1839302
2024
items
1
surface-science-reports
0
author
asc
22030
https://www.ipcms.fr/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-57fa99c169a345c9736f67d4e1670db5%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%22VW7M8944%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Adinov%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Adinov%2C%20O.%20Kovalenko%2C%20J.-L.%20Rehspringer%2C%20L.%20Mager%2C%20Functionalization%20of%20micro-size%20garnet%20at%20the%20end%20of%20optical%20fiber%20for%20magneto-optical%20applications%2C%20Optics%20Express%2032%20%282024%29%207651%26%23x2013%3B7658.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1364%5C%2FOE.503864%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1364%5C%2FOE.503864%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Functionalization%20of%20micro-size%20garnet%20at%20the%20end%20of%20optical%20fiber%20for%20magneto-optical%20applications%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Issatay%22%2C%22lastName%22%3A%22Adinov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Oleksandr%22%2C%22lastName%22%3A%22Kovalenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Luc%22%2C%22lastName%22%3A%22Rehspringer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Loic%22%2C%22lastName%22%3A%22Mager%22%7D%5D%2C%22abstractNote%22%3A%22We%20utilized%20a%20metal%20propionate%20solution%20to%20prepare%20polycrystalline%20bismuth%20-substituted%20yttrium%20iron%20garnets%20through%20the%20metal%20-organic%20decomposition%20process.%20After%20conducting%20thorough%20optimization%2C%20we%20successfully%20synthesized%20a%20garnet%20that%20exhibited%20a%20high%20magneto%20-optic%20response%20directly%20at%20the%20end%20of%20an%20optical%20fiber.%20A%20notable%20achievement%20of%20our%20work%20lies%20in%20the%20ability%20to%20restrict%20the%20size%20and%20position%20of%20the%20garnet%20to%20match%20the%20dimensions%20of%20the%20fiber%27s%20core.%20The%20functionalized%20fiber%20was%20integrated%20into%20a%20magneto%20-optical%20sensor%20setup%2C%20offering%20the%20flexibility%20to%20operate%20either%20in%20the%20Faraday%20rotation%20or%20magnetic%20circular%20dichroism%20mode.%20%28c%29%202024%20Optica%20Publishing%20Group%20under%20the%20terms%20of%20the%20Optica%20Open%20Access%20Publishing%20Agreement%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1364%5C%2FOE.503864%22%2C%22ISSN%22%3A%221094-4087%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1364%5C%2FOE.503864%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22WWGPR7DV%22%2C%22CF4ZI7HM%22%2C%22UBUT97QT%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A07%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22RW8YA6GU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Andoche%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Andoche%2C%20L.%20Mouawad%2C%20P.-A.%20Hervieux%2C%20X.%20Mougeot%2C%20J.%20Machado%2C%20J.P.%20Santos%2C%20Influence%20of%20atomic%20modeling%20on%20electron%20capture%20and%20shaking%20processes%2C%20Physical%20Review%20A%20109%20%282024%29%20032826.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevA.109.032826%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevA.109.032826%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Influence%20of%20atomic%20modeling%20on%20electron%20capture%20and%20shaking%20processes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adrien%22%2C%22lastName%22%3A%22Andoche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Mouawad%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22X.%22%2C%22lastName%22%3A%22Mougeot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Machado%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20P.%22%2C%22lastName%22%3A%22Santos%22%7D%5D%2C%22abstractNote%22%3A%22Ongoing%20experimental%20efforts%20to%20measure%20with%20unprecedented%20precision%20electron%20-capture%20probabilities%20challenge%20the%20current%20theoretical%20models.%20The%20short%20range%20of%20the%20weak%20interaction%20necessitates%20an%20accurate%20description%20of%20the%20atomic%20structure%20down%20to%20the%20nucleus%20region.%20A%20recent%20electron%20-capture%20modeling%20has%20been%20modified%20in%20order%20to%20test%20the%20influence%20of%20three%20different%20atomic%20descriptions%20on%20the%20decay%20and%20shaking%20probabilities.%20To%20this%20end%2C%20a%20specific%20atomic%20modeling%20was%20developed%20in%20the%20framework%20of%20the%20relativistic%20density%20-functional%20theory%2C%20exploring%20several%20exchange%20-correlation%20functionals%20and%20self%20-interaction%20-corrected%20models.%20It%20was%20found%20that%20the%20probabilities%20of%20total%20shaking%2C%20tested%20on%20both%20photoionization%20and%20electron%20-capture%20processes%2C%20depend%20strongly%20on%20the%20accuracy%20of%20the%20atomic%20modeling.%20Predictions%20of%20capture%20probabilities%20have%20been%20compared%20with%20experimental%20values%20evaluated%20from%20available%20published%20data%20for%20different%20radionuclides%20from%207Be%20to%20138La.%20New%20high%20-precision%20measurements%20are%20strongly%20encouraged%20because%20the%20accuracy%20of%20the%20current%20experimental%20values%20is%20insufficient%20to%20test%20the%20models%20beyond%20the%20inner%20shells.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevA.109.032826%22%2C%22ISSN%22%3A%222469-9926%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevA.109.032826%22%2C%22collections%22%3A%5B%2288PVNMDA%22%2C%22CHW2VGSR%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A02%3A06Z%22%7D%7D%2C%7B%22key%22%3A%22Q7UJE9M6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Barbosa%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Barbosa%2C%20O.%20Urquidi%2C%20J.%20Brazard%2C%20T.B.M.%20Adachi%2C%20In%20situ%5C%2FIn%20vivo%20Optical%20Microspectroscopy%20to%20Probe%20the%20Emergence%20of%20Morphology%2C%20Chimia%2078%20%282024%29%2050%26%23x2013%3B58.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.2533%5C%2Fchimia.2024.50%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.2533%5C%2Fchimia.2024.50%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22In%20situ%5C%2FIn%20vivo%20Optical%20Microspectroscopy%20to%20Probe%20the%20Emergence%20of%20Morphology%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Natercia%22%2C%22lastName%22%3A%22Barbosa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Oscar%22%2C%22lastName%22%3A%22Urquidi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Brazard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takuji%20B.%20M.%22%2C%22lastName%22%3A%22Adachi%22%7D%5D%2C%22abstractNote%22%3A%22Morphology%20governs%20function.%20Yet%2C%20understanding%20and%20controlling%20the%20emergence%20of%20morphology%20at%20the%20molecular%20level%20remains%20challenging.%20The%20difficulty%20in%20studying%20the%20early%20stage%20of%20morphology%20formation%20is%20due%20to%20its%20stochastic%20nature%20both%20spatially%20and%20temporally%20occurring%20at%20the%20nanoscale.%20This%20nature%20has%20been%20particularly%20detrimental%20for%20the%20application%20of%20optical%20spectroscopy.%20To%20overcome%20this%20problem%2C%20we%20have%20been%20developing%20new%20in%20situ%5C%2Fin%20vivo%20optical%20spectroscopy%20tools%2C%20which%20are%20label%20-free%20and%20non-invasive.%20This%20account%20highlights%20several%20examples%20of%20how%20optical%20spectroscopy%20can%20become%20an%20important%20tool%20in%20studying%20the%20birth%20of%20morphology.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.2533%5C%2Fchimia.2024.50%22%2C%22ISSN%22%3A%220009-4293%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.2533%5C%2Fchimia.2024.50%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A08%3A54Z%22%7D%7D%2C%7B%22key%22%3A%22ADNYDDQV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bel-Hadj%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Bel-Hadj%2C%20M.%20Guerboub%2C%20A.%20Lambrecht%2C%20G.%20Ori%2C%20C.%20Massobrio%2C%20E.%20Martin%2C%20Thermal%20conductivity%20of%20crystalline%20Ge2Sb2Te5%3A%20lattice%20contribution%20and%20size%20effects%20in%20the%20cubic%20phase%20quantified%20by%20approach-to-equilibrium%20molecular%20dynamics%2C%20Journal%20of%20Physics%20D-Applied%20Physics%2057%20%282024%29%20235303.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fad316b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fad316b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Thermal%20conductivity%20of%20crystalline%20Ge2Sb2Te5%3A%20lattice%20contribution%20and%20size%20effects%20in%20the%20cubic%20phase%20quantified%20by%20approach-to-equilibrium%20molecular%20dynamics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ibrahim%22%2C%22lastName%22%3A%22Bel-Hadj%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohammed%22%2C%22lastName%22%3A%22Guerboub%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Achille%22%2C%22lastName%22%3A%22Lambrecht%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guido%22%2C%22lastName%22%3A%22Ori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Carlo%22%2C%22lastName%22%3A%22Massobrio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Evelyne%22%2C%22lastName%22%3A%22Martin%22%7D%5D%2C%22abstractNote%22%3A%22Approach-to-equilibrium%20molecular%20dynamics%20simulations%20are%20carried%20out%20for%20the%20cubic%20phase%20of%20crystalline%20Ge2Sb2Te5%2C%20using%20interatomic%20forces%20derived%20from%20a%20machine%20learning%20interatomic%20potential%20%28MLIP%29%20trained%20with%20ab%20initio%20calculations.%20The%20use%20of%20this%20MLIP%20potential%20significantly%20reduces%20the%20computational%20burden%2C%20allowing%20for%20the%20study%20of%20systems%20over%2070%20nm%20in%20length.%20Above%2020%20nm%2C%20the%20thermal%20conductivity%20of%20the%20lattice%20plateaus%20at%200.37%20%2B%5C%2F-%200.01%20W%20K-1%20m%28-1%29%20in%20agreement%20with%20measurements%20reported%20in%20the%20literature.%20However%2C%20below%2020%20nm%2C%20size%20effects%20lead%20to%20a%20reduction%20in%20thermal%20conductivity%20which%20is%20systematically%20calculated.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1088%5C%2F1361-6463%5C%2Fad316b%22%2C%22ISSN%22%3A%220022-3727%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1088%5C%2F1361-6463%5C%2Fad316b%22%2C%22collections%22%3A%5B%22NZSFH59F%22%2C%22CF4ZI7HM%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A11%3A26Z%22%7D%7D%2C%7B%22key%22%3A%223VKLK6U7%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Belotcerkovtceva%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ED.%20Belotcerkovtceva%2C%20H.%20Nameirakpam%2C%20G.%20Datt%2C%20U.%20Noumbe%2C%20M.V.%20Kamalakar%2C%20High%20current%20treated-passivated%20graphene%20%28CTPG%29%20towards%20stable%20nanoelectronic%20and%20spintronic%20circuits%2C%20Nanoscale%20Horizons%209%20%282024%29%20456%26%23x2013%3B464.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd3nh00338h%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd3nh00338h%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22High%20current%20treated-passivated%20graphene%20%28CTPG%29%20towards%20stable%20nanoelectronic%20and%20spintronic%20circuits%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daria%22%2C%22lastName%22%3A%22Belotcerkovtceva%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Henry%22%2C%22lastName%22%3A%22Nameirakpam%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gopal%22%2C%22lastName%22%3A%22Datt%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ulrich%22%2C%22lastName%22%3A%22Noumbe%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%20Venkata%22%2C%22lastName%22%3A%22Kamalakar%22%7D%5D%2C%22abstractNote%22%3A%22Achieving%20enhanced%20and%20stable%20electrical%20quality%20of%20scalable%20graphene%20is%20crucial%20for%20practical%20graphene%20device%20applications.%20Accordingly%2C%20encapsulation%20has%20emerged%20as%20an%20approach%20for%20improving%20electrical%20transport%20in%20graphene.%20In%20this%20study%2C%20we%20demonstrate%20high-current%20treatment%20of%20graphene%20passivated%20by%20AlOx%20nanofilms%20as%20a%20new%20means%20to%20enhance%20the%20electrical%20quality%20of%20graphene%20for%20its%20scalable%20utilization.%20Our%20experiments%20and%20electrical%20measurements%20on%20large-scale%20chemical%20vapor-deposited%20%28CVD%29%20graphene%20devices%20reveal%20that%20high-current%20treatment%20causes%20persistent%20and%20irreversible%20de-trapping%20density%20in%20both%20bare%20graphene%20and%20graphene%20covered%20by%20AlOx.%20Strikingly%2C%20despite%20possible%20interfacial%20defects%20in%20graphene%20covered%20with%20AlOx%2C%20the%20high-current%20treatment%20enhances%20its%20carrier%20mobility%20by%20up%20to%20200%25%20in%20contrast%20to%20bare%20graphene%20samples%2C%20where%20mobility%20decreases.%20Spatially%20resolved%20Raman%20spectroscopy%20mapping%20confirms%20that%20surface%20passivation%20by%20AlOx%2C%20followed%20by%20the%20current%20treatment%2C%20reduces%20the%20number%20of%20sp3%20defects%20in%20graphene.%20These%20results%20suggest%20that%20for%20current%20treated-passivated%20graphene%20%28CTPG%29%2C%20the%20high-current%20treatment%20considerably%20reduces%20charged%20impurity%20and%20trapped%20charge%20densities%2C%20thereby%20reducing%20Coulomb%20scattering%20while%20mitigating%20any%20electromigration%20of%20carbon%20atoms.%20Our%20study%20unveils%20CTPG%20as%20an%20innovative%20system%20for%20practical%20utilization%20in%20graphene%20nanoelectronic%20and%20spintronic%20integrated%20circuits.High%20current-treated%20AlOx%20passivated-graphene%20%28CTPG%29%20with%20enhanced%20carrier%20mobility%20offers%20promise%20for%20stability%20and%20scalability%20in%20graphene%20nanoelectronic%20and%20spintronic%20devices.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd3nh00338h%22%2C%22ISSN%22%3A%222055-6756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd3nh00338h%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22N8397DCZ%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A04Z%22%7D%7D%2C%7B%22key%22%3A%222AMRBARG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bernardez%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.J.V.%20Bernardez%2C%20N.%20Vukadinovic%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Stoeffler%2C%20Tuning%20Dynamic%20Susceptibility%20in%20Barium%20Hexaferrite%20Core-Shell%20Nanoparticles%20through%20Size-Dependent%20Resonance%20Modes%2C%20ACS%20Applied%20Electronic%20Materials%20Early%20access%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.4c00096%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.4c00096%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tuning%20Dynamic%20Susceptibility%20in%20Barium%20Hexaferrite%20Core-Shell%20Nanoparticles%20through%20Size-Dependent%20Resonance%20Modes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Jose%20Vazquez%22%2C%22lastName%22%3A%22Bernardez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Vukadinovic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chistophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Stoeffler%22%7D%5D%2C%22abstractNote%22%3A%22M-type%20hexagonal%20ferrites%20present%20compelling%20prospects%20for%20the%20design%20of%20high-performance%20multifunctional%20absorbers%20operating%20within%20the%20Ku%2C%20K%2C%20and%20Ka%20frequency%20ranges%2C%20spanning%2012%20to%2040%20GHz%20at%20a%20zero-applied%20magnetic%20field.%20While%20it%20is%20widely%20acknowledged%20that%20the%20operational%20frequency%20of%20this%20compound%20can%20be%20manipulated%20through%20chemical%20substitution%2C%20the%20ongoing%20challenge%20lies%20in%20achieving%20precise%20control%20over%20the%20absorption%20bandwidth%20via%20the%20spectral%20line%20width%20of%20its%20dynamic%20susceptibility.%20For%20this%20purpose%2C%20we%20investigate%20by%20means%20of%20micromagnetic%20simulations%20core-shell%20nanoparticles%20with%20an%20M-type%20hexagonal%20ferrite%20shell%20grown%20on%20top%20of%20a%20nonmagnetic%20core.%20This%20configuration%20allows%20the%20modulation%20of%20the%20number%20and%20the%20frequency%20of%20the%20resonance%20modes%20only%20by%20controlling%20the%20thickness%20and%20the%20size%20of%20the%20ferrite%20magnetic%20shell.%20This%20phenomenon%20is%20produced%20at%20microwave%20frequencies%20for%20relatively%20large%20particles%20%28external%20diameter%20from%20150%20to%20500%20nm%29%20and%20produces%20supplementary%20resonance%20peaks%20at%20amplitudes%20comparable%20to%20the%20main%20ferromagnetic%20mode%20of%20a%20solid%20sphere.%20The%20study%20of%20the%20magnetization%20dynamics%20of%20these%20size-dependent%20modes%20confirmed%20their%20nature%20as%20essentially%20exchange%20resonance%20modes.%20The%20limitations%20of%20available%20analytical%20models%20for%20describing%20the%20behavior%20of%20such%20modes%20in%20hollow%20spheres%20are%20highlighted.%20As%20for%20most%20commercial%20applications%2C%20these%20properties%20are%20present%20at%20a%20zero-applied%20magnetic%20field%2C%20and%20the%20simulations%20performed%20evidence%20that%20the%20system%20is%20resistant%20to%20experimental%20deviations.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsaelm.4c00096%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsaelm.4c00096%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%222A2F8AAB%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A07%3A40Z%22%7D%7D%2C%7B%22key%22%3A%22JQXRJ366%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bizeau%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Bizeau%2C%20M.%20Rabineau%2C%20J.%20Buisson%2C%20T.%20Lucante%2C%20C.%20Leuvrey%2C%20K.%20Parkhomenko%2C%20P.%20Lavalle%2C%20D.%20Mertz%2C%20Powerful%20Protein%20Nanoreservoirs%20Based%20on%20Stellate%20Mesoporous%20Silica%20Embedded%20in%20Composite%20Hydrogels%3A%20From%20Burst%20Release%20to%20Retention%2C%20Macromolecular%20Chemistry%20and%20Physics%20%282024%29%202400035.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fmacp.202400035%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fmacp.202400035%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Powerful%20Protein%20Nanoreservoirs%20Based%20on%20Stellate%20Mesoporous%20Silica%20Embedded%20in%20Composite%20Hydrogels%3A%20From%20Burst%20Release%20to%20Retention%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joelle%22%2C%22lastName%22%3A%22Bizeau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Morgane%22%2C%22lastName%22%3A%22Rabineau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julie%22%2C%22lastName%22%3A%22Buisson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Theo%22%2C%22lastName%22%3A%22Lucante%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ksenia%22%2C%22lastName%22%3A%22Parkhomenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Lavalle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Mertz%22%7D%5D%2C%22abstractNote%22%3A%22In%20the%20biomaterials%20field%2C%20one%20major%20issue%20with%20hydrogels%20%28HGs%29%20loaded%20with%20active%20therapeutics%20is%20the%20spontaneous%20leaking%20of%20the%20cargo%20occurring%20rapidly%2C%20usually%20over%20several%20hours.%20However%2C%20biological%20processes%20involved%20in%20regenerative%20medicine%20would%20require%20to%20have%20a%20sustained%20drug%20delivery%20lasting%20over%20weeks%5C%2Fmonths%20or%20be%20triggered%20only%20when%20a%20specific%20biochemical%20stimulus%20%28enzymatic%2C%20cellular%2C%20or%20antimicrobial%29%20is%20applied.%20In%20this%20work%2C%20this%20challenge%20is%20addressed%20by%20demonstrating%20that%20the%20spontaneous%20protein%20release%20from%20an%20agarose%20HG%20%28used%20as%20model%20HG%29%20can%20be%20partially%20or%20totally%20blocked%20by%20the%20incorporation%20of%20stellate%20mesoporous%20silica%20%28STMS%29%20nanoparticles%20%28NPs%2C%20approximate%20to%20150%20%2B%5C%2F-%2028%20nm%20size%2C%2015%20nm%20pore%29%20within%20the%20HG.%20It%20is%20shown%20here%20that%20the%20porous%20silica%20NPs%20act%20as%20sub-micrometer%20size%20reservoirs%20ensuring%20precise%20level%20retention%20simply%20by%20playing%20on%20the%20amount%20of%20STMS%20embedded%20in%20the%20HG.%20Further%2C%20this%20effect%20is%20shown%20for%20various%20proteins%20demonstrating%20the%20versatility%20of%20this%20concept.The%20well-known%20challenge%20of%20controlling%20the%20release%20of%20therapeutics%20from%20hydrogels%20is%20addressed%20here%20by%20embedding%20stellate%20mesoporous%20silica%20%28STMS%29%20nanoparticles%20into%20agarose%20hydrogels.%20It%20is%20shown%20that%20such%20an%20STMS%20acts%20as%20efficient%20nanoreservoirs%20as%20proteins%20preferentially%20adsorb%20on%20STMS%20inside%20the%20hydrogel%20and%20the%20amount%20of%20retained%20proteins%20is%20controlled%20by%20the%20amount%20of%20embedded%20STMS.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fmacp.202400035%22%2C%22ISSN%22%3A%221022-1352%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fmacp.202400035%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22UBUT97QT%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A12%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22VAMNXKNE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Brouillac%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Brouillac%2C%20N.%20McIntosh%2C%20B.%20Heinrich%2C%20O.%20Jeannin%2C%20O.%20De%20Sagazan%2C%20N.%20Coulon%2C%20J.%20Rault-Berthelot%2C%20J.%20Cornil%2C%20E.%20Jacques%2C%20C.%20Quinton%2C%20C.%20Poriel%2C%20Grafting%20Electron-Accepting%20Fragments%20on%20%5B4%5Dcyclo-2%2C7-carbazole%20Scaffold%3A%20Tuning%20the%20Structural%20and%20Electronic%20Properties%20of%20Nanohoops%2C%20Advanced%20Science%20%282024%29%202309115.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadvs.202309115%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadvs.202309115%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Grafting%20Electron-Accepting%20Fragments%20on%20%5B4%5Dcyclo-2%2C7-carbazole%20Scaffold%3A%20Tuning%20the%20Structural%20and%20Electronic%20Properties%20of%20Nanohoops%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Brouillac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nemo%22%2C%22lastName%22%3A%22McIntosh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Jeannin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22De%20Sagazan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Coulon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joelle%22%2C%22lastName%22%3A%22Rault-Berthelot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Cornil%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuel%22%2C%22lastName%22%3A%22Jacques%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cassandre%22%2C%22lastName%22%3A%22Quinton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cyril%22%2C%22lastName%22%3A%22Poriel%22%7D%5D%2C%22abstractNote%22%3A%22Since%20the%20first%20applications%20of%20nanohoops%20in%20organic%20electronics%20appear%20promising%2C%20the%20time%20has%20come%20to%20go%20deeper%20into%20their%20rational%20design%20in%20order%20to%20reach%20high-efficiency%20materials.%20To%20do%20so%2C%20systematic%20studies%20dealing%20with%20the%20incorporation%20of%20electron-rich%20and%5C%2For%20electron-poor%20functional%20units%20on%20nanohoops%20have%20to%20be%20performed.%20Herein%2C%20the%20synthesis%2C%20the%20electrochemical%2C%20photophysical%2C%20thermal%2C%20and%20structural%20properties%20of%20two%20%5B4%5Dcyclo-2%2C7-carbazoles%2C%20%5B4%5DC-Py-Cbz%2C%20and%20%5B4%5DC-Pm-Cbz%2C%20possessing%20electron-withdrawing%20units%20on%20their%20nitrogen%20atoms%20%28pyridine%20or%20pyrimidine%29%20are%20reported.%20The%20synthesis%20of%20these%20nanohoops%20is%20first%20optimized%20and%20a%20high%20yield%20above%2050%25%20is%20reached.%20Through%20a%20structure-properties%20relationship%20study%2C%20it%20is%20shown%20that%20the%20substituent%20has%20a%20significant%20impact%20on%20some%20physicochemical%20properties%20%28eg%20HOMO%5C%2FLUMO%20levels%29%20while%20others%20are%20kept%20unchanged%20%28eg%20fluorescence%29.%20Incorporation%20in%20electronic%20devices%20shows%20that%20the%20most%20electrically%20efficient%20Organic%20Field-Effect%20transistors%20are%20obtained%20with%20%5B4%5DC-Py-Cbz%20although%20this%20compound%20does%20not%20present%20the%20best-organized%20semiconductor%20layer.%20These%20experimental%20data%20are%20finally%20confronted%20with%20the%20electronic%20couplings%20between%20the%20nanohoops%20determined%20at%20the%20DFT%20level%20and%20have%20highlighted%20the%20origin%20in%20the%20difference%20of%20charge%20transport%20properties.%20%5B4%5DC-Py-Cbz%20has%20the%20advantage%20of%20a%20more%202D-like%20transport%20character%20than%20%5B4%5DC-Pm-Cbz%2C%20which%20alleviates%20the%20impact%20of%20defects%20and%20structural%20organization.The%20synthesis%2C%20the%20electrochemical%2C%20photophysical%2C%20thermal%2C%20and%20structural%20properties%20of%20two%20%5B4%5Dcyclo-2%2C7-carbazoles%2C%20%5B4%5DC-Py-Cbz%20and%20%5B4%5DC-Pm-Cbz%2C%20possessing%20electron-withdrawing%20units%20on%20their%20nitrogen%20atoms%20%28i.e.%2C%20pyridine%20and%20pyrimidine%29%20are%20reported.%20Incorporation%20in%20electronic%20devices%20shows%20that%20the%20most%20electrically%20efficient%20OFETs%20are%20obtained%20with%20%5B4%5DC-Py-Cbz%20although%20this%20compound%20does%20not%20present%20the%20best-organized%20semiconductor%20layer.image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadvs.202309115%22%2C%22ISSN%22%3A%222198-3844%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadvs.202309115%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A07Z%22%7D%7D%2C%7B%22key%22%3A%2247978LHR%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Carrad%5Cu00f2%20and%20Ravindra%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Carrad%26%23xF2%3B%2C%20N.M.%20Ravindra%2C%20Advanced%20Functional%20and%20Structural%20Thin%20Films%20and%20Coatings%20and%20Honorary%20Palkwoski%20Session%2C%20JOM%2076%20%282024%29%20610%26%23x2013%3B611.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-023-06327-y%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1007%5C%2Fs11837-023-06327-y%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Advanced%20Functional%20and%20Structural%20Thin%20Films%20and%20Coatings%20and%20Honorary%20Palkwoski%20Session%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adele%22%2C%22lastName%22%3A%22Carrad%5Cu00f2%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%20M.%22%2C%22lastName%22%3A%22Ravindra%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1007%5C%2Fs11837-023-06327-y%22%2C%22ISSN%22%3A%221047-4838%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1007%5C%2Fs11837-023-06327-y%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A10Z%22%7D%7D%2C%7B%22key%22%3A%22AE3D5YF5%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Consolaro%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EV.G.%20Consolaro%2C%20V.%20Rouchon%2C%20O.%20Ersen%2C%20Electron%20beam%20damages%20in%20zeolites%3A%20A%20review%2C%20Microporous%20and%20Mesoporous%20Materials%20364%20%282024%29%20112835.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.micromeso.2023.112835%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.micromeso.2023.112835%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electron%20beam%20damages%20in%20zeolites%3A%20A%20review%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valentina%20Girelli%22%2C%22lastName%22%3A%22Consolaro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Virgile%22%2C%22lastName%22%3A%22Rouchon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%5D%2C%22abstractNote%22%3A%22The%20analysis%20of%20nanomaterials%20by%20electron%20microscopy-based%20techniques%20has%20brought%20huge%20progress%20in%20the%20general%20comprehension%20of%20the%20matter%20at%20the%20sub-nanometric%20scale.%20Some%20materials%20remain%20however%20difficult%20to%20investigate%2C%20in%20particular%20by%20transmission%20electron%20microscopy%20due%20to%20their%20instability%20under%20a%20highly%20energetic%20electron%20beam.%20Zeolites%2C%20which%20play%20a%20key%20role%20in%20nowadays%20societies%2C%20belong%20to%20this%20category%20of%20beam%20sensitive%20materials.%20Therefore%2C%20their%20instability%20under%20the%20beam%20has%20sparked%20the%20interest%20in%20understanding%20the%20source%20of%20the%20damage%20and%20furtherly%20providing%20clues%20to%20circumvent%20it.%20In%20this%20review%20a%20brief%20excursus%20on%20the%20common%20mechanisms%20of%20material%20degradation%20under%20electron%20exposure%20is%20proposed%2C%20considering%20the%20type%20of%20interaction%20between%20the%20highly%20energetic%20electrons%20and%20the%20specimen.%20The%20phenomenology%20of%20the%20damage%20in%20zeolites%20is%20also%20described%2C%20evoking%20the%20observable%20effects%2C%20such%20as%20the%20amorphization%20and%20anisotropic%20shrinkage%20of%20zeolitic%20grains%20but%20also%20the%20eventual%20bubble%20formation%20and%20metallic%20precipitation%20of%20the%20stabilizing%20cationic%20agents.%20Ionization%20mechanisms%20are%20then%20imputable%20for%20explaining%20the%20observed%20phenomena%2C%20from%20the%20radiolytic%20process%20responsible%20for%20generating%20strain%20centers%20to%20charging%20effects%20which%20can%20lead%20to%20ionic%20currents%20inside%20the%20specimen.%20However%2C%20the%20research%20on%20the%20application%20of%20electron%20microscopy%20for%20zeolite%20study%20has%20progressed%20with%20the%20purpose%20of%20reducing%20the%20damaging%20effects.%20From%20the%20optimization%20of%20the%20preparation%20protocol%20to%20the%20introduction%20of%20highly%20advanced%20TEM%20techniques%2C%20nowadays%20it%20is%20possible%20to%20reach%20a%20sub-Angstrom%20resolution%20and%20probe%20single%20framework%20and%20non-framework%20atoms%2C%20before%20irreversibly%20compromising%20the%20zeolite%27s%20structure%20and%20morphology.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.micromeso.2023.112835%22%2C%22ISSN%22%3A%221387-1811%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.micromeso.2023.112835%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222024-04-29T14%3A36%3A13Z%22%7D%7D%2C%7B%22key%22%3A%22NYIUY7CX%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Del%20Giudice%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Del%20Giudice%2C%20G.%20Voegeli%2C%20J.-M.%20Strub%2C%20B.%20Heinrich%2C%20L.%20Douce%2C%20Ionic%20Liquid%20Crystals%20Based%20on%20Loop-Shaped%20Copper%28I%29%20Complexes.%2C%20Inorganic%20Chemistry%2063%20%282024%29%206103%26%23x2013%3B6110.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.4c00728%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.4c00728%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ionic%20Liquid%20Crystals%20Based%20on%20Loop-Shaped%20Copper%28I%29%20Complexes.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Del%20Giudice%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Voegeli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Strub%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Douce%22%7D%5D%2C%22abstractNote%22%3A%22This%20paper%20describes%20the%20synthesis%20and%20characterization%20of%20liquid%20crystals%20based%20on%20loop-shaped%20cationic%20copper%28I%29%20complexes%20of%20a%20multidentate%20ligand.%20Their%20synthesis%20involves%20the%20one-pot%20reaction%20of%20an%20alkyloxy-decorated%20pyridine-aldehyde%20unit%20with%20a%20diamine%20%282%2C2%27-%28ethylenedioxy%29bis%28ethylamine%29%29%20spacer%20to%20form%20in%20situ%20a%20pyridine-imine%20quadridentate-N4-donor%20ligand%2C%20L%2C%20which%20is%20able%20to%20chelate%20a%20copper%28I%29%20center%20associated%20with%20various%20noncoordinating%20anions.%20All%20of%20these%20compounds%20were%20characterized%20by%20NMR%2C%20IR%2C%20and%20electronic%20absorption%20spectroscopy%2C%20and%20more%20particularly%20by%20X-ray%20diffraction%20and%20mass%20spectroscopy%2C%20enabling%20unambiguous%20assignment%20of%20the%20%5BML%5D%2B%20mononuclear%20nature%20of%20the%20cationic%20components.%20The%20presence%20of%20six%20flexible%20alkyloxy%20chains%20at%20each%20end%20of%20the%20ligand%20associated%20with%20the%20rigidity%20of%20the%20core%20complex%20causes%20induction%20of%20a%20liquid%20crystal%20state%20with%20a%20columnar%20self-organized%20architecture%2C%20where%20the%20columns%20are%20packed%20in%20a%20hexagonal%20two-dimensional%20network.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.4c00728%22%2C%22ISSN%22%3A%221520-510X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.inorgchem.4c00728%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22VYTETDZF%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A10%3A28Z%22%7D%7D%2C%7B%22key%22%3A%22CL3IA2RE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Desbuis%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EV.%20Desbuis%2C%20D.%20Lacour%2C%20C.%20Tiusan%2C%20C.%20Vautrin%2C%20S.%20Migot%2C%20J.%20Ghanbaja%2C%20Y.%20Lu%2C%20W.%20Weber%2C%20M.%20Hehn%2C%20Manipulation%20of%20low-energy%20spin%20precession%20in%20a%20magnetic%20thin%20film%20by%20tuning%20its%20molecular%20field%2C%20Physical%20Review%20B%20109%20%282024%29%20024403.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.109.024403%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.109.024403%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Manipulation%20of%20low-energy%20spin%20precession%20in%20a%20magnetic%20thin%20film%20by%20tuning%20its%20molecular%20field%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valentin%22%2C%22lastName%22%3A%22Desbuis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Lacour%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Coriolan%22%2C%22lastName%22%3A%22Tiusan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christopher%22%2C%22lastName%22%3A%22Vautrin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Migot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Ghanbaja%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuan%22%2C%22lastName%22%3A%22Lu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wolfgang%22%2C%22lastName%22%3A%22Weber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michel%22%2C%22lastName%22%3A%22Hehn%22%7D%5D%2C%22abstractNote%22%3A%22The%20low%20-energy%20electronic%20spin%20precession%20is%20measured%20in%20the%20molecular%20field%20of%20a%20CoAl%20thin%20film.%20Designed%20to%20have%20a%20low%20Curie%20temperature%2C%20the%20variation%20of%20the%20CoAl%20molecular%20field%20results%20in%20an%20electronic%20spin%20precession%20angle%20that%20varies%20with%20temperature.%20The%20behavior%20is%20observed%20for%20injection%20energies%20between%200.9%20and%201.2%20eV%20and%20the%20results%20are%20explained%20on%20the%20basis%20of%20an%20exchange%20field%20varying%20with%20temperature.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.109.024403%22%2C%22ISSN%22%3A%222469-9950%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevB.109.024403%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22TR4ZUX8B%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A06%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22U6XGDWDN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Go%5Cu0142%5Cu0119biewski%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Go%26%23x142%3B%26%23x119%3Bbiewski%2C%20R.%20Hertel%2C%20M.%20d%26%23x2019%3BAquino%2C%20V.%20Vasyuchka%2C%20M.%20Weiler%2C%20P.%20Pirro%2C%20M.%20Krawczyk%2C%20S.%20Fukami%2C%20H.%20Ohno%2C%20J.%20Llandro%2C%20Collective%20Spin-Wave%20Dynamics%20in%20Gyroid%20Ferromagnetic%20Nanostructures%2C%20ACS%20Appl.%20Mater.%20Interfaces%2016%20%282024%29%2022177%26%23x2013%3B22188.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.4c02366%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.4c02366%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Collective%20Spin-Wave%20Dynamics%20in%20Gyroid%20Ferromagnetic%20Nanostructures%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mateusz%22%2C%22lastName%22%3A%22Go%5Cu0142%5Cu0119biewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Riccardo%22%2C%22lastName%22%3A%22Hertel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Massimiliano%22%2C%22lastName%22%3A%22d%5Cu2019Aquino%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vitaliy%22%2C%22lastName%22%3A%22Vasyuchka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathias%22%2C%22lastName%22%3A%22Weiler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philipp%22%2C%22lastName%22%3A%22Pirro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maciej%22%2C%22lastName%22%3A%22Krawczyk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shunsuke%22%2C%22lastName%22%3A%22Fukami%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hideo%22%2C%22lastName%22%3A%22Ohno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Justin%22%2C%22lastName%22%3A%22Llandro%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsami.4c02366%22%2C%22ISSN%22%3A%221944-8244%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.4c02366%22%2C%22collections%22%3A%5B%22UJZN2BUR%22%2C%22UVN4N32C%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A07%3A20Z%22%7D%7D%2C%7B%22key%22%3A%22QU5MFQKL%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hemmerle%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Hemmerle%2C%20N.%20Aubert%2C%20T.%20Moreno%2C%20P.%20Kekicheff%2C%20B.%20Heinrich%2C%20S.%20Spagnoli%2C%20M.%20Goldmann%2C%20G.%20Ciatto%2C%20P.%20Fontaine%2C%20Opportunities%20and%20new%20developments%20for%20the%20study%20of%20surfaces%20and%20interfaces%20in%20soft%20condensed%20matter%20at%20the%20SIRIUS%20beamline%20of%20Synchrotron%20SOLEIL.%2C%20Journal%20of%20Synchrotron%20Radiation%2031%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600577523008810%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600577523008810%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Opportunities%20and%20new%20developments%20for%20the%20study%20of%20surfaces%20and%20interfaces%20in%20soft%20condensed%20matter%20at%20the%20SIRIUS%20beamline%20of%20Synchrotron%20SOLEIL.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arnaud%22%2C%22lastName%22%3A%22Hemmerle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Aubert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Moreno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Kekicheff%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22Spagnoli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michel%22%2C%22lastName%22%3A%22Goldmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gianluca%22%2C%22lastName%22%3A%22Ciatto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Fontaine%22%7D%5D%2C%22abstractNote%22%3A%22The%20SIRIUS%20beamline%20of%20Synchrotron%20SOLEIL%20is%20dedicated%20to%20X-ray%20scattering%20and%20spectroscopy%20of%20surfaces%20and%20interfaces%2C%20covering%20the%20tender%20to%20mid-hard%20X-ray%20range%20%281.1-13%5Cu2005keV%29.%20The%20beamline%20has%20hosted%20a%20wide%20range%20of%20experiments%20in%20the%20field%20of%20soft%20interfaces%20and%20beyond%2C%20providing%20various%20grazing-incidence%20techniques%20such%20as%20diffraction%20and%20wide-angle%20scattering%20%28GIXD%5C%2FGIWAXS%29%2C%20small-angle%20scattering%20%28GISAXS%29%20and%20X-ray%20fluorescence%20in%20total%20reflection%20%28TXRF%29.%20SIRIUS%20also%20offers%20specific%20sample%20environments%20tailored%20for%20in%20situ%20complementary%20experiments%20on%20solid%20and%20liquid%20surfaces.%20Recently%2C%20the%20beamline%20has%20added%20compound%20refractive%20lenses%20associated%20with%20a%20transfocator%2C%20allowing%20for%20the%20X-ray%20beam%20to%20be%20focused%20down%20to%2010%5Cu2005m%20%2A%2010%5Cu2005m%20while%20maintaining%20a%20reasonable%20flux%20on%20the%20sample.%20This%20new%20feature%20opens%20up%20new%20possibilities%20for%20faster%20GIXD%20measurements%20at%20the%20liquid-air%20interface%20and%20for%20measurements%20on%20samples%20with%20narrow%20geometries.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1107%5C%2FS1600577523008810%22%2C%22ISSN%22%3A%221600-5775%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1107%5C%2FS1600577523008810%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222023-11-17T16%3A24%3A18Z%22%7D%7D%2C%7B%22key%22%3A%226VSXXXJB%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kousar%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Kousar%2C%20S.%20Rasheed%2C%20K.%20Yasmeen%2C%20A.R.%20Umar%2C%20M.H.%20Laiche%2C%20M.%20Masood%2C%20H.%20Muhammad%2C%20M.%20Hanif%2C%20Efficient%20synergistic%20degradation%20of%20Congo%20red%20and%20omeprazole%20in%20wastewater%20using%20rGO%5C%2FAg%40ZnO%20nanocomposite%2C%20Journal%20of%20Water%20Process%20Engineering%2058%20%282024%29%20104775.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jwpe.2024.104775%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jwpe.2024.104775%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Efficient%20synergistic%20degradation%20of%20Congo%20red%20and%20omeprazole%20in%20wastewater%20using%20rGO%5C%2FAg%40ZnO%20nanocomposite%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nazish%22%2C%22lastName%22%3A%22Kousar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sufian%22%2C%22lastName%22%3A%22Rasheed%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kousar%22%2C%22lastName%22%3A%22Yasmeen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdul%20Rehman%22%2C%22lastName%22%3A%22Umar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mouna%20Hind%22%2C%22lastName%22%3A%22Laiche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohsin%22%2C%22lastName%22%3A%22Masood%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haji%22%2C%22lastName%22%3A%22Muhammad%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Muddasir%22%2C%22lastName%22%3A%22Hanif%22%7D%5D%2C%22abstractNote%22%3A%22Photocatalytic%20degradation%20is%20an%20effective%20and%20eco-friendly%20technique%20that%20can%20address%20environmental%20pollution%2C%20especially%20water%20pollution.%20We%20prepared%20rGO-decorated%20with%20silver-doped%20zinc%20oxide%20%28rGO%5C%2FAg%40ZnO%29%20nanocomposite%20as%20the%20efficient%20photocatalyst%20for%20Congo%20red%20and%20Omeprazole%20degradation.%20The%20nanocomposite%20was%20characterized%20using%20advanced%20spectroscopic%20and%20imaging%20techniques.%20The%20low%20band%20gap%20of%202.05%20eV%20enables%20rGO%5C%2FAg%40ZnO%20nanocomposites%20to%20be%20an%20efficient%20photocatalyst%20for%20the%20degradation%20of%20multiple%20pollutants.%20The%20BET%20analysis%20revealed%20that%20the%20rGO%5C%2FAg%40ZnO%20nanocomposite%20possesses%20a%20substantial%20surface%20area%20of%2051%20m%282%29%5C%2Fg%2C%20indicative%20of%20enhanced%20porosity%2C%20while%20the%20estimated%20surface%20area%20for%20Ag%40ZnO%20is%20approximately%2018.56%20m%282%29%5C%2Fg%2C%20reflecting%20the%20significant%20contribution%20of%20rGO%20to%20the%20composite%27s%20adsorptive%20properties.%20The%20rGO%5C%2FAg%40ZnO%20nanocomposites%20showed%20an%20excellent%2093.77%20%25%20degradation%20of%20Congo%20red%20in%2040%20min%20and%2095.6%20%25%20degradation%20of%20Omeprazole%20in%2030%20min%20under%20the%20optimized%20conditions.%20The%20photocatalyst%20rGO%5C%2FAg%40ZnO%20retains%20its%20efficiency%20over%20five%20cycles%2C%20providing%20a%20cost-effective%2C%20eco-friendly%20solution%20for%20continuous%20water%20pollutant%20treatment.%20The%20exceptional%20degradation%20efficiency%20of%20rGO%5C%2FAg%40ZnO%20was%20achieved%20through%20optimization%20of%20the%20photocatalytic%20process%20while%20previously%20reported%20materials%20exhibit%20longer%20degradation%20times%20with%20lower%20degradation%20percentages%20%2880-90%20%25%29.%20These%20excellent%20photocatalytic%20properties%20highlight%20rGO%5C%2FAg%40ZnO%20as%20an%20effective%20and%20rapid%20solution%20to%20address%20the%20water%20pollution%20caused%20by%20different%20environmental%20contaminants.%20The%20results%20support%20the%20practical%20use%20of%20rGO%5C%2FAg%40ZnO%20in%20real-world%20water%20treatment%20systems%20contributing%20to%20a%20healthier%20environment.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jwpe.2024.104775%22%2C%22ISSN%22%3A%222214-7144%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jwpe.2024.104775%22%2C%22collections%22%3A%5B%229USMFXMV%22%2C%22DEB5KWFS%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A13Z%22%7D%7D%2C%7B%22key%22%3A%228LDBSSH9%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kurucz%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Kurucz%2C%20I.%20Nikolinakos%2C%20J.%20Soueiti%2C%20T.%20Baron%2C%20F.%20Grifoni%2C%20W.%20Naim%2C%20Y.%20Pellegrin%2C%20F.%20Sauvage%2C%20F.%20Odobel%2C%20S.%20Haacke%2C%20Transparent%20Near-IR%20Dye-Sensitized%20Solar%20Cells%3A%20Ultrafast%20Spectroscopy%20Reveals%20the%20Effects%20of%20Driving%20Force%20and%20Dye%20Aggregation%2C%20ChemPhotoChem%20%282024%29%20e202300175.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.202300175%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcptc.202300175%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Transparent%20Near-IR%20Dye-Sensitized%20Solar%20Cells%3A%20Ultrafast%20Spectroscopy%20Reveals%20the%20Effects%20of%20Driving%20Force%20and%20Dye%20Aggregation%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mate%22%2C%22lastName%22%3A%22Kurucz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ilias%22%2C%22lastName%22%3A%22Nikolinakos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jimmy%22%2C%22lastName%22%3A%22Soueiti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibaut%22%2C%22lastName%22%3A%22Baron%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fionnuala%22%2C%22lastName%22%3A%22Grifoni%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Waad%22%2C%22lastName%22%3A%22Naim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yann%22%2C%22lastName%22%3A%22Pellegrin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frederic%22%2C%22lastName%22%3A%22Sauvage%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Odobel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Haacke%22%7D%5D%2C%22abstractNote%22%3A%22In%20the%20context%20of%20developing%20transparent%20near-IR%20absorbing%20dye-sensitized%20solar%20cells%2C%20diketopyrrolopyrrole%20%28DPP%29%20cyanine%20dyes%20have%20recently%20emerged%20as%20an%20alternative%20to%20strongly%20aggregating%20linear%20cyanines.%20In%20our%20efforts%20to%20increase%20both%20the%20power%20conversion%20efficiency%20%28PCE%29%20and%20the%20average%20visible%20transmittance%20%28AVT%29%2C%20a%20thienylated%20version%2C%20called%20TB202%2C%20that%20shows%20a%20red-shifted%20absorption%20with%20respect%20to%20our%20champion%20dye%20TB207%20was%20designed.%20However%2C%20the%20lower%20energy%20LUMO%20level%20of%20TB202%20brings%20along%20a%20lower%20driving%20force%20%28-Delta%20G%29%20for%20carrier%20injection%2C%20which%20we%20recently%20identified%20as%20the%20main%20parameter%20limiting%20the%20PCE%20to%201.5%20%25%20in%20the%20best%20device%20conditions.%20In%20the%20present%20paper%2C%20we%20publish%20a%20detailed%20account%20of%20the%20effect%20of%20the%20de-aggregating%20cheno-deoxycholic%20acid%20%28CDCA%29%20for%20both%20TB207%20and%20TB202.%20Both%20transient%20absorption%20%28TAS%29%20and%20fluorescence%20up-conversion%20%28FLUPS%29%20data%20are%20presented%2C%20which%20allow%20to%20quantitively%20compare%20the%20effect%20of%20-Delta%20G%20and%20the%20CDCA%20concentration%2C%20in%20terms%20of%20the%20kinetic%20competition%20of%20ensemble%20averaged%20carrier%20injection%20and%20monomer-to-aggregate%20energy%20transfer%20%28ET%29%20rates.%20A%20comprehensive%20picture%20emerges%20on%20how%20ET%20is%20reduced%20by%20higher%20CDCA%20concentrations%2C%20leading%20in%20the%20best%20device%20conditions%20to%20injection%20efficiencies%20in%20the%20range%20of%2065%20%25%20for%20TB207%20and%20only%2035%20%25%20for%20TB202.Near-IR%20dyes%20for%20transparent%20dye-sensitized%20solar%20cells%3A%20The%20effects%20of%20small%20driving%20forces%20%28-Delta%20G%29%20and%20excited%20state%20quenching%20by%20energy%20transfer%20to%20aggregates%20studied%20by%20femtosecond%20differential%20absorption%20and%20fluorescence%20spectroscopy%20for%20two%20DPP%20cyanine%20dyes.%2Bimage%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fcptc.202300175%22%2C%22ISSN%22%3A%222367-0932%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fcptc.202300175%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22VDSXEDFS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lambrecht%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Lambrecht%2C%20G.%20Ori%2C%20C.%20Massobrio%2C%20M.%20Boero%2C%20E.%20Martin%2C%20ADynMat%20Consortium%2C%20Assessing%20the%20thermal%20conductivity%20of%20amorphous%20SiN%20by%20approach-to-equilibrium%20molecular%20dynamics%2C%20Journal%20of%20Chemical%20Physics%20160%20%282024%29%20094505.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0193566%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F5.0193566%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Assessing%20the%20thermal%20conductivity%20of%20amorphous%20SiN%20by%20approach-to-equilibrium%20molecular%20dynamics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Achille%22%2C%22lastName%22%3A%22Lambrecht%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guido%22%2C%22lastName%22%3A%22Ori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Carlo%22%2C%22lastName%22%3A%22Massobrio%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mauro%22%2C%22lastName%22%3A%22Boero%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Evelyne%22%2C%22lastName%22%3A%22Martin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22name%22%3A%22ADynMat%20Consortium%22%7D%5D%2C%22abstractNote%22%3A%22First-principles%20molecular%20dynamics%20combined%20with%20the%20approach-to-equilibrium%20molecular%20dynamics%20methodology%20is%20employed%20to%20calculate%20the%20thermal%20conductivity%20of%20non-stoichiometric%20amorphous%20SiN.%20This%20is%20achieved%20by%20implementing%20thermal%20transients%20in%20five%20distinct%20models%20of%20different%20sizes%20along%20the%20direction%20of%20the%20heat%20transport.%20Such%20models%20have%20identical%20structural%20features%20and%20are%20representative%20of%20the%20same%20material%2C%20thereby%20allowing%20for%20a%20reliable%20analysis%20of%20thermal%20conductivity%20trends%20as%20a%20function%20of%20the%20relevant%20cell%20dimension.%20In%20line%20with%20the%20known%20physical%20law%20of%20heat%20propagation%20at%20short%20scale%2C%20the%20thermal%20conductivity%20increases%20in%20size%20with%20the%20direction%20of%20heat%20transport.%20The%20observed%20behavior%20is%20rationalized%20accounting%20for%20previous%20results%20on%20crystalline%20and%20amorphous%20materials%2C%20thus%20providing%20a%20unified%20description%20holding%20for%20a%20large%20class%20of%20materials%20and%20spanning%20a%20wide%20range%20of%20heat%20propagation%20lengths.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1063%5C%2F5.0193566%22%2C%22ISSN%22%3A%220021-9606%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F5.0193566%22%2C%22collections%22%3A%5B%22NZSFH59F%22%2C%22CF4ZI7HM%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A11%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22WMVTI7DM%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Llopez%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Llopez%2C%20F.%20Leroy%2C%20C.%20Tagne-Kaegom%2C%20B.%20Croes%2C%20A.%20Michon%2C%20C.%20Mastropasqua%2C%20M.%20Al%20Khalfioui%2C%20S.%20Curiotto%2C%20P.%20Muller%2C%20A.%20Saol%2C%20B.%20Kierren%2C%20G.%20Kremer%2C%20P.L.%20Fevre%2C%20F.%20Bertran%2C%20Y.%20Fagot-Revurat%2C%20F.%20Cheynis%2C%20Van%20der%20Waals%20Epitaxy%20of%20Weyl-Semimetal%20Td-WTe2.%2C%20ACS%20Applied%20Materials%20%26amp%3B%20Interfaces%2016%20%282024%29%2020878%26%23x2013%3B20885.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.4c00676%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.4c00676%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Van%20der%20Waals%20Epitaxy%20of%20Weyl-Semimetal%20Td-WTe2.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Llopez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frederic%22%2C%22lastName%22%3A%22Leroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Calvin%22%2C%22lastName%22%3A%22Tagne-Kaegom%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Boris%22%2C%22lastName%22%3A%22Croes%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adrien%22%2C%22lastName%22%3A%22Michon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chiara%22%2C%22lastName%22%3A%22Mastropasqua%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohamed%22%2C%22lastName%22%3A%22Al%20Khalfioui%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefano%22%2C%22lastName%22%3A%22Curiotto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Muller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andres%22%2C%22lastName%22%3A%22Saol%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Kierren%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geoffroy%22%2C%22lastName%22%3A%22Kremer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%20Le%22%2C%22lastName%22%3A%22Fevre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Bertran%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yannick%22%2C%22lastName%22%3A%22Fagot-Revurat%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabien%22%2C%22lastName%22%3A%22Cheynis%22%7D%5D%2C%22abstractNote%22%3A%22Epitaxial%20growth%20of%20WTe2%20offers%20significant%20advantages%2C%20including%20the%20production%20of%20high-quality%20films%2C%20possible%20long-range%20in-plane%20ordering%2C%20and%20precise%20control%20over%20layer%20thicknesses.%20However%2C%20the%20mean%20island%20size%20of%20WTe2%20grown%20by%20molecular%20beam%20epitaxy%20%28MBE%29%20in%20the%20literature%20is%20only%20a%20few%20tens%20of%20nanometers%2C%20which%20is%20not%20suitable%20for%20the%20implementation%20of%20devices%20at%20large%20lateral%20scales.%20Here%20we%20report%20the%20growth%20of%20Td%20-WTe2%20ultrathin%20films%20by%20MBE%20on%20monolayer%20%28ML%29%20graphene%2C%20reaching%20a%20mean%20flake%20size%20of%20%5Cu2243110%20nm%2C%20which%20is%2C%20on%20overage%2C%20more%20than%20three%20times%20larger%20than%20previous%20results.%20WTe2%20films%20thicker%20than%205%20nm%20have%20been%20successfully%20synthesized%20and%20exhibit%20the%20expected%20Td%20phase%20atomic%20structure.%20We%20rationalize%20the%20epitaxial%20growth%20of%20Td-WTe2%20and%20propose%20a%20simple%20model%20to%20estimate%20the%20mean%20flake%20size%20as%20a%20function%20of%20growth%20parameters%20that%20can%20be%20applied%20to%20other%20transition%20metal%20dichalcogenides%20%28TMDCs%29.%20Based%20on%20nucleation%20theory%20and%20the%20Kolmogorov-Johnson-Meh-Avrami%20%28KJMA%29%20equation%2C%20our%20analytical%20model%20supports%20experimental%20data%20showing%20a%20critical%20coverage%20of%200.13%20ML%20above%20which%20WTe2%20nucleation%20becomes%20negligible.%20The%20quality%20of%20monolayer%20WTe2%20films%20is%20demonstrated%20by%20electronic%20band%20structure%20analysis%20using%20angle-resolved%20photoemission%20spectroscopy%20%28ARPES%29%2C%20which%20is%20in%20agreement%20with%20first-principles%20calculations%20performed%20on%20free-standing%20WTe2%20and%20previous%20reports.%20We%20found%20electron%20pockets%20at%20the%20Fermi%20level%2C%20indicating%20a%20n-type%20doping%20of%20WTe2%20with%20an%20electron%20density%20of%20n%20%3D%202.0%20%5Cu00b1%200.5%20%2A%201012%20cm-2%20for%20each%20electron%20pocket.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsami.4c00676%22%2C%22ISSN%22%3A%221944-8252%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsami.4c00676%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22MKAFAH44%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A07%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22LMGRUTHU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lyu%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EY.%20Lyu%2C%20F.%20Gao%2C%20P.%20Cheng%2C%20L.%20Chen%2C%20S.%20Klyatskaya%2C%20M.%20Ruben%2C%20J.%20Rosen%2C%20J.V.%20Barth%2C%20J.%20Bjoerk%2C%20K.%20Wu%2C%20Y.-Q.%20Zhang%2C%20Unraveling%20Enyne%20Bonding%20via%20Dehydrogenation-Hydrogenation%20Processes%20in%20On-Surface%20Synthesis%20with%20Terminal%20Alkynes%2C%20Advanced%20Materials%20Interfaces%20%282024%29%202400222.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmi.202400222%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmi.202400222%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unraveling%20Enyne%20Bonding%20via%20Dehydrogenation-Hydrogenation%20Processes%20in%20On-Surface%20Synthesis%20with%20Terminal%20Alkynes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuanhao%22%2C%22lastName%22%3A%22Lyu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Feng%22%2C%22lastName%22%3A%22Gao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peng%22%2C%22lastName%22%3A%22Cheng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lan%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Svetlana%22%2C%22lastName%22%3A%22Klyatskaya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Rosen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johannes%20V.%22%2C%22lastName%22%3A%22Barth%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jonas%22%2C%22lastName%22%3A%22Bjoerk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kehui%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yi-Qi%22%2C%22lastName%22%3A%22Zhang%22%7D%5D%2C%22abstractNote%22%3A%22On-surface%20reactions%20of%20terminal%20alkynes%20in%20ultrahigh%20vacuum%20have%20attracted%20widespread%20attention%20due%20to%20their%20high%20technological%20promise.%20However%2C%20employing%20different%20precursors%20and%20substrate%20materials%20often%20intricate%20reaction%20schemes%20appear%20far%20from%20being%20well-understood.%20Thus%2C%20recent%20investigations%20of%20alkyne%20coupling%20on%20noble%20metal%20surfaces%20suggest%20non-dehydrogenative%20scenarios%2C%20contradicting%20earlier%20reports.%20Herein%2C%20the%20study%20employs%20noncontact%20atomic%20force%20microscopy%20%28nc-AFM%29%20with%20high%20spatial%20resolution%20to%20conclusively%20characterize%20exemplary%20alkyne%20coupling%20products.%20Contrary%20to%20initial%20interpretations%20proposing%20dehydrogenative%20homocoupling%20on%20Ag%28111%29%2C%20bond-resolved%20AFM%20imaging%20reveals%20the%20expression%20of%20enyne%20motifs.%20Based%20on%20complementary%2C%20extensive%20density%20functional%20theory%20calculations%2C%20the%20pertaining%20reaction%20mechanisms%20are%20explored.%20It%20is%20proposed%20that%20enyne%20formation%20initiates%20with%20a%20direct%20carbon-carbon%20coupling%20between%20two%20alkyne%20groups%2C%20followed%20by%20surface-assisted%20dehydrogenation-hydrogenation%20processes.%20Thereby%20consecutive%20steps%20of%20atomic%20hydrogen%20cleavage%2C%20surface%20migration%20and%20recombination%20to%20a%20different%20carbon%20atom%20enable%20bridging%20via%20carbon-carbon%20double%20bonding.%20The%20new%20results%20shed%20light%20on%20subtle%2C%20but%20crucial%20surface-mediated%20hydrogen%20transfer%20processes%20involved%20in%20the%20chemical%20bond%20formation%2C%20which%20are%20suggested%20to%20be%20of%20general%20relevance%20in%20on-surface%20synthesis.%20Terminal%20alkyne%20coupling%20on%20Ag%28111%29%20in%20ultrahigh%20vacuum%20is%20conclusively%20examined%20by%20bond-resolved%20atomic%20force%20microscopy%20and%20density%20functional%20theory%20modeling.%20The%20prevailing%20bonding%20motif%20is%20the%20enyne%20moiety%2C%20originating%20from%20a%20distinct%20surface-mediated%20dehydrogenation-hydrogenation%20reaction%20pathway.%20The%20findings%20highlight%20the%20important%20role%20of%20hydrogen%20transfer%20in%20the%20course%20of%20on-surface%20synthesis%20procedures.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadmi.202400222%22%2C%22ISSN%22%3A%222196-7350%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadmi.202400222%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A08%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22GLBAN77R%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Maity%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.%20Maity%2C%20J.-F.%20Dayen%2C%20B.%20Doudin%2C%20R.%20Gumeniuk%2C%20B.%20Kundys%2C%20Graphene%20Magnetoresistance%20Control%20by%20Photoferroelectric%20Substrate.%2C%20ACS%20Nano%2018%20%282024%29%204726%26%23x2013%3B4732.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.3c07277%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.3c07277%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Graphene%20Magnetoresistance%20Control%20by%20Photoferroelectric%20Substrate.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krishna%22%2C%22lastName%22%3A%22Maity%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Francois%22%2C%22lastName%22%3A%22Dayen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bernard%22%2C%22lastName%22%3A%22Doudin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Roman%22%2C%22lastName%22%3A%22Gumeniuk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bohdan%22%2C%22lastName%22%3A%22Kundys%22%7D%5D%2C%22abstractNote%22%3A%22Ultralow%20dimensionality%20of%202D%20layers%20magnifies%20their%20sensitivity%20to%20adjacent%20charges%20enabling%20even%20postprocessing%20electric%20control%20of%20multifunctional%20structures.%20However%2C%20functionalizing%202D%20layers%20remains%20an%20important%20challenge%20for%20on-demand%20device-property%20exploitation.%20Here%20we%20report%20that%20an%20electrical%20and%20even%20fully%20optical%20way%20to%20control%20and%20write%20modifications%20to%20the%20magnetoresistive%20response%20of%20CVD-deposited%20graphene%20is%20achievable%20through%20the%20electrostatics%20of%20the%20photoferroelectric%20substrate.%20For%20electrical%20control%2C%20the%20ferroelectric%20polarization%20switch%20modifies%20graphene%20magnetoresistance%20by%2067%25%20due%20to%20a%20Fermi%20level%20shift%20with%20related%20modification%20in%20charge%20mobility.%20A%20similar%20function%20is%20also%20attained%20entirely%20by%20bandgap%20light%20due%20to%20the%20substrate%20photovoltaic%20effect.%20Moreover%2C%20an%20all-optical%20way%20to%20imprint%20and%20recover%20graphene%20magnetoresistance%20by%20light%20is%20reported%20as%20well%20as%20magnetic%20control%20of%20graphene%20transconductance.%20These%20findings%20extend%20photoferroelectric%20control%20in%202D%20structures%20to%20magnetic%20dimensions%20and%20advance%20wireless%20operation%20for%20sensors%20and%20field-effect%20transistors.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsnano.3c07277%22%2C%22ISSN%22%3A%221936-086X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsnano.3c07277%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22N8397DCZ%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22ZKI2XW85%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mohapatra%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Mohapatra%2C%20W.%20Weber%2C%20B.%20Gobaut%2C%20M.%20Bowen%2C%20S.%20Boukari%2C%20V.%20Da%20Costa%2C%20Polarization%20Vector%20Canting%20in%20Croconic%20Acid%20Ferroelectric%20Nanoscopic%20Regions%2C%20Advanced%20Materials%20Technologies%20%282024%29%202301257.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmt.202301257%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmt.202301257%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Polarization%20Vector%20Canting%20in%20Croconic%20Acid%20Ferroelectric%20Nanoscopic%20Regions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sambit%22%2C%22lastName%22%3A%22Mohapatra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wolfgang%22%2C%22lastName%22%3A%22Weber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Gobaut%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martin%22%2C%22lastName%22%3A%22Bowen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Samy%22%2C%22lastName%22%3A%22Boukari%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Victor%22%2C%22lastName%22%3A%22Da%20Costa%22%7D%5D%2C%22abstractNote%22%3A%22Croconic%20acid%20is%20reported%20to%20be%20the%20organic%20ferroelectric%20with%20the%20highest%20above-room-temperature%20saturation%20polarization%20in%20its%20crystal%20form%2C%20at%20a%20value%20on%20par%20with%20that%20of%20commonly%20used%20inorganic%20ferroelectrics.%20Owing%20to%20its%20organic%20nature%2C%20high%20polarization%20value%2C%20and%20small%20coercive%20field%2C%20Croconic%20acid%20is%20considered%20as%20a%20potential%20candidate%20in%20energy-efficient%20and%20environmentally%20benign%20composite%20multiferroic%20heterostructures.%20However%2C%20understanding%20the%20magnetoelectric%20mechanism%20at%20the%20ferroelectric%5C%2Fferromagnetic%20interface%20in%20these%20structures%20requires%20a%20detailed%20understanding%20of%20the%20orientation%20of%20the%20polarization%20vector%20in%20its%20thin%20film%20form.%20To%20maximize%20the%20magnetoelectric%20effect%2C%20the%20polarization%20vector%20should%20point%20out%20of%20the%20film%20plane%2C%20yet%20the%20polarization%20in%20ultra-thin%20Croconic%20acid%20films%20is%20predicted%20to%20lie%20in%20the%20film%20plane.%20Nevertheless%2C%20polycrystalline%20films%20show%20some%20promise%20in%20this%20direction.%20In%20this%20article%2C%20by%20combining%20in%20situ%20piezoreponse%20force%20microscopy%20imaging%20with%20nanoscopic%20polarization%20reversal%20spectroscopy%2C%20the%20authors%20qualitatively%20analyze%20the%20polarization%20switching%20and%20its%20orientation%20in%20polycrystalline%20Croconic%20acid%20films%20and%20show%20that%20it%20is%20canted%20with%20respect%20to%20the%20film%20plane%2C%20with%20a%20component%20along%20the%20out-of-plane%20direction.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadmt.202301257%22%2C%22ISSN%22%3A%222365-709X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadmt.202301257%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22TR4ZUX8B%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A23Z%22%7D%7D%2C%7B%22key%22%3A%22EVGZ7QGQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Nakamura%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EH.%20Nakamura%2C%20H.%20Ohta%2C%20R.%20Kobayashi%2C%20T.%20Waki%2C%20Y.%20Tabata%2C%20H.%20Ikeno%2C%20C.%20M%26%23xE9%3Bny%2C%20Site-selective%20cobalt%20substitution%20in%20La-Co%20co-substituted%20magnetoplumbite-type%20ferrites%3A%20%26lt%3BSUP%26gt%3B59%26lt%3B%5C%2FSUP%26gt%3BCo-NMR%20and%20DFT%20calculation%20study%2C%20Journal%20of%20Physics-Materials%207%20%282024%29%20025012.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2515-7639%5C%2Fad3b6d%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2515-7639%5C%2Fad3b6d%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Site-selective%20cobalt%20substitution%20in%20La-Co%20co-substituted%20magnetoplumbite-type%20ferrites%3A%20%3CSUP%3E59%3C%5C%2FSUP%3ECo-NMR%20and%20DFT%20calculation%20study%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroyuki%22%2C%22lastName%22%3A%22Nakamura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hiroto%22%2C%22lastName%22%3A%22Ohta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ryuya%22%2C%22lastName%22%3A%22Kobayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Takeshi%22%2C%22lastName%22%3A%22Waki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshikazu%22%2C%22lastName%22%3A%22Tabata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hidekazu%22%2C%22lastName%22%3A%22Ikeno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%5D%2C%22abstractNote%22%3A%22The%20La-Co%20co-substituted%20magnetoplumbite-type%20%28M-type%29%20ferrites%20AFe%2812%29O%2819%29%20%28A%20%3D%20Ca%2C%20Sr%20and%20Ba%2C%20ion%20sizes%20Ca2%2B%3C%20Sr2%2B%3C%20Ba2%2B%29%20with%20Co%20compositions%20around%200.2%20have%20been%20subjected%20to%20Co-59-NMR.%20The%20results%20show%20that%20Co%20occupies%20the%204f%281%29%2C%202a%20and%2012k%20sites%2C%20and%20that%20the%20smaller%20the%20A%20ion%2C%20the%20more%20Co%20tends%20to%20occupy%20the%204f%281%29%20minority%20spin%20site%2C%20which%20is%20effective%20in%20enhancing%20both%20uniaxial%20anisotropy%20and%20magnetisation.%20First-principles%20total%20energy%20calculations%20based%20on%20density%20functional%20theory%20%28DFT%29%20of%20undoped%20AFe%2812%29O%2819%29%20and%20a%20supercell%20%282x2x1%20of%20the%20unit%20cell%29%20in%20which%201%5C%2F96%20of%20Fe3%2B%20is%20replaced%20by%20Co2%2B%20were%20performed%20to%20predict%20the%20stable%20structure%20and%20Co%20occupancy%20sites.%20The%20results%20show%20that%20regardless%20of%20A%2C%20Co%20is%20most%20stable%20when%20it%20occupies%20the%204f%281%29%20site%2C%20followed%20by%20the%202a%20and%2012k%20sites%20with%20energy%20differences%20on%20the%20order%20of%20100%20meV%2C%20and%20Co%20practically%20does%20not%20occupy%20the%202b%20and%204f%282%29%20sites.%20As%20the%20A%20ion%20becomes%20smaller%2C%20the%20energy%20difference%20when%20Co%20occupies%20each%20Fe%20site%20tends%20to%20increase%2C%20and%20the%20Co%20occupancy%20of%20the%204f%281%29%20site%20also%20increases.%20The%20site%20selectivity%20of%20Co%20can%20be%20roughly%20explained%20as%20a%20result%20of%20the%20difference%20in%20uniaxial%20strain%20along%20the%20c-axis%20associated%20with%20the%20difference%20in%20A.%20However%2C%20the%20influence%20of%20the%20A%20ion%20differs%20between%20the%20R%20and%20S%20blocks%20and%20the%20local%20strain%20also%20has%20a%20secondary%20effect%20on%20the%20Co%20distribution.%20Based%20on%20these%20results%2C%20the%20guidelines%20for%20improving%20the%20performance%20%28anisotropy%20and%20magnetisation%29%20of%20La-Co%20co-substituted%20M-type%20ferrite%20magnets%20with%20a%20limited%20amount%20of%20Co%20can%20be%20summarised%20as%20follows%3A%20It%20is%20effective%20to%20select%20as%20small%20A%20ions%20as%20possible%20and%20to%20post-anneal%20at%20low%20temperature%20or%20cool%20slowly%20to%20concentrate%20Co%20at%20the%204f%281%29%20site%20in%20tetrahedral%20coordination.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1088%5C%2F2515-7639%5C%2Fad3b6d%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1088%5C%2F2515-7639%5C%2Fad3b6d%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A09%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22C8CIYMUF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pakalni%5Cu0161kis%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Pakalni%26%23x161%3Bkis%2C%20G.%20Niaura%2C%20R.%20Ramanauskas%2C%20D.%20Karpinsky%2C%20G.%20Rogez%2C%20M.%20Lenertz%2C%20J.%20Robert%2C%20P.%20Rabu%2C%20S.-W.%20Chen%2C%20T.C.-K.%20Yang%2C%20R.%20Skaud%26%23x17E%3Bius%2C%20A.%20Kareiva%2C%20Temperature-driven%20magnetic%20and%20structural%20transitions%20in%20multiferroic%20Lu%281-x%29ScxFeO3%2C%20Journal%20of%20Alloys%20and%20Compounds%20972%20%282024%29%20172805.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2023.172805%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2023.172805%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Temperature-driven%20magnetic%20and%20structural%20transitions%20in%20multiferroic%20Lu%281-x%29ScxFeO3%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrius%22%2C%22lastName%22%3A%22Pakalni%5Cu0161kis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gediminas%22%2C%22lastName%22%3A%22Niaura%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Rimantas%22%2C%22lastName%22%3A%22Ramanauskas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dmitry%22%2C%22lastName%22%3A%22Karpinsky%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Rogez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Rabu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shih-Wen%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%20Chung-Kuang%22%2C%22lastName%22%3A%22Yang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ram%5Cu016bnas%22%2C%22lastName%22%3A%22Skaud%5Cu017eius%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aivaras%22%2C%22lastName%22%3A%22Kareiva%22%7D%5D%2C%22abstractNote%22%3A%22Novel%20metastable%20hexagonal%20Lu%281-x%29SxFeO3%20compounds%20were%20prepared%20by%20an%20ethylene%20glycol-based%20small%20molecule%20sol-gel%20synthesis%20route.%20Samples%20were%20investigated%20by%20means%20of%20XRD%2C%20Raman%20spectroscopy%2C%20XPS%2C%20SEM%20and%20magnetometry%20techniques.%20Based%20on%20the%20obtained%20data%20several%20different%20phase%20composition%20regions%20were%20discovered%20at%20room%20temperature%20depending%20on%20the%20Sc%20content.%20Three%20dominant%20phases%20were%20observed%20and%20denoted%20as%20the%20orthorhombic%20Pnma%2C%20hexagonal%20P63cm%2C%20and%20cubic%20Ia-3%20with%20the%20hexagonal%20phase%20being%20stable%20without%20any%20additional%20phases%20when%200.40%20%5Cu2264%20x%20%3C%200.65.%20Temperature%20dependent%20structural%20analysis%20allowed%20for%20the%20construction%20of%20the%20phase%20diagram%20which%20revealed%20that%20upon%20increasing%20Sc%20content%20the%20reversible%20polar%20to%20non-polar%20phase%20transition%20temperature%20can%20be%20decreased%20from%20above%201200%20%5Cu00b0C%20%28when%20x%20%3D%200.15%29%20to%20around%20800%20%5Cu00b0C%20%28x%20%3D%200.75%29.%20SEM%20analysis%20indicated%20a%20rapid%20reduction%20in%20particle%20size%20from%20%5Cu223c2.726%20%5Cu00b5m%20when%20x%20%3D%200%20down%20to%20%5Cu223c0.962%20%5Cu00b5m%20when%20x%20%3D%200.75%2C%20however%20in%20the%20case%20when%20x%20%3D%201%2C%20an%20increase%20in%20particle%20size%20was%20observed.%20XPS%20analysis%20confirmed%20the%20elemental%20composition%20and%20its%20changes%20as%20well%20as%20the%20stability%20of%20the%203%20%2B%20oxidation%20state%20of%20the%20iron%20ions.%20Magnetization%20measurements%20confirmed%20a%20non-zero%20room%20temperature%20magnetization%20as%20well%20as%20the%20spin%20reorientation%20transitions%20whose%20critical%20temperatures%20TN%20increases%20from%20156%20K%20%28x%20%3D%200.25%29%20to%20170%20K%20%28x%20%3D%200.75%29.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2023.172805%22%2C%22ISSN%22%3A%220925-8388%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0925838823041087%22%2C%22collections%22%3A%5B%22M244N6AF%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%5D%2C%22dateModified%22%3A%222024-04-29T14%3A36%3A02Z%22%7D%7D%2C%7B%22key%22%3A%22SCK3BK65%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Parker%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.A.%20Parker%2C%20M.L.%20De%20Marco%2C%20A.%20Castro-Grijalba%2C%20A.%20Ghoridi%2C%20D.%20Portehault%2C%20S.%20Pechev%2C%20E.A.%20Hillard%2C%20S.%20Lacomme%2C%20A.%20Bessiere%2C%20F.%20Cunin%2C%20P.%20Rosa%2C%20M.%20Gonidec%2C%20G.L.%20Drisko%2C%20Size-tunable%20silicon%20nanoparticles%20synthesized%20in%20solution%20via%20a%20redox%20reaction%2C%20Nanoscale%2016%20%282024%29%207958%26%23x2013%3B7964.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd3nr05793c%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd3nr05793c%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Size-tunable%20silicon%20nanoparticles%20synthesized%20in%20solution%20via%20a%20redox%20reaction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Megan%20A.%22%2C%22lastName%22%3A%22Parker%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Letizia%22%2C%22lastName%22%3A%22De%20Marco%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexander%22%2C%22lastName%22%3A%22Castro-Grijalba%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anissa%22%2C%22lastName%22%3A%22Ghoridi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Portehault%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stanislav%22%2C%22lastName%22%3A%22Pechev%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elizabeth%20A.%22%2C%22lastName%22%3A%22Hillard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sabrina%22%2C%22lastName%22%3A%22Lacomme%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aurelie%22%2C%22lastName%22%3A%22Bessiere%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frederique%22%2C%22lastName%22%3A%22Cunin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Rosa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathieu%22%2C%22lastName%22%3A%22Gonidec%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Glenna%20L.%22%2C%22lastName%22%3A%22Drisko%22%7D%5D%2C%22abstractNote%22%3A%22A%20current%20challenge%20in%20silicon%20chemistry%20is%20to%20perform%20liquid-phase%20synthesis%20of%20silicon%20nanoparticles%2C%20which%20would%20permit%20the%20use%20of%20colloidal%20synthesis%20techniques%20to%20control%20size%20and%20shape.%20Herein%20we%20show%20how%20silicon%20nanoparticles%20were%20synthesized%20at%20ambient%20temperature%20and%20pressure%20in%20organic%20solvents%20through%20a%20redox%20reaction.%20Specifically%2C%20a%20hexacoordinated%20silicon%20complex%2C%20bis%28N%2CN%27-diisopropylbutylamidinato%29dichlorosilane%2C%20was%20reduced%20by%20a%20silicon%20Zintl%20phase%2C%20sodium%20silicide%20%28Na4Si4%29.%20The%20resulting%20silicon%20nanoparticles%20were%20crystalline%20with%20sizes%20tuned%20from%20a%20median%20particle%20diameter%20of%2015%20nm%20to%2045%20nm%20depending%20on%20the%20solvent.%20Photoluminescence%20measurements%20performed%20on%20colloidal%20suspensions%20of%20the%2045%20nm%20diameter%20silicon%20nanoparticles%20indicated%20a%20blue%20emission%20signal%2C%20attributed%20to%20the%20partial%20oxidation%20of%20the%20Si%20nanocrystals%20or%20to%20the%20presence%20of%20nitrogen%20impurities.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd3nr05793c%22%2C%22ISSN%22%3A%222040-3364%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd3nr05793c%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A14%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22FVJZPPVU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pena%20Corredor%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Pena%20Corredor%2C%20M.%20Gamarde%2C%20L.%20El%20Khabchi%2C%20M.J.V.%20Bernardez%2C%20M.%20Lenertz%2C%20C.%20Leuvrey%2C%20L.%20Schlur%2C%20F.%20Roulland%2C%20N.%20Viart%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20Room-temperature%20magnetism%20and%20controlled%20cation%20distribution%20in%20vanadium%20ferrite%20thin%20films%2C%20Materials%20Chemistry%20and%20Physics%20314%20%282024%29%20128856.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2023.128856%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2023.128856%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Room-temperature%20magnetism%20and%20controlled%20cation%20distribution%20in%20vanadium%20ferrite%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Pena%20Corredor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthieu%22%2C%22lastName%22%3A%22Gamarde%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lamiae%22%2C%22lastName%22%3A%22El%20Khabchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Jose%20Vazquez%22%2C%22lastName%22%3A%22Bernardez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%5D%2C%22abstractNote%22%3A%22Spinel%20oxides%20demonstrate%20significant%20technological%20promise%20due%20to%20the%20vast%20array%20of%20interrelated%20physical%20properties%20that%20their%20unique%20structure%20supports.%20Specifically%2C%20the%20Fe1%2BxV2-xO4%20spinel%20system%20garners%20extensive%20interest%20due%20to%20the%20presence%20of%20orbitally%20ordered%20states%20and%20multiferroism.%20This%20study%20focuses%20on%20the%20elaboration%20of%20high-quality%20Fe2VO4%20%28x%20%3D%201%29%20thin%20films%20on%20MgO%20substrates%20via%20pulsed%20laser%20deposition%20from%20a%20bulk%20ceramic%20target.%20X-ray%20diffraction%20structural%20analyses%20confirm%20the%20epitaxial%20growth%20of%20the%20films%2C%20their%20high%20crystallinity%20and%20fully%20strained%20nature.%20The%20cationic%20distribution%20and%20stoichiometry%20were%20investigated%20using%20Resonant%20Elastic%20X-ray%20Scattering%20experiments%2C%20in%20conjunction%20with%20comprehensive%20characterization%20of%20the%20films%27%20magnetic%20and%20electrical%20properties.%20The%20films%20exhibit%20room-temperature%20magnetism%2C%20with%20a%20magnetization%20consistent%20with%20the%20%28Fe3%2B%29Td%5BFe2%2BV3%2B%202%20%5DOhO4%20inverse%20spinel%20structure%20unveiled%20by%20anomalous%20diffraction.%20This%20work%20represents%20the%20inaugural%20successful%20deposition%20of%20Fe2VO4%20thin%20films%2C%20thereby%20expanding%20the%20family%20of%20spinel%20vanadium%20oxide%20thin%20films%20with%20a%20new%20member%20that%20demonstrates%20room-temperature%20magnetic%20properties.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.matchemphys.2023.128856%22%2C%22ISSN%22%3A%220254-0584%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.matchemphys.2023.128856%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A27Z%22%7D%7D%2C%7B%22key%22%3A%225FAESGGL%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Przydacz%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Przydacz%2C%20M.%20Jedrzejczyk%2C%20J.%20Rogowski%2C%20D.%20Ihiawakrim%2C%20N.%20Keller%2C%20A.M.%20Ruppert%2C%20TiO2%20supported%20non-noble%20Ni-Fe%20catalysts%20for%20the%20high%20yield%20production%20of%202%2C5-dimethylfuran%20biofuel%2C%20FUEL%20356%20%282024%29%20129606.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.fuel.2023.129606%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.fuel.2023.129606%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22TiO2%20supported%20non-noble%20Ni-Fe%20catalysts%20for%20the%20high%20yield%20production%20of%202%2C5-dimethylfuran%20biofuel%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martyna%22%2C%22lastName%22%3A%22Przydacz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcin%22%2C%22lastName%22%3A%22Jedrzejczyk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacek%22%2C%22lastName%22%3A%22Rogowski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Agnieszka%20M.%22%2C%22lastName%22%3A%22Ruppert%22%7D%5D%2C%22abstractNote%22%3A%22The%20establishment%20of%20the%20future%20biorefinery%20schemes%20requires%20the%20sustainable%20conversion%20and%20valorisation%20of%20renewable%20bioresources%20into%20eco-friendly%20fuels%20and%20chemicals.%20To%20this%20end%2C%202%2C5-dimethylfuran%20%28DMF%29%20is%20a%20promising%20biofuel%20competitive%20to%20benchmarks%20like%20ethanol%20due%20to%20high-value%20intrinsic%20properties.%20It%20can%20be%20produced%20by%20the%20catalytic%20hydrogenation%20of%20the%205-hydroxymethylfurfural%20%28HMF%29%20platform%20molecule%2C%20one%20of%20the%20biobased%20intermediate%20chemicals%20derived%20from%20the%20abundant%20lignocellulosic%20biomass.%20We%20evidenced%20that%20bimetallic%20NiFe%20alloys%20supported%20on%20TiO2%20are%20earth-abundant%20non-noble%20metal-based%20catalysts%20allowing%20the%20high%20yield%20production%20of%20DMF%20to%20be%20achieved.%20We%20showed%20that%20the%20preparation%20method%20and%20the%20reduction%20temperature%20of%20the%20catalyst%20are%20of%20prime%20importance%2C%20and%20are%20directly%20influencing%20the%20structure%20of%20the%20supported%20NiFe%20bimetallic%20particles%20and%20in%20consequence%20the%20catalyst%20behaviour.%20The%20highest%20yield%20to%20DMF%20is%20obtained%20on%20a%20catalyst%20prepared%20by%20co-impregnation%20and%20reduced%20at%20500%20degrees%20C%2C%20that%20features%20an%20unperfect%20core%5C%2Fshell%20structure%20of%20the%20NiFe%20alloy%2C%20with%20a%20partial%20Fe%20shell%20surrounding%20an%20Fe-enriched%20Ni%20core.%20The%20key-feature%20necessary%20for%20achieving%20high%20performance%20lies%20on%20the%20surface%20structure%20of%20the%20NiFe%20alloy%20that%20allows%20for%20an%20optimum%20availability%20of%20highly%20active%20Ni%20domains.%20The%20Ni%20atoms%20were%20maintained%20highly%20dispersed%20by%20the%20presence%20of%20Fe-containing%20surface%20phases.%20The%20specific%20surface%20structure%20is%20proposed%20to%20promote%20the%20HMF%20adsorption%20through%20the%20carbonyl%20group%2C%20while%20preventing%20from%20the%20hydrogenation%20of%20the%20aromatic%20furan%20ring%20to%20maintain%20high%20selectivity.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.fuel.2023.129606%22%2C%22ISSN%22%3A%220016-2361%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.fuel.2023.129606%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%5D%2C%22dateModified%22%3A%222023-11-17T16%3A23%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22UWPRMLWS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Roslawska%20and%20Schull%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Roslawska%2C%20G.%20Schull%2C%20Photo-induced%20chemistry%20with%20sub-molecular%20resolution%2C%20Nature%20Nanotechnology%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41565-024-01623-3%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41565-024-01623-3%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Photo-induced%20chemistry%20with%20sub-molecular%20resolution%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Roslawska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Schull%22%7D%5D%2C%22abstractNote%22%3A%22By%20confining%20and%20concentrating%20light%20in%20a%20nanometric%20volume%20at%20the%20apex%20of%20a%20metallic%20tip%2C%20sub-molecule-scale%20control%20of%20a%20basic%20photochemical%20reaction%20-%20phototautomerization%20-%20is%20now%20shown%20to%20be%20possible.%20Applicable%20to%20other%20photo-induced%20reactions%2C%20this%20technique%20signals%20a%20new%20strategy%20for%20the%20synthesis%20of%20complex%20molecules%20on%20surfaces.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41565-024-01623-3%22%2C%22ISSN%22%3A%221748-3387%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41565-024-01623-3%22%2C%22collections%22%3A%5B%229USMFXMV%22%2C%22DEB5KWFS%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A14%3A42Z%22%7D%7D%2C%7B%22key%22%3A%22X5MDR2SK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Roslawska%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Roslawska%2C%20K.%20Kaiser%2C%20M.%20Romeo%2C%20E.%20Devaux%2C%20F.%20Scheurer%2C%20S.%20Berciaud%2C%20T.%20Neuman%2C%20G.%20Schull%2C%20Submolecular-scale%20control%20of%20phototautomerization.%2C%20Nature%20Nanotechnology%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41565-024-01622-4%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41565-024-01622-4%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Submolecular-scale%20control%20of%20phototautomerization.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Roslawska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Katharina%22%2C%22lastName%22%3A%22Kaiser%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michelangelo%22%2C%22lastName%22%3A%22Romeo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eloise%22%2C%22lastName%22%3A%22Devaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Scheurer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Berciaud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomas%22%2C%22lastName%22%3A%22Neuman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Schull%22%7D%5D%2C%22abstractNote%22%3A%22Optically%20activated%20reactions%20initiate%20biological%20processes%20such%20as%20photosynthesis%20or%20vision%2C%20but%20can%20also%20control%20polymerization%2C%20catalysis%20or%20energy%20conversion.%20Methods%20relying%20on%20the%20manipulation%20of%20light%20at%20macroscopic%20and%20mesoscopic%20scales%20are%20used%20to%20control%20on-surface%20photochemistry%2C%20but%20do%20not%20offer%20atomic-scale%20control.%20Here%20we%20take%20advantage%20of%20the%20confinement%20of%20the%20electromagnetic%20field%20at%20the%20apex%20of%20a%20scanning%20tunnelling%20microscope%20tip%20to%20drive%20the%20phototautomerization%20of%20a%20free-base%20phthalocyanine%20with%20submolecular%20precision.%20We%20can%20control%20the%20reaction%20rate%20and%20the%20relative%20tautomer%20population%20through%20a%20change%20in%20the%20laser%20excitation%20wavelength%20or%20through%20the%20tip%20position.%20Atomically%20resolved%20tip-enhanced%20photoluminescence%20spectroscopy%20and%20hyperspectral%20mapping%20unravel%20an%20excited-state%20mediated%20process%2C%20which%20is%20quantitatively%20supported%20by%20a%20comprehensive%20theoretical%20model%20combining%20ab%20initio%20calculations%20with%20a%20parametric%20open-quantum-system%20approach.%20Our%20experimental%20strategy%20may%20allow%20insights%20in%20other%20photochemical%20reactions%20and%20proof%20useful%20to%20control%20complex%20on-surface%20reactions.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41565-024-01622-4%22%2C%22ISSN%22%3A%221748-3395%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41565-024-01622-4%22%2C%22collections%22%3A%5B%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22KYKXGQVF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sancey%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20Sancey%2C%20Y.%20Corvis%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20N.%20Tsapis%2C%20A%20special%20issue%20dedicated%20to%20the%202022%20meeting%20of%20the%20French%20society%20for%20nanomedicine.%2C%20International%20Journal%20of%20Pharmaceutics%20654%20%282024%29%20124006.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.ijpharm.2024.124006%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.ijpharm.2024.124006%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20special%20issue%20dedicated%20to%20the%202022%20meeting%20of%20the%20French%20society%20for%20nanomedicine.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lucie%22%2C%22lastName%22%3A%22Sancey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yohann%22%2C%22lastName%22%3A%22Corvis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Tsapis%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.ijpharm.2024.124006%22%2C%22ISSN%22%3A%221873-3476%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.ijpharm.2024.124006%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22UBUT97QT%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A10%3A45Z%22%7D%7D%2C%7B%22key%22%3A%223WG7CN7Y%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sartori%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.%20Sartori%2C%20R.%20Lopez-Martin%2C%20F.%20Choueikani%2C%20A.%20Gloter%2C%20J.-M.%20Greneche%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20D.%20Taverna%2C%20J.A.%20De%20Toro%2C%20B.P.%20Pichon%2C%20Magnetic%20anisotropy%20engineering%20in%20onion-structured%20metal%20oxide%20nanoparticles%20combining%20dual%20exchange%20coupling%20and%20proximity%20effects%2C%20Nanoscale%20Advances%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd3na01108a%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd3na01108a%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetic%20anisotropy%20engineering%20in%20onion-structured%20metal%20oxide%20nanoparticles%20combining%20dual%20exchange%20coupling%20and%20proximity%20effects%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kevin%22%2C%22lastName%22%3A%22Sartori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Raul%22%2C%22lastName%22%3A%22Lopez-Martin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fadi%22%2C%22lastName%22%3A%22Choueikani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Gloter%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dario%22%2C%22lastName%22%3A%22Taverna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jose%20A.%22%2C%22lastName%22%3A%22De%20Toro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%5D%2C%22abstractNote%22%3A%22A%20series%20of%20exchange-coupled%20magnetic%20nanoparticles%20combining%20several%20magnetic%20phases%20in%20an%20onion-type%20structure%20were%20synthesized%20by%20performing%20a%20three-step%20seed-mediated%20growth%20process.%20Iron%20and%20cobalt%20precursors%20were%20alternatively%20decomposed%20in%20high-boiling-temperature%20solvents%20%28288-310%20degrees%20C%29%20to%20successively%20grow%20CoO%20and%20Fe3-delta%20O4%20shells%20%28the%20latter%20in%20three%20stages%29%20on%20the%20surface%20of%20Fe3-delta%20O4%20seeds.%20The%20structure%20and%20chemical%20composition%20of%20these%20nanoparticles%20were%20investigated%20in%20depth%20by%20combining%20a%20wide%20panel%20of%20advanced%20techniques%2C%20such%20as%20scanning%20transmission%20electron%20microscopy%20%28STEM%29%2C%20electron%20energy-loss%20spectroscopy-spectrum%20imaging%20%28EELS-SI%29%2C%2057Fe%20M%20%26%20ouml%3Bssbauer%20spectrometry%2C%20and%20X-ray%20circular%20magnetic%20dichroism%20%28XMCD%29%20techniques.%20The%20size%20of%20the%20nanoparticles%20increased%20progressively%20after%20each%20thermal%20decomposition%20step%2C%20but%20the%20crystal%20structure%20of%20core-shell%20nanoparticles%20was%20significantly%20modified%20during%20the%20growth%20of%20the%20second%20shell.%20Indeed%2C%20the%20antiferromagnetic%20CoO%20phase%20was%20progressively%20replaced%20by%20the%20CoFe2O4%20ferrimagnet%20due%20to%20the%20concomitant%20processes%20of%20partial%20solubilization%5C%2Fcrystallization%20and%20the%20interfacial%20cationic%20diffusion%20of%20iron.%20A%20much%20more%20complex%20chemical%20structure%20than%20that%20suggested%20by%20a%20simple%20size%20variation%20of%20the%20nanoparticles%20is%20thus%20proposed%2C%20namely%20Fe3-delta%20O4%40CoO-CoFe2O4%40Fe3-delta%20O4%2C%20where%20an%20intermediate%20Co-based%20layer%20was%20shown%20to%20progressively%20become%20a%20single%2C%20hybrid%20magnetic%20phase%20%28attributed%20to%20proximity%20effects%29%20with%20a%20reduction%20in%20the%20CoO%20amount.%20In%20turn%2C%20the%20dual%20exchange-coupling%20of%20this%20hybrid%20Co-based%20intermediate%20layer%20%28with%20high%20anisotropy%20and%20ordering%20temperature%29%20with%20the%20surrounding%20ferrite%20%28core%20and%20outer%20shells%29%20stabilized%20the%20particle%20moment%20well%20above%20room%20temperature.%20These%20effects%20allow%20for%20the%20production%20of%20Fe%20oxide-based%20magnetic%20nanoparticles%20with%20high%20effective%20anisotropy%2C%20thus%20revealing%20the%20potential%20of%20this%20strategy%20to%20design%20rare-earth-free%20permanent%20nanomagnets%20at%20room%20temperature.%20A%20series%20of%20exchange-coupled%20magnetic%20nanoparticles%20combining%20several%20magnetic%20phases%20in%20an%20onion-type%20structure%20were%20synthesized%20by%20performing%20a%20three-step%20seed-mediated%20growth%20process.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd3na01108a%22%2C%22ISSN%22%3A%222516-0230%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd3na01108a%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22UBUT97QT%22%2C%227T9UG4M4%22%5D%2C%22dateModified%22%3A%222024-05-07T12%3A09%3A40Z%22%7D%7D%2C%7B%22key%22%3A%22PV2VEHG9%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Temdie%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20Temdie%2C%20V.%20Castel%2C%20V.%20Vlaminck%2C%20M.B.%20Jungfleisch%2C%20R.%20Bernard%2C%20H.%20Majjad%2C%20D.%20Stoeffler%2C%20Y.%20Henry%2C%20M.%20Bailleul%2C%20Probing%20Spin%20Wave%20Diffraction%20Patterns%20of%20Curved%20Antennas%2C%20Physical%20Review%20Applied%2021%20%282024%29%20014032.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevApplied.21.014032%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevApplied.21.014032%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Probing%20Spin%20Wave%20Diffraction%20Patterns%20of%20Curved%20Antennas%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Temdie%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Castel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Vlaminck%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%20B.%22%2C%22lastName%22%3A%22Jungfleisch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Romain%22%2C%22lastName%22%3A%22Bernard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hicham%22%2C%22lastName%22%3A%22Majjad%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniel%22%2C%22lastName%22%3A%22Stoeffler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yves%22%2C%22lastName%22%3A%22Henry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthieu%22%2C%22lastName%22%3A%22Bailleul%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20on%20the%20dependence%20of%20curvilinear%20-shaped%20coplanar%20waveguides%20on%20the%20near%20-field%20diffraction%20%28NFD%29%20patterns%20of%20spin%20waves%20propagating%20in%20perpendicularly%20magnetized%20thin%20films.%20Implementing%20the%20propagating%20spin%20-wave%20spectroscopy%20techniques%20on%20either%20concentrically%20or%20eccentrically%20shaped%20antennas%2C%20we%20show%20how%20the%20link%20budget%20is%20directly%20affected%20by%20the%20spin%20-wave%20interference%2C%20in%20good%20agreement%20with%20NFD%20simulations.%20This%20work%20demonstrates%20the%20feasibility%20of%20inductively%20probing%20a%20magnon%20interference%20pattern%20with%20a%20resolution%20down%20to%201%20mu%20m2%2C%20and%20provides%20a%20methodology%20for%20shaping%20spin%20-wave%20beams%20from%20an%20antenna%20design.%20This%20methodology%20is%20successfully%20implemented%20in%20the%20case%20study%20of%20a%20spin%20-wave%20Young%27s%20interference%20experiment.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevApplied.21.014032%22%2C%22ISSN%22%3A%222331-7019%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevApplied.21.014032%22%2C%22collections%22%3A%5B%22QK933HES%22%2C%22UJZN2BUR%22%2C%22UVN4N32C%22%2C%222A2F8AAB%22%2C%22N8397DCZ%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A34Z%22%7D%7D%2C%7B%22key%22%3A%2284XWQGQY%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thakkar%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.V.%20Thakkar%2C%20T.%20Nabiyeva%2C%20Q.%20Weinbach%2C%20H.%20Bhatia%2C%20Z.%20Liu%2C%20T.%20Fert%26%23xE9%3B%2C%20C.%20Leuvrey%2C%20A.%20Carvalho%2C%20B.C.%20Schroeder%2C%20L.%20Biniek%2C%20N-type%20thermoelectric%20bulk%20composite%20based%20on%20poly%20%28nickel-ethylenetetrathiolate%29%3A%20The%20positive%20effect%20of%20porosity%20on%20decreasing%20thermal%20conductivity%2C%20Polymer%20296%20%282024%29%20126761.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.polymer.2024.126761%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.polymer.2024.126761%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22N-type%20thermoelectric%20bulk%20composite%20based%20on%20poly%20%28nickel-ethylenetetrathiolate%29%3A%20The%20positive%20effect%20of%20porosity%20on%20decreasing%20thermal%20conductivity%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Swapneel%20Vijay%22%2C%22lastName%22%3A%22Thakkar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Turkan%22%2C%22lastName%22%3A%22Nabiyeva%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Quentin%22%2C%22lastName%22%3A%22Weinbach%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Harsh%22%2C%22lastName%22%3A%22Bhatia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zilu%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tom%22%2C%22lastName%22%3A%22Fert%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alain%22%2C%22lastName%22%3A%22Carvalho%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bob%20C.%22%2C%22lastName%22%3A%22Schroeder%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laure%22%2C%22lastName%22%3A%22Biniek%22%7D%5D%2C%22abstractNote%22%3A%22Recent%20progress%20in%20the%20research%20of%20n%20-type%20materials%20for%20organic%20thermoelectrics%20has%20drawn%20the%20attention%20to%20the%20metal%20coordination%20polymer%20poly%28nickel-ethylenetetrathiolate%29%20%28poly%28Ni-ett%29%29.%20These%20polymers%20have%20excellent%20stability%20in%20air%20because%20their%20backbone%20structure%20is%20composed%20of%20air%20-stable%20ligands%20and%20exhibit%20good%20electronic%20properties%20when%20pressed%20into%20pellets%20or%20grown%20into%20crystals.%20However%2C%20due%20to%20their%20brittle%20nature%20and%20limited%20solubility%2C%20they%20are%20often%20blended%20with%20solution%20processable%20but%20electrically%20insulating%20polymers%20to%20produce%20composite%20films.%20Herein%2C%20we%20demonstrate%20the%20possibility%20of%20exploiting%20the%203D%20structuring%20ability%20of%20a%20polymer%20scaffolding%20matrix%20%28based%20on%20polyvinylidene%20fluoride%20%28PVDF%29%29%20to%20fabricate%20porous%20bulk%20structures.%20Porosity%20is%20introduced%20to%20reduce%20the%20lattice%20contribution%20to%20the%20thermal%20conductivity%20and%20used%20as%20a%20lever%20to%20increase%20the%20thermoelectric%20efficiency%20of%20the%20composite%20aerogel%20poly%28Ni-ett%29%3A%20PVDF.%20For%20practical%20applications%2C%20these%20materials%20have%20great%20potential%20for%20vertical%20thermoelectric%20generators%2C%20as%20the%20low%20thermal%20conductivity%20and%20millimetre%20-thick%20samples%20would%20allow%20a%20thermal%20gradient%20to%20be%20maintained%20across%20it%20%28without%20actively%20cooling%20one%20side%2C%20as%20in%20the%20case%20of%20certain%20thin-film%20technologies%29.%20In%20this%20manuscript%2C%20we%20present%20an%20original%20approach%20for%20the%20fabrication%20of%20novel%20n%20-type%20polymer%20aerogels%20resulting%20in%20lightweight%20and%20bulk%20size%20thermoelectric%20materials.%20The%20composite%20aerogels%20exhibit%20a%20low%20thermal%20conductivity%20of%2052%20mW%20m-1%20K-1%2C%20and%20their%20figure%20of%20merit%20zT%20is%20comparable%20to%20the%20dense%20neat%20pellet%20with%20reasonable%20stability%20over%20six%20months.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.polymer.2024.126761%22%2C%22ISSN%22%3A%220032-3861%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.polymer.2024.126761%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22MKAFAH44%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A15%3A36Z%22%7D%7D%2C%7B%22key%22%3A%22EJIQ7DCY%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20J.%20Frey%2C%20Y.%20Geiger%2C%20S.%20Bellemin-Laponnaz%2C%20Les%20effets%20non%20lin%26%23xE9%3Baires%20en%20catalyse%20asym%26%23xE9%3Btrique%2C%20L%26%23x2019%3Bactualit%26%23xE9%3B%20Chimique%20%282024%29%2040%26%23x2013%3B49.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fnew.societechimiquedefrance.fr%5C%2Fnumero%5C%2Fles-effets-non-lineaires-en-catalyse-asymetrique-p40-n491%5C%2F%27%3Ehttps%3A%5C%2F%5C%2Fnew.societechimiquedefrance.fr%5C%2Fnumero%5C%2Fles-effets-non-lineaires-en-catalyse-asymetrique-p40-n491%5C%2F%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22magazineArticle%22%2C%22title%22%3A%22Les%20effets%20non%20lin%5Cu00e9aires%20en%20catalyse%20asym%5Cu00e9trique%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Frey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yannick%22%2C%22lastName%22%3A%22Geiger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22St%5Cu00e9phane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22french%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fnew.societechimiquedefrance.fr%5C%2Fnumero%5C%2Fles-effets-non-lineaires-en-catalyse-asymetrique-p40-n491%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A37Z%22%7D%7D%2C%7B%22key%22%3A%22IX7URXAS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20Y.%20Geiger%2C%20S.%20Bellemin-Laponnaz%2C%20Divergence%20of%20catalytic%20systems%20in%20the%20zinc-catalysed%20alkylation%20of%20benzaldehyde%20mediated%20by%20chiral%20proline-based%20ligands%2C%20Nature%20Synthesis%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs44160-024-00491-y%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs44160-024-00491-y%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Divergence%20of%20catalytic%20systems%20in%20the%20zinc-catalysed%20alkylation%20of%20benzaldehyde%20mediated%20by%20chiral%20proline-based%20ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yannick%22%2C%22lastName%22%3A%22Geiger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22Asymmetric%20catalysis%20has%20expanded%20the%20range%20of%20chiral%20products%20readily%20accessible%20through%20increasingly%20efficient%20synthetic%20catalysts.%20The%20development%20of%20these%20catalysts%20often%20starts%20with%20a%20result%20obtained%20by%20systematic%20screening%20of%20known%20privileged%20chiral%20structures%20and%20assumes%20that%20the%20active%20species%20would%20be%20an%20isolated%20monomolecular%20species.%20Here%20we%20report%20the%20study%20of%20three%20proline-derived%20ligands%2C%20diphenyl-N-methyl-prolinol%2C%20diphenylprolinol%20and%205-%28hydroxydiphenylmethyl%29-2-pyrrolidinone%2C%20in%20the%20zinc-catalysed%20alkylation%20of%20benzaldehyde.%20The%20three%20ligands%20exhibit%20different%20system-level%20behaviour%2C%20characterized%20by%20multiple%20levels%20of%20aggregation%20that%20may%20be%20catalytically%20active%20simultaneously.%20While%20diphenyl-N-methyl-prolinol%20behaves%20as%20expected%20from%20a%20mechanistic%20point%20of%20view%2C%20diphenylprolinol%20shows%20enantiodivergence%20during%20the%20reaction%20due%20to%20an%20asymmetric%20autoinduction%20process.%20With%205-%28hydroxydiphenylmethyl%29-2-pyrrolidinone%2C%20we%20were%20able%20to%20establish%20the%20possibility%20of%20at%20least%20trimeric%20active%20species%20in%20equilibrium%20with%20less%20aggregated%20active%20species.%20Simulations%20using%20a%20mathematical%20model%20confirm%20the%20possibility%20of%20such%20systems-level%20behaviour.%20Parallel%20study%20of%20the%20three%20systems%20reveals%20three%20distinct%20system-level%20behaviours%20that%20are%20central%20to%20the%20efficiency%20of%20the%20catalytic%20reaction.Three%20closely%20related%20proline-based%20ligands%20give%20rise%20to%20different%20catalytic%20systems%20in%20asymmetric%20dialkylzinc%20addition%20reactions.%20Mechanistic%20studies%20reveal%20that%20monomeric%2C%20dimeric%20and%20product-catalyst%20complexes%20and%20aggregates%20larger%20than%20dimers%20are%20all%20catalytically%20active.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs44160-024-00491-y%22%2C%22ISSN%22%3A%222731-0582%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs44160-024-00491-y%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A14%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22ZZEQIZ86%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20V.%20Giuso%2C%20F.%20Polo%2C%20P.%20Mercandelli%2C%20Y.-T.%20Chen%2C%20C.-H.%20Chang%2C%20M.%20Mauro%2C%20S.%20Bellemin-Laponnaz%2C%20A%20stable%20and%20true-blue%20emissive%20hexacoordinate%20Si%28iv%29%20N-heterocyclic%20carbene%20complex%20and%20its%20use%20in%20organic%20light-emitting%20diodes%2C%20Dalton%20Transactions%2053%20%282024%29%206445%26%23x2013%3B6450.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4dt00420e%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4dt00420e%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20stable%20and%20true-blue%20emissive%20hexacoordinate%20Si%28iv%29%20N-heterocyclic%20carbene%20complex%20and%20its%20use%20in%20organic%20light-emitting%20diodes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Giuso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierluigi%22%2C%22lastName%22%3A%22Mercandelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yi-Ting%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chih-Hao%22%2C%22lastName%22%3A%22Chang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22A%20neutral%20hexacoordinate%20Si%28iv%29%20complex%20containing%20two%20tridentate%20N-heterocyclic%20carbene%20ligands%20is%20synthesised%20and%20characterized%20by%20X-ray%20crystallography%2C%20optical%20spectroscopy%2C%20electrochemistry%20and%20computational%20methods.%20The%20stable%20compound%20exhibits%20remarkable%20deep-blue%20photoluminescence%20particularly%20in%20the%20solid%20state%2C%20which%20enables%20its%20use%20as%20an%20electroluminescent%20material%20in%20organic%20light-emitting%20diodes.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4dt00420e%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4dt00420e%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A09%3A25Z%22%7D%7D%2C%7B%22key%22%3A%222CC9BYQK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Xi%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EQ.%20Xi%2C%20V.%20Papaefthimiou%2C%20N.%20Le%20Breton%2C%20M.%20Lenertz%2C%20M.%20Takashima%2C%20V.%20Keller%2C%20B.%20Vileno%2C%20T.%20Cottineau%2C%20Influence%20of%20Nitridation%20Conditions%20on%20the%20Doping%20Sites%20and%20Photocatalytic%20Visible%20Light%20Activity%20of%20Nb%2CN-Codoped%20TiO2%2C%20Chemistry%20of%20Materials%2036%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.3c03280%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.3c03280%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Influence%20of%20Nitridation%20Conditions%20on%20the%20Doping%20Sites%20and%20Photocatalytic%20Visible%20Light%20Activity%20of%20Nb%2CN-Codoped%20TiO2%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Qingyang%22%2C%22lastName%22%3A%22Xi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vasiliki%22%2C%22lastName%22%3A%22Papaefthimiou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nolwenn%22%2C%22lastName%22%3A%22Le%20Breton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mai%22%2C%22lastName%22%3A%22Takashima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerie%22%2C%22lastName%22%3A%22Keller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Vileno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Cottineau%22%7D%5D%2C%22abstractNote%22%3A%22The%20photocatalytic%20performance%20of%20Nb%2CN-codoped%20TiO2%20nanoparticles%20obtained%20via%20the%20sol-gel%20method%20was%20compared%20to%20that%20of%20N-doped%20TiO2.%20The%20study%20focused%20on%20investigating%20the%20effects%20of%20nitridation%20conditions%20on%20nitrogen%20insertion%20with%20a%20highlight%20on%20the%20nature%20of%20the%20doping%20sites%20in%20the%20photocatalyst%20depending%20on%20the%20initial%20presence%20of%20niobium%20in%20the%20TiO2.%20The%20photodegradation%20of%20methylene%20blue%20in%20solution%20under%20UV%2C%20visible%2C%20and%20simulated%20solar%20light%20was%20used%20to%20evaluate%20the%20photocatalytic%20activity%20of%20TiO2%2C%20Nb-%20or%20N-doped%20TiO2%2C%20and%20Nb%2CN-codoped%20TiO2%20nanoparticles.%20Codoped%20TiO2%20produced%20by%20mild%20thermal%20nitridation%20exhibits%20the%20best%20photocatalytic%20activity%2C%20with%20a%20strong%20contribution%20from%20visible%20light.%20On%20the%20contrary%2C%20the%20codoped%20TiO2%20produced%20by%20more%20intense%20thermal%20nitridation%20presents%20lower%20photocatalytic%20performances%20than%20TiO2%20despite%20a%20small%20improvement%20of%20activity%20in%20the%20visible%20range.%20In%20addition%20to%20material%20characterization%20%28X-ray%20diffraction%2C%20UV-vis%20spectroscopy%2C%20and%20X-ray%20photoelectron%20spectroscopy%29%2C%20electron%20paramagnetic%20resonance%20and%20reversed%20double-beam%20photoacoustic%20spectroscopy%20measurements%20were%20used%20to%20identify%20the%20respective%20doping%20sites%20and%20ultimately%20propose%20the%20electronic%20band%20structure%20for%20each%20sample%20of%20Nb%3ATiO2%2C%20N%3ATiO2%2C%20and%20Nb%2CN%3ATiO2.%20Proper%20thermal%20nitridation%20conditions%20improve%20the%20charge%20compensation%20between%20Nb5%2B%20and%20N3-%2C%20thereby%20enhancing%20the%20photocatalytic%20activity.%20However%2C%20too%20intense%20nitridation%20conditions%20led%20to%20the%20generation%20of%20oxygen%20vacancies%20and%20a%20large%20amount%20of%20Ti3%2B%20acting%20as%20charge%20recombination%20centers%2C%20resulting%20in%20significant%20deterioration%20of%20the%20photocatalytic%20performances.%20This%20study%20highlights%20the%20importance%20of%20understanding%20the%20intricate%20charge%20compensation%20process%20in%20codoped%20%28M%2CN%29%20TiO2%20materials%2C%20as%20the%20photocatalytic%20performance%20cannot%20be%20elucidated%20solely%20by%20the%20cation%5C%2Fanion%20ratio%20but%20also%20by%20considering%20the%20nature%20of%20the%20doping%20sites%20generated%20during%20synthesis.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.3c03280%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.chemmater.3c03280%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A07%3A51Z%22%7D%7D%2C%7B%22key%22%3A%222ZGN3HPY%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zahn%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Zahn%2C%20M.%20Pastore%2C%20J.L.P.%20Lustres%2C%20P.C.%20Gros%2C%20S.%20Haacke%2C%20K.%20Heyne%2C%20Femtosecond%20Infrared%20Spectroscopy%20Resolving%20the%20Multiplicity%20of%20High-Spin%20Crossover%20States%20in%20Transition%20Metal%20Iron%20Complexes.%2C%20Journal%20of%20the%20American%20Chemical%20Society%20146%20%282024%29%209347%26%23x2013%3B9355.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjacs.4c01637%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjacs.4c01637%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Femtosecond%20Infrared%20Spectroscopy%20Resolving%20the%20Multiplicity%20of%20High-Spin%20Crossover%20States%20in%20Transition%20Metal%20Iron%20Complexes.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clark%22%2C%22lastName%22%3A%22Zahn%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mariachiara%22%2C%22lastName%22%3A%22Pastore%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J%20Luis%20Perez%22%2C%22lastName%22%3A%22Lustres%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%20C%22%2C%22lastName%22%3A%22Gros%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stefan%22%2C%22lastName%22%3A%22Haacke%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Karsten%22%2C%22lastName%22%3A%22Heyne%22%7D%5D%2C%22abstractNote%22%3A%22Tuning%20the%20photophysical%20properties%20of%20iron-based%20transition-metal%20complexes%20is%20crucial%20for%20their%20employment%20as%20photosensitizers%20in%20solar%20energy%20conversion.%20For%20the%20optimization%20of%20these%20new%20complexes%2C%20a%20detailed%20understanding%20of%20the%20excited-state%20deactivation%20paths%20is%20necessary.%20Here%2C%20we%20report%20femtosecond%20transient%20mid-IR%20spectroscopy%20data%20on%20a%20recently%20developed%20octahedral%20ligand-field%20enhancing%20%5BFe%28dqp%292%5D2%2B%20%28C1%29%20complex%20with%20dqp%20%3D%202%2C6-diquinolylpyridine%20and%20prototypical%20%5BFe%28bpy%293%5D2%2B%20%28C0%29.%20By%20combining%20mid-IR%20spectroscopy%20with%20quantum%20chemical%20DFT%20calculations%2C%20we%20propose%20a%20method%20for%20disentangling%20the%205Q1%20and%203T1%20multiplicities%20of%20the%20long-lived%20metal-centered%20%28MC%29%20states%2C%20applicable%20to%20a%20variety%20of%20metal-organic%20iron%20complexes.%20Our%20results%20for%20C0%20align%20well%20with%20the%20established%20assignment%20toward%20the%205Q1%2C%20validating%20our%20approach.%20For%20C1%2C%20we%20find%20that%20deactivation%20of%20the%20initially%20excited%20metal-to-ligand%20charge-transfer%20state%20leads%20to%20a%20population%20of%20a%20long-lived%20MC%205Q1%20state.%20Analysis%20of%20transient%20changes%20in%20the%20mid-IR%20shows%20an%20ultrafast%20sub%20200%20fs%20rearrangement%20of%20ligand%20geometry%20for%20both%20complexes%2C%20accompanying%20the%20MLCT%20%20MC%20deactivation.%20This%20confirms%20that%20the%20flexibility%20in%20the%20ligand%20sphere%20supports%20the%20stabilization%20of%20high%20spin%20states%20and%20plays%20a%20crucial%20role%20in%20the%20MLCT%20lifetime%20of%20metal-organic%20iron%20complexes.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Fjacs.4c01637%22%2C%22ISSN%22%3A%221520-5126%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fjacs.4c01637%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%2295EJ8IDX%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A11%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22WJYXUXS6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zeng%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.-Y.%20Zeng%2C%20W.-J.%20Deng%2C%20K.-Q.%20Zhao%2C%20C.%20Redshaw%2C%20B.%20Donnio%2C%20Phenanthrothiophene-Triazine%20Star-Shaped%20Discotic%20Liquid%20Crystals%3A%20Synthesis%2C%20Self-Assembly%2C%20and%20Stimuli-Responsive%20Fluorescence%20Properties%2C%20Chemistry-a%20European%20Journal%20%282024%29%20e202400296.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202400296%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202400296%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Phenanthrothiophene-Triazine%20Star-Shaped%20Discotic%20Liquid%20Crystals%3A%20Synthesis%2C%20Self-Assembly%2C%20and%20Stimuli-Responsive%20Fluorescence%20Properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chong-Yang%22%2C%22lastName%22%3A%22Zeng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wen-Jing%22%2C%22lastName%22%3A%22Deng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Carl%22%2C%22lastName%22%3A%22Redshaw%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22Lipophilic%20biphenylthiophene-%20and%20phenanthrothiophene-triazine%20compounds%2C%20BPTTn%20and%20CPTTn%2C%20respectively%2C%20were%20prepared%20by%20a%20tandem%20procedure%20involving%20successive%20Suzuki-Miyaura%20coupling%20and%20Scholl%20cyclodehydrogenation%20reactions.%20These%20compounds%20display%20photoluminescence%20in%20solution%20and%20in%20thin%20film%20state%2C%20solvatochromism%20with%20increasing%20solvent%27s%20polarity%2C%20as%20well%20as%20acidochromism%20and%20metal%20ion%20recognition%20stimuli-responsive%20fluorescence.%20Protonation%20of%20BPTT10%20and%20CPTT10%20by%20trifluoroacetic%20acid%20results%20in%20fluorescence%20quenching%2C%20which%20is%20reversibly%20restored%20once%20treated%20with%20triethylamine%20%28ON-OFF%20switch%29.%20DFT%20computational%20studies%20show%20that%20intramolecular%20charge%20transfer%20%28ICT%29%20phenomena%20occurs%20for%20both%20molecules%2C%20and%20reveal%20that%20protonation%20enhances%20the%20electron-withdrawing%20ability%20of%20the%20triazine%20core%20and%20reduces%20the%20band%20gap.%20This%20acidochromic%20behavior%20was%20applied%20to%20a%20prototype%20fluorescent%20anti-counterfeiting%20device.%20They%20also%20specifically%20recognize%20Fe3%2B%20through%20coordination%2C%20and%20the%20recognition%20mechanism%20is%20closely%20related%20to%20the%20photoinduced%20electron%20transfer%20between%20Fe3%2B%20and%20BPTT10%5C%2FCPTT10.%20CPTTn%20self-assemble%20into%20columnar%20rectangular%20%28Colrec%29%20mesophase%2C%20which%20can%20be%20modulated%20by%20oleic%20acid%20via%20the%20formation%20of%20a%20hydrogen-bonded%20supramolecular%20liquid%20crystal%20hexagonal%20Colhex%20mesophase.%20Finally%2C%20CPTTn%20also%20form%20organic%20gels%20in%20alkanes%20at%20low%20critical%20gel%20concentration%20%283.0%20mg%5C%2FmL%29.%20Therefore%2C%20these%20star-shaped%20triazine%20molecules%20possess%20many%20interesting%20features%20and%20thus%20hold%20great%20promises%20for%20information%20processing%2C%20liquid%20crystal%20semiconductors%20and%20organogelators.Triazine-based%20mesogens%20with%20three%20pending%20discoid%20arms%20have%20been%20shown%20to%20self-organize%20into%20rectangular%20columnar%20mesophases%20and%20form%20gels%20in%20various%20solvents.%20The%20solvatochromic-%2C%20acidochromic-%20and%20metal%20recognition-response%20photoluminescence%20of%20these%20mesogens%20offer%20applications%20in%20stimuli-responsive%20fluorescence%20anti-counterfeiting%20and%20as%20selective%20metal-ion%20recognition.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchem.202400296%22%2C%22ISSN%22%3A%220947-6539%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchem.202400296%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A08%3A22Z%22%7D%7D%2C%7B%22key%22%3A%22MAQSKNWN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zhang%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.-L.%20Zhang%2C%20W.-H.%20Yu%2C%20K.-Q.%20Zhao%2C%20P.%20Hu%2C%20B.-Q.%20Wang%2C%20B.%20Donnio%2C%20Mesomorphism%20Modulation%20of%20Perfluorinated%20Janus%20Triphenylenes%20by%20Inhomogeneous%20Chain%20Substitution%20Patterns%2C%20Chemistry-an%20Asian%20Journal%2019%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fasia.202301080%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fasia.202301080%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Mesomorphism%20Modulation%20of%20Perfluorinated%20Janus%20Triphenylenes%20by%20Inhomogeneous%20Chain%20Substitution%20Patterns%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kai-Li%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wen-Hao%22%2C%22lastName%22%3A%22Yu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ping%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bi-Qin%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22Two%20isomeric%20series%20of%20compounds%20with%20%5C%22inverted%5C%22%20chains%27%20substitution%20patterns%2C%207%2C10-dialkoxy-1%2C2%2C3%2C4-tetrafluoro-6%2C11-dimethoxytriphenylene%20and%206%2C11-dialkoxy-1%2C2%2C3%2C4-tetrafluoro-7%2C10-dimethoxytriphenylene%2C%20labelled%20respectively%20p-TPFn%20and%20m-TPFn%2C%20and%20two%20non-fluorinated%20homologous%20isomers%2C%203%2C6-dibutoxy-2%2C7-dimethoxytriphenylene%20and%202%2C7-dibutoxy-3%2C6-dimethoxytriphenylene%2C%20p-TP4%20and%20m-TP4%2C%20respectively%2C%20were%20synthesized%20in%20three%20steps%20and%20obtained%20in%20good%20yields%20by%20the%20efficient%20transition-metal-free%2C%20fluoroarene%20nucleophilic%20substitution%20via%20the%20reaction%20of%20appropriate%202%2C2%27-dilithium%20biphenylenes%20with%20either%20perfluorobenzene%2C%20C6F6%2C%20to%20yield%20p-TPFn%20and%20m-TPFn%2C%20or%20o-difluorobenzene%2C%20C6H4F2%2C%20for%20p-TP4%20and%20m-TP4%2C%20respectively.%20The%20single-crystal%20structures%20of%20p-TPF4%2C%20m-TPF4%20and%20p-TP4%2C%20unequivocally%20confirmed%20that%20the%20cyclization%20reactions%20occurred%20at%20the%20expected%20positions%2C%20and%20that%20the%20fluorinated%20molecules%20stack%20up%20into%20columns%20with%20short%20separation%2C%20a%20propitious%20situation%20for%20the%20emergence%20of%20columnar%20mesophases.%20The%20mesomorphous%20properties%20were%20found%20to%20be%20greatly%20affected%20by%20both%20chains%27%20length%20and%20positional%20isomerism%3A%20a%20Col%28hex%29%20phase%20is%20found%20for%20p-TPF4%20and%20m-TPF4%2C%20but%20mesomorphism%20vanishes%20in%20p-TP%3Cbold%3EF%3C%5C%2Fbold%3E6%2C%20and%20changes%20for%20the%20isomeric%20homologs%20m-TPFn%2C%20with%20the%20induction%20for%20n%20%3E%3D%206%20of%20a%20lamello-columnar%20phase%2C%20LamCol%28rec%29.%20As%20expected%2C%20both%20non-fluorinated%20compounds%20are%20deprived%20of%20mesomorphism.%20These%20compounds%20emit%20blue-violet%20colour%20in%20solution%2C%20independently%20of%20the%20chains%27%20substitution%20pattern%2C%20and%20the%20absolute%20fluorescence%20quantum%20yields%20can%20reach%20up%20to%2046%20%25.%20In%20thin%20films%2C%20fluorescence%20is%20slightly%20redshifted.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fasia.202301080%22%2C%22ISSN%22%3A%221861-4728%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fasia.202301080%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T13%3A06%3A40Z%22%7D%7D%2C%7B%22key%22%3A%225V479VAZ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zhou%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EY.%20Zhou%2C%20S.%20Santos%2C%20M.%20Shamzhy%2C%20M.%20Marinova%2C%20A.-M.%20Blanchenet%2C%20Y.G.%20Kolyagin%2C%20P.%20Simon%2C%20M.%20Trentesaux%2C%20S.%20Sharna%2C%20O.%20Ersen%2C%20V.L.%20Zholobenko%2C%20M.%20Saeys%2C%20A.Y.%20Khodakov%2C%20V.V.%20Ordomsky%2C%20Liquid%20metals%20for%20boosting%20stability%20of%20zeolite%20catalysts%20in%20the%20conversion%20of%20methanol%20to%20hydrocarbons%2C%20Nature%20Communications%2015%20%282024%29%202228.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41467-024-46232-9%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41467-024-46232-9%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Liquid%20metals%20for%20boosting%20stability%20of%20zeolite%20catalysts%20in%20the%20conversion%20of%20methanol%20to%20hydrocarbons%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yong%22%2C%22lastName%22%3A%22Zhou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sara%22%2C%22lastName%22%3A%22Santos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mariya%22%2C%22lastName%22%3A%22Shamzhy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maya%22%2C%22lastName%22%3A%22Marinova%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Marie%22%2C%22lastName%22%3A%22Blanchenet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yury%20G.%22%2C%22lastName%22%3A%22Kolyagin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pardis%22%2C%22lastName%22%3A%22Simon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martine%22%2C%22lastName%22%3A%22Trentesaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sharmin%22%2C%22lastName%22%3A%22Sharna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vladimir%20L.%22%2C%22lastName%22%3A%22Zholobenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mark%22%2C%22lastName%22%3A%22Saeys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrei%20Y.%22%2C%22lastName%22%3A%22Khodakov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vitaly%20V.%22%2C%22lastName%22%3A%22Ordomsky%22%7D%5D%2C%22abstractNote%22%3A%22Methanol-to-hydrocarbons%20%28MTH%29%20process%20has%20been%20considered%20one%20of%20the%20most%20practical%20approaches%20for%20producing%20value-added%20products%20from%20methanol.%20However%2C%20the%20commonly%20used%20zeolite%20catalysts%20suffer%20from%20rapid%20deactivation%20due%20to%20coke%20deposition%20and%20require%20regular%20regeneration%20treatments.%20We%20demonstrate%20that%20low-melting-point%20metals%2C%20such%20as%20Ga%2C%20can%20effectively%20promote%20more%20stable%20methanol%20conversion%20in%20the%20MTH%20process%20by%20slowing%20coke%20deposition%20and%20facilitating%20the%20desorption%20of%20carbonaceous%20species%20from%20the%20zeolite.%20The%20ZSM-5%20zeolite%20physically%20mixed%20with%20liquid%20gallium%20exhibited%20an%20enhanced%20lifetime%20in%20the%20MTH%20reaction%2C%20which%20increased%20by%20a%20factor%20of%20up%20to%20similar%20to%2014%20as%20compared%20to%20the%20parent%20ZSM-5.%20These%20results%20suggest%20an%20alternative%20route%20to%20the%20design%20and%20preparation%20of%20deactivation-resistant%20zeolite%20catalysts.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41467-024-46232-9%22%2C%22ISSN%22%3A%222041-1723%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41467-024-46232-9%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%2C%22NA8RB2RI%22%5D%2C%22dateModified%22%3A%222024-04-29T15%3A14%3A24Z%22%7D%7D%5D%7D
[1]
I. Adinov, O. Kovalenko, J.-L. Rehspringer, L. Mager, Functionalization of micro-size garnet at the end of optical fiber for magneto-optical applications, Optics Express 32 (2024) 7651–7658. https://doi.org/10.1364/OE.503864.
[1]
A. Andoche, L. Mouawad, P.-A. Hervieux, X. Mougeot, J. Machado, J.P. Santos, Influence of atomic modeling on electron capture and shaking processes, Physical Review A 109 (2024) 032826. https://doi.org/10.1103/PhysRevA.109.032826.
[1]
N. Barbosa, O. Urquidi, J. Brazard, T.B.M. Adachi, In situ/In vivo Optical Microspectroscopy to Probe the Emergence of Morphology, Chimia 78 (2024) 50–58. https://doi.org/10.2533/chimia.2024.50.
[1]
I. Bel-Hadj, M. Guerboub, A. Lambrecht, G. Ori, C. Massobrio, E. Martin, Thermal conductivity of crystalline Ge2Sb2Te5: lattice contribution and size effects in the cubic phase quantified by approach-to-equilibrium molecular dynamics, Journal of Physics D-Applied Physics 57 (2024) 235303. https://doi.org/10.1088/1361-6463/ad316b.
[1]
D. Belotcerkovtceva, H. Nameirakpam, G. Datt, U. Noumbe, M.V. Kamalakar, High current treated-passivated graphene (CTPG) towards stable nanoelectronic and spintronic circuits, Nanoscale Horizons 9 (2024) 456–464. https://doi.org/10.1039/d3nh00338h.
[1]
M.J.V. Bernardez, N. Vukadinovic, C. Lefèvre, D. Stoeffler, Tuning Dynamic Susceptibility in Barium Hexaferrite Core-Shell Nanoparticles through Size-Dependent Resonance Modes, ACS Applied Electronic Materials Early access (2024). https://doi.org/10.1021/acsaelm.4c00096.
[1]
J. Bizeau, M. Rabineau, J. Buisson, T. Lucante, C. Leuvrey, K. Parkhomenko, P. Lavalle, D. Mertz, Powerful Protein Nanoreservoirs Based on Stellate Mesoporous Silica Embedded in Composite Hydrogels: From Burst Release to Retention, Macromolecular Chemistry and Physics (2024) 2400035. https://doi.org/10.1002/macp.202400035.
[1]
C. Brouillac, N. McIntosh, B. Heinrich, O. Jeannin, O. De Sagazan, N. Coulon, J. Rault-Berthelot, J. Cornil, E. Jacques, C. Quinton, C. Poriel, Grafting Electron-Accepting Fragments on [4]cyclo-2,7-carbazole Scaffold: Tuning the Structural and Electronic Properties of Nanohoops, Advanced Science (2024) 2309115. https://doi.org/10.1002/advs.202309115.
[1]
A. Carradò, N.M. Ravindra, Advanced Functional and Structural Thin Films and Coatings and Honorary Palkwoski Session, JOM 76 (2024) 610–611. https://doi.org/10.1007/s11837-023-06327-y.
[1]
V.G. Consolaro, V. Rouchon, O. Ersen, Electron beam damages in zeolites: A review, Microporous and Mesoporous Materials 364 (2024) 112835. https://doi.org/10.1016/j.micromeso.2023.112835.
[1]
N. Del Giudice, G. Voegeli, J.-M. Strub, B. Heinrich, L. Douce, Ionic Liquid Crystals Based on Loop-Shaped Copper(I) Complexes., Inorganic Chemistry 63 (2024) 6103–6110. https://doi.org/10.1021/acs.inorgchem.4c00728.
[1]
V. Desbuis, D. Lacour, C. Tiusan, C. Vautrin, S. Migot, J. Ghanbaja, Y. Lu, W. Weber, M. Hehn, Manipulation of low-energy spin precession in a magnetic thin film by tuning its molecular field, Physical Review B 109 (2024) 024403. https://doi.org/10.1103/PhysRevB.109.024403.
[1]
M. Gołębiewski, R. Hertel, M. d’Aquino, V. Vasyuchka, M. Weiler, P. Pirro, M. Krawczyk, S. Fukami, H. Ohno, J. Llandro, Collective Spin-Wave Dynamics in Gyroid Ferromagnetic Nanostructures, ACS Appl. Mater. Interfaces 16 (2024) 22177–22188. https://doi.org/10.1021/acsami.4c02366.
[1]
A. Hemmerle, N. Aubert, T. Moreno, P. Kekicheff, B. Heinrich, S. Spagnoli, M. Goldmann, G. Ciatto, P. Fontaine, Opportunities and new developments for the study of surfaces and interfaces in soft condensed matter at the SIRIUS beamline of Synchrotron SOLEIL., Journal of Synchrotron Radiation 31 (2024). https://doi.org/10.1107/S1600577523008810.
[1]
N. Kousar, S. Rasheed, K. Yasmeen, A.R. Umar, M.H. Laiche, M. Masood, H. Muhammad, M. Hanif, Efficient synergistic degradation of Congo red and omeprazole in wastewater using rGO/Ag@ZnO nanocomposite, Journal of Water Process Engineering 58 (2024) 104775. https://doi.org/10.1016/j.jwpe.2024.104775.
[1]
M. Kurucz, I. Nikolinakos, J. Soueiti, T. Baron, F. Grifoni, W. Naim, Y. Pellegrin, F. Sauvage, F. Odobel, S. Haacke, Transparent Near-IR Dye-Sensitized Solar Cells: Ultrafast Spectroscopy Reveals the Effects of Driving Force and Dye Aggregation, ChemPhotoChem (2024) e202300175. https://doi.org/10.1002/cptc.202300175.
[1]
A. Lambrecht, G. Ori, C. Massobrio, M. Boero, E. Martin, ADynMat Consortium, Assessing the thermal conductivity of amorphous SiN by approach-to-equilibrium molecular dynamics, Journal of Chemical Physics 160 (2024) 094505. https://doi.org/10.1063/5.0193566.
[1]
A. Llopez, F. Leroy, C. Tagne-Kaegom, B. Croes, A. Michon, C. Mastropasqua, M. Al Khalfioui, S. Curiotto, P. Muller, A. Saol, B. Kierren, G. Kremer, P.L. Fevre, F. Bertran, Y. Fagot-Revurat, F. Cheynis, Van der Waals Epitaxy of Weyl-Semimetal Td-WTe2., ACS Applied Materials & Interfaces 16 (2024) 20878–20885. https://doi.org/10.1021/acsami.4c00676.
[1]
Y. Lyu, F. Gao, P. Cheng, L. Chen, S. Klyatskaya, M. Ruben, J. Rosen, J.V. Barth, J. Bjoerk, K. Wu, Y.-Q. Zhang, Unraveling Enyne Bonding via Dehydrogenation-Hydrogenation Processes in On-Surface Synthesis with Terminal Alkynes, Advanced Materials Interfaces (2024) 2400222. https://doi.org/10.1002/admi.202400222.
[1]
K. Maity, J.-F. Dayen, B. Doudin, R. Gumeniuk, B. Kundys, Graphene Magnetoresistance Control by Photoferroelectric Substrate., ACS Nano 18 (2024) 4726–4732. https://doi.org/10.1021/acsnano.3c07277.
[1]
S. Mohapatra, W. Weber, B. Gobaut, M. Bowen, S. Boukari, V. Da Costa, Polarization Vector Canting in Croconic Acid Ferroelectric Nanoscopic Regions, Advanced Materials Technologies (2024) 2301257. https://doi.org/10.1002/admt.202301257.
[1]
H. Nakamura, H. Ohta, R. Kobayashi, T. Waki, Y. Tabata, H. Ikeno, C. Mény, Site-selective cobalt substitution in La-Co co-substituted magnetoplumbite-type ferrites: <SUP>59</SUP>Co-NMR and DFT calculation study, Journal of Physics-Materials 7 (2024) 025012. https://doi.org/10.1088/2515-7639/ad3b6d.
[1]
A. Pakalniškis, G. Niaura, R. Ramanauskas, D. Karpinsky, G. Rogez, M. Lenertz, J. Robert, P. Rabu, S.-W. Chen, T.C.-K. Yang, R. Skaudžius, A. Kareiva, Temperature-driven magnetic and structural transitions in multiferroic Lu(1-x)ScxFeO3, Journal of Alloys and Compounds 972 (2024) 172805. https://doi.org/https://doi.org/10.1016/j.jallcom.2023.172805.
[1]
M.A. Parker, M.L. De Marco, A. Castro-Grijalba, A. Ghoridi, D. Portehault, S. Pechev, E.A. Hillard, S. Lacomme, A. Bessiere, F. Cunin, P. Rosa, M. Gonidec, G.L. Drisko, Size-tunable silicon nanoparticles synthesized in solution via a redox reaction, Nanoscale 16 (2024) 7958–7964. https://doi.org/10.1039/d3nr05793c.
[1]
A. Pena Corredor, M. Gamarde, L. El Khabchi, M.J.V. Bernardez, M. Lenertz, C. Leuvrey, L. Schlur, F. Roulland, N. Viart, C. Lefèvre, Room-temperature magnetism and controlled cation distribution in vanadium ferrite thin films, Materials Chemistry and Physics 314 (2024) 128856. https://doi.org/10.1016/j.matchemphys.2023.128856.
[1]
M. Przydacz, M. Jedrzejczyk, J. Rogowski, D. Ihiawakrim, N. Keller, A.M. Ruppert, TiO2 supported non-noble Ni-Fe catalysts for the high yield production of 2,5-dimethylfuran biofuel, FUEL 356 (2024) 129606. https://doi.org/10.1016/j.fuel.2023.129606.
[1]
A. Roslawska, G. Schull, Photo-induced chemistry with sub-molecular resolution, Nature Nanotechnology (2024). https://doi.org/10.1038/s41565-024-01623-3.
[1]
A. Roslawska, K. Kaiser, M. Romeo, E. Devaux, F. Scheurer, S. Berciaud, T. Neuman, G. Schull, Submolecular-scale control of phototautomerization., Nature Nanotechnology (2024). https://doi.org/10.1038/s41565-024-01622-4.
[1]
L. Sancey, Y. Corvis, S. Bégin-Colin, N. Tsapis, A special issue dedicated to the 2022 meeting of the French society for nanomedicine., International Journal of Pharmaceutics 654 (2024) 124006. https://doi.org/10.1016/j.ijpharm.2024.124006.
[1]
K. Sartori, R. Lopez-Martin, F. Choueikani, A. Gloter, J.-M. Greneche, S. Bégin-Colin, D. Taverna, J.A. De Toro, B.P. Pichon, Magnetic anisotropy engineering in onion-structured metal oxide nanoparticles combining dual exchange coupling and proximity effects, Nanoscale Advances (2024). https://doi.org/10.1039/d3na01108a.
[1]
L. Temdie, V. Castel, V. Vlaminck, M.B. Jungfleisch, R. Bernard, H. Majjad, D. Stoeffler, Y. Henry, M. Bailleul, Probing Spin Wave Diffraction Patterns of Curved Antennas, Physical Review Applied 21 (2024) 014032. https://doi.org/10.1103/PhysRevApplied.21.014032.
[1]
S.V. Thakkar, T. Nabiyeva, Q. Weinbach, H. Bhatia, Z. Liu, T. Ferté, C. Leuvrey, A. Carvalho, B.C. Schroeder, L. Biniek, N-type thermoelectric bulk composite based on poly (nickel-ethylenetetrathiolate): The positive effect of porosity on decreasing thermal conductivity, Polymer 296 (2024) 126761. https://doi.org/10.1016/j.polymer.2024.126761.
[1]
T. Thierry, J. Frey, Y. Geiger, S. Bellemin-Laponnaz, Les effets non linéaires en catalyse asymétrique, L’actualité Chimique (2024) 40–49. https://new.societechimiquedefrance.fr/numero/les-effets-non-lineaires-en-catalyse-asymetrique-p40-n491/.
[1]
T. Thierry, Y. Geiger, S. Bellemin-Laponnaz, Divergence of catalytic systems in the zinc-catalysed alkylation of benzaldehyde mediated by chiral proline-based ligands, Nature Synthesis (2024). https://doi.org/10.1038/s44160-024-00491-y.
[1]
T. Thierry, V. Giuso, F. Polo, P. Mercandelli, Y.-T. Chen, C.-H. Chang, M. Mauro, S. Bellemin-Laponnaz, A stable and true-blue emissive hexacoordinate Si(iv) N-heterocyclic carbene complex and its use in organic light-emitting diodes, Dalton Transactions 53 (2024) 6445–6450. https://doi.org/10.1039/d4dt00420e.
[1]
Q. Xi, V. Papaefthimiou, N. Le Breton, M. Lenertz, M. Takashima, V. Keller, B. Vileno, T. Cottineau, Influence of Nitridation Conditions on the Doping Sites and Photocatalytic Visible Light Activity of Nb,N-Codoped TiO2, Chemistry of Materials 36 (2024). https://doi.org/10.1021/acs.chemmater.3c03280.
[1]
C. Zahn, M. Pastore, J.L.P. Lustres, P.C. Gros, S. Haacke, K. Heyne, Femtosecond Infrared Spectroscopy Resolving the Multiplicity of High-Spin Crossover States in Transition Metal Iron Complexes., Journal of the American Chemical Society 146 (2024) 9347–9355. https://doi.org/10.1021/jacs.4c01637.
[1]
C.-Y. Zeng, W.-J. Deng, K.-Q. Zhao, C. Redshaw, B. Donnio, Phenanthrothiophene-Triazine Star-Shaped Discotic Liquid Crystals: Synthesis, Self-Assembly, and Stimuli-Responsive Fluorescence Properties, Chemistry-a European Journal (2024) e202400296. https://doi.org/10.1002/chem.202400296.
[1]
K.-L. Zhang, W.-H. Yu, K.-Q. Zhao, P. Hu, B.-Q. Wang, B. Donnio, Mesomorphism Modulation of Perfluorinated Janus Triphenylenes by Inhomogeneous Chain Substitution Patterns, Chemistry-an Asian Journal 19 (2024). https://doi.org/10.1002/asia.202301080.
[1]
Y. Zhou, S. Santos, M. Shamzhy, M. Marinova, A.-M. Blanchenet, Y.G. Kolyagin, P. Simon, M. Trentesaux, S. Sharna, O. Ersen, V.L. Zholobenko, M. Saeys, A.Y. Khodakov, V.V. Ordomsky, Liquid metals for boosting stability of zeolite catalysts in the conversion of methanol to hydrocarbons, Nature Communications 15 (2024) 2228. https://doi.org/10.1038/s41467-024-46232-9.