%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22TR4ZUX8B%22%5D%2C%22dateModified%22%3A%222021-11-17T14%3A54%3A40Z%22%7D%7D%2C%7B%22key%22%3A%22QD8A63H9%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Baaziz%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EW.%20Baaziz%2C%20S.%20Valette%2C%20A.-S.%20Gay%2C%20C.%20Hirlimann%2C%20O.%20Ersen%2C%20A%20New%20Methodology%20for%20Quantifying%20the%20Surface%20Crystallography%20of%20Particles%20from%20their%20Tomographic%20Reconstruction%3A%20Application%20to%20Pd%20Nanoparticles%20Embedded%20in%20a%20Mesoporous%20Silica%20Shell%2C%20ChemCatChem%2012%20%282020%29%201%26%23x2013%3B10.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcctc.202000275%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcctc.202000275%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20New%20Methodology%20for%20Quantifying%20the%20Surface%20Crystallography%20of%20Particles%20from%20their%20Tomographic%20Reconstruction%3A%20Application%20to%20Pd%20Nanoparticles%20Embedded%20in%20a%20Mesoporous%20Silica%20Shell%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%22%2C%22lastName%22%3A%22Valette%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Sophie%22%2C%22lastName%22%3A%22Gay%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charles%22%2C%22lastName%22%3A%22Hirlimann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%5D%2C%22abstractNote%22%3A%22In%20this%20work%2C%20we%20propose%20an%20experimental%20approach%20allowing%20for%20the%20identification%20and%20the%20subsequent%20quantification%20of%20nanoparticles%20crystallographic%20facets%2C%20based%20on%203D%20data%20obtained%20using%20Transmission%20Electron%20Microscopy%20%28TEM%29.%20The%20particle%20shape%20and%20faceting%20can%20be%20determined%20using%20Electron%20Tomography%20%28ET%29%20combined%20with%20High-Resolution%20TEM%20%28HR-TEM%29.%20The%20quantitative%20analysis%20of%20faceting%20is%20carried%20out%20on%20the%20particles%203D%20models%20using%20a%20geometrical%20approach%20that%20automatically%20detects%20planar%20regions%20on%20particle%20boundaries.%20In%20order%20to%20check%20the%20reliability%20of%20our%20approach%2C%20we%20analyzed%20palladium%20particles%20confined%20inside%20or%20located%20at%20the%20outer%20surface%20of%20a%20mesoporous%20silica%20shell%20%28Pd%40SiO2%29%20after%20an%20annealing%20treatment%20at%20250%20degrees%20C%20under%20hydrogen%20for%2012%20hours.%20From%20the%20materials%20perspective%2C%20the%20aim%20of%20the%20current%20work%20is%20to%20investigate%20the%20encapsulation%20effect%20of%20silica%20%28SiO2%29%20shells%20on%20the%20change%20in%20morphology%20and%20faceting%20of%20palladium%20nanoparticles%20during%20such%20annealing%20treatment.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fcctc.202000275%22%2C%22ISSN%22%3A%221867-3880%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fcctc.202000275%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222020-08-06T11%3A55%3A47Z%22%7D%7D%2C%7B%22key%22%3A%229992CG3X%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bachellier%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Bachellier%2C%20B.%20Verlhac%2C%20L.%20Garnier%2C%20J.%20Zaldivar%2C%20C.%20Rubio-Verdu%2C%20P.%20Abufager%2C%20M.%20Ormaza%2C%20D.-J.%20Choi%2C%20M.-L.%20Bocquet%2C%20J.%20Pascual%20I.%2C%20N.%20Lorente%2C%20L.%20Limot%2C%20Vibron-assisted%20spin%20excitation%20in%20a%20magnetically%20anisotropic%20molecule%2C%20Nature%20Communications%2011%20%282020%29%201619.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41467-020-15266-0%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41467-020-15266-0%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Vibron-assisted%20spin%20excitation%20in%20a%20magnetically%20anisotropic%20molecule%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Bachellier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Verlhac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Garnier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Zaldivar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Rubio-Verdu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Abufager%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Ormaza%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D-J%22%2C%22lastName%22%3A%22Choi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M-L%22%2C%22lastName%22%3A%22Bocquet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%2C%20I%22%2C%22lastName%22%3A%22Pascual%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Lorente%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Limot%22%7D%5D%2C%22abstractNote%22%3A%22The%20electrical%20control%20and%20readout%20of%20molecular%20spin%20states%20are%20key%20for%20high-density%20storage.%20Expectations%20are%20that%20electrically-driven%20spin%20and%20vibrational%20excitations%20in%20a%20molecule%20should%20give%20rise%20to%20new%20conductance%20features%20in%20the%20presence%20of%20magnetic%20anisotropy%2C%20offering%20alternative%20routes%20to%20study%20and%2C%20ultimately%2C%20manipulate%20molecular%20magnetism.%20Here%2C%20we%20use%20inelastic%20electron%20tunneling%20spectroscopy%20to%20promote%20and%20detect%20the%20excited%20spin%20states%20of%20a%20prototypical%20molecule%20with%20magnetic%20anisotropy.%20We%20demonstrate%20the%20existence%20of%20a%20vibron-assisted%20spin%20excitation%20that%20can%20exceed%20in%20energy%20and%20in%20amplitude%20a%20simple%20excitation%20among%20spin%20states.%20This%20excitation%2C%20which%20can%20be%20quenched%20by%20structural%20changes%20in%20the%20magnetic%20molecule%2C%20is%20explained%20using%20first-principles%20calculations%20that%20include%20dynamical%20electronic%20correlations.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41467-020-15266-0%22%2C%22ISSN%22%3A%222041-1723%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41467-020-15266-0%22%2C%22collections%22%3A%5B%229USMFXMV%22%2C%22DEB5KWFS%22%5D%2C%22dateModified%22%3A%222020-08-05T14%3A43%3A44Z%22%7D%7D%2C%7B%22key%22%3A%22H3ZUV5N6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Balfourier%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Balfourier%2C%20N.%20Luciani%2C%20G.%20Wang%2C%20G.%20Lelong%2C%20O.%20Ersen%2C%20A.%20Khelfa%2C%20D.%20Alloyeau%2C%20F.%20Gazeau%2C%20F.%20Carn%2C%20Unexpected%20intracellular%20biodegradation%20and%20recrystallization%20of%20gold%20nanoparticles%2C%20Proceedings%20of%20the%20National%20Academy%20of%20Sciences%20of%20the%20United%20States%20of%20America%20117%20%282020%29%20103%26%23x2013%3B113.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1073%5C%2Fpnas.1911734116%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1073%5C%2Fpnas.1911734116%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unexpected%20intracellular%20biodegradation%20and%20recrystallization%20of%20gold%20nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alice%22%2C%22lastName%22%3A%22Balfourier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Luciani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gerald%22%2C%22lastName%22%3A%22Lelong%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelali%22%2C%22lastName%22%3A%22Khelfa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Alloyeau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florence%22%2C%22lastName%22%3A%22Gazeau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florent%22%2C%22lastName%22%3A%22Carn%22%7D%5D%2C%22abstractNote%22%3A%22Gold%20nanoparticles%20are%20used%20in%20an%20expanding%20spectrum%20of%20biomedical%20applications.%20However%2C%20little%20is%20known%20about%20their%20long-term%20fate%20in%20the%20organism%20as%20it%20is%20generally%20admitted%20that%20the%20inertness%20of%20gold%20nanoparticles%20prevents%20their%20biodegradation.%20In%20this%20work%2C%20the%20biotransformations%20of%20gold%20nanoparticles%20captured%20by%20primary%20fibroblasts%20were%20monitored%20during%20up%20to%206%20mo.%20The%20combination%20of%20electron%20microscopy%20imaging%20and%20transcriptomics%20study%20reveals%20an%20unexpected%202-step%20process%20of%20biotransformation.%20First%2C%20there%20is%20the%20degradation%20of%20gold%20nanoparticles%2C%20with%20faster%20disappearance%20of%20the%20smallest%20size.%20This%20degradation%20is%20mediated%20by%20NADPH%20oxidase%20that%20produces%20highly%20oxidizing%20reactive%20oxygen%20species%20in%20the%20lysosome%20combined%20with%20a%20cell-protective%20expression%20of%20the%20nuclear%20factor%2C%20erythroid%202.%20Second%2C%20a%20gold%20recrystallization%20process%20generates%20biomineralized%20nanostructures%20consisting%20of%202.5-nm%20crystalline%20particles%20self-assembled%20into%20nanoleaves.%20Metallothioneins%20are%20strongly%20suspected%20to%20participate%20in%20buildings%20blocks%20biomineralization%20that%20self-assembles%20in%20a%20process%20that%20could%20be%20affected%20by%20a%20chelating%20agent.%20These%20degradation%20products%20are%20similar%20to%20aurosomes%20structures%20revealed%2050%20y%20ago%20in%20vivo%20after%20gold%20salt%20therapy.%20Overall%2C%20we%20bring%20to%20light%20steps%20in%20the%20lifecycle%20of%20gold%20nanoparticles%20in%20which%20cellular%20pathways%20are%20partially%20shared%20with%20ionic%20gold%2C%20revealing%20a%20common%20gold%20metabolism.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1073%5C%2Fpnas.1911734116%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1073%5C%2Fpnas.1911734116%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222020-02-03T10%3A42%3A22Z%22%7D%7D%2C%7B%22key%22%3A%22BUT2Y5X8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Banhart%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EF.%20Banhart%2C%20Elemental%20carbon%20in%20the%20sp%281%29%20hybridization%2C%20ChemTexts%206%20%282020%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs40828-019-0098-z%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs40828-019-0098-z%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Elemental%20carbon%20in%20the%20sp%281%29%20hybridization%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florian%22%2C%22lastName%22%3A%22Banhart%22%7D%5D%2C%22abstractNote%22%3A%22Hybridizations%20of%20carbon%20atoms%20are%20textbook%20examples%20of%20different%20types%20of%20chemical%20bonds.%20Likewise%2C%20the%20elemental%20phases%20of%20carbon%2C%20graphite%20and%20diamond%20are%20well%20known%20as%20materials%20in%20pure%20sp%282%29%20or%20sp%283%29%20hybridizations.%20However%2C%20what%20is%20much%20less%20known%20is%20the%20elemental%20carbon%20phase%20in%20the%20sp%281%29%20%28or%20sp%29%20hybridization.%20The%20phase%20is%20called%20carbyne%20and%20still%20somewhat%20elusive%2C%20although%20many%20reports%20on%20successful%20syntheses%20have%20been%20given.%20Carbyne%20is%20assumed%20to%20consist%20of%20densely%20packed%20linear%20chains%20of%20carbon%20atoms%20and%20appears%20to%20be%20a%20rather%20unstable%20material.%20Individual%20chains%20of%20carbon%20atoms%20are%20perfectly%20one-dimensional%20structures%20and%20show%20many%20highly%20interesting%20physical%20properties%20of%20classical%201D%20materials.%20This%20article%20first%20gives%20an%20overview%20of%20the%20relation%20between%20the%20differently%20hybridized%20elemental%20phases%20of%20carbon%20and%20then%20focuses%20on%20the%20structure%20and%20the%20properties%20of%20individual%20sp%281%29%20chains%20of%20carbon%20atoms.%20A%20brief%20survey%20of%20the%20synthesis%20of%20individual%20carbon%20chains%20as%20well%20as%20bulk%20carbyne%20is%20given%20at%20the%20end%20of%20the%20article.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1007%5C%2Fs40828-019-0098-z%22%2C%22ISSN%22%3A%222199-3793%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1007%5C%2Fs40828-019-0098-z%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222023-06-15T14%3A49%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22D2PJCQ8X%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Barsella%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Barsella%2C%20M.A.%20Hurier%2C%20M.D.%20Pichois%2C%20M.%20Vomir%2C%20H.%20Hasan%2C%20L.%20Mager%2C%20B.%20Donnio%2C%20J.-L.%20Gallani%2C%20M.V.%20Rastei%2C%20Photonic%20Excitation%20of%20a%20Micromechanical%20Cantilever%20in%20Electrostatic%20Fields%2C%20Physical%20Review%20Letters%20125%20%282020%29%20254301.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.125.254301%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.125.254301%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Photonic%20Excitation%20of%20a%20Micromechanical%20Cantilever%20in%20Electrostatic%20Fields%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Barsella%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marion%20A.%22%2C%22lastName%22%3A%22Hurier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Manouel%20D.%22%2C%22lastName%22%3A%22Pichois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%22%2C%22lastName%22%3A%22Vomir%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22H.%22%2C%22lastName%22%3A%22Hasan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lo%5Cu00efc%22%2C%22lastName%22%3A%22Mager%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Louis%22%2C%22lastName%22%3A%22Gallani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%20V.%22%2C%22lastName%22%3A%22Rastei%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevLett.125.254301%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevLett.125.254301%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22CHW2VGSR%22%2C%22VRM2E3H6%22%2C%22WWGPR7DV%22%2C%22BMA9GKQT%22%2C%22JZU5CN8N%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222021-04-30T14%3A18%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22BJACBWUD%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Batista%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.T.F.%20Batista%2C%20W.%20Baaziz%2C%20A.-L.%20Taleb%2C%20J.%20Chaniot%2C%20M.%20Moreaud%2C%20C.%20Legens%2C%20A.%20Aguilar-Tapia%2C%20O.%20Proux%2C%20J.-L.%20Hazemann%2C%20F.%20Diehl%2C%20C.%20Chizallet%2C%20A.-S.%20Gay%2C%20O.%20Ersen%2C%20P.%20Raybaud%2C%20Atomic%20Scale%20Insight%20into%20the%20Formation%2C%20Size%2C%20and%20Location%20of%20Platinum%20Nanoparticles%20Supported%20on%20gamma-Alumina%2C%20ACS%20Catalysis%2010%20%282020%29%204193%26%23x2013%3B4204.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facscatal.0c00042%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facscatal.0c00042%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Atomic%20Scale%20Insight%20into%20the%20Formation%2C%20Size%2C%20and%20Location%20of%20Platinum%20Nanoparticles%20Supported%20on%20gamma-Alumina%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ana%20T.%20F.%22%2C%22lastName%22%3A%22Batista%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Lise%22%2C%22lastName%22%3A%22Taleb%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johan%22%2C%22lastName%22%3A%22Chaniot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Moreaud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christele%22%2C%22lastName%22%3A%22Legens%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Aguilar-Tapia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Proux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Louis%22%2C%22lastName%22%3A%22Hazemann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Diehl%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Celine%22%2C%22lastName%22%3A%22Chizallet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Sophie%22%2C%22lastName%22%3A%22Gay%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pascal%22%2C%22lastName%22%3A%22Raybaud%22%7D%5D%2C%22abstractNote%22%3A%22A%20clear%20description%20of%20the%20morphology%20and%20location%2C%20with%20respect%20to%20the%20support%2C%20of%20metallic%20subnanometric%20particles%20remains%20a%20current%20strenuous%20experimental%20challenge%20in%20numerous%20catalytic%20applications%20such%20as%20naphtha%20reforming%20and%20biomass%20conversion.%20High-resolution%20HAADF-STEM%20coupled%20with%20in%20situ%20and%20tomographic%20analyses%20have%20been%20undertaken%20on%20a%20platinum%20%28Pt%29%20active%20phase%20supported%20on%20chlorinated%20alumina%20%28gamma-Al2O3%29%20with%200.3%20and%201%20wt%20%25%20Pt%20loadings%2C%20highlighting%20the%20formation%20of%20flat%20nanoparticles%20%28NPs%29%20of%200.9%20nm%20diameter%20and%20Pt%20single%20atoms%20%28SAs%29%20in%20the%20reduced%20state.%20While%20SAs%20and%20weakly%20cohesive%20clusters%20are%20predominantly%20observed%20in%20the%20oxide%20state%2C%20with%20a%20coordination%20sphere%20of%20Pt%20composed%20of%20O%20and%20Cl%20as%20revealed%20by%20EXAFS%2C%20the%20ratio%20between%20SAs%20and%20Pt%20NPs%20in%20the%20reduced%20state%20is%20found%20to%20be%20about%202.8.%20This%20ratio%20is%20the%20same%20for%20the%20two%20metal%20loadings%3A%20both%20the%20total%20numbers%20of%20NPs%20and%20SAs%20increase%20at%20a%20higher%20metal%20loading.%20Electron%20tomography%20reveals%20that%20the%20vast%20majority%20of%20NPs%20are%20located%20on%20the%20edges%20or%20defects%20%28steps%2C%20kinks%29%20of%20the.-alumina%20support%20crystallites.%20DFT%20calculations%20further%20highlight%20the%20optimized%20structures%20of%20NPs%20located%20at%20the%20gamma-Al2O3%20%28110%29-%28100%29%20edge%20and%20near-edge%20with%20a%20stability%20competing%20with%20NPs%20located%20either%20on%20the%20%28110%29%20or%20on%20the%20%28100%29%20gamma-Al2O3%20facet.%20A%20mathematical%20analysis%20of%20the%20segmented%20volumes%20shows%20that%20the%20average%20geodesic%20distances%20between%20NPs%20is%20linked%20to%20Pt%20loading%3A%209%20nm%20for%201%20wt%20%25%20Pt%20and%2016%20nm%20for%200.3%20wt%20%25%20Pt.%20Evaluation%20of%20support%20tortuosity%20descriptors%20using%20the%20nanoparticle%20positions%20confirms%20a%20uniform%20distribution%20on%20the%20support.%20A%20square%20network%20geometric%20model%20compatible%20with%20the%20geodesic%20distances%20between%20NPs%20reveals%20that%20one%20to%20five%20NPs%20can%20be%20present%20at%20the%20same%20time%20on%20each%20alumina%20crystallite%20depending%20on%20Pt%20loading.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facscatal.0c00042%22%2C%22ISSN%22%3A%222155-5435%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facscatal.0c00042%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A32%3A32Z%22%7D%7D%2C%7B%22key%22%3A%22NZEV6W3N%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Beaubras%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EF.%20Beaubras%2C%20J.-M.%20Rueff%2C%20O.%20Perez%2C%20F.%20Veillon%2C%20V.%20Caignaert%2C%20J.-F.%20Lohier%2C%20J.%20Cardin%2C%20G.%20Rogez%2C%20C.%20Jestin%2C%20H.%20Couthon%2C%20P.-A.%20Jaffres%2C%20M%28H2O%29%28PO3C10H6OH%29center%20dot%28H2O%29%280.5%29%20%28M%20%3D%20Co%2C%20Mn%2C%20Zn%2C%20Cu%29%3A%20a%20new%20series%20of%20layered%20metallophosphonate%20compounds%20obtained%20from%206-hydroxy-2-naphthylphosphonic%20acid%2C%20Dalton%20Transactions%2049%20%282020%29%203877%26%23x2013%3B3891.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt03947c%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt03947c%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22M%28H2O%29%28PO3C10H6OH%29center%20dot%28H2O%29%280.5%29%20%28M%20%3D%20Co%2C%20Mn%2C%20Zn%2C%20Cu%29%3A%20a%20new%20series%20of%20layered%20metallophosphonate%20compounds%20obtained%20from%206-hydroxy-2-naphthylphosphonic%20acid%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Felicien%22%2C%22lastName%22%3A%22Beaubras%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Michel%22%2C%22lastName%22%3A%22Rueff%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Perez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabien%22%2C%22lastName%22%3A%22Veillon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Caignaert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Francois%22%2C%22lastName%22%3A%22Lohier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julien%22%2C%22lastName%22%3A%22Cardin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Rogez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charlotte%22%2C%22lastName%22%3A%22Jestin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Helene%22%2C%22lastName%22%3A%22Couthon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Alain%22%2C%22lastName%22%3A%22Jaffres%22%7D%5D%2C%22abstractNote%22%3A%22Four%20new%20metallophosphonates%20M%28H2O%29%28PO3C10H6OH%29%28H2O%29%280.5%29%20%28M%20%3D%20Mn%2C%20Co%2C%20Cu%2C%20Zn%29%20were%20obtained%20as%20single%20crystal%20and%20polycrystalline%20powders%20by%20hydrothermal%20synthesis%20from%20the%20precursors%206-hydroxy-2-naphthylphosphonic%20acid%20and%20the%20corresponding%20metal%20salts.%20These%20analogous%20hybrids%20crystalized%20in%20the%20space%20group%20P12%281%29%5C%2Fc1%20in%20a%20lamellar%20structure.%20Their%20layered%20structures%20consisted%20of%20inorganic%20%5BM%28H2O%29%28PO3C%29%5D%20layers%20stacked%20with%20organic%20bilayers%20of%206-hydroxy-2-naphthyl%20moieties%20%5Cu201cHO-C10H6%5Cu201d%20and%20free%20water%20molecules.%20Their%20structures%20were%20determined%20by%20single%20crystal%20X-ray%20diffraction%20and%20confirmed%20by%20powder%20X-ray%20diffraction%20and%20Le%20Bail%20refinement%20for%20the%20powder%20sample.%20The%20removal%20of%20water%20upon%20heating%20at%20250%20degrees%20C%20was%20studied%20by%20thermogravimetric%20analysis%20and%20temperature-dependent%20powder%20X-ray%20diffraction.%20Their%20magnetic%20properties%20were%20studied%20by%20SQUID%20magnetometry%20and%20show%20antiferromagnetic%20behavior%20for%20the%20Co%20analogue%20and%20the%20occurrence%20of%20a%20canted%20antiferromagnetic%20order%20at%20T-N%20%3D%2012.2%20K%20for%20the%20Mn%20analogue.%20The%20Cu%20compound%20displayed%20an%20unprecedented%20ferromagnetic%20behavior.%20Their%20absorption%20and%20luminescence%20properties%20were%20investigated%20and%20revealed%20that%20the%20ligand%20and%20the%20compounds%20displayed%20a%20common%20behavior%20below%20a%20wavelength%20of%20400%20nm.%20Specific%20absorption%20bands%20were%20found%20in%20the%20compounds%20with%20Co2%2B%20and%20Cu2%2B%20at%20539%20nm%20and%20849%20nm%2C%20respectively.%20Moreover%2C%20particular%20luminescence%20bands%20were%20found%20for%20the%20compounds%20with%20Mn2%2B%2C%20Co2%2B%20and%20Zn2%2B%20at%20598%20nm%2C%20551%20nm%20and%20530%20and%20611%20nm%2C%20respectively.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9dt03947c%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc9dt03947c%22%2C%22collections%22%3A%5B%22M244N6AF%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A32%3A57Z%22%7D%7D%2C%7B%22key%22%3A%228WV7KMNJ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bellemin-Laponnaz%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Bellemin-Laponnaz%2C%20N-Heterocyclic%20Carbene%20Platinum%20Complexes%3A%20A%20Big%20Step%20Forward%20for%20Effective%20Antitumor%20Compounds%2C%20European%20Journal%20of%20Inorganic%20Chemistry%202020%20%282020%29%2010%26%23x2013%3B20.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.201900960%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.201900960%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22N-Heterocyclic%20Carbene%20Platinum%20Complexes%3A%20A%20Big%20Step%20Forward%20for%20Effective%20Antitumor%20Compounds%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22The%20discovery%20of%20cisplatin%20is%20an%20important%20milestone%20in%20the%20history%20of%20successful%20anticancer%20drugs.%20This%20is%20also%20a%20notable%20example%20of%20the%20translational%20scientific%20achievement%20that%20remains%20a%20driving%20force%20in%20multidisciplinary%20research.%20The%20clinical%20success%20of%20cisplatin%20has%20led%20chemists%20to%20vary%20the%20ligands%20around%20the%20platinum%20metal%20to%20improve%20cisplatin%27s%20effectiveness%20while%20reducing%20its%20side%20effects.%20While%20there%20have%20been%20more%20failures%20than%20successes%2C%20key%20developments%20in%20the%20elucidation%20of%20mechanisms%20of%20the%20tumor-resistance%20properties%20have%20been%20accomplished.%20N-Heterocyclic%20carbene%20as%20ligand%20for%20organometallic%20chemistry%20is%20a%20relatively%20young%20area%20that%20offers%20new%20opportunities%20in%20many%20fields%20including%20bio-inorganic%20chemistry.%20These%20ligands%20fit%20the%20prerequisites%20for%20metal%20drug%20development%20and%20recent%20achievements%20have%20demonstrated%20the%20great%20potential%20of%20these%20compounds.%20The%20properties%20of%20these%20metal%20NHC%20complexes%20also%20allow%20for%20easy%20post-functionalization%2C%20thus%20enabling%20molecular%20diversity%20for%20efficient%20drug%20design.%20Overall%2C%20N-heterocyclic%20carbene%20ligands%20reveal%20new%20opportunities%20for%20Pt%20drug%20development.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fejic.201900960%22%2C%22ISSN%22%3A%221434-1948%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.201900960%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222021-04-30T13%3A58%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22SJWMMMWK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Benaissa%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Benaissa%2C%20R.%20El%20Bouayadi%2C%20D.%20Ihiawakrim%2C%20O.%20Ersen%2C%20Ideality%20factor%20and%20barrier%20height%20for%20a%20GaN%20nanomembrane%20electrically%20contacted%20with%20a%20tungsten%20nano-tip%20in%20a%20TEM%2C%20Journal%20of%20Applied%20Physics%20127%20%282020%29%20075109.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.5128868%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.5128868%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ideality%20factor%20and%20barrier%20height%20for%20a%20GaN%20nanomembrane%20electrically%20contacted%20with%20a%20tungsten%20nano-tip%20in%20a%20TEM%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Benaissa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22El%20Bouayadi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%5D%2C%22abstractNote%22%3A%22In%20the%20present%20article%2C%20the%20electrical%20characteristics%20of%20a%20freestanding%20gallium%20nitride%20nanomembrane%20in%20contact%20with%20a%20tungsten%20nanoprobe%20are%20evaluated%20using%20scanning%20tunneling%20microscopy%20in%20an%20aberration-corrected%20transmission%20electron%20microscope%20without%20any%20lithographic%20patterning.%20We%20report%20here%20barrier%20height%20%28Phi%20B%3D0.33%20%2B%5C%2F-%200.05eV%20and%20ideality%20factor%20%28eta%20W%5C%2F%20GaN-NM%3D1.620%20%2B%5C%2F-%200.07%29%20parameters%20as%20extracted%20from%20I-V%20characteristic%20curve.%20Our%20experimental%20findings%2C%20combined%20with%20analytical%20calculations%2C%20show%20that%20the%20use%20of%20nanosized%20edge%20contacts%20results%20in%20a%20reduced%20barrier%20height%2C%20which%20is%20very%20promising%20for%20achieving%20a%20high%20%60on%27%20current%2C%20large%20photoresponse%2C%20and%20high-frequency%20operation%20in%20FET%20devices.%20Published%20under%20license%20by%20AIP%20Publishing.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1063%5C%2F1.5128868%22%2C%22ISSN%22%3A%220021-8979%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F1.5128868%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222021-02-10T16%3A16%3A43Z%22%7D%7D%2C%7B%22key%22%3A%2254SKCPWE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Berciaud%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Berciaud%2C%20M.%20Potemski%2C%20C.%20Faugeras%2C%20Many-Body%20Effects%20in%20Suspended%20Graphene%20Probed%20through%20Magneto-Phonon%20Resonances%2C%20Physica%20Status%20Solidi-Rapid%20Research%20Letters%20%282020%29%202000345.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fpssr.202000345%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fpssr.202000345%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Many-Body%20Effects%20in%20Suspended%20Graphene%20Probed%20through%20Magneto-Phonon%20Resonances%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Berciaud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marek%22%2C%22lastName%22%3A%22Potemski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Faugeras%22%7D%5D%2C%22abstractNote%22%3A%22Micro-magneto-Raman%20scattering%20spectroscopy%20is%20made%20use%20of%20to%20probe%20magneto-phonon%20resonances%20%28MPR%29%20in%20suspended%20mono-%20to%20pentalayer%20graphene.%20MPR%20correspond%20to%20avoided%20crossings%20between%20zone-center%20optical%20phonons%20%28G-mode%29%20and%20optically%20active%20inter-Landau%20level%20%28LL%29%20transitions%20and%20provide%20a%20tool%20to%20perform%20LL%20spectroscopy%20at%20a%20fixed%20energy%20%28approximate%20to%20197%20meV%29%20set%20by%20the%20G-mode%20phonon.%20Using%20a%20single-particle%20effective%20bilayer%20model%2C%20the%20velocity%20parameter%20associated%20with%20each%20MPR%20is%20readily%20extracted.%20A%20single%20velocity%20parameter%20slightly%20above%20the%20bulk%20graphite%20value%20suffices%20to%20fit%20all%20MPR%20forN%20%3E%3D%202%20layer%20systems.%20In%20contrast%2C%20in%20monolayer%20graphene%2C%20it%20is%20found%20that%20the%20velocity%20parameter%20increases%20significantly%20from%20%281.23%20%2B%5C%2F-%200.01%29%20x%2010%286%29%20m%20s%28-1%29up%20to%20%281.45%20%2B%5C%2F-%200.02%29%20x%2010%286%29%20m%20s%28-1%29as%20the%20first%20to%20third%20optically%20active%20inter-LL%20transitions%20couple%20to%20the%20G-mode%20phonon.%20This%20result%20is%20understood%20as%20a%20signature%20of%20enhanced%20many-body%20effects%20in%20unscreened%20graphene.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fpssr.202000345%22%2C%22ISSN%22%3A%221862-6254%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fpssr.202000345%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22N8397DCZ%22%5D%2C%22dateModified%22%3A%222024-08-21T09%3A43%3A41Z%22%7D%7D%2C%7B%22key%22%3A%22C4PB8GME%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bergeard%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Bergeard%2C%20M.%20Hehn%2C%20K.%20Carva%2C%20P.%20Balaz%2C%20S.%20Mangin%2C%20G.%20Malinowski%2C%20Tailoring%20femtosecond%20hot-electron%20pulses%20for%20ultrafast%20spin%20manipulation%2C%20Applied%20Physics%20Letters%20117%20%282020%29%20222408.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0018502%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0018502%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tailoring%20femtosecond%20hot-electron%20pulses%20for%20ultrafast%20spin%20manipulation%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Bergeard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Hehn%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Carva%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Balaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Mangin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Malinowski%22%7D%5D%2C%22abstractNote%22%3A%22We%20have%20measured%20the%20hot-electron-induced%20demagnetization%20of%20a%20%5BCo%5C%2FPt%5D%282%29%20multilayer%20in%20M%28x%20nm%29%5C%2FCu%28100nm%29%5C%2F%5BCo%280.6nm%29%5C%2FPt%281.1nm%29%5D%282%29%20samples%20depending%20on%20the%20nature%20of%20the%20capping%20layer%20M%20and%20its%20thickness%20x.%20We%20found%20out%20that%20a%20Pt%20layer%20is%20more%20efficient%20than%20%5BCo%5C%2FPt%5D%28X%29%2C%20Cu%2C%20or%20MgO%20layers%20in%20converting%20infrared%20%28IR%29%20photon%20pulses%20into%20hot-electron%20pulses%20at%20a%20given%20laser%20power.%20We%20also%20found%20out%20that%20the%20maximum%20relative%20demagnetization%20amplitude%20is%20achieved%20for%20M%28x%29%20%3D%20Pt%20%287nm%29.%20Our%20experimental%20results%20show%20qualitative%20agreement%20with%20numerical%20simulations%20based%20on%20the%20superdiffusive%20spin%20transport%20model.%20We%20concluded%20that%20the%20maximum%20relative%20demagnetization%20amplitude%2C%20which%20corresponds%20to%20the%20highest%20photon%20conversion%20into%20hot%20electrons%2C%20is%20an%20interplay%20between%20the%20IR%20penetration%20depth%20and%20the%20hot-electron%20inelastic%20mean%20free%20path%20within%20the%20capping%20layer.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0018502%22%2C%22ISSN%22%3A%220003-6951%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F5.0018502%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22MKAFAH44%22%5D%2C%22dateModified%22%3A%222021-02-17T16%3A06%3A23Z%22%7D%7D%2C%7B%22key%22%3A%225DU8U3J3%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Berro%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EY.%20Berro%2C%20S.%20Gueddida%2C%20Y.%20Bouizi%2C%20C.%20Bellouard%2C%20E.-E.%20Bendeif%2C%20A.%20Gansmuller%2C%20A.%20Celzard%2C%20V.%20Fierro%2C%20D.%20Ihiawakrim%2C%20O.%20Ersen%2C%20M.%20Kassir%2C%20F.E.H.%20Hassan%2C%20S.%20Lebegue%2C%20M.%20Badawi%2C%20N.%20Canilho%2C%20A.%20Pasc%2C%20Imprinting%20isolated%20single%20iron%20atoms%20onto%20mesoporous%20silica%20by%20templating%20with%20metallosurfactants%2C%20Journal%20of%20Colloid%20and%20Interface%20Science%20573%20%282020%29%20193%26%23x2013%3B203.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jcis.2020.03.095%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jcis.2020.03.095%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Imprinting%20isolated%20single%20iron%20atoms%20onto%20mesoporous%20silica%20by%20templating%20with%20metallosurfactants%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Berro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Gueddida%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Bouizi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Bellouard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22El-E%22%2C%22lastName%22%3A%22Bendeif%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Gansmuller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Celzard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V%22%2C%22lastName%22%3A%22Fierro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Kassir%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%20El%20Haj%22%2C%22lastName%22%3A%22Hassan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Lebegue%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Badawi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Canilho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Pasc%22%7D%5D%2C%22abstractNote%22%3A%22Hypothesis%3A%20One%20of%20the%20main%20drawbacks%20of%20metal-supported%20materials%2C%20traditionally%20prepared%20by%20the%20impregnation%20of%20metal%20salts%20onto%20pre-synthesized%20porous%20supports%2C%20is%20the%20formation%20of%20large%20and%20unevenly%20dispersed%20particles.%20Generally%2C%20the%20larger%20are%20the%20particles%2C%20the%20lower%20is%20the%20number%20of%20catalytic%20sites.%20Maximum%20atom%20exposure%20can%20be%20reached%20within%20single-atom%20materials%2C%20which%20appear%20therefore%20as%20the%20next%20generation%20of%20porous%20catalysts.%20Experiments%3A%20Herein%2C%20we%20designed%20single%20iron%20atom-supported%20silica%20materials%20through%20sol-gel%20hydrothermal%20treatment%20using%20mixtures%20of%20a%20non-ionic%20surfactant%20%28Pluronic%20P123%29%20and%20a%20metallosurfactant%20%28cetyltrimethylammoniumtrichloromonobromoferrate%2C%20CTAF%29%20as%20porogens.%20The%20ratio%20between%20the%20Pluronic%20P123%20and%20the%20CTAF%20enables%20to%20control%20the%20silica%20structural%20and%20textural%20properties.%20More%20importantly%2C%20CTAF%20acts%20as%20an%20iron%20source%2C%20which%20amount%20could%20be%20simply%20tuned%20by%20varying%20the%20non-ionic%5C%2Fmetallo%20surfactants%20molar%20ratio.%20Findings%3A%20The%20fine%20distribution%20of%20iron%20atoms%20onto%20the%20silica%20mesopores%20results%20from%20the%20iron%20distribution%20within%20the%20mixed%20micelles%2C%20which%20serve%20as%20templates%20for%20the%20polymerization%20of%20the%20silica%20matrix.%20Several%20characterization%20methods%20were%20used%20to%20determine%20the%20structural%20and%20textural%20properties%20of%20the%20silica%20material%20%28XRD%2C%20N-2%20sorption%20isotherms%20and%20TEM%29%20and%20the%20homogeneous%20distribution%20and%20lack%20of%20clustering%20of%20iron%20atoms%20in%20the%20resulting%20materials%20%28elemental%20analysis%2C%20magnetic%20measurements%2C%20pair%20distribution%20function%20%28PDF%29%2C%20MAS-NMR%20and%20TEM%20mapping%29.%20The%20oxidation%20and%20spin%20state%20of%20single-iron%20atoms%20determined%20from%20their%20magnetic%20properties%20were%20confirmed%20by%20DFT%20calculations.%20This%20strategy%20might%20find%20straightforward%20applications%20in%20preparing%20versatile%20single%20atom%20catalysts%2C%20with%20improved%20efficiency%20compared%20to%20nanosized%20ones.%20%28C%29%202020%20Elsevier%20Inc.%20All%20rights%20reserved.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jcis.2020.03.095%22%2C%22ISSN%22%3A%220021-9797%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jcis.2020.03.095%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222021-02-10T16%3A16%3A26Z%22%7D%7D%2C%7B%22key%22%3A%22HUTDXZMJ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Besli%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.M.%20Besli%2C%20C.%20Usubelli%2C%20M.%20Metzger%2C%20V.%20Pande%2C%20K.%20Harry%2C%20D.%20Nordlund%2C%20S.%20Sainio%2C%20J.%20Christensen%2C%20M.M.%20Doeff%2C%20S.%20Kuppan%2C%20Effect%20of%20Liquid%20Electrolyte%20Soaking%20on%20the%20Interfacial%20Resistance%20of%20Li7La3Zr2O12%20for%20All-Solid-State%20Lithium%20Batteries%2C%20ACS%20Applied%20Materials%20%26amp%3B%20Interfaces%2012%20%282020%29%2020605%26%23x2013%3B20612.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.0c06194%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.0c06194%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Effect%20of%20Liquid%20Electrolyte%20Soaking%20on%20the%20Interfacial%20Resistance%20of%20Li7La3Zr2O12%20for%20All-Solid-State%20Lithium%20Batteries%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Muenir%20M.%22%2C%22lastName%22%3A%22Besli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Camille%22%2C%22lastName%22%3A%22Usubelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michael%22%2C%22lastName%22%3A%22Metzger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vikram%22%2C%22lastName%22%3A%22Pande%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katherine%22%2C%22lastName%22%3A%22Harry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dennis%22%2C%22lastName%22%3A%22Nordlund%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sami%22%2C%22lastName%22%3A%22Sainio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jake%22%2C%22lastName%22%3A%22Christensen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marca%20M.%22%2C%22lastName%22%3A%22Doeff%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Saravanan%22%2C%22lastName%22%3A%22Kuppan%22%7D%5D%2C%22abstractNote%22%3A%22The%20impact%20of%20liquid%20electrolyte%20soaking%20on%20the%20interfacial%20resistance%20between%20the%20garnet-structured%20Li7La3Zr2O12%28LLZO%29%20solid%20electrolyte%20and%20metallic%20lithium%20has%20been%20studied.%20Lithium%20carbonate%20%28Li2CO3%29%20formed%20by%20inadvertent%20exposure%20of%20LLZO%20to%20ambient%20conditions%20is%20generally%20known%20to%20increase%20interfacial%20impedance%20and%20decrease%20lithium%20wettability.%20Soaking%20LLZO%20powders%20and%20pellets%20in%20the%20electrolyte%20containing%20lithium%20tetrafluoroborate%20%28LiBF4%29%20shows%20a%20significantly%20reduced%20interfacial%20resistance%20and%20improved%20contact%20between%20lithium%20and%20LLZO.%20Raman%20spectroscopy%2C%20X-ray%20diffraction%2C%20and%20soft%20X-ray%20absorption%20spectroscopy%20reveal%20how%20Li2CO3%20is%20continuously%20removed%20with%20increasing%20soaking%20time.%20On-line%20mass%20spectrometry%20and%20free%20energy%20calculations%20show%20how%20LiBF4%20reacts%20with%20surface%20carbonate%20to%20form%20carbon%20dioxide.%20Using%20a%20very%20simple%20and%20scalable%20process%20that%20does%20not%20involve%20heat-treatment%20and%20expensive%20coating%20techniques%2C%20we%20show%20that%20the%20Li-LLZO%20interfacial%20resistance%20can%20be%20reduced%20by%20an%20order%20of%20magnitude.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsami.0c06194%22%2C%22ISSN%22%3A%221944-8244%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsami.0c06194%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A33%3A31Z%22%7D%7D%2C%7B%22key%22%3A%2244P8S4SK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Biesuz%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Biesuz%2C%20E.%20Zera%2C%20M.%20Tomasi%2C%20P.%20Jana%2C%20O.%20Ersen%2C%20W.%20Baaziz%2C%20A.%20Lindemann%2C%20G.D.%20Soraru%2C%20Polymer-derived%20Si3N4%20nanofelts%20for%20flexible%2C%20high%20temperature%2C%20lightweight%20and%20easy-manufacturable%20super-thermal%20insulators%2C%20Applied%20Materials%20Today%2020%20%282020%29%20100648.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apmt.2020.100648%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apmt.2020.100648%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Polymer-derived%20Si3N4%20nanofelts%20for%20flexible%2C%20high%20temperature%2C%20lightweight%20and%20easy-manufacturable%20super-thermal%20insulators%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mattia%22%2C%22lastName%22%3A%22Biesuz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emanuele%22%2C%22lastName%22%3A%22Zera%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michele%22%2C%22lastName%22%3A%22Tomasi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Prasanta%22%2C%22lastName%22%3A%22Jana%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andre%22%2C%22lastName%22%3A%22Lindemann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gian%20Domenico%22%2C%22lastName%22%3A%22Soraru%22%7D%5D%2C%22abstractNote%22%3A%22Nowadays%2C%20the%20best%20thermal%20insulators%20are%20aerogel-based%20materials.%20However%2C%20their%20industrial%20application%20is%20constrained%20by%20a%20complex%20synthesis%20route%20%28requiring%20supercritical%20drying%29%20and%20by%20their%20fragility.%20Moreover%2C%20the%20most%20common%20aerogels%2C%20based%20on%20amorphous%20SiO2%2C%20have%20a%20poor%20thermal%20stability.%20In%20this%20work%2C%20a%20fast%20and%20simple%20synthesis%20route%20to%20ultra-highly-insulating%20Si3N4%20nanofelts%20is%20developed.%20The%20process%20is%20based%20on%20a%20specific%20treatment%20of%20SiOC%20polymer-derived%20ceramics%20in%20N-2%20atmosphere.%20The%20obtained%20nanofelts%20possess%20porosity%20as%20high%20as%2099.7%25%20%2810%20kg%20m%20-3%29%20and%20thermal%20conductivity%20down%20to%2011%20mW%20m%28-1%29%20K-1%20in%20Ar%20atmosphere%2C%20which%20is%20among%20the%20lowest%20ever%20measured.%20The%20new%20material%20surpasses%20aerogels%20in%20terms%20of%20flexibility%20and%20temperature%20resistance.%20Moreover%2C%20it%20can%20be%20easily%20shaped%20in%20physical%20objects%20of%20indus%20trial%20interest.%20Thus%2C%20it%20offers%20a%20unique%20combination%20of%20intriguing%20properties%20such%20as%20thermal%20insulation%2C%20lightweight%2C%20temperature%20resistance%20and%20flexibility.%20These%2C%20combined%20with%20the%20simple%20manufacturing%20process%2C%20could%20lead%20to%20far-reaching%20implications%20in%20multiple%20technological%20fields.%20%28c%29%202020%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apmt.2020.100648%22%2C%22ISSN%22%3A%222352-9407%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.apmt.2020.100648%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222021-02-17T16%3A24%3A57Z%22%7D%7D%2C%7B%22key%22%3A%223RX9DFR5%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bigi%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Bigi%2C%20S.K.%20Chaluvadi%2C%20A.%20Galdi%2C%20L.%20Maritato%2C%20C.%20Aruta%2C%20R.%20Ciancio%2C%20J.%20Fujii%2C%20B.%20Gobaut%2C%20P.%20Torelli%2C%20I.%20Vobornik%2C%20G.%20Panaccione%2C%20G.%20Rossi%2C%20P.%20Orgiani%2C%20Predominance%20of%20z%282%29-orbitals%20at%20the%20surface%20of%20both%20hole-%20and%20electron-doped%20manganites%2C%20Journal%20of%20Electron%20Spectroscopy%20and%20Related%20Phenomena%20245%20%282020%29%20147016.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.elspec.2020.147016%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.elspec.2020.147016%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Predominance%20of%20z%282%29-orbitals%20at%20the%20surface%20of%20both%20hole-%20and%20electron-doped%20manganites%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Bigi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20Kumar%22%2C%22lastName%22%3A%22Chaluvadi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Galdi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Maritato%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Aruta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Ciancio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Fujii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Beno%5Cu00eet%22%2C%22lastName%22%3A%22Gobaut%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Torelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I%22%2C%22lastName%22%3A%22Vobornik%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Panaccione%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Rossi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Orgiani%22%7D%5D%2C%22abstractNote%22%3A%22The%20electronic%20properties%20of%20hole-%20and%20electron-doped%20manganites%20were%20probed%20by%20a%20combination%20of%20x-ray%20absorption%20and%20photoemission%20spectroscopies.%20Hole-doped%20La0.7Ba0.3MnO3%20and%20electron-doped%20La0.7Ce0.3MnO3%20thin%20films%20were%20epitaxially%20grown%20on%20SrTiO3%20substrates%20by%20means%20of%20pulsed%20laser%20deposition.%20Ex-situ%20x-ray%20diffraction%20demonstrated%20the%20substrate%5C%2Ffilm%20epitaxy%20relation%20and%20in-situ%20low%20energy%20electron%20diffraction%20provided%20evidence%20of%20high%20structural%20order%20of%20film%20surfaces.%20By%20combining%20synchrotron%20x-ray%20absorption%20and%20x-ray%20photoemission%20spectroscopy%2C%20evidence%20of%20Mn%20ions%20into%20a%202%2B%20state%20as%20a%20result%20of%20the%20Ce4%2B%20substitution%20in%20the%20electron-doped%20manganites%20was%20provided.%20Angular%20resolved%20photo-emission%20spectroscopy%20%28ARPES%29%20results%20showed%20a%20predominance%20of%20z%282%29-orbitals%20at%20the%20surface%20of%20both%20hole-%20and%2C%20unexpectedly%2C%20electron-doped%20manganites%20thus%20questioning%20the%20validity%20of%20the%20commonly%20accepted%20scenario%20describing%20the%20electron%20filling%20in%20manganites%27%203d%20orbitals%20in%20oxide%20manganites.%20The%20precise%20determination%20of%20the%20electronic%20and%20orbital%20properties%20of%20the%20terminating%20layers%20of%20oxide%20manganites%20paves%20the%20way%20for%20engineering%20multi-layered%20heterostructures%20thus%20leading%20to%20novel%20opportunities%20in%20the%20field%20of%20quantum%20electronics.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.elspec.2020.147016%22%2C%22ISSN%22%3A%220368-2048%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.elspec.2020.147016%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22TR4ZUX8B%22%5D%2C%22dateModified%22%3A%222021-02-17T16%3A08%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22964GNIXZ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bonfiglio%20and%20Mauro%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Bonfiglio%2C%20M.%20Mauro%2C%20PhosphorescentTris-Bidentate%20Ir%28III%29Complexes%20with%20N-Heterocyclic%20Carbene%20Scaffolds%3A%20Structural%20Diversity%20and%20Optical%20Properties%2C%20European%20Journal%20of%20Inorganic%20Chemistry%20%282020%29%203427%26%23x2013%3B3442.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.202000509%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.202000509%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22PhosphorescentTris-Bidentate%20Ir%28III%29Complexes%20with%20N-Heterocyclic%20Carbene%20Scaffolds%3A%20Structural%20Diversity%20and%20Optical%20Properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Bonfiglio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22N-heterocyclic%20carbenes%20%28NHCs%29%20are%20highly%20versatile%20ligands%20with%20unique%20features%20that%20are%20able%20to%20engage%20into%20robust%20metal-ligand%20bonds%2C%20owing%20to%20their%20strong%20electron%20sigma-donating%20and%20relatively%20weak%20pi-accepting%20abilities.%20Aiming%20at%20efficient%20and%20stable%20emitters%2C%20coordination%20features%20of%20NHCs%20have%20been%20successfully%20employed%20for%20modulating%20both%20optical%20and%20redox%20properties%20yielding%20outstanding%20Ir%28III%29complexes.%20In%20addition%2C%20NHCs%20are%20an%20unparalleled%20tool%20that%20helps%20to%20suppressing%20nonradiative%20pathways%20and%20shift%20emission%20into%20the%20blue%20region.%20As%20a%20result%2C%20Ir%28III%29complexes%20with%20NHC%20ligands%20represent%20an%20appealing%20class%20of%20phosphorescent%20emitters%20that%20show%20great%20potential%20application%20in%20light-emitting%20devices%2C%20electro-chemiluminescence%20and%20biomedicine.%20Herein%2C%20the%20interplay%20between%20structural%20diversity%20and%20photophysical%20properties%20will%20be%20discussed%20for%20a%20colorful%20palette%20of%20Ir-III-NHC%20complexes%20in%20a%20systematic%20approach.%20Finally%2C%20their%20employment%20in%20optoelectronic%20devices%20and%20biomedicine%20will%20be%20described.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fejic.202000509%22%2C%22ISSN%22%3A%221434-1948%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fejic.202000509%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222022-02-11T12%3A29%3A54Z%22%7D%7D%2C%7B%22key%22%3A%22QI8G6BXA%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bonfiglio%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Bonfiglio%2C%20L.%20Pallova%2C%20V.%20Cesar%2C%20C.%20Gourlaouen%2C%20S.%20Bellemin-Laponnaz%2C%20C.%20Daniel%2C%20F.%20Polo%2C%20M.%20Mauro%2C%20Phosphorescent%20Cationic%20Heterodinuclear%20Ir-III%5C%2FM%28I%29Complexes%20%28M%3DCu-I%2C%20Au-I%29%20with%20a%20Hybrid%20Janus-Type%20N-Heterocyclic%20Carbene%20Bridge%2C%20Chemistry-a%20European%20Journal%2026%20%282020%29%201%26%23x2013%3B17.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202002767%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202002767%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Phosphorescent%20Cationic%20Heterodinuclear%20Ir-III%5C%2FM%28I%29Complexes%20%28M%3DCu-I%2C%20Au-I%29%20with%20a%20Hybrid%20Janus-Type%20N-Heterocyclic%20Carbene%20Bridge%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Bonfiglio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lenka%22%2C%22lastName%22%3A%22Pallova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Cesar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chantal%22%2C%22lastName%22%3A%22Daniel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22A%20novel%20class%20of%20phosphorescent%20cationic%20heterobimetallic%20Ir-III%5C%2FM%28I%29complexes%2C%20where%20M-I%3DCu-I%284%29%20and%20Au-I%285%29%2C%20is%20reported.%20The%20two%20metal%20centers%20are%20connected%20by%20the%20hybrid%20bridging%201%2C3-dimesityl-5-acetylimidazol-2-ylidene-4-olate%20%28IMesAcac%29%20ligand%20that%20combines%20both%20a%20chelating%20acetylacetonato-like%20and%20a%20monodentate%20N-heterocyclic%20carbene%20site%20coordinated%20onto%20an%20Ir%28III%29and%20a%20M%28I%29center%2C%20respectively.%20Complexes%204and5have%20been%20prepared%20straightforwardly%20by%20a%20stepwise%20site-selective%20metalation%20with%20the%20zwitterionic%20%5B%28IPr%29M-I%28IMesAcac%29%5D%20metalloproligand%20%28IPr%3D1%2C3-%282%2C6-diisopropylphenyl%29-2H-imidazol-2-ylidene%29%20and%20they%20have%20been%20fully%20characterized%20by%20spectroscopic%2C%20electrochemical%2C%20and%20computational%20investigation.%20Complexes%204and5display%20intense%20red%20emission%20arising%20from%20a%20low-energy%20excited%20state%20that%20is%20located%20onto%20the%20%5Cu201cIr%28C%3C%5E%3EN%29%5Cu201d%20moiety%20featuring%20an%20admixed%20triplet%20ligand-centered%5C%2Fmetal-to-ligand%20charge%20transfer%20%28%28IL%29-I-3%5C%2F%28MLCT%29-M-1%29%20character.%20Comparison%20with%20the%20benchmark%20mononuclear%20complexes%20reveals%20negligible%20electronic%20coupling%20between%20the%20two%20distal%20metal%20centers%20at%20the%20electronic%20ground%20state.%20The%20bimetallic%20systems%20display%20enhanced%20photophysical%20properties%20in%20comparison%20with%20the%20parental%20congeners.%20Noteworthy%2C%20similar%20non-radiative%20rate%20constants%20have%20been%20determined%20along%20with%20a%20two-fold%20increase%20of%20radiative%20rate%2C%20yielding%20brightly%20red-emitting%20cyclometalating%20Ir%28III%29complexes.%20This%20finding%20is%20ascribed%20to%20the%20increased%20MLCT%20character%20of%20the%20emitting%20state%20in%20complexes%204and5due%20to%20the%20smaller%20energy%20gap%20between%20the%283%29IL%20and%281%29MLCT%20manifolds%2C%20which%20mix%20via%20spin-orbit%20coupling.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchem.202002767%22%2C%22ISSN%22%3A%220947-6539%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchem.202002767%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222021-04-30T13%3A59%3A32Z%22%7D%7D%2C%7B%22key%22%3A%22I6K7SXWK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bonfiglio%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Bonfiglio%2C%20K.%20Magra%2C%20C.%20Cebrian%2C%20F.%20Polo%2C%20P.C.%20Gros%2C%20P.%20Mercandelli%2C%20M.%20Mauro%2C%20Red-emitting%20neutral%20rhenium%28I%29%20complexes%20bearing%20a%20pyridyl%20pyridoannelated%20N-heterocyclic%20carbene%2C%20Dalton%20Transactions%2049%20%282020%29%203102%26%23x2013%3B3111.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt04890a%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt04890a%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Red-emitting%20neutral%20rhenium%28I%29%20complexes%20bearing%20a%20pyridyl%20pyridoannelated%20N-heterocyclic%20carbene%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Bonfiglio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kevin%22%2C%22lastName%22%3A%22Magra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristina%22%2C%22lastName%22%3A%22Cebrian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%20C.%22%2C%22lastName%22%3A%22Gros%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierluigi%22%2C%22lastName%22%3A%22Mercandelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22Two%20novel%20rhenium%28I%29%20tricarbonyl%20complexes%20of%20general%20formula%20fac-%5BRe%28N%3C%5E%3EC%3A%29%28CO%29%283%29X%5D%20are%20herein%20presented%2C%20where%20N%3C%5E%3EC%3A%20is%20the%20pyridoannelated%20N-heterocyclic%20carbene%20%28NHC%29%20arising%20from%202-%282-pyridinyl%29%20imidazo%5B1%2C5-a%5Dpyridinium%20hexafluorophosphate%20proligand%2C%20namely%20%5Bpyipy%5DPF6%2C%20and%20X%20being%20Cl%20and%20Br.%20The%20synthetic%20pathway%20is%20a%20one-pot%20reaction%20that%20starts%20from%20the%20azolium%20salt%20as%20the%20NHC%20source%20and%20%5BRe%28CO%29%285%29X%5D%20to%20yield%20the%20desired%20charge-neutral%20fac-%5BRe%28%20pyipy%29%28CO%29%283%29X%5D%20complexes%20%281-2%29.%20Both%20complexes%20were%20thoroughly%20characterized%20by%20spectroscopic%2C%20electrochemical%2C%20theoretical%20investigation%20as%20well%20as%20X-ray%20diffraction%20analysis.%20They%20display%20a%20rather%20similar%20electronic%20absorption%20spectrum%20in%20dilute%20CH2Cl2%20solution%2C%20which%20is%20characterized%20by%20a%20broad%20profile%20extending%20into%20the%20blue%20region.%20This%20lowest-lying%20absorption%20band%20is%20attributed%20to%20a%20transition%20with%20admixed%20metal-to-ligand%20charge%20transfer%20and%20intraligand%20charge%20transfer%20%28%28MLCT%29-M-1%5C%2F%28ILCT%29-I-1%29%20character.%20Degassed%20samples%20of%20the%20complexes%20display%20moderate%20%28Phi%20approximate%20to%201.5%25%29%20and%20long-lived%20%28tau%20%3D%2012.8-13.4%20mu%20s%29%20red%20photoluminescence%20with%20highly%20structured%20profile%20independent%20of%20the%20nature%20of%20the%20ancillary%20halogen%20ligand%20and%20little%20sensitivity%20to%20the%20solvent%20polarity%2C%20highlighting%20the%20markedly%20different%20nature%20of%20the%20emitting%20excited%20state%20in%20comparison%20with%20the%20lowest-lying%20absorption.%20Indeed%2C%20photoluminescence%20is%20ascribed%20to%20a%20long-lived%20excited%20state%20with%20metal-perturbed%20triplet%20ligand-centred%20%28%28LC%29-L-3%29%20character%20as%20supported%20by%20both%20experimental%20and%20density%20functional%20theory%20%28DFT%29%20investigations.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9dt04890a%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc9dt04890a%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A33%3A57Z%22%7D%7D%2C%7B%22key%22%3A%227D2W43R9%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Botzung%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Botzung%2C%20D.%20Hagenmueller%2C%20S.%20Schutz%2C%20J.%20Dubail%2C%20G.%20Pupillo%2C%20J.%20Schachenmayer%2C%20Dark%20state%20semilocalization%20of%20quantum%20emitters%20in%20a%20cavity%2C%20Physical%20Review%20B%20102%20%282020%29%20144202.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.102.144202%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.102.144202%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Dark%20state%20semilocalization%20of%20quantum%20emitters%20in%20a%20cavity%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Botzung%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Hagenmueller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Schutz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Dubail%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guido%22%2C%22lastName%22%3A%22Pupillo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johannes%22%2C%22lastName%22%3A%22Schachenmayer%22%7D%5D%2C%22abstractNote%22%3A%22We%20study%20a%20disordered%20ensemble%20of%20quantum%20emitters%20collectively%20coupled%20to%20a%20lossless%20cavity%20mode.%20The%20latter%20is%20found%20to%20modify%20the%20localization%20properties%20of%20the%20%5Cu201cdark%5Cu201d%20eigenstates%2C%20which%20exhibit%20a%20character%20of%20being%20localized%20on%20multiple%20noncontiguous%20sites.%20We%20denote%20such%20states%20as%20semilocalized%20and%20characterize%20them%20by%20means%20of%20standard%20localization%20measures.%20We%20show%20that%20those%20states%20can%20very%20efficiently%20contribute%20to%20coherent%20energy%20transport.%20Our%20paper%20underlines%20the%20important%20role%20of%20dark%20states%20in%20systems%20with%20strong%20light-matter%20coupling.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.102.144202%22%2C%22ISSN%22%3A%222469-9950%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevB.102.144202%22%2C%22collections%22%3A%5B%22D8DBRKSX%22%5D%2C%22dateModified%22%3A%222022-02-11T14%3A01%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22NWE4STXN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bouche%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Bouche%2C%20B.%20Vincent%2C%20T.%20Achard%2C%20S.%20Bellemin-Laponnaz%2C%20N-Heterocyclic%20Carbene%20Platinum%28IV%29%20as%20Metallodrug%20Candidates%3A%20Synthesis%20and%28195%29Pt%20NMR%20Chemical%20Shift%20Trend%2C%20Molecules%2025%20%282020%29%203148.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules25143148%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules25143148%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22N-Heterocyclic%20Carbene%20Platinum%28IV%29%20as%20Metallodrug%20Candidates%3A%20Synthesis%20and%28195%29Pt%20NMR%20Chemical%20Shift%20Trend%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathilde%22%2C%22lastName%22%3A%22Bouche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bruno%22%2C%22lastName%22%3A%22Vincent%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Achard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22A%20series%20of%20octahedral%20platinum%28IV%29%20complexes%20functionalized%20with%20bothN-heterocyclic%20carbene%20%28NHC%29%20ligands%20were%20synthesized%20according%20to%20a%20straightforward%20procedure%20and%20characterized.%20The%20coordination%20sphere%20around%20the%20metal%20was%20varied%2C%20investigating%20the%20influence%20of%20the%20substituted%20NHC%20and%20the%20amine%20ligand%20in%20trans%20position%20to%20the%20NHC.%20The%20influence%20of%20those%20structural%20variations%20on%20the%20chemical%20shift%20of%20the%20platinum%20center%20were%20evaluated%20by%28195%29Pt%20NMR.%20This%20spectroscopy%20provided%20more%20insights%20on%20the%20impact%20of%20the%20structural%20changes%20on%20the%20electronic%20density%20at%20the%20platinum%20center.%20Investigation%20of%20the%20in%20vitro%20cytotoxicities%20of%20representative%20complexes%20were%20carried%20on%20three%20cancer%20cell%20lines%20and%20showed%20IC%2850%29values%20down%20to%20the%20low%20micromolar%20range%20that%20compare%20favorably%20with%20the%20benchmark%20cisplatin%20or%20their%20platinum%28II%29%20counterparts%20bearing%20NHC%20ligands.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3390%5C%2Fmolecules25143148%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fmolecules25143148%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222021-04-30T13%3A55%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22C3M8JTWB%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Boussadia%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Boussadia%2C%20A.%20Beghidja%2C%20L.%20Gali%2C%20C.%20Beghidja%2C%20M.%20Elhabiri%2C%20P.%20Rabu%2C%20G.%20Rogez%2C%20Coordination%20properties%20of%20two%20new%20Schiff-base%20phenoxy-carboxylates%20and%20comparative%20study%20of%20their%20antioxidant%20activities%2C%20Inorganica%20Chimica%20Acta%20508%20%282020%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.ica.2020.119656%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.ica.2020.119656%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Coordination%20properties%20of%20two%20new%20Schiff-base%20phenoxy-carboxylates%20and%20comparative%20study%20of%20their%20antioxidant%20activities%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ahlem%22%2C%22lastName%22%3A%22Boussadia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adel%22%2C%22lastName%22%3A%22Beghidja%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lynda%22%2C%22lastName%22%3A%22Gali%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chahrazed%22%2C%22lastName%22%3A%22Beghidja%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mourad%22%2C%22lastName%22%3A%22Elhabiri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Rabu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Rogez%22%7D%5D%2C%22abstractNote%22%3A%22Two%20novel%20tridentate%20Schiff-base%20ligands%20containing%20carboxylate%20groups%20were%20obtained%20from%20the%20condensation%20of%203-amino-4-hydroxybenzoic%20acid%20with%20either%20acetylacetone%20%28H3L1%29%20or%20salicylaldehyde%20%28H3L2%29.%20H3L1%20reacted%20with%20copper%28II%29%20acetate%20and%20pyridine%20%28strongly%20coordinating%20solvent%29%20to%20afford%20the%20C1%20complex%2C%20while%20reaction%20of%20H3L2%20with%20nickel%28II%29%20acetate%20and%20pyridine%20afforded%20two%20types%20of%20complexes%20C2%20and%20C3.%20The%20two%20ligands%20and%20their%20metal%20complexes%20were%20fully%20characterized%20by%20elemental%20analysis%2C%20XRD%20and%20spectroscopic%20analysis.%20Upon%20its%20fully%20deprotonated%20state%2C%20%28L-1%29%283-%29%20coordinates%20in%20a%20keto-enamine%20fashion%20and%20acts%20as%20a%20ditopic%20binder%20through%20an%20ONO%20tridentate%20donor%20system%20and%20an%20O%20monodentate%20donor%20system%20%28carboxylate%29.%20Upon%20its%20doubly%20deprotonated%20state%2C%20%28HL2%29%282-%29%20ligand%20acts%20either%20as%20monotopic%20tridentate%20binder%20%28Le.%20enol-imine%20form%20with%20an%20ONO%20donor%20system%20that%20lead%20to%20complex%20C2%29%20or%20as%20a%20ditopic%20ligand%20%28ONO%20tridentate%20and%20O%20monodentate%20donor%20systems%20to%20afford%20complex%20C3%29.%20The%20molecular%20structure%20of%20all%20the%20compounds%20were%20determined%20by%20single%20crystal%20X-ray%20diffraction%20studies%20and%20revealed%20several%20important%20characteristics.%20In%20complex%20C1%2C%20the%20Cu%28II%29%20cations%20are%20five-coordinated%20with%20a%20slightly%20distorted%20square%20pyramidal%20geometry%2C%20while%20in%20C2%20and%20C3%20complexes%2C%20the%20Ni%28II%29%20ions%20are%20four%20and%20six-coordinated%20with%20a%20square%20planar%20and%20a%20slightly%20distorted%20octahedral%20geometry%2C%20respectively.%20Following%20this%20structural%20investigation%2C%20the%20antioxidant%20activities%20of%20the%20free%20ligands%20and%20their%20metal%20complexes%20were%20then%20investigated%20and%20demonstrated%20interesting%20antioxidant%20features%20especially%20for%20H3L2%20and%20complex%20C3.%20Lastly%2C%20temperature%20dependent%20magnetic%20susceptibility%20measurements%20showed%20the%20presence%20of%20ferromagnetic%20interactions%20in%20C1%20mediated%20through%20the%20phenoxido%20bridges.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.ica.2020.119656%22%2C%22ISSN%22%3A%220020-1693%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.ica.2020.119656%22%2C%22collections%22%3A%5B%22M244N6AF%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A34%3A24Z%22%7D%7D%2C%7B%22key%22%3A%22TKUM8SQB%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Brachnakova%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.%20Brachnakova%2C%20S.%20Matejova%2C%20J.%20Moncol%2C%20R.%20Herchel%2C%20J.%20Pavlik%2C%20E.%20Moreno-Pineda%2C%20M.%20Ruben%2C%20I.%20Salitros%2C%20Stereochemistry%20of%20coordination%20polyhedra%20vs.%20single%20ion%20magnetism%20in%20penta-%20and%20hexacoordinated%20Co%28II%29%20complexes%20with%20tridentate%20rigid%20ligands%2C%20Dalton%20Transactions%2049%20%282020%29%201249%26%23x2013%3B1264.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt04592a%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt04592a%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Stereochemistry%20of%20coordination%20polyhedra%20vs.%20single%20ion%20magnetism%20in%20penta-%20and%20hexacoordinated%20Co%28II%29%20complexes%20with%20tridentate%20rigid%20ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Barbora%22%2C%22lastName%22%3A%22Brachnakova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Simona%22%2C%22lastName%22%3A%22Matejova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jan%22%2C%22lastName%22%3A%22Moncol%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Radovan%22%2C%22lastName%22%3A%22Herchel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jan%22%2C%22lastName%22%3A%22Pavlik%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eufemio%22%2C%22lastName%22%3A%22Moreno-Pineda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ivan%22%2C%22lastName%22%3A%22Salitros%22%7D%5D%2C%22abstractNote%22%3A%22A%20tridentate%20ligand%20L%20%282%2C6-bis%281-%283%2C5-di-tert-butylbenzyl%29-1H-benzimidazol-2-yl%29pyridine%29%20was%20synthesized%20and%20used%20for%20the%20preparation%20of%20three%20pentacoordinated%20Co%28II%29%20complexes%20of%20formula%20%5BCo%28L%29X-2%5D%20%28where%20X%20%3D%20NCS-%20for%201%2C%20X%20%3D%20Cl-%20for%202%20and%20X%20%3D%20Br-%20for%203%29%20and%20one%20ionic%20compound%204%20%28%5BCo%28L%29%282%29%5DBr-2%20center%20dot%202CH%283%29OH%20center%20dot%20H2O%29%20containing%20a%20hexacoordinated%20Co%28II%29%20centre.%20Static%20magnetic%20data%20were%20analysed%20with%20respect%20to%20the%20spin%20%281-3%29%20or%20the%20Griffith-Figgis%20%284%29%20Hamiltonian.%20Ab%20initio%20calculations%20enable%20us%20to%20identify%20the%20positive%20axial%20magnetic%20anisotropy%20parameter%20D%20accompanied%20by%20a%20significant%20degree%20of%20rhombicity%20in%20the%20reported%20complexes.%20Also%2C%20magneto-structural%20correlation%20was%20outlined%20for%20this%20class%20of%20compounds.%20Moreover%2C%20all%20four%20compounds%20exhibit%20slow%20relaxation%20of%20magnetisation%20at%20an%20applied%20static%20magnetic%20field%20with%20either%20both%20low-%20and%20high-frequency%20relaxation%20channels%20%283%29%20or%20a%20single%20high-frequency%20relaxation%20process%20%281%2C%202%20and%204%29.%20The%20interplay%20between%20the%20stereochemistry%20of%20coordination%20polyhedra%2C%20magnetic%20anisotropy%20and%20the%20relaxation%20processes%20was%20investigated%20and%20discussed%20in%20detail.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9dt04592a%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc9dt04592a%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A34%3A51Z%22%7D%7D%2C%7B%22key%22%3A%22JTZK7344%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Brandl%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Brandl%2C%20S.%20Johannsen%2C%20D.%20Haussinger%2C%20N.%20Suryadevara%2C%20A.%20Prescimone%2C%20S.%20Bernhard%2C%20M.%20Gruber%2C%20M.%20Ruben%2C%20R.%20Berndt%2C%20M.%20Mayor%2C%20Iron%20in%20a%20Cage%3A%20Fixation%20of%20a%20Fe%28II%29tpy%282%29Complex%20by%20Fourfold%20Interlinking%2C%20Angewandte%20Chemie-International%20Edition%2059%20%282020%29%201%26%23x2013%3B7.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.202006340%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fanie.202006340%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Iron%20in%20a%20Cage%3A%20Fixation%20of%20a%20Fe%28II%29tpy%282%29Complex%20by%20Fourfold%20Interlinking%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Brandl%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sven%22%2C%22lastName%22%3A%22Johannsen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Haussinger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nithin%22%2C%22lastName%22%3A%22Suryadevara%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alessandro%22%2C%22lastName%22%3A%22Prescimone%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Bernhard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Manuel%22%2C%22lastName%22%3A%22Gruber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Richard%22%2C%22lastName%22%3A%22Berndt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcel%22%2C%22lastName%22%3A%22Mayor%22%7D%5D%2C%22abstractNote%22%3A%22The%20coordination%20sphere%20of%20the%20Fe%28II%29%20terpyridine%20complex1is%20rigidified%20by%20fourfold%20interlinking%20of%20both%20terpyridine%20ligands.%20Profiting%20from%20an%20octa-aldehyde%20precursor%20complex%2C%20the%20ideal%20dimensions%20of%20the%20interlinking%20structures%20are%20determined%20by%20reversible%20Schiff-base%20formation%2C%20before%20irreversible%20Wittig%20olefination%20provided%20the%20rigidified%20complex.%20Reversed-phase%20HPLC%20enables%20the%20isolation%20of%20the%20all-transisomer%20of%20the%20Fe%28II%29%20terpyridine%20complex1%2C%20which%20is%20fully%20characterized.%20While%20temperature%20independent%20low-spin%20states%20were%20recorded%20with%20superconducting%20quantum%20interference%20device%20%28SQUID%29%20measurements%20for%20both%2C%20the%20open%20precursor8and%20the%20interlinked%20complex1%2C%20evidence%20of%20the%20increased%20rigidity%20of%20the%20ligand%20sphere%20in1was%20provided%20by%20proton%20T%282%29relaxation%20NMR%20experiments.%20The%20ligand%20sphere%20fixation%20in%20the%20macrocyclized%20complex1even%20reaches%20a%20level%20resisting%20substantial%20deformation%20upon%20deposition%20on%20an%20Au%28111%29%20surface%2C%20as%20demonstrated%20by%20its%20pristine%20form%20in%20a%20low%20temperature%20ultra-high%20vacuum%20scanning%20tunneling%20microscope%20experiment.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fanie.202006340%22%2C%22ISSN%22%3A%221433-7851%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fanie.202006340%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%5D%2C%22dateModified%22%3A%222020-08-05T14%3A44%3A03Z%22%7D%7D%2C%7B%22key%22%3A%224HZE8NW8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bui%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.M.%20Bui%2C%20M.%20Boero%2C%20K.%20Shiraishi%2C%20A.%20Oshiyama%2C%20A%20two-dimensional%20liquid-like%20phase%20on%20Ga-rich%20GaN%20%280001%29%20surfaces%20evidenced%20by%20first%20principles%20molecular%20dynamics%2C%20in%3A%20Japanese%20Journal%20of%20Applied%20Physics%2C%202020%3A%20p.%20SGGK04.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7567%5C%2F1347-4065%5C%2Fab650b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.7567%5C%2F1347-4065%5C%2Fab650b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22A%20two-dimensional%20liquid-like%20phase%20on%20Ga-rich%20GaN%20%280001%29%20surfaces%20evidenced%20by%20first%20principles%20molecular%20dynamics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kieu%20My%22%2C%22lastName%22%3A%22Bui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mauro%22%2C%22lastName%22%3A%22Boero%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kenji%22%2C%22lastName%22%3A%22Shiraishi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Atsushi%22%2C%22lastName%22%3A%22Oshiyama%22%7D%5D%2C%22abstractNote%22%3A%22First%20principles%20molecular%20dynamics%20simulations%20have%20been%20used%20as%20a%20tool%20to%20investigate%20at%20an%20atomistic%20level%20the%20finite%20temperature%20behavior%20of%20a%20typical%20GaN%20growing%20surface.%20At%201300%20K%2C%20Ga%20adatoms%20show%20a%20high%20degree%20of%20destabilization%20and%20a%20departure%20of%20the%20diffusivity%20from%20an%20ordinary%20Arrhenius%20trend.%20Two%20signatures%2C%20a%20drastic%20change%20in%20the%20radial%20distribution%20function%20and%20a%20sudden%20increase%20of%20the%20diffusion%20constant%2C%20allow%20to%20quantify%20such%20a%20diffusion%20process.%20Such%20a%20high%20diffusivity%20results%20in%20the%20arising%20of%20a%20pronounced%20peak%20at%20about%202.6%20angstrom%2C%20typical%20of%20Ga-Ga%20bonds%2C%20indicating%20a%20tendency%20to%20cluster%20together%20of%20the%20Ga%20adatoms.%20Along%20with%20the%20remarkable%20diffusivity%20observed%20at%201300%20K%2C%20this%20result%20indicates%20rather%20clearly%20that%20at%20the%20typical%20experimental%20temperature%2C%20the%20epitaxial%20growth%20occurs%20not%20on%20a%20rigid%20surface%20in%20which%20Ga%20adatoms%20are%20tightly%20bound%20to%20specific%20sites%2C%20but%20rather%20on%20a%20two-dimensional%20liquid%20state.%20%28C%29%202020%20The%20Japan%20Society%20of%20Applied%20Physics%22%2C%22date%22%3A%222020%22%2C%22proceedingsTitle%22%3A%22Japanese%20Journal%20of%20Applied%20Physics%22%2C%22conferenceName%22%3A%22International%20Conference%20on%20Solid%20State%20Devices%20and%20Materials%20%28SSDM%29%2C%20Nagoya%20Univ%2C%20Nagoya%2C%20JAPAN%2C%2002-05%20septembre%2C%202019%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.7567%5C%2F1347-4065%5C%2Fab650b%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.7567%5C%2F1347-4065%5C%2Fab650b%22%2C%22collections%22%3A%5B%22NZSFH59F%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A35%3A11Z%22%7D%7D%2C%7B%22key%22%3A%229ARVCP5B%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Burel%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Burel%2C%20A.%20Teolis%2C%20A.%20Alsayed%2C%20C.B.%20Murray%2C%20B.%20Donnio%2C%20R.%20Dreyfus%2C%20Plasmonic%20Elastic%20Capsules%20as%20Colorimetric%20Reversible%20pH-Microsensors%2C%20Small%2016%20%282020%29%201903897.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.201903897%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.201903897%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Plasmonic%20Elastic%20Capsules%20as%20Colorimetric%20Reversible%20pH-Microsensors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C%5Cu00e9line%22%2C%22lastName%22%3A%22Burel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Teolis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ahmed%22%2C%22lastName%22%3A%22Alsayed%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christopher%20B.%22%2C%22lastName%22%3A%22Murray%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R%5Cu00e9mi%22%2C%22lastName%22%3A%22Dreyfus%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20There%20is%20a%20crucial%20need%20for%20effective%20and%20easily%20dispersible%20colloidal%20microsensors%20able%20to%20detect%20local%20pH%20changes%20before%20irreversible%20damages%20caused%20by%20demineralization%2C%20corrosion%2C%20or%20biofilms%20occur.%20One%20class%20of%20such%20microsensors%20is%20based%20on%20molecular%20dyes%20encapsulated%20or%20dispersed%20either%20in%20polymer%20matrices%20or%20in%20liquid%20systems%20exhibiting%20different%20colors%20upon%20pH%20variations.%20They%20are%20efficient%20but%20often%20rely%20on%20sophisticated%20and%20costly%20syntheses%2C%20and%20present%20significant%20risks%20of%20leakage%20and%20photobleaching%20damages%2C%20which%20is%20detrimental%20for%20mainstream%20applications.%20Another%20approach%20consists%20of%20exploiting%20the%20distance-dependent%20plasmonic%20properties%20of%20metallic%20nanoparticles.%20Still%2C%20assembling%20nanoparticles%20into%20dispersible%20colloidal%20pH-sensitive%20sensors%20remains%20a%20challenge.%20Here%2C%20it%20is%20shown%20how%20to%20combine%20optically%20active%20plasmonic%20gold%20nanoparticles%20and%20pH-responsive%20thin%20shells%20into%20%5Cu201cplasmocapsules.%5Cu201d%20Upon%20pH%20change%2C%20plasmocapsules%20swell%20or%20shrink.%20Concomitantly%2C%20the%20distance%20between%20the%20gold%20nanoparticles%20embedded%20in%20the%20polymeric%20matrix%20varies%2C%20resulting%20in%20an%20unambiguous%20color%20change.%20Billions%20of%20micron-size%20sensors%20can%20thus%20be%20easily%20fabricated.%20They%20are%20nonintrusive%2C%20reusable%2C%20and%20sense%20local%20pH%20changes.%20Each%20plasmocapsule%20is%20an%20independent%20reversible%20microsensor%20over%20a%20large%20pH%20range.%20Finally%2C%20their%20potential%20use%20for%20the%20detection%20of%20bacterial%20growth%20is%20demonstrated%2C%20thus%20proving%20that%20plasmocapsules%20are%20a%20new%20class%20of%20sensing%20materials.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fsmll.201903897%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.201903897%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222022-03-14T14%3A01%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22WHJZNVZQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Califano%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EF.%20Califano%2C%20G.%20Manfredi%2C%20F.%20Valentini%2C%20Special%20Issue%3A%20The%20many%20facets%20of%20the%20Vlasov%20equation%2C%20Journal%20of%20Plasma%20Physics%2086%20%282020%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1017%5C%2FS0022377820000811%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1017%5C%2FS0022377820000811%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Special%20Issue%3A%20The%20many%20facets%20of%20the%20Vlasov%20equation%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Califano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giovanni%22%2C%22lastName%22%3A%22Manfredi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Valentini%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1017%5C%2FS0022377820000811%22%2C%22ISSN%22%3A%220022-3778%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1017%5C%2FS0022377820000811%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222020-09-18T13%3A44%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22AMVK75H8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Carvalho%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.-A.%20Carvalho%2C%20H.%20Dekkiche%2C%20S.%20Richeter%2C%20C.%20Bailly%2C%20L.%20Karmazin%2C%20D.%20McKearney%2C%20D.B.%20Leznoff%2C%20G.%20Rogez%2C%20B.%20Vileno%2C%20S.%20Choua%2C%20R.%20Ruppert%2C%20Antiferromagnetic%20coupling%20in%20copper%28II%29porphyrin%20dimers%20linked%20by%20copper%28II%29%20or%20palladium%28II%29%20ion%2C%20Journal%20of%20Porphyrins%20and%20Phthalocyanines%2024%20%282020%29%20238%26%23x2013%3B246.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1142%5C%2FS1088424619501037%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1142%5C%2FS1088424619501037%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Antiferromagnetic%20coupling%20in%20copper%28II%29porphyrin%20dimers%20linked%20by%20copper%28II%29%20or%20palladium%28II%29%20ion%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mary-Ambre%22%2C%22lastName%22%3A%22Carvalho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Herve%22%2C%22lastName%22%3A%22Dekkiche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%22%2C%22lastName%22%3A%22Richeter%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bailly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lydia%22%2C%22lastName%22%3A%22Karmazin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Declan%22%2C%22lastName%22%3A%22McKearney%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%20B.%22%2C%22lastName%22%3A%22Leznoff%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Rogez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Vileno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22Choua%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Romain%22%2C%22lastName%22%3A%22Ruppert%22%7D%5D%2C%22abstractNote%22%3A%22The%20synthesis%20of%20porphyrin%20dimers%20linked%20by%20metal%20ions%20is%20described%20and%20the%20X-ray%20structure%20of%20two%20new%20dimers%20is%20presented.%20As%20previously%20shown%20for%20diamagnetic%20metal%20ions%2C%20strong%20electronic%20interactions%20between%20the%20individual%20subunits%20were%20observed.%20Antiferromagnetic%20coupling%20between%20copper%28II%29porphyrins%20linked%20by%20palladium%28II%29%20or%20copper%28II%29%20ions%20was%20studied%20by%20EPR%20and%20SQUID%20measurements.%20For%20the%20palladium%28II%29-linked%20dimer%2C%20the%20very%20small%20antiferromagnetic%20coupling%20was%20estimated%20by%20EPR%20measurements%20%28J%20%3C%20-1%20cm%28-1%29%29.%20For%20the%20trinuclear-copper%28II%29-linked%20dimer%2C%20a%20large%20antiferromagnetic%20coupling%20between%20the%20copper%28II%29%20ions%20was%20measured.%20In%20this%20trinuclear%20compound%2C%20the%20linking%20copper%28II%29%20ion%20is%20used%20as%20a%20relay%20to%20increase%20the%20interaction%20between%20the%20two%20copper%28II%29porphyrins.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1142%5C%2FS1088424619501037%22%2C%22ISSN%22%3A%221088-4246%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1142%5C%2FS1088424619501037%22%2C%22collections%22%3A%5B%22M244N6AF%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A35%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22PGJYRPMS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Charignon%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EE.%20Charignon%2C%20M.%20Bouche%2C%20C.%20Clave-Darcissac%2C%20G.%20Dahm%2C%20G.%20Ichim%2C%20A.%20Clotagatide%2C%20H.C.%20Mertani%2C%20P.%20Telouk%2C%20J.%20Caramel%2C%20J.-J.%20Diaz%2C%20S.%20Bellemin-Laponnaz%2C%20P.%20Bouvet%2C%20C.%20Billotey%2C%20In%20Cellulo%20Evaluation%20of%20the%20Therapeutic%20Potential%20of%20NHC%20Platinum%20Compounds%20in%20Metastatic%20Cutaneous%20Melanoma%2C%20International%20Journal%20of%20Molecular%20Sciences%2021%20%282020%29%207626.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fijms21217826%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fijms21217826%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22In%20Cellulo%20Evaluation%20of%20the%20Therapeutic%20Potential%20of%20NHC%20Platinum%20Compounds%20in%20Metastatic%20Cutaneous%20Melanoma%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elsa%22%2C%22lastName%22%3A%22Charignon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathilde%22%2C%22lastName%22%3A%22Bouche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Caroline%22%2C%22lastName%22%3A%22Clave-Darcissac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Georges%22%2C%22lastName%22%3A%22Dahm%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gabriel%22%2C%22lastName%22%3A%22Ichim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anthony%22%2C%22lastName%22%3A%22Clotagatide%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hichem%20C.%22%2C%22lastName%22%3A%22Mertani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Telouk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julie%22%2C%22lastName%22%3A%22Caramel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Jacques%22%2C%22lastName%22%3A%22Diaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Bouvet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Claire%22%2C%22lastName%22%3A%22Billotey%22%7D%5D%2C%22abstractNote%22%3A%22We%20describe%20here%20the%20evaluation%20of%20the%20cytotoxic%20efficacy%20of%20two%20platinum%20%28II%29%20complexes%20bearing%20an%20N-heterocyclic%20carbene%20%28NHC%29%20ligand%2C%20a%20pyridine%20ligand%20and%20bromide%20or%20iodide%20ligands%20on%20a%20panel%20of%20human%20metastatic%20cutaneous%20melanoma%20cell%20lines%20representing%20different%20genetic%20subsets%20including%20BRAF-inhibitor-resistant%20cell%20lines%2C%20namely%20A375%2C%20SK-MEL-28%2C%20MeWo%2C%20HMCB%2C%20A375-R%2C%20SK-MEL-5-R%20and%20501MEL-R.%20Cisplatin%20and%20dacarbazine%20were%20also%20studied%20for%20comparison%20purposes.%20Remarkably%2C%20the%20iodine-labelled%20Pt-NHC%20complex%20strongly%20inhibited%20proliferation%20of%20all%20tested%20melanoma%20cells%20after%201-h%20exposure%2C%20likely%20due%20to%20its%20rapid%20uptake%20by%20melanoma%20cells.%20The%20mechanism%20of%20this%20inhibitory%20activity%20involves%20the%20formation%20of%20DNA%20double-strand%20breaks%20and%20apoptosis.%20Considering%20the%20intrinsic%20chemoresistance%20of%20metastatic%20melanoma%20cells%20of%20current%20systemic%20treatments%2C%20these%20findings%20are%20promising%20and%20could%20give%20research%20opportunities%20in%20the%20future%20to%20improve%20the%20prognosis%20of%20patients%20suffering%20from%20unresectable%20metastatic%20melanoma%20that%20are%20not%20eligible%20or%20that%20do%20not%20respond%20to%20the%20most%20effective%20drugs%20available%20to%20date%2C%20namely%20BRAF%20inhibitors%20and%20the%20anti-PD-1%20monoclonal%20antibody%20%28mAb%29.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3390%5C%2Fijms21217826%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fijms21217826%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222021-04-30T14%3A01%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22Q5MQZGS7%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Chen%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EX.%20Chen%2C%20M.%20Boero%2C%20O.%20Lopez-Acevedo%2C%20Atomic%20structure%20and%20origin%20of%20chirality%20of%20DNA-stabilized%20silver%20clusters%2C%20Physical%20Review%20Materials%204%20%282020%29%20065601.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.4.065601%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.4.065601%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Atomic%20structure%20and%20origin%20of%20chirality%20of%20DNA-stabilized%20silver%20clusters%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xi%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mauro%22%2C%22lastName%22%3A%22Boero%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olga%22%2C%22lastName%22%3A%22Lopez-Acevedo%22%7D%5D%2C%22abstractNote%22%3A%22DNA-stabilized%20silver%20clusters%20%28Ag%3ADNAs%29%20have%20attracted%20much%20attention%20due%20to%20their%20unique%20sequence-dependent%20fluorescence%20and%20many%20potential%20applications%3B%20however%2C%20the%20understandings%20of%20their%20atomic%20structures%20and%20functional%20properties%20are%20still%20limited%2C%20which%20hamper%20the%20further%20development%20of%20the%20novel%20nanoclusters.%20Using%20the%20advanced%20computational%20methods%2C%20we%20propose%20three%20atomistic%20models%20for%20the%20Ag%3ADNAs%2C%20which%20all%20contain%20a%20four-electron%20silver%20core%20with%20a%20two-row%20planar%20shape%20stabilized%20by%20the%20nitrogen%20atoms%20in%20the%20DNA.%20By%20comparing%20experimental%20and%20time-dependent%20density%20functional%20theory-simulated%20circular%20dichroism%20spectra%2C%20we%20have%20confirmed%20that%20these%20core%20structures%20should%20commonly%20exist%20in%20the%20Ag%3ADNAs.%20We%20then%20analyze%20the%20electronic%20and%20optical%20properties%20of%20the%20clusters%20and%20discover%20that%20the%20silver%20to%20DNA%20transitions%20have%20essential%20contributions%20to%20the%20chiroptical%20properties%20of%20the%20clusters.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevMaterials.4.065601%22%2C%22ISSN%22%3A%222475-9953%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevMaterials.4.065601%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222020-06-19T08%3A46%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22ZE4WAKXG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Chen%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EW.%20Chen%2C%20J.%20Egly%2C%20A.%20Pobtador-Bahamonde%20I.%2C%20A.%20Maisse-Francois%2C%20S.%20Bellemin-Laponnaz%2C%20T.%20Achard%2C%20Synthesis%2C%20characterization%2C%20catalytic%20and%20biological%20application%20of%20half-sandwich%20ruthenium%20complexes%20bearing%20hemilabile%20%28kappa%202-C%2CS%29-thioether-functionalised%20NHC%20ligands%2C%20Dalton%20Transactions%2049%20%282020%29%203243%26%23x2013%3B3252.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt04825a%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9dt04825a%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synthesis%2C%20characterization%2C%20catalytic%20and%20biological%20application%20of%20half-sandwich%20ruthenium%20complexes%20bearing%20hemilabile%20%28kappa%202-C%2CS%29-thioether-functionalised%20NHC%20ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Weiguang%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julien%22%2C%22lastName%22%3A%22Egly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amatia%2C%20I%22%2C%22lastName%22%3A%22Pobtador-Bahamonde%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aline%22%2C%22lastName%22%3A%22Maisse-Francois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Achard%22%7D%5D%2C%22abstractNote%22%3A%22A%20series%20of%20cationic%20Ru%28ii%29%28eta%286%29-p-cymene%29%20complexes%20with%20thioether-functionalised%20N-heterocyclic%20carbene%20ligands%20have%20been%20prepared%20and%20fully%20characterized.%20Steric%20and%20electronic%20influence%20of%20the%20R%20thioether%20substituent%20on%20the%20coordination%20of%20the%20sulfur%20atom%20was%20investigated.%20The%20molecular%20structure%20of%20three%20of%20them%20has%20been%20determined%20by%20means%20of%20X-ray%20diffractrometry%20and%20confirmed%20the%20bidentate%20%28kappa%282%29-C%2CS%29%20coordination%20mode%20of%20the%20ligand.%20Interestingly%2C%20only%20a%20single%20diastereomer%2C%20as%20an%20enantiomeric%20couple%2C%20was%20observed%20in%20the%20solid%20state%20for%20complexes%201c%2C%201i%20and%201j.%20DFT%20calculations%20established%20a%20low%20energy%20inversion%20barrier%20between%20the%20two%20diastereomers%20through%20a%20sulfur%20pyramidal%20inversion%20pathway%20with%20R%20donating%20group%20while%20a%20dissociative%5C%2Fassociative%20mechanism%20is%20more%20likely%20with%20R%20substituents%20that%20contain%20electron%20withdrawing%20group%2C%20thus%20suggesting%20that%20the%20only%20species%20observed%20by%20the%20H-1-NMR%20correspond%20to%20an%20average%20resonance%20position%20of%20a%20fluxional%20mixtures%20of%20isomers.%20All%20these%20complexes%20were%20found%20to%20catalyse%20the%20oxydant-free%20double%20dehydrogenation%20of%20primary%20amine%20into%20nitrile.%20Ru%20complex%20bearing%20NHC-functionalised%20S-tBu%20group%20was%20further%20investigated%20in%20a%20wide%20range%20of%20amines%20and%20was%20found%20more%20selective%20for%20alkyl%20amine%20substrates%20than%20for%20benzylamine%20derivatives.%20Finally%2C%20preliminary%20results%20of%20the%20biological%20effects%20on%20various%20human%20cancer%20cells%20of%20four%20selected%20Ru%20complexes%20are%20reported.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9dt04825a%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc9dt04825a%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A36%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22NQ5TWK7F%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cidrim%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Cidrim%2C%20T.S.%20do%20Espirito%20Santo%2C%20J.%20Schachenmayer%2C%20R.%20Kaiser%2C%20R.%20Bachelard%2C%20Photon%20Blockade%20with%20Ground-State%20Neutral%20Atoms%2C%20Physical%20Review%20Letters%20125%20%282020%29%20073601.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.125.073601%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevLett.125.073601%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Photon%20Blockade%20with%20Ground-State%20Neutral%20Atoms%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Cidrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%20S.%22%2C%22lastName%22%3A%22do%20Espirito%20Santo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johannes%22%2C%22lastName%22%3A%22Schachenmayer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Kaiser%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Bachelard%22%7D%5D%2C%22abstractNote%22%3A%22We%20show%20that%20induced%20dipole-dipole%20interactions%20allow%20for%20photon%20blockade%20in%20subwavelength%20ensembles%20of%20two-level%2C%20ground-state%20neutral%20atoms.%20Our%20protocol%20relies%20on%20the%20energy%20shift%20of%20the%20single-excitation%2C%20superradiant%20state%20of%20N%20atoms%2C%20which%20can%20be%20engineered%20to%20yield%20an%20effective%20two-level%20system.%20A%20coherent%20pump%20induces%20Rabi%20oscillation%20between%20the%20ground%20state%20and%20a%20collective%20bright%20state%2C%20with%20at%20most%20a%20single%20excitation%20shared%20among%20all%20atoms.%20The%20possibility%20of%20using%20clock%20transitions%20that%20are%20long-lived%20and%20relatively%20robust%20against%20stray%20fields%2C%20alongside%20new%20prospects%20on%20experiments%20with%20subwavelength%20lattices%2C%20makes%20our%20proposal%20a%20promising%20alternative%20for%20quantum%20information%20protocols.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevLett.125.073601%22%2C%22ISSN%22%3A%220031-9007%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevLett.125.073601%22%2C%22collections%22%3A%5B%22D8DBRKSX%22%5D%2C%22dateModified%22%3A%222022-02-11T14%3A01%3A54Z%22%7D%7D%2C%7B%22key%22%3A%22ITNE8LKC%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Costa%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.S.%20Costa%2C%20G.%20Hao%2C%20A.T.%20N%26%23x2019%3BDiaye%2C%20L.%20Routaboul%2C%20P.%20Braunstein%2C%20X.%20Zhang%2C%20J.%20Zhang%2C%20T.K.%20Ekanayaka%2C%20Q.-Y.%20Shi%2C%20V.%20Schlegel%2C%20B.%20Doudin%2C%20A.%20Enders%2C%20P.A.%20Dowben%2C%20Manipulation%20of%20the%20molecular%20spin%20crossover%20transition%20of%20Fe%28H2B%28pz%292%292%28bipy%29%20by%20addition%20of%20polar%20molecules%2C%20Journal%20of%20Physics%3A%20Condensed%20Matter%2032%20%282020%29%20034001.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648x%5C%2Fab468c%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648x%5C%2Fab468c%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Manipulation%20of%20the%20molecular%20spin%20crossover%20transition%20of%20Fe%28H2B%28pz%292%292%28bipy%29%20by%20addition%20of%20polar%20molecules%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paulo%20S.%22%2C%22lastName%22%3A%22Costa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guanhua%22%2C%22lastName%22%3A%22Hao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alpha%20T.%22%2C%22lastName%22%3A%22N%27Diaye%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lucie%22%2C%22lastName%22%3A%22Routaboul%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Braunstein%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xin%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jian%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thilini%20K.%22%2C%22lastName%22%3A%22Ekanayaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Qin-Yin%22%2C%22lastName%22%3A%22Shi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vicki%22%2C%22lastName%22%3A%22Schlegel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bernard%22%2C%22lastName%22%3A%22Doudin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Axel%22%2C%22lastName%22%3A%22Enders%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%20A.%22%2C%22lastName%22%3A%22Dowben%22%7D%5D%2C%22abstractNote%22%3A%22The%20addition%20of%20various%20dipolar%20molecules%20is%20shown%20to%20affect%20the%20temperature%20dependence%20of%20the%20spin%20state%20occupancy%20of%20the%20much%20studied%20spin%20crossover%20Fe%28II%29%20complex%2C%20%5BFeH2B%28pz%2922%28bipy%29%5D%20%28pz%20%3D%20pyrazol-1-yl%2C%20bipy%20%3D%202%2C2%5Cu2032-bipyridine%29.%20Specifically%2C%20the%20addition%20of%20benzimidazole%20results%20in%20a%20re-entrant%20spin%20crossover%20transition%2C%20i.e.%20the%20spin%20state%20starts%20in%20the%20mostly%20low%20spin%20state%2C%20then%20high%20spin%20state%20occupancy%20increases%2C%20and%20finally%20the%20high%20spin%20state%20occupancy%20decreases%20with%20increasing%20temperature.%20This%20behavior%20contrasts%20with%20that%20observed%20when%20the%20highly%20polar%20p%20-benzoquinonemonoimine%20zwitterion%20C6H2%28%5Cu2026NH2%292%28%5Cu2026O%292%20was%20mixed%20with%20%5BFeH2B%28pz%2922%28bipy%29%5D%2C%20which%20resulted%20in%20locking%20%5BFeH2B%28pz%2922%28bipy%29%5D%20largely%20into%20a%20low%20spin%20state%20while%20addition%20of%20the%20ethyl%20derivative%20C6H2%28%5Cu2026NHC2H5%292%28%5Cu2026O%292%20did%20not%20appear%20to%20perturb%20the%20spin%20crossover%20transition%20of%20%5BFeH2B%28pz%2922%28bipy%29%5D.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-648x%5C%2Fab468c%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-648x%5C%2Fab468c%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22N8397DCZ%22%5D%2C%22dateModified%22%3A%222022-02-14T10%3A42%3A02Z%22%7D%7D%2C%7B%22key%22%3A%22JI6YKCJ2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cotin%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Cotin%2C%20F.%20Perton%2C%20C.%20Petit%2C%20S.%20Sall%2C%20C.%20Kiefer%2C%20V.%20Begin%2C%20B.%20Pichon%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Mertz%2C%20J.-M.%20Greneche%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Harnessing%20Composition%20of%20Iron%20Oxide%20Nanoparticle%3A%20Impact%20of%20Solvent-Mediated%20Ligand-Ligand%20Interaction%20and%20Competition%20between%20Oxidation%20and%20Growth%20Kinetics%2C%20Chemistry%20of%20Materials%2032%20%282020%29%209245%26%23x2013%3B9259.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.0c03041%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.0c03041%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Harnessing%20Composition%20of%20Iron%20Oxide%20Nanoparticle%3A%20Impact%20of%20Solvent-Mediated%20Ligand-Ligand%20Interaction%20and%20Competition%20between%20Oxidation%20and%20Growth%20Kinetics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geoffrey%22%2C%22lastName%22%3A%22Cotin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francis%22%2C%22lastName%22%3A%22Perton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Petit%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Secou%22%2C%22lastName%22%3A%22Sall%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Celine%22%2C%22lastName%22%3A%22Kiefer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valentin%22%2C%22lastName%22%3A%22Begin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Mertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22The%20composition%20of%20metal%20oxide%20nanoparticles%20is%20of%20great%20importance%20for%20their%20applications%20because%20defects%20and%5C%2For%20deviation%20from%20stoichiometry%20strongly%20affect%20their%20physical%20properties.%20We%20report%20here%20on%20the%20crucial%20role%20of%20synthesis%20parameters%20such%20as%20solvent%2C%20ligand%2C%20and%20iron%20precursors%20on%20the%20composition%20of%20spinel%20iron%20oxide%20nanoparticles%20synthesized%20by%20the%20thermal%20decomposition%20method.%20At%20first%2C%20the%20investigation%20of%20the%20thermal%20decomposition%20of%20iron%20stearates%20bearing%20either%20two%20or%20three%20stearate%20chains%20by%20thermogravimetric%20analysis%2C%20infrared%20spectroscopy%2C%20and%20Mossbauer%20spectrometry%20as%20a%20function%20of%20temperature%20and%20syntheses%20with%20only%20oleic%20acid%20and%20iron%20stearate%20confirmed%20that%20the%20composition%20of%20the%20first%20nuclei%20is%20wustite%20Fe1-xO.%20The%20synthesis%20of%20nanoparticles%20with%20high%20sizes%20requires%20the%20use%20of%20very%20high%20boiling%20point%20solvents%20to%20ensure%20an%20effective%20growth%20step.%20We%20observed%20that%20when%20the%20grain%20growth%20and%20oxidation%20kinetics%20are%20similar%2C%20nanoparticles%20with%20a%20spinel%20composition%20and%20no%20defects%20are%20produced.%20An%20oxidation%20rate%20slower%20than%20the%20nuclei%20growth%20rate%20favors%20the%20formation%20of%20core-shell%20Fe1-xO%40Fe3-xO4%20NPs.%20The%20oxidation%20kinetics%20is%20shown%20to%20be%20influenced%20by%20surfactant%20and%20solvent%20natures.%20Indeed%2C%20surfactants%20such%20as%20oleic%20acid%20form%20a%20dense%20monolayer%20at%20the%20nuclei%20surface%2C%20and%20oxidation%20kinetics%20will%20depend%20on%20this%20monolayer%20permeability.%20Temperature%2C%20solvents%20with%20high%20surfactant%20affinity%2C%20deprotonated%20surfactants%2C%20or%20decomposition%20products%20of%20solvents%20affect%20the%20monolayer%20stability%20and%20thus%20the%20nanoparticle%20composition.%20The%20solvents%27%20nature%20and%20solvent-mediated%20ligand-ligand%20interactions%20are%20thus%20evidenced%20to%20be%20important%20parameters%20to%20control%20the%20formation%20of%20defect-free%20and%20stoichiometric%20oxide%20nanoparticles.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.0c03041%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.chemmater.0c03041%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222021-09-06T12%3A41%3A26Z%22%7D%7D%2C%7B%22key%22%3A%22RS9JT3F8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Couzon%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Couzon%2C%20L.%20Bois%2C%20C.%20Fellah%2C%20C.%20Loestean%2C%20F.%20Chassagneux%2C%20R.%20Chiriac%2C%20F.%20Toche%2C%20L.%20Khrouz%2C%20A.%20Brioude%2C%20O.%20Ersen%2C%20L.%20Roiban%2C%20Manganese%20oxidation%20states%20repartition%20in%20a%20channel-like%20mesoporous%20zirconium%20oxide%2C%20Journal%20of%20Porous%20Materials%2027%20%282020%29%201823%26%23x2013%3B1835.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10934-020-00962-5%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs10934-020-00962-5%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Manganese%20oxidation%20states%20repartition%20in%20a%20channel-like%20mesoporous%20zirconium%20oxide%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nelly%22%2C%22lastName%22%3A%22Couzon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurence%22%2C%22lastName%22%3A%22Bois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clementine%22%2C%22lastName%22%3A%22Fellah%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristian%22%2C%22lastName%22%3A%22Loestean%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fernand%22%2C%22lastName%22%3A%22Chassagneux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rodica%22%2C%22lastName%22%3A%22Chiriac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Toche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lhoussain%22%2C%22lastName%22%3A%22Khrouz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arnaud%22%2C%22lastName%22%3A%22Brioude%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lucian%22%2C%22lastName%22%3A%22Roiban%22%7D%5D%2C%22abstractNote%22%3A%22Here%2C%20we%20present%20a%20characterization%20of%20mesoporous%20mixed%20manganese%20zirconium%20oxide%20%28MnZr%29%20synthesized%20by%20evaporation%20induced%20self-assembly%20method%20involving%20a%20block%20copolymer%20self-assembly%20method.%20The%20MnZr%20oxide%20has%20been%20fully%20characterized%20by%20X-ray%20diffraction%2C%20transmission%20electronic%20microscopy%2C%20analytical%20electronic%20tomography%2C%20nitrogen%20adsorption%5C%2Fdesorption%20isotherms%2C%20thermogravimetric%20analysis%2C%20X-ray%20photoelectron%20spectroscopy%20and%20electronic%20paramagnetic%20resonance.%20Electronic%20tomography%20analysis%20reveals%20that%20a%20mesoporous%20solid%20solution%20MnZr%20was%20successfully%20obtained%20by%20this%20way%2C%20with%20a%20homogeneous%20dispersion%20of%20Mn.%20X-ray%20diffraction%2C%20X-ray%20photoelectron%20spectroscopy%2C%20thermal%20analysis%20and%20electronic%20paramagnetic%20resonance%20inform%20about%20the%20manganese%20oxidation%20states%20present%20%28Mn2%2B%2C%20Mn3%2B%2C%20Mn4%2B%29%20and%20their%20location%20within%20the%20sample.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1007%5C%2Fs10934-020-00962-5%22%2C%22ISSN%22%3A%221380-2224%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1007%5C%2Fs10934-020-00962-5%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222022-02-10T15%3A46%3A39Z%22%7D%7D%2C%7B%22key%22%3A%22RXW3WUMJ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Craciun%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.D.%20Craciun%2C%20B.%20Donnio%2C%20J.-L.%20Gallani%2C%20M.V.%20Rastei%2C%20High-resolution%20manipulation%20of%20gold%20nanorods%20with%20an%20atomic%20force%20microscope%2C%20Nanotechnology%2031%20%282020%29%20085302.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6528%5C%2Fab5404%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6528%5C%2Fab5404%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22High-resolution%20manipulation%20of%20gold%20nanorods%20with%20an%20atomic%20force%20microscope%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20D.%22%2C%22lastName%22%3A%22Craciun%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Louis%22%2C%22lastName%22%3A%22Gallani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%20V.%22%2C%22lastName%22%3A%22Rastei%22%7D%5D%2C%22abstractNote%22%3A%22The%20controlled%20manipulation%20and%20precise%20positioning%20of%20nanoparticles%20on%20surfaces%20is%20a%20critical%20requisite%20for%20studying%20interparticle%20interactions%20in%20various%20research%20fields%20including%20spintronics%2C%20plasmonics%2C%20and%20nanomagnetism.%20We%20present%20here%20a%20method%20where%20an%20atomic%20force%20microscope%20operating%20in%20vacuum%20is%20used%20to%20accurately%20rotate%20and%20displace%20CTAB-coated%20gold%20nanorods%20on%20silica%20surfaces.%20The%20method%20relies%20on%20operating%20an%20AFM%20in%20a%20bimodal%20way%20which%20includes%20both%20dynamic%20and%20contact%20modes.%20Moreover%2C%20the%20phase%20of%20the%20oscillating%20probe%20is%20used%20to%20monitor%20the%20nanoparticle%20trajectory%2C%20which%20amplitude%20variations%20are%20employed%20to%20evaluate%20the%20energy%20dissipation%20during%20manipulation.%20The%20nanoscale%20displacement%20modes%20involve%20nanorod%20in-plane%20rotation%20and%20sliding%2C%20but%20no%20rolling%20events.%20The%20transitions%20between%20these%20displacement%20modes%20depend%20on%20the%20angle%20between%20the%20scan%20axis%20direction%20and%20the%20nanorod%20long%20axis.%20The%20findings%20reveal%20the%20importance%20of%20mean%20tip-substrate%20distance%20and%20of%20oscillation%20amplitude%20of%20the%20tip.%20The%20role%20of%20substrate%20surface%20and%20of%20CTAB%20molecular%20bi-layer%20at%20nanorod%20surface%20is%20also%20discussed.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-6528%5C%2Fab5404%22%2C%22ISSN%22%3A%220957-4484%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6528%5C%2Fab5404%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22VRM2E3H6%22%2C%22BMA9GKQT%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222021-04-30T14%3A19%3A10Z%22%7D%7D%2C%7B%22key%22%3A%226842DHE6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cypriano%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Cypriano%2C%20M.%20Bahri%2C%20K.%20Dembele%2C%20W.%20Baaziz%2C%20P.%20Leao%2C%20D.A.%20Bazylinski%2C%20F.%20Abreu%2C%20O.%20Ersen%2C%20M.%20Farina%2C%20J.%20Werckmann%2C%20Insight%20on%20thermal%20stability%20of%20magnetite%20magnetosomes%3A%20implications%20for%20the%20fossil%20record%20and%20biotechnology%2C%20Scientific%20Reports%2010%20%282020%29%206706.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-020-63531-5%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-020-63531-5%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Insight%20on%20thermal%20stability%20of%20magnetite%20magnetosomes%3A%20implications%20for%20the%20fossil%20record%20and%20biotechnology%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jefferson%22%2C%22lastName%22%3A%22Cypriano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mounib%22%2C%22lastName%22%3A%22Bahri%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kassioge%22%2C%22lastName%22%3A%22Dembele%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pedro%22%2C%22lastName%22%3A%22Leao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dennis%20A.%22%2C%22lastName%22%3A%22Bazylinski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fernanda%22%2C%22lastName%22%3A%22Abreu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcos%22%2C%22lastName%22%3A%22Farina%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacques%22%2C%22lastName%22%3A%22Werckmann%22%7D%5D%2C%22abstractNote%22%3A%22Magnetosomes%20are%20intracellular%20magnetic%20nanocrystals%20composed%20of%20magnetite%20%28Fe3O4%29%20or%20greigite%20%28Fe3S4%29%2C%20enveloped%20by%20a%20lipid%20bilayer%20membrane%2C%20produced%20by%20magnetotactic%20bacteria.%20Because%20of%20the%20stability%20of%20these%20structures%20in%20certain%20environments%20after%20cell%20death%20and%20lysis%2C%20magnetosome%20magnetite%20crystals%20contribute%20to%20the%20magnetization%20of%20sediments%20as%20well%20as%20providing%20a%20fossil%20record%20of%20ancient%20microbial%20ecosystems.%20The%20persistence%20or%20changes%20of%20the%20chemical%20and%20magnetic%20features%20of%20magnetosomes%20under%20certain%20conditions%20in%20different%20environments%20are%20important%20factors%20in%20biotechnology%20and%20paleomagnetism.%20Here%20we%20evaluated%20the%20thermal%20stability%20of%20magnetosomes%20in%20a%20temperature%20range%20between%20150%20and%20500%20degrees%20C%20subjected%20to%20oxidizing%20conditions%20by%20using%20in%20situ%20scanning%20transmission%20electron%20microscopy.%20Results%20showed%20that%20magnetosomes%20are%20stable%20and%20structurally%20and%20chemically%20unaffected%20at%20temperatures%20up%20to%20300%20degrees%20C.%20Interestingly%2C%20the%20membrane%20of%20magnetosomes%20was%20still%20observable%20after%20heating%20the%20samples%20to%20300%20degrees%20C.%20When%20heated%20between%20300%20degrees%20C%20and%20500%20degrees%20C%20cavity%20formation%20in%20the%20crystals%20was%20observed%20most%20probably%20associated%20to%20the%20partial%20transformation%20of%20magnetite%20into%20maghemite%20due%20to%20the%20Kirkendall%20effect%20at%20the%20nanoscale.%20This%20study%20provides%20some%20insight%20into%20the%20stability%20of%20magnetosomes%20in%20specific%20environments%20over%20geological%20periods%20and%20offers%20novel%20tools%20to%20investigate%20biogenic%20nanomaterials.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41598-020-63531-5%22%2C%22ISSN%22%3A%222045-2322%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41598-020-63531-5%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222020-09-18T13%3A45%3A17Z%22%7D%7D%2C%7B%22key%22%3A%226QUTQIZQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dai%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Dai%2C%20K.-Q.%20Zhao%2C%20B.-Q.%20Wang%2C%20P.%20Hu%2C%20B.%20Heinrich%2C%20B.%20Donnio%2C%20Liquid%20crystal%20ionic%20self-assembly%20and%20anion-selective%20photoluminescence%20in%20discotic%20azatriphenylenes%2C%20Journal%20of%20Materials%20Chemistry%20C%208%20%282020%29%204215%26%23x2013%3B4225.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9tc05829j%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9tc05829j%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Liquid%20crystal%20ionic%20self-assembly%20and%20anion-selective%20photoluminescence%20in%20discotic%20azatriphenylenes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jia%22%2C%22lastName%22%3A%22Dai%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bi-Qin%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ping%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20on%20the%20straightforward%20synthesis%20of%20a%20new%20series%20of%20ionic%20discotic%20liquid%20crystals%20based%20on%20positively%20charged%20azatriphenylene.%20In%20our%20design%2C%20the%20quaternized%20azatriphenylene%20core%20is%20surrounded%20by%20four%20to%20six%20flexible%20aliphatic%20chains%20and%20various%20types%20of%20anions%2C%20including%20small%20inorganic%20anions%20%28i.e.%20Br-%2C%20I-%2C%20NO3-%2C%20BF4-%2C%20PF6-%29%2C%20and%20organic%20ones%20such%20as%20triflate%2C%20bis%28trifluoromethylsulfonyl%29imide%2C%20tosylate%2C%20saccharinate%2C%20d%20and%20l%20camphorsulfate%2C%20alkylsulfonates%2C%20and%20alkylsulfates.%20The%20mesophases%20and%20thermal%20behaviour%20of%20the%20salts%20were%20characterized%20by%20polarizing%20optical%20microscopy%2C%20differential%20scanning%20calorimetry%2C%20thermal%20gravimetry%20and%20small-angle%20X-ray%20scattering.%20A%20classical%20hexagonal%20columnar%20mesophase%2C%20i.e.%20p6mm-Col%28hex%29%2C%20was%20observed%20for%20most%20salts.%20Two%20exotic%20new%20phases%20were%20however%20identified%20for%20four%20compounds%2C%20namely%20a%20mesophase%20with%20a%20hexagonal%20lattice%20of%20p3m1%20symmetry%20%28Hex%29%2C%20and%20another%20mesophase%20with%20a%20rectangular%20lattice%20of%20pseudo-hexagonal%20geometry%20%28i.e.%20a%5C%2Fb%20%3D%20root%203%29%20of%20p2mg%20symmetry%20%28Rec%28phex%29%29.%20The%20former%20results%20from%20the%20bulkiness%20of%20the%20triflimide%20anion%20and%20the%20arrangement%20of%20columns%20into%20a%20honeycomb%20lattice%2C%20whereas%20the%20latter%20is%20induced%20by%20the%20clustering%20of%20three%20columns%2C%20disposed%20according%20to%20a%20low-symmetry%20rectangular%20lattice.%20Their%20temperature%20ranges%20and%20stabilities%20strongly%20depend%20as%20expected%20on%20the%20anion%20type%20and%20the%20number%20%28and%20length%29%20of%20the%20alkyl%20side-chains%20%28O-%20and%20N-alkyl%2C%20respectively%29%2C%20highlighting%20the%20delicate%20balance%20and%20interplay%20between%20van%20der%20Waals%2C%20electrostatic%20and%20pi-pi%20core%20interactions.%20The%20UV%5C%2FVis%20absorption%20and%20fluorescent%20emission%20spectra%20were%20measured%2C%20and%20a%20strong%20yellow%20light%20photoluminescence%20was%20observed%20depending%20on%20the%20anion%20type%2C%20whereas%20anion-selective%20luminescence%20was%20observed%20in%20thin%20films.%20The%20neutral%20azatriphenylene%20precursor%2C%206%2C7%2C10%2C11-tetrakis%28hexyloxy%29dibenzo%5Bf%2Ch%5Disoquinoline%2C%20is%20also%20an%20interesting%20luminophore%2C%20showing%20an%20absolute%20emission%20quantum%20yield%20of%2075%25%2C%20while%20the%20corresponding%20salts%20exhibit%20anion-selective%20emission%20quantum%20yields%20as%20high%20as%2020%25.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9tc05829j%22%2C%22ISSN%22%3A%222050-7526%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc9tc05829j%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22BMA9GKQT%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A36%3A41Z%22%7D%7D%2C%7B%22key%22%3A%22W35NBZFN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Daoura%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EO.%20Daoura%2C%20G.%20El%20Chawich%2C%20M.%20Boutros%2C%20N.%20El%20Hassan%2C%20P.%20Massiani%2C%20O.%20Ersen%2C%20W.%20Baaziz%2C%20F.%20Launay%2C%20Aqueous%20nickel%28II%29%20hydroxycarbonate%20instead%20of%20nickel%280%29%20colloids%20as%20precursors%20of%20stable%20Ni-silica%20based%20catalysts%20for%20the%20dry%20reforming%20of%20methane%2C%20Catalysis%20Communications%20138%20%282020%29%20105953.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.catcom.2020.105953%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.catcom.2020.105953%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Aqueous%20nickel%28II%29%20hydroxycarbonate%20instead%20of%20nickel%280%29%20colloids%20as%20precursors%20of%20stable%20Ni-silica%20based%20catalysts%20for%20the%20dry%20reforming%20of%20methane%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Oscar%22%2C%22lastName%22%3A%22Daoura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ghenwa%22%2C%22lastName%22%3A%22El%20Chawich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maya%22%2C%22lastName%22%3A%22Boutros%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nissrine%22%2C%22lastName%22%3A%22El%20Hassan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pascale%22%2C%22lastName%22%3A%22Massiani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Franck%22%2C%22lastName%22%3A%22Launay%22%7D%5D%2C%22abstractNote%22%3A%22Nickel%28II%29%20hydroxycarbonate%20colloids%20were%20synthesized%20in%20water%20by%20the%20reaction%20of%20nickel%28II%29%20with%20carbonate%20in%20the%20presence%20of%20hexadecyltrimethylammonium%20bromide.%20Then%2C%20they%20were%20dispersed%20onto%20SBA-15%20affording%2C%20after%20calcination%20and%20reduction%2C%20a%20supported%203%20wt%25%20nickel%280%29%20catalyst%20for%20the%20dry%20reforming%20of%20methane%20%28DRM%29.%20This%20material%2C%20compared%20to%20reference%20ones%20obtained%20by%20impregnation%2C%20either%20by%20organic%20Ni%280%29%20colloids%20or%20by%20aqueous%20nickel%28II%29%2C%20was%20characterized%20by%20small%20nickel%20nanoparticles%20leading%20to%20improved%20activity%20and%20stability.%20Such%20use%20of%20aqueous%20nickel%28II%29%20hydroxycarbonate%20colloids%20instead%20of%20organic%20Ni%280%29%20ones%20synthesized%20with%20harmful%20reagents%20is%20a%20new%20and%20a%20more%20efficient%20and%20environment-friendly%20approach.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.catcom.2020.105953%22%2C%22ISSN%22%3A%221566-7367%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.catcom.2020.105953%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222022-01-22T15%3A36%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22AC93PPJ8%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Darari%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Darari%2C%20A.%20Frances-Monerris%2C%20B.%20Marekha%2C%20A.%20Doudouh%2C%20E.%20Wenger%2C%20A.%20Monari%2C%20S.%20Haacke%2C%20P.C.%20Gros%2C%20Towards%20Iron%28II%29%20Complexes%20with%20Octahedral%20Geometry%3A%20Synthesis%2C%20Structure%20and%20Photophysical%20Properties%2C%20Molecules%2025%20%282020%29%205991.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules25245991%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules25245991%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Towards%20Iron%28II%29%20Complexes%20with%20Octahedral%20Geometry%3A%20Synthesis%2C%20Structure%20and%20Photophysical%20Properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohamed%22%2C%22lastName%22%3A%22Darari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Frances-Monerris%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bogdan%22%2C%22lastName%22%3A%22Marekha%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelatif%22%2C%22lastName%22%3A%22Doudouh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuel%22%2C%22lastName%22%3A%22Wenger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Monari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Haacke%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%20C.%22%2C%22lastName%22%3A%22Gros%22%7D%5D%2C%22abstractNote%22%3A%22The%20control%20of%20ligand-field%20splitting%20in%20iron%20%28II%29%20complexes%20is%20critical%20to%20slow%20down%20the%20metal-to-ligand%20charge%20transfer%20%28MLCT%29-excited%20states%20deactivation%20pathways.%20The%20gap%20between%20the%20metal-centered%20states%20is%20maximal%20when%20the%20coordination%20sphere%20of%20the%20complex%20approaches%20an%20ideal%20octahedral%20geometry.%20Two%20new%20iron%28II%29%20complexes%20%28C1%20and%20C2%29%2C%20prepared%20from%20pyridylNHC%20and%20pyridylquinoline%20type%20ligands%2C%20respectively%2C%20have%20a%20near-perfect%20octahedral%20coordination%20of%20the%20metal.%20The%20photophysics%20of%20the%20complexes%20have%20been%20further%20investigated%20by%20means%20of%20ultrafast%20spectroscopy%20and%20TD-DFT%20modeling.%20For%20C1%2C%20it%20is%20shown%20that-despite%20the%20geometrical%20improvement-the%20excited%20state%20deactivation%20is%20faster%20than%20for%20the%20parent%20pseudo-octahedral%20C0%20complex.%20This%20unexpected%20result%20is%20due%20to%20the%20increased%20ligand%20flexibility%20in%20C1%20that%20lowers%20the%20energetic%20barrier%20for%20the%20relaxation%20of%20%28MLCT%29-M-3%20into%20the%20%28MC%29-M-3%20state.%20For%20C2%2C%20the%20effect%20of%20the%20increased%20ligand%20field%20is%20not%20strong%20enough%20to%20close%20the%20prominent%20deactivation%20channel%20into%20the%20metal-centered%20quintet%20state%2C%20as%20for%20other%20Fe-polypyridine%20complexes.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3390%5C%2Fmolecules25245991%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fmolecules25245991%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%5D%2C%22dateModified%22%3A%222021-02-17T16%3A28%3A09Z%22%7D%7D%2C%7B%22key%22%3A%224TSQG6I2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Darcheville%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Darcheville%2C%20A.-L.%20Adenot-Engelvin%2C%20C.%20Boscher%2C%20N.%20Vukadinovic%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20A.%20Thiaville%2C%20C.%20Sanchez%2C%20Evidence%20of%20the%20Superparamagnetic%20State%20in%20the%20Zero-Field%20Microwave%20Susceptibility%20Spectra%20of%20Ferrimagnetic%20Nanoparticles%2C%20IEEE%20Magnetics%20Letters%2011%20%282020%29%206105305.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2FLMAG.2020.3026228%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2FLMAG.2020.3026228%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Evidence%20of%20the%20Superparamagnetic%20State%20in%20the%20Zero-Field%20Microwave%20Susceptibility%20Spectra%20of%20Ferrimagnetic%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marie%22%2C%22lastName%22%3A%22Darcheville%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Lise%22%2C%22lastName%22%3A%22Adenot-Engelvin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Boscher%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Vukadinovic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andre%22%2C%22lastName%22%3A%22Thiaville%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Sanchez%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigated%20the%20static%20and%20dynamic%20magnetic%20properties%20of%20Zn%3Csub%3E0.4%3C%5C%2Fsub%3EFe%3Csub%3E2.6%3C%5C%2Fsub%3EO%3Csub%3E4%3C%5C%2Fsub%3E%20nanoparticles%20synthesized%20by%20thermal%20decomposition.%20Two%20ranges%20of%20diameter%20were%20used%3A%20small%20particles%20%28diameter%20about%206.2%20nm%29%20and%20larger%20ones%20%28diameter%20about%2022.4%20nm%29.%20The%20nanoparticle%20microstructure%20was%20characterized%20by%20transmission%20electron%20microscopy.%20The%20temperature%20dependence%20of%20the%20zero-field%20dynamic%20permeability%20for%20both%20nanoparticle%20sizes%20was%20studied%2C%20revealing%20a%20superparamagnetic%20state%20for%20the%20small%20ones.%20Effects%20of%20the%20nanoparticle%20size%20on%20the%20dynamic%20permeability%20were%20analyzied%2C%20and%20linked%20to%20the%20superparamagnetic%20state.%20A%20dynamic%20susceptibility%20model%20was%20found%20to%20reproduce%20the%20experimental%20behavior%20as%20well%20as%20its%20temperature%20dependence.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1109%5C%2FLMAG.2020.3026228%22%2C%22ISSN%22%3A%221949-307X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1109%5C%2FLMAG.2020.3026228%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A29%3A02Z%22%7D%7D%2C%7B%22key%22%3A%225V97JAZH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22David%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.R.%20David%2C%20S.%20Fritsch%2C%20A.%20Forster%2C%20D.%20Ihiawakrim%2C%20V.A.%20Geoffroy%2C%20Flocking%20asbestos%20waste%2C%20an%20iron%20and%20magnesium%20source%20for%20Pseudomonas%2C%20Science%20of%20the%20Total%20Environment%20709%20%282020%29%20135936.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.scitotenv.2019.135936%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.scitotenv.2019.135936%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Flocking%20asbestos%20waste%2C%20an%20iron%20and%20magnesium%20source%20for%20Pseudomonas%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%20R.%22%2C%22lastName%22%3A%22David%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sarah%22%2C%22lastName%22%3A%22Fritsch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne%22%2C%22lastName%22%3A%22Forster%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerie%20A.%22%2C%22lastName%22%3A%22Geoffroy%22%7D%5D%2C%22abstractNote%22%3A%22Iron%20and%20magnesium%20are%20essential%20nutrients%20for%20most%20microorganisms.%20In%20the%20environment%2C%20the%20availability%20of%20iron%20is%20low%20relative%20to%20that%20of%20magnesium.%20Microorganisms%20have%20developed%20various%20iron%20acquisition%20systems%2C%20which%20have%20been%20well%20studied%2C%20whereas%20few%20studies%20have%20examined%20magnesium%20acquisition.%20The%20production%20of%20siderophores%20is%20one%20of%20the%20efficient%20strategies%20widely%20used%20to%20sustain%20iron%20nutritional%20requirements.%20Many%20studies%20have%20shown%20that%20minerals%2C%20such%20as%20clays%2C%20iron%20oxides%2C%20and%20silicates%2C%20can%20serve%20as%20nutrient%20sources%20for%20bacteria.%20Asbestos%2C%20a%20natural%20fibrous%20silicate%20present%20in%20soil%20contains%20iron%20and%5C%2For%20magnesium%2C%20depending%20on%20the%20species%20of%20asbestos.%20Our%20aim%20was%20to%20study%20the%20acquisition%20of%20iron%20and%20magnesium%20from%20flocking%20asbestos%20waste%20by%20Pseudomonas%20aeruginosa%20and%20the%20involvement%20of%20the%20siderophores%2C%20pyoverdine%20and%20pyochelin.%20Flocking%20asbestos%20waste%20promoted%20growth%20under%20iron-%20and%20magnesium-limited%20conditions%2C%20together%20with%20a%20decrease%20in%20pyoverdine%20production%2C%20correlating%20with%20the%20dissolution%20of%20iron%20from%20the%20waste.%20In%20long-term%20experiments%2C%20flocking%20asbestos%20waste%20provided%20these%20two%20essential%20elements%20for%20bacterial%20growth%20and%20resulted%20in%20a%20decrease%20of%20iron%20in%20asbestos%20fibers.%20Among%20the%20enzymes%20required%20for%20pyochelin%20and%20pyoverdine%20synthesis%2C%20PchA%20and%20PvdJ%20were%20tagged%20with%20the%20fluorescent%20protein%20mCherry%20to%20analyze%20the%20expression%20patterns%20of%20proteins%20involved%20in%20siderophore%20production.%20Both%20enzymes%20were%20produced%20in%20the%20presence%20of%20flocking%20asbestos%20waste%2C%20suggesting%20a%20role%20of%20the%20pyoverdine%20and%20pyochelin%20pathway%20in%20asbestos%20dissolution.%20We%20investigated%20the%20involvement%20of%20each%20siderophore%20in%20iron%20and%20magnesium%20removal%20using%20mutants%20in%20one%20or%20both%20siderophore%20pathways.%20We%20observed%20a%20significant%20increase%20in%20iron%20extraction%20in%20the%20presence%20of%20siderophores%20and%20the%20absence%20of%20one%20of%20the%20two%20siderophores%20could%20be%20compensated%20by%20the%20other.%20Flocking%20asbestos%20waste%20represents%20an%20iron%20and%20magnesium%20source%20for%20P.%20aeruginosa%2C%20with%20iron%20removal%20linked%20to%20a%20siderophore-driven%20mechanism.%20%28C%29%202019%20Elsevier%20B.V.%20All%20rights%20reserved.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.scitotenv.2019.135936%22%2C%22ISSN%22%3A%220048-9697%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.scitotenv.2019.135936%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222020-03-10T15%3A52%3A11Z%22%7D%7D%2C%7B%22key%22%3A%223BRSZ9DH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22David%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.R.%20David%2C%20D.%20Ihiawakrim%2C%20R.%20Regis%2C%20V.A.%20Geoffroy%2C%20Efficiency%20of%20pyoverdines%20in%20iron%20removal%20from%20flocking%20asbestos%20waste%3A%20An%20innovative%20bacterial%20bioremediation%20strategy%2C%20Journal%20of%20Hazardous%20Materials%20394%20%282020%29%20122532.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jhazmat.2020.122532%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jhazmat.2020.122532%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Efficiency%20of%20pyoverdines%20in%20iron%20removal%20from%20flocking%20asbestos%20waste%3A%20An%20innovative%20bacterial%20bioremediation%20strategy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%20R.%22%2C%22lastName%22%3A%22David%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Robert%22%2C%22lastName%22%3A%22Regis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerie%20A.%22%2C%22lastName%22%3A%22Geoffroy%22%7D%5D%2C%22abstractNote%22%3A%22The%20use%20of%20asbestos-containing%20products%20has%20been%20banned%20in%20many%20countries%20since%20the%20beginning%20of%20the%2080%27s%20due%20to%20its%20carcinogenic%20properties.%20However%2C%20asbestos%20is%20widely%20present%20in%20private%20and%20public%20buildings%2C%20resulting%20in%20the%20need%20to%20process%20a%20vast%20amount%20of%20asbestos-containing%20waste.%20Among%20the%20current%20technologies%20for%20the%20destruction%20of%20asbestos%20fibers%2C%20biodegradation%20by%20fungi%2C%20lichens%2C%20and%2C%20more%20recently%2C%20bacteria%20has%20been%20described.%20We%20previously%20reported%20the%20involvement%20of%20the%20bacterial%20siderophore%20pyoverdine%20in%20the%20release%20of%20iron%20from%20the%20two%20asbestos%20groups%2C%20serpentines%20and%20amphiboles.%20Among%20the%20large%20diversity%20encountered%20in%20the%20pyoverdine%20family%2C%20we%20examined%20whether%20these%20siderophores%20can%20alter%20flocking%20asbestos%20waste%20as%20well.%20All%20the%20tested%20pyoverdines%20were%20efficient%20in%20chrysotile-gypsum%20and%20amosite-gypsum%20weathering%2C%20although%20some%20exhibited%20higher%20iron%20dissolution.%20Iron%20was%20solubilized%20by%20pyoverdines%20from%20Pseudomonas%20aeruginosa%20and%20mandelii%20in%20a%20time-dependent%20manner%20from%20chrysotile-gypsum%20within%2024%20h.%20Renewal%20of%20pyoverdine-containing%20supernatant%20every%2024%20or%2096%20h%20allowed%20iron%20removal%20from%20chrysotile-gypsum%20at%20each%20cycle%2C%20until%20a%20limit%20was%20reached%20after%2042%20days%20of%20total%20incubation.%20Moreover%2C%20the%20dissolution%20was%20concentration-dependent%2C%20as%20demonstrated%20for%20the%20pyoverdine%20of%20P.%20mandelii.%20Pyoverdine-asbestos%20weathering%20could%20therefore%20become%20an%20innovative%20method%20to%20reduce%20anthropogenic%20waste.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jhazmat.2020.122532%22%2C%22ISSN%22%3A%220304-3894%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jhazmat.2020.122532%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222021-02-10T16%3A16%3A06Z%22%7D%7D%5D%7D
[1]
T. Achard, L. Egger, C. Tortoreto, L. Guénée, J. Lacour, Preparation and Structural Characterization of [CpRu(1,10-phenanthroline)(CH3CN)][X] and Precursor Complexes (X=PF6, BArF, TRISPHAT-N), Helvetica Chimica Acta 103 (2020) e2000190. https://doi.org/https://doi.org/10.1002/hlca.202000190.
[1]
L. Aggar, D. Bradai, Y.I. Bourezg, M. Abdesselam, A.C. Chami, C. Mocuta, D. Thiaudiere, C. Speisser, D. Muller, C. Bouillet, F. Le Normand, GaN nanocrystals obtained by Ga and N implantations and thermal treatment under N-2 into SiO2/Si and SiNx/Si wafers, Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms 485 (2020) 57–67. https://doi.org/10.1016/j.nimb.2020.10.012.
[1]
A.-A. Andelescu, B. Heinrich, M.A. Spirache, E. Voirin, M. La Deda, G. Di Maio, E.I. Szerb, B. Donnio, O. Costisor, Playing with Pt-II and Zn-II Coordination to Obtain Luminescent Metallomesogens, Chemistry-a European Journal 26 (2020) 4850–4860. https://doi.org/10.1002/chem.202000124.
[1]
I. Anefnaf, S. Aazou, G. Schmerber, S. Refki, N. Zimmermann, T. Heiser, G. Ferblantier, A. Slaoui, A. Dinia, M. Abd-Lefdil, Z. Sekkat, Polyethylenimine-Ethoxylated Interfacial Layer for Efficient Electron Collection in SnO2-Based Inverted Organic Solar Cells, Crystals 10 (2020). https://doi.org/10.3390/cryst10090731.
[1]
I. Anefnaf, S. Aazou, G. Schmerber, A. Dinia, Z. Sekkat, Study the effect of fullerene derivatives ratio on P3HT-based inverted organic solar cells, in: Z.H. Kafafi, P.A. Lane, K. Lee, H.W. Ade, Y.-L. (Lynn) Loo (Eds.), Organic, Hybrid, and Perovskite Photovoltaics XXI, SPIE, 2020: pp. 57–66. https://doi.org/10.1117/12.2568790.
[1]
G. Avedissian, J. Arabski, J.A. Wytko, J. Weiss, C. Mény, Probing the Growth of Organic Molecular Films Embedded between Cobalt and Iron Electrodes: Ferromagnetic Nuclear Resonance Approach, Advanced Functional Materials 2005605 (2020) 1–6. https://doi.org/10.1002/adfm.202005605.
[1]
G. Avedissian, J. Arabski, J.A. Wytko, J. Weiss, C. Mény, Revealing the morphology and the magnetic properties of single buried cobalt-ZnTPP hybrid interfaces by ferromagnetic nuclear resonance spectroscopy, Physical Review B 102 (2020) 184114. https://doi.org/10.1103/PhysRevB.102.184114.
[1]
W. Baaziz, S. Valette, A.-S. Gay, C. Hirlimann, O. Ersen, A New Methodology for Quantifying the Surface Crystallography of Particles from their Tomographic Reconstruction: Application to Pd Nanoparticles Embedded in a Mesoporous Silica Shell, ChemCatChem 12 (2020) 1–10. https://doi.org/10.1002/cctc.202000275.
[1]
N. Bachellier, B. Verlhac, L. Garnier, J. Zaldivar, C. Rubio-Verdu, P. Abufager, M. Ormaza, D.-J. Choi, M.-L. Bocquet, J. Pascual I., N. Lorente, L. Limot, Vibron-assisted spin excitation in a magnetically anisotropic molecule, Nature Communications 11 (2020) 1619. https://doi.org/10.1038/s41467-020-15266-0.
[1]
A. Balfourier, N. Luciani, G. Wang, G. Lelong, O. Ersen, A. Khelfa, D. Alloyeau, F. Gazeau, F. Carn, Unexpected intracellular biodegradation and recrystallization of gold nanoparticles, Proceedings of the National Academy of Sciences of the United States of America 117 (2020) 103–113. https://doi.org/10.1073/pnas.1911734116.
[1]
F. Banhart, Elemental carbon in the sp(1) hybridization, ChemTexts 6 (2020). https://doi.org/10.1007/s40828-019-0098-z.
[1]
A. Barsella, M.A. Hurier, M.D. Pichois, M. Vomir, H. Hasan, L. Mager, B. Donnio, J.-L. Gallani, M.V. Rastei, Photonic Excitation of a Micromechanical Cantilever in Electrostatic Fields, Physical Review Letters 125 (2020) 254301. https://doi.org/10.1103/PhysRevLett.125.254301.
[1]
A.T.F. Batista, W. Baaziz, A.-L. Taleb, J. Chaniot, M. Moreaud, C. Legens, A. Aguilar-Tapia, O. Proux, J.-L. Hazemann, F. Diehl, C. Chizallet, A.-S. Gay, O. Ersen, P. Raybaud, Atomic Scale Insight into the Formation, Size, and Location of Platinum Nanoparticles Supported on gamma-Alumina, ACS Catalysis 10 (2020) 4193–4204. https://doi.org/10.1021/acscatal.0c00042.
[1]
F. Beaubras, J.-M. Rueff, O. Perez, F. Veillon, V. Caignaert, J.-F. Lohier, J. Cardin, G. Rogez, C. Jestin, H. Couthon, P.-A. Jaffres, M(H2O)(PO3C10H6OH)center dot(H2O)(0.5) (M = Co, Mn, Zn, Cu): a new series of layered metallophosphonate compounds obtained from 6-hydroxy-2-naphthylphosphonic acid, Dalton Transactions 49 (2020) 3877–3891. https://doi.org/10.1039/c9dt03947c.
[1]
S. Bellemin-Laponnaz, N-Heterocyclic Carbene Platinum Complexes: A Big Step Forward for Effective Antitumor Compounds, European Journal of Inorganic Chemistry 2020 (2020) 10–20. https://doi.org/10.1002/ejic.201900960.
[1]
M. Benaissa, R. El Bouayadi, D. Ihiawakrim, O. Ersen, Ideality factor and barrier height for a GaN nanomembrane electrically contacted with a tungsten nano-tip in a TEM, Journal of Applied Physics 127 (2020) 075109. https://doi.org/10.1063/1.5128868.
[1]
S. Berciaud, M. Potemski, C. Faugeras, Many-Body Effects in Suspended Graphene Probed through Magneto-Phonon Resonances, Physica Status Solidi-Rapid Research Letters (2020) 2000345. https://doi.org/10.1002/pssr.202000345.
[1]
N. Bergeard, M. Hehn, K. Carva, P. Balaz, S. Mangin, G. Malinowski, Tailoring femtosecond hot-electron pulses for ultrafast spin manipulation, Applied Physics Letters 117 (2020) 222408. https://doi.org/10.1063/5.0018502.
[1]
Y. Berro, S. Gueddida, Y. Bouizi, C. Bellouard, E.-E. Bendeif, A. Gansmuller, A. Celzard, V. Fierro, D. Ihiawakrim, O. Ersen, M. Kassir, F.E.H. Hassan, S. Lebegue, M. Badawi, N. Canilho, A. Pasc, Imprinting isolated single iron atoms onto mesoporous silica by templating with metallosurfactants, Journal of Colloid and Interface Science 573 (2020) 193–203. https://doi.org/10.1016/j.jcis.2020.03.095.
[1]
M.M. Besli, C. Usubelli, M. Metzger, V. Pande, K. Harry, D. Nordlund, S. Sainio, J. Christensen, M.M. Doeff, S. Kuppan, Effect of Liquid Electrolyte Soaking on the Interfacial Resistance of Li7La3Zr2O12 for All-Solid-State Lithium Batteries, ACS Applied Materials & Interfaces 12 (2020) 20605–20612. https://doi.org/10.1021/acsami.0c06194.
[1]
M. Biesuz, E. Zera, M. Tomasi, P. Jana, O. Ersen, W. Baaziz, A. Lindemann, G.D. Soraru, Polymer-derived Si3N4 nanofelts for flexible, high temperature, lightweight and easy-manufacturable super-thermal insulators, Applied Materials Today 20 (2020) 100648. https://doi.org/10.1016/j.apmt.2020.100648.
[1]
C. Bigi, S.K. Chaluvadi, A. Galdi, L. Maritato, C. Aruta, R. Ciancio, J. Fujii, B. Gobaut, P. Torelli, I. Vobornik, G. Panaccione, G. Rossi, P. Orgiani, Predominance of z(2)-orbitals at the surface of both hole- and electron-doped manganites, Journal of Electron Spectroscopy and Related Phenomena 245 (2020) 147016. https://doi.org/10.1016/j.elspec.2020.147016.
[1]
A. Bonfiglio, M. Mauro, PhosphorescentTris-Bidentate Ir(III)Complexes with N-Heterocyclic Carbene Scaffolds: Structural Diversity and Optical Properties, European Journal of Inorganic Chemistry (2020) 3427–3442. https://doi.org/10.1002/ejic.202000509.
[1]
A. Bonfiglio, L. Pallova, V. Cesar, C. Gourlaouen, S. Bellemin-Laponnaz, C. Daniel, F. Polo, M. Mauro, Phosphorescent Cationic Heterodinuclear Ir-III/M(I)Complexes (M=Cu-I, Au-I) with a Hybrid Janus-Type N-Heterocyclic Carbene Bridge, Chemistry-a European Journal 26 (2020) 1–17. https://doi.org/10.1002/chem.202002767.
[1]
A. Bonfiglio, K. Magra, C. Cebrian, F. Polo, P.C. Gros, P. Mercandelli, M. Mauro, Red-emitting neutral rhenium(I) complexes bearing a pyridyl pyridoannelated N-heterocyclic carbene, Dalton Transactions 49 (2020) 3102–3111. https://doi.org/10.1039/c9dt04890a.
[1]
T. Botzung, D. Hagenmueller, S. Schutz, J. Dubail, G. Pupillo, J. Schachenmayer, Dark state semilocalization of quantum emitters in a cavity, Physical Review B 102 (2020) 144202. https://doi.org/10.1103/PhysRevB.102.144202.
[1]
M. Bouche, B. Vincent, T. Achard, S. Bellemin-Laponnaz, N-Heterocyclic Carbene Platinum(IV) as Metallodrug Candidates: Synthesis and(195)Pt NMR Chemical Shift Trend, Molecules 25 (2020) 3148. https://doi.org/10.3390/molecules25143148.
[1]
A. Boussadia, A. Beghidja, L. Gali, C. Beghidja, M. Elhabiri, P. Rabu, G. Rogez, Coordination properties of two new Schiff-base phenoxy-carboxylates and comparative study of their antioxidant activities, Inorganica Chimica Acta 508 (2020). https://doi.org/10.1016/j.ica.2020.119656.
[1]
B. Brachnakova, S. Matejova, J. Moncol, R. Herchel, J. Pavlik, E. Moreno-Pineda, M. Ruben, I. Salitros, Stereochemistry of coordination polyhedra vs. single ion magnetism in penta- and hexacoordinated Co(II) complexes with tridentate rigid ligands, Dalton Transactions 49 (2020) 1249–1264. https://doi.org/10.1039/c9dt04592a.
[1]
T. Brandl, S. Johannsen, D. Haussinger, N. Suryadevara, A. Prescimone, S. Bernhard, M. Gruber, M. Ruben, R. Berndt, M. Mayor, Iron in a Cage: Fixation of a Fe(II)tpy(2)Complex by Fourfold Interlinking, Angewandte Chemie-International Edition 59 (2020) 1–7. https://doi.org/10.1002/anie.202006340.
[1]
K.M. Bui, M. Boero, K. Shiraishi, A. Oshiyama, A two-dimensional liquid-like phase on Ga-rich GaN (0001) surfaces evidenced by first principles molecular dynamics, in: Japanese Journal of Applied Physics, 2020: p. SGGK04. https://doi.org/10.7567/1347-4065/ab650b.
[1]
C. Burel, A. Teolis, A. Alsayed, C.B. Murray, B. Donnio, R. Dreyfus, Plasmonic Elastic Capsules as Colorimetric Reversible pH-Microsensors, Small 16 (2020) 1903897. https://doi.org/10.1002/smll.201903897.
[1]
F. Califano, G. Manfredi, F. Valentini, Special Issue: The many facets of the Vlasov equation, Journal of Plasma Physics 86 (2020). https://doi.org/10.1017/S0022377820000811.
[1]
M.-A. Carvalho, H. Dekkiche, S. Richeter, C. Bailly, L. Karmazin, D. McKearney, D.B. Leznoff, G. Rogez, B. Vileno, S. Choua, R. Ruppert, Antiferromagnetic coupling in copper(II)porphyrin dimers linked by copper(II) or palladium(II) ion, Journal of Porphyrins and Phthalocyanines 24 (2020) 238–246. https://doi.org/10.1142/S1088424619501037.
[1]
E. Charignon, M. Bouche, C. Clave-Darcissac, G. Dahm, G. Ichim, A. Clotagatide, H.C. Mertani, P. Telouk, J. Caramel, J.-J. Diaz, S. Bellemin-Laponnaz, P. Bouvet, C. Billotey, In Cellulo Evaluation of the Therapeutic Potential of NHC Platinum Compounds in Metastatic Cutaneous Melanoma, International Journal of Molecular Sciences 21 (2020) 7626. https://doi.org/10.3390/ijms21217826.
[1]
X. Chen, M. Boero, O. Lopez-Acevedo, Atomic structure and origin of chirality of DNA-stabilized silver clusters, Physical Review Materials 4 (2020) 065601. https://doi.org/10.1103/PhysRevMaterials.4.065601.
[1]
W. Chen, J. Egly, A. Pobtador-Bahamonde I., A. Maisse-Francois, S. Bellemin-Laponnaz, T. Achard, Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (kappa 2-C,S)-thioether-functionalised NHC ligands, Dalton Transactions 49 (2020) 3243–3252. https://doi.org/10.1039/c9dt04825a.
[1]
A. Cidrim, T.S. do Espirito Santo, J. Schachenmayer, R. Kaiser, R. Bachelard, Photon Blockade with Ground-State Neutral Atoms, Physical Review Letters 125 (2020) 073601. https://doi.org/10.1103/PhysRevLett.125.073601.
[1]
P.S. Costa, G. Hao, A.T. N’Diaye, L. Routaboul, P. Braunstein, X. Zhang, J. Zhang, T.K. Ekanayaka, Q.-Y. Shi, V. Schlegel, B. Doudin, A. Enders, P.A. Dowben, Manipulation of the molecular spin crossover transition of Fe(H2B(pz)2)2(bipy) by addition of polar molecules, Journal of Physics: Condensed Matter 32 (2020) 034001. https://doi.org/10.1088/1361-648x/ab468c.
[1]
G. Cotin, F. Perton, C. Petit, S. Sall, C. Kiefer, V. Begin, B. Pichon, C. Lefèvre, D. Mertz, J.-M. Greneche, S. Bégin-Colin, Harnessing Composition of Iron Oxide Nanoparticle: Impact of Solvent-Mediated Ligand-Ligand Interaction and Competition between Oxidation and Growth Kinetics, Chemistry of Materials 32 (2020) 9245–9259. https://doi.org/10.1021/acs.chemmater.0c03041.
[1]
N. Couzon, L. Bois, C. Fellah, C. Loestean, F. Chassagneux, R. Chiriac, F. Toche, L. Khrouz, A. Brioude, O. Ersen, L. Roiban, Manganese oxidation states repartition in a channel-like mesoporous zirconium oxide, Journal of Porous Materials 27 (2020) 1823–1835. https://doi.org/10.1007/s10934-020-00962-5.
[1]
A.D. Craciun, B. Donnio, J.-L. Gallani, M.V. Rastei, High-resolution manipulation of gold nanorods with an atomic force microscope, Nanotechnology 31 (2020) 085302. https://doi.org/10.1088/1361-6528/ab5404.
[1]
J. Cypriano, M. Bahri, K. Dembele, W. Baaziz, P. Leao, D.A. Bazylinski, F. Abreu, O. Ersen, M. Farina, J. Werckmann, Insight on thermal stability of magnetite magnetosomes: implications for the fossil record and biotechnology, Scientific Reports 10 (2020) 6706. https://doi.org/10.1038/s41598-020-63531-5.
[1]
J. Dai, K.-Q. Zhao, B.-Q. Wang, P. Hu, B. Heinrich, B. Donnio, Liquid crystal ionic self-assembly and anion-selective photoluminescence in discotic azatriphenylenes, Journal of Materials Chemistry C 8 (2020) 4215–4225. https://doi.org/10.1039/c9tc05829j.
[1]
O. Daoura, G. El Chawich, M. Boutros, N. El Hassan, P. Massiani, O. Ersen, W. Baaziz, F. Launay, Aqueous nickel(II) hydroxycarbonate instead of nickel(0) colloids as precursors of stable Ni-silica based catalysts for the dry reforming of methane, Catalysis Communications 138 (2020) 105953. https://doi.org/10.1016/j.catcom.2020.105953.
[1]
M. Darari, A. Frances-Monerris, B. Marekha, A. Doudouh, E. Wenger, A. Monari, S. Haacke, P.C. Gros, Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties, Molecules 25 (2020) 5991. https://doi.org/10.3390/molecules25245991.
[1]
M. Darcheville, A.-L. Adenot-Engelvin, C. Boscher, N. Vukadinovic, C. Lefèvre, A. Thiaville, C. Sanchez, Evidence of the Superparamagnetic State in the Zero-Field Microwave Susceptibility Spectra of Ferrimagnetic Nanoparticles, IEEE Magnetics Letters 11 (2020) 6105305. https://doi.org/10.1109/LMAG.2020.3026228.
[1]
S.R. David, S. Fritsch, A. Forster, D. Ihiawakrim, V.A. Geoffroy, Flocking asbestos waste, an iron and magnesium source for Pseudomonas, Science of the Total Environment 709 (2020) 135936. https://doi.org/10.1016/j.scitotenv.2019.135936.
[1]
S.R. David, D. Ihiawakrim, R. Regis, V.A. Geoffroy, Efficiency of pyoverdines in iron removal from flocking asbestos waste: An innovative bacterial bioremediation strategy, Journal of Hazardous Materials 394 (2020) 122532. https://doi.org/10.1016/j.jhazmat.2020.122532.