Publication List (S. Bellemin-Laponnaz)

139) Marinova, M.; Bonnefont, A.; Achard, T.; maisse-François, A.; Bellemin-Laponnaz, S. Polymerization/depolymerization of chiral metallo-supramolecular assembly induced by redox change. Chirality 2021, accepted.

138) Le Roux, S.; Ori, G.; Bellemin-Laponnaz, S.; Boero, M. Tridentate Complexes of Group 4 Bearing Bis-Aryloxide N-Heterocyclic Carbene Ligand: Structure, Spin Density and Charge States. Chem. Phys. Lett. 2021, accepted.

137) De Marco, R.; Dal Grande, M.; Baron, M.; Orian, L.; Graiff, C.; Achard, T.; Bellemin-Laponnaz, S.; Pöthig, A.; Tubaro, C. Synthesis, Structural Characterization and Antiproliferative Activity of Gold(I) and Gold(III) Complexes Bearing Thioether-Functionalized N-Heterocyclic Carbenes. 2021 Submitted.

136) Hammoud, F.; Rahal, M.; Egly, J.; Morlet-Savary, F.;Hijazi, A.; Bellemin-Laponnaz, S.; Mauro, M.; Lalevée, J. Cubane Cu4I4(phosphine)4 Complexes as New Co-initiator for Free Radical Photopolymerization: Towards Aromatic Amine-Free Systems, Polymer Chemistry 2021, accepted. DOI:10.1039/D1PY00277E.

135) Geiger, Y.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Absence of Non-Linear Effects despite evidence for catalyst aggregation. Eur. J. Org. Chem. 2021, 2916-2922.

ChemRxiv 2021 Preprint, doi.org/10.26434/chemrxiv.13911659.v1

134) Achard, T.; Bellemin-Laponnaz, S. Recent advances on catalytic osmium-free olefin syn-dihydroxylation. Eur. J. Org. Chem. 2021, 877–896.

133) Geiger, Y.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Hyperpositive non-linear effects: enantiodivergence and modelling. Chem. Science 2020, 11, 12453-12463.

Highlighted in Nature Chemistry Reviews
Unmasking unusual behaviour 5th November 2020

132) Charigon, E.; Bouché, M.; Clave-Darcissac, C.; Dahm, G.; Ichim, G.; Clotagatide, A.; Mertani, H. C.; Telouk, P.; Caramel, J.; Diaz, J. J.; Bellemin-Laponnaz, S.; Bouvet, P.; Billotey, C. In Cellulo Evaluation of the Therapeutic Potential of NHC Platinum compounds in Metastatic Cutaneous Melanoma. Int. J. Mol. Sci. 2020, 21, 7826. Link

131) Bonfiglio, A.; Pallova, L.; César, V.; Gourlaouen, C.; Bellemin-Laponnaz, S.; Daniel, C.; Polo, F.; Mauro M. Phosphorescent cationic heterodinuclear Ir(III)/M(I) complexes (M = Cu(I), Au(I)) with a hybrid Janus-type N-heterocyclic carbene bridge. Chem. Eur. J. 2020, 26, 11751-11766.

130) Bouché, M.; Vincent, B.; Achard, T.; Bellemin-Laponnaz, S. N-Heterocyclic Carbene Platinum(IV) as metallodrug candidates: synthesis and 195Pt NMR chemical shift trend. Molecules (Special Issue) 2020, 25, 3148.

129) Egly, J.; Bissessar, D.; Achard, T.; Steffanut, P.; Mauro, M.; Bellemin-Laponnaz, S. Copper(I) complexes with remotely functionalized phosphine ligands: synthesis, structural variety, photophysics and effect onto the thermally-activated delayed fluorescence. Inorg. Chim. Acta (Special Issue) 2021, 514, 119971.

128) Marinova, M.; Bonnefont, A.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Chiral stimuli-responsive metallo-supramolecular assembly induced by Cu(II)/Cu(I) change. Chem. Commun. 2020, 56, 8703-8706.

127) Geiger, Y.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Observation of hyperpositive non-linear effect in catalytic asymmetric organozinc additions to aldehydes. Chirality (Special Issue) 2020, 32, 1250-1256.

126) Romain, C.; Bellemin-Laponnaz, S.; Dagorne, S. Recent progress on NHC-stabilized early transition metal (Group 3-7) complexes: synthesis and applications. Coord. Chem. Rev. (Special Issue) 2020, 422, 213411.

125) Geiger, Y.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Enantiodivergent non-linear effects in asymmetric catalysis. ChemRxiv 2020, Preprint.

124) Verron, R.; Achard, T.; Seguin, C.; Fournel, S.; Bellemin-Laponnaz, S. Synthesis and characterization of N-heterocyclic carbene dithiocarbamate platinum complexes with antitumoral activity. Eur. J. Inorg. Chem. 2020, 2552-2557.

123) Geiger, Y.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Hyperpositive non-linear effects in asymmetric catalysis. Nature Catalysis 2020, 3, 422-426.

Highlighted in Chemistry World 25th March 2020

Highlighted in University of Strasbourg News 20th April 2020

Highlighted in CNRS INC News 9th June 2020

122) Chen, W.; Egly, J.; Poblador-Bahamonde, A. I. I.; Maisse-François, A.; Bellemin-Laponnaz, S.; Achard, T. Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (κ2–C,S)-thioether-functionalised NHC ligands. Dalton Trans. 2020, 49, 3243-3252.

121) Bellemin-Laponnaz, S. N-heterocyclic carbene platinum complexes: a big step forward for effective anti-tumor compounds. Eur. J. Inorg. Chem. 2020, 10-20.

120) Dahm, G.; Bouché, M.; Bailly, C.; Karmazin, L.; Bellemin-Laponnaz, S. Synthesis and structural characterization of benzyl-functionalized N-heterocyclic carbene platinum complexes: dramatic substituent effect on anti-cancer activity. J. Organomet. Chem. (Special Issue) 2019, 899, 120908.

119) Torres-Werlé, M.; Heinrich, B.; Maisse-François, A.; Bellemin-Laponnaz, S. Synthesis of alternating metallo-copolymers by chiral recognition. Chirality (Special Issue) 2019, 31, 903-909.

118) Harlepp, S.; Chardon, E.; Bouché, M.; Dahm, G.; Maaloun, M.; Bellemin-Laponnaz, S. N-Heterocyclic Carbene Platinum Complexes Featuring an Anthracenyl Moiety: Anti-Cancer Activity and DNA Interaction. Int. J. Mol. Sci. 2019, 20, 4198. Preprint available here.

117) Bissessar, D.; Egly, J.; Achard, T.; Steffanut, P.; Bellemin-Laponnaz, S. Catalyst-free hydrophosphination of alkenes in presence of 2-methyltetrahydrofuran: a green and easy access to a wide range of tertiary phosphines. RSC Advances 2019, 9, 27250.

116) Achard, T.; Egly, J.; Sigrist, M.; Maisse-François, A.; Bellemin-Laponnaz, S. Easy ruthenium-catalysed oxidation of primary amines to nitriles under oxidant free conditions. Chem. Eur. J. 2019, 25, 13271-13274.

115) Geiger, Y.; Achard, T.; Maisse-François, A.; Bellemin-Laponnaz, S. Observation of Hyperpositive Non-Linear Effects in Asymmetric Catalysis, ChemRxiv 2019, Preprint.

114) Monticelli, M.; Baron, M.; Tubaro, C.; Bellemin-Laponnaz, S.; Graiff, C.; Bottaro, G. Armelao, L.; Orian, L. Structural and luminescent properties of homoleptic silver(I), gold(I) and palladium(II) complexes with nNHC-tzNHC heteroditopic carbene ligands. ACS Omega 2019, 4, 4192-4205

113) Marinova, M.; Torres-Werlé, M.; Taupier, G.; Maisse-François, A.; Achard, T.; Boeglin, A.; Dorkenoo, K. D.; Bellemin-Laponnaz, S. Chiral Self-sorting Process with Ditopic Ligands: Alternate- or Block-Metallopolymer Assembly as Function of the Metal Ion. ACS Omega 2019, 4, 2676-2683.

112) Ulm, F.; Poblador-Bahamonde, A. I.; Choppin, S.; Bellemin-Laponnaz, S.; Chetcuti, M. J.; Achard, T.; Ritleng, V.  Synthesis, characterization, and catalytic application in aldehyde hydrosilylation of half-sandwich nickel complexes bearing (κ1C)- and hemilabile (κ2C,S)-thioether-functionalised NHC ligands. Dalton Trans. 2018, 47, 17134-17145.

111) César, V.; Mallardo, V.; Nano, A.; DePeter, S. F.; Bastin, S.; Sournia-Saquet, A.; Maisse-François, A.; Lugan, N.; Bellemin-Laponnaz, S. Homo- and hetero-polymetallic complexes of the hybrid, ambidentate N-Heterocyclic Carbene ligand IMes-acac. ACS Omega 2018, 3, 15582-15591.

110) Wantz, M.; Bouché, M.; dahm, G.; Chekkat, N.; Fournel, S.; Bellemin-Laponnaz, S. N-Heterocyclic Carbene-Polyethyleneimine (PEI) Platinum Complexes Inducing Human Cancer Cell Death: Polymer Carrier Impact. Int. J. Mol. Sci. 2018, 19, 3472.

109) Bouché, M.; Bonnefont, A.; Achard, T.; Bellemin-Laponnaz, S. Exploring Diversity in Platinum(IV) N-Heterocyclic Carbene Complexes: Synthesis, Characterization, Reactivity and Biological Evaluation. Dalton Trans. 2018, 11491-11502.

108) Bouché, M.; Fournel, S.; Kichler, A.; Selvam, T.; Gallani, J. -L.; Bellemin-Laponnaz, S. Straightforward synthesis of biocompatible PEI-coated gold nanopaticles. Eur. J. Inorg. Chem. 2018, 2972-2975.

107) Egly, J.; Bouché, M.; Chen, W.; Maisse-François, A.; Achard, T.; Bellemin-Laponnaz, S. Synthesis, structural characterisation and anti-proliferative activity of (κ1C)- and (κ2C,S)-Pt(II) complexes bearing thioether-functionalized N-heterocyclic carbenes. Eur. J. Inorg. Chem. 2018, 159-166.

106) Bellemin-Laponnaz, S.; Mauro, M. Self-repairing and photosensitive gels that adapt to their environment. Des gels autoréparants et photosensibles qui s’adaptent à leur milieu. L’actualité chimique 2018, 432.

105) Mauro, M.; Bellemin-Laponnaz, S.; Cebrian Avila, C. Metal-containing polymers as light-emitting and light-responsive materials and beyond. Chem. Eur. J. 2017, 23, 17626-17636.

104) El Garah, M.; Borré, E.; Ciesielski, A.; Dianat, A.; Gutierrez, R.; Cuniberti, G.; Bellemin-Laponnaz, S.; Mauro, M.; Samori, P. Light-induced contraction/expansion of one-dimensional photo-switchable metallopolymer monitored at the solid-liquid interface. Small 2017, 1701790.

103) Chardon, E.; Dahm, G.; Guichard, G.; Bellemin-Laponnaz, S. Synthesis and structural characterization of alkyne-functionalized N-heterocyclic carbene complexes of ruthenium, palladium and rhodium. Inorg. Chim. Acta 2017, 467, 33-38.

102) Borré, E.; Stumbe, J. -F.; Bellemin-Laponnaz, S.; Mauro, M. Control of the light-response in supramolecular metallopolymeric gels by tuning the coordination metal. Chem. Commun. 2017, 53, 8344-8347.

101) Monticelli, M.; Bellemin-Laponnaz, S.; Tubaro, C.; Rancan, M.  Synthesis, structure and antitumoral activity of triazole-functionalised NHC metal complexe, Eur. J. Inorg. Chem. 2017, 2488-2495.

100) Taupier, G.; Torres-Werlé, M.; Boeglin, A.; Maisse-François, A.; Achard, T.; Bellemin-Laponnaz, S.; Dorkenoo, H. D.  Optically Active Sum-Frequency Generation as an Advanced Tool for Chiral Metallopolymer Material. Appl. Phys. Lett. 2017, 110, 021904.

99) Bellemin-Laponnaz, S.; Achard, T.; Bissessar, D.; Geiger, Y.; Maisse-François, A. Synthesis and application of dynamic self-supported enantioselective catalysts. Coord. Chem. Rev. 2017, 332, 38-47.

98) Borré, E.; Bellemin-Laponnaz, S.; Mauro, M. Amphiphilic metallopolymers for photoswitchable supramolecular hydrogels. Chem. Eur. J. 2016, 22, 18718-18721.

97) Chekkat, N.; Dahm, G.; Chardon, E.; Wantz, M.; Sitz, J.; Decossas, M.; Lambert, O.; Frisch, B.; Rubbiani, R.; Gasser, G.; Guichard, G.; Fournel, S.; Bellemin-Laponnaz, S. N-Heterocyclic Carbene-Polyethyleneimine Platinum Complexes with Potent in vitro and in vivo Antitumor Efficacy. Bioconjugate Chem. 2016, 27, 1942-1948.

96) Bouché, M.; Dahm, G.; Wantz, M.; Fournel, S.; Achard, T.; Bellemin-Laponnaz, S. Platinum(IV) N-heterocyclic carbene complexes: synthesis, characterisation and cytotoxic activity. Dalton Trans. 2016, 45, 11362-11368.

95) Bissessar, D.; Achard, T.; Bellemin-Laponnaz, S.; Robust and Recyclable Self-Supported Chiral Nickel Catalyst for the Enantioselective Michael Addition, Adv. Synth. Catal. 2016, 358, 1982-1988.

94) Bouché, M.; Dahm, G.; Maisse-François, A.; Achard, T.; Bellemin-Laponnaz, S.; Selective formation of cis N-Heterocyclic Carbene-Pt(II)-Pnictogen Complexes and In Vitro Evaluation of their Cytotoxic Activities Toward Cancer Cells. Eur. J. Inorg. Chem. 2016, 2828-2836.

93) Borré, E.; Dahm, G.; Guichard, G.; Bellemin-Laponnaz, S.; Post-functionalization of platinum-NHC complexes by oxime ligation for ligand targeted therapy. New J. Chem. 2016, 40, 3164-3171.

92) Borré, E.; Stumbe, J. -F.; Bellemin-Laponnaz, S.; Mauro, M., Light-powered Self-healable Metallosupramolecular Soft Actuators. Angew. Chem. Int. Ed. 2016, 55, 1313-1317.

91) César, V.; Gade, L. H.; Bellemin-Laponnaz, S. Cobalt, Rhodium and Iridium Complexes in Catalysis in  « N-Heterocyclic Carbenes » 2nd Edition. Ed.: Silvia Díez-González, RSC Publishing, Cambridge, ISBN: 978-1-78262-423-3.

90) Baron, M.; Bellemin-Laponnaz, S.; Tubaro, C.; Heinrich, B.; Basato, M.; Accorsi, G. Synthesis and Thermotropic Behaviour of Bis(Imidazolium) Salts Bearing Long-Chain Alkyl-Substituents and of the Corresponding Dinuclear Gold Carbene Complexes. J. Organomet. Chem. 2016, 801, 60-67.

89) Romain, C.; Specklin, D.; Miqueu, K.; Sotiropoulos, J. -M.; Fliedel, C.; Bellemin-Laponnaz, S; Dagorne S. Unusual Benzyl Migration Reactivity in NHC-bearing Group 4 Metal Chelates: Synthesis, Characterization, and Mechanistic Investigations. Organometallics 2015, 34, 4854–4863.

88) Dahm, G.; Borré, E.; Fu, C.; Bellemin-Laponnaz, S.; Mauro, M. Tridentate Complexes of Pd(II) and Pt(II) Bearing bis-Aryloxide Triazole Ligands: a Joint Experimental and Theoretical Investigation. Chem. Asian J. 2015, 10, 2368-2379.

87) Dahm, G.; Bailly, C.; Karmazin, L.; Bellemin-Laponnaz, S. Synthesis, Structural characterization and in vitro anti-cancer activity of functionalized N-heterocyclic carbene platinum and palladium complexes. J. Organomet. Chem. 2015, 794, 115-124.

86) Dahm, G.; Borré, E.; Guichard, G.; Bellemin-Laponnaz, S. A Chemoselective and Modular Post-Synthetic Multi-Functionalization of Platinum-NHC Complexes Eur. J. Inorg. Chem. 2015, 10, 1665-1668.

85) César, V.; Mallardo, V.; Nano, A.; Dahm, G.; Lugan, N.; Lavigne, G.; Bellemin-Laponnaz S. IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand. Chem. Commun. 2015, 51, 5271-5274.

84) Baron, M.; Bellemin-Laponnaz, S.; Tubaro, C.; Basato, M.; Bogialli, S.; Dolmella, A. Synthesis and biological assays on cancer cells of binuclear gold complexes with novel functionalised di(N-heterocylic carbene) ligands. J. Inorg. Biochem. 2014141, 94-102.

83) Torres-Werlé, M.; Nano, A.; Maisse-François, A.; Bellemin-Laponnaz, S. Asymmetric benzoylation and Henry reaction using reusable polytopic bis(oxazoline) ligands and copper(II). New J. Chem. 2014, 38, 4748-4753.

82) Bellemin-Laponnaz, S.; Dagorne, S.; Dümpelmann, R.; Steffanut, P. Combining NHC bis-Phenolate Ligands with Oxophilic Metal Centers: A Powerful Approach for the Development of Robust and Highly Effective Organometallic Catalysts. Chimia 2014, 68, 500-504.

81) Bellemin-Laponnaz, S.; Dagorne, S. Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications. Chem. Rev. 2014, 114, 8747-8774.

80) Borré, E.; Dahm, G.; Aliprandi, A.; Mauro, M.; Dagorne, S.; Bellemin-Laponnaz, S. Tridentate Complexes of group 10 Bearing Bis-Aryloxide N-Heterocyclic Carbene Ligands: Synthesis, Structural, Spectroscopic, and Computational Characterization. Organometallics 2014, 33, 4374-4384.

79) Romain, C. ; Choua, S. ; Collin, J. -P. ; Heinrich, M. ; Bailly, C. ; Karmazin-Brelot, L. ; Bellemin-Laponnaz, S. ; Dagorne, S. Redox and Luminescent properties of Robust and Air-stable NHC Group 4 Metal Complexes. Inorg. Chem. 2014, 53, 7371-7376.

78) Romain, C. ; Fliedel, C. ; Bellemin-Laponnaz, S. ; Dagorne, S. NHC Bis-Phenolate Aluminum Chelates : Synthesis, Structure and Use in Lactide and Trimethylene Carbonate Polymerization. Organometallics 2014, 33, 5730-5739.

77) Bellemin-Laponnaz S. ; Dagorne S. ; Coordination chemistry, reactivity and applications of early transition metal complexes bearing N-heterocyclic carbene ligands. Contribution dans l’ouvrage : “N-Heterocyclic Carbenes : Effective Tools for Organometallic Synthesis”. Éditeur : S. Nolan ; Wiley, 2014, ISBN : 978-3-527-33490-2

76) Torres, M. ; Maisse-François, A. ; Bellemin-Laponnaz, S. ; Highly Recyclable Self-Supported Chiral Catalysts for the Enantioselective α-Hydrazination of β-Ketoesters. ChemCatChem 2013, 5, 3078-3085.

75) Dagorne, S. ; Bellemin-Laponnaz, S. ; Romain, C. ; Neutral and Cationic N-Heterocyclic Carbene Zirconium and Hafnium Benzyl Complexes : Highly Regioselective Oligomerization of 1-Hexene with a Preference for Trimer Formation. Organometallics 2013, 32, 2736-2743.

74) Chardon, E. ; Dahm, G. ; Guichard, G. ; Bellemin-Laponnaz, S. ; Exploring Nitrogen Ligand Diversity in trans-N-Heterocyclic Carbene-Amine Platinum Complexes : Synthesis, Characterization and Application to Fluorescence. Chem. Asian J. 2013, 8, 1232-1242.

73) Chardon, E. ; Dahm, G. ; Guichard, G. ; Bellemin-Laponnaz, S. ; Derivatisation of preformed platinum N-heterocyclic carbene complexes with amino acid and peptide ligands, and cytotoxic activities towards human cancer cells. Organometallics 2012, 31, 7618-7621.

72) Chardon, E. ; Puleo, G. L. ; Dahm, G. ; Fournel, S. ; Guichard, G. ; Bellemin-Laponnaz, S. ; Easy Derivatisation of Group 10 N-Heterocyclic Carbene Complexes and In Vitro Evaluation of an Anticancer Oestradiol-Conjugate ChemPlusChem 2012, 77, 1028-1038.

71) Bellemin-Laponnaz, S. ; Dagorne, S. ; Coordination chemistry and applications of salen, salan and salalen metal complexes. Contribution dans l’ouvrage : “The Chemistry of Metal Phenolates”. Éditeur : J. Zabicky ; Wiley, 2012, DOI : 10.1002/9780470682531.pat0611

70) Torres, M. ; Heinrich, B. ; Miqueu, K. ; Bellemin-Laponnaz, S. ; Chirality-driven metallo-copolymer formation. Eur. J. Inorg. Chem. 2012, 3384–3387.

69) Romain, C. ; Heinrich, B. ; Bellemin-Laponnaz, S. ; Dagorne, S. A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide. Chem. Commun. 2012, 2213-2215.

68) Maisse-François, A. ; Azor, L. ; Schmitt, A. L. ; Coquel, A. ; Brelot, L. ; Welter, R. ; Bellemin-Laponnaz, S. ; Dagorne, S. Structural Diversity and Versatility for Organoaluminum Complexes Supported by Monoanionic and Di-anionic Aminophenolate Bidentate Ligands. J. Organomet. Chem. 2012, 696, 4248-4256.

67) Nano, A. ; Brelot, L. ; Rogez, G. ; Maisse-François, A. ; Bellemin-Laponnaz, S. Ditopic Bis(oxazolines) : Synthesis and Structural Studies of Zinc(II), Copper(II) and Nickel(II) Complexes. Inorg. Chim. Acta 2011, 376, 285-289.

66) Chardon, E. ; Puleo, G. L. ; Dahm, G. ; Guichard, G. ; Bellemin-Laponnaz, S. Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement. Chem. Commun. 2011, 47, 5864–5866.

65) Benhamou, L. ; Chardon, E. ; Lavigne, G. ; Bellemin-Laponnaz, S. ; César, V. Synthetic routes to N-Heterocyclic carbene precursors. Chem. Rev. 2011, 111, 2705-2733.

64) Romain, C. ; Brelot, L. ; Bellemin-Laponnaz, S. ; Dagorne, S. Synthesis and Structural Characterization of a Novel Family of Titanium complexes Bearing a Tridentate bis-phenolate-N-heterocyclic carbene dianionic ligand and their use in the controlled ROP of rac-lactide. Organometallics 2010, 29, 1191-1198.

63) Romain, C. ; Miqueu, K. ; Sotiropoulos, J. M. ; Bellemin-Laponnaz, S. ; Dagorne, S. Coordination of a tridentate bis-aryloxide-NHC chelating ligand to Zr(IV) : unprecedented non-innocent behaviour of an NHC-based ligand coordinated onto an early-transition and high-oxidation-state metal center. Angew. Chem. Int. Ed. 2010, 49, 2198-2201.

62) Issenhuth, J. T. ; Notter, F.-P. ; Dagorne, S. ; Dedieu, A. ; Bellemin-Laponnaz, S. Mechanistic Studies on the Copper-Catalyzed Hydrosilylation of Ketones. Eur. J. Inorg. Chem. 2010, 529-541.

61) Issenhuth, J. T. ; Dagorne, S. ; Bellemin-Laponnaz, S. Enantioselective Hydrosilylation of Prochiral Ketones Catalyzed by Chiral BINAP-Copper(I) Complexes. C. R. Chimie 2010, 13, 353-357.

60) Bellemin-Laponnaz, S. Synthesis of N,O-Heterocyclic Carbene and Coordination to Rhodium(I) and Copper(I). Polyhedron (Special Issue – The Next Generation) 2010, 29, 30-33.

59) Bellemin-Laponnaz, S. Perrhenate esters in new catalytic reactions. ChemCatChem 2009, 1, 357-362.

58) Issenhuth, J. T. ; Pluvinage, J. ; Welter, R. ; Bellemin-Laponnaz, S. ; Dagorne, S. Novel Neutral and Cationic Aluminium Alkyl Complexes Supported by Potentially Tridentate O,N,N type Aminophenolate Ligands and Their Use in Propylene Oxide Polymerization. Eur. J. Inorg. Chem. 2009, 4701-4709.

57) César, V. ; Gade, L. H. ; Bellemin-Laponnaz, S. NHC-Cobalt, Rhodium and Iridium Complexes in Catalysis. Contribution dans l’ouvrage : “N-Heterocyclic Carbenes : from laboratories curiosities to efficient synthetic tools”. Éditrice : S. Díez-González ; RSC Publishing, Londres, ISBN : 978-1849730426.

56) Schneider, N. ; Finger, M. ; Haferkemper, C. ; Bellemin-Laponnaz, S. ; Hofmann, P. ; Gade, L. H. Multiple Reaction Pathways in Rhodium Catalyzed Hydrosilylations of Ketones. Chem. Eur. J. 2009, 11515-11529.

55) Gaab, M. ; Bellemin-Laponnaz, S. ; Gade, L. H. Catalysis in a Tea Bag : Synthesis, Catalytic Performance and Recycling of Dendrimer-Immobilized Bis- and Trisoxazoline Copper Catalysts. Chem. Eur. J. 2009, 15, 5450-5462.

54) Dagorne S. ; Bellemin-Laponnaz, S. Organic transformations mediated by Group 13 metal compounds. Contribution dans l’ouvrage : “The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities”. Éditeur : S. Aldridge, A. J. Downs, Wiley, London, ISBN : 978-0-470-68191-6.

53) Bellemin-Laponnaz, S. ; Welter, R. ; Brelot, L. ; Dagorne, S. Synthesis and Structure of V(V) and Mn(III) NHC Complexes Supported a Tridentate Bis-aryloxide-N-heterocyclic Carbene Ligand. J. Organomet. Chem. 2009, 694, 604-606.

52) Schneider, N. ; Finger, M. ; Haferkemper, C. ; Bellemin-Laponnaz, S. ; Hofmann, P. ; Gade, L. H. Metal Silylenes, Generated by Double Si-H Activation, as Key Intermediates in the Rh-Catalyzed Hydrosilylation of Ketones. Angew. Chem. Int. Ed. 2009, 48, 1609-1613.

51) César, V. ; Bellemin-Laponnaz, S. Les ligands carbènes N-hétérocycliques. L’actualité chimique 2009, 326, 10-16.

50) Ward, B. D.; Lukešová, L.; Bellemin-Laponnaz, S.; Wadepohl, H.; Gade, L. H.
Scandium-Catalyzed Polymerization of propene – 1-heptene: Remarkable Activity and Tacticity Control. Eur. J. Inorg. Chem. 2009, 866-871.

49) Schneider, N.; Kruck, M.; Bellemin-Laponnaz, S.; Wadepohl,H.; Gade, L. H. Chiral Oxazoline-NHC Ligands with and without CR2-Bridges: A Comparative Study in Rhodium Hydrosilylation Catalysis. Eur. J. Inorg. Chem. 2009, 493-500.

48) Schneider, N.; Bellemin-Laponnaz, S.; Wadepohl, H.; Gade, L. H. A New Class of Modular Oxazoline-NHC Ligands and their Coordination Chemistry with Platinum Metals. Eur. J. Inorg. Chem. 2008, 5587-5598.

47) Jacques, B. ; Dro, C. ; Bellemin-Laponnaz, S. ; Wadepohl, H. ; Gade, L. H. Self-Assembly of a Cyclic Zn4O4 Tetramer by Aerobic Oxidation of a Bisoxazoline : A molecular ‘Nest’ for Nucleophilic OH-. Angew. Chem. Int. Ed. 2008, 47, 4546-4550.

46) Issenhuth, J. T. ; Dagorne, S. ; Bellemin-Laponnaz, S. A Practical Concept for the Kinetic Resolution of a Chiral Secondary Alcohol based on a Polymeric Silane. J. Mol. Catal. A. 2008, 286, 6-10.

45) Foltz, C., Bellemin-Laponnaz, S. ; Enders, M. ; Wadepohl, H. ; Gade, L. H. Thermal rearrangement of 2-bromooxazolines to α-bromoisocyanates. Org. Lett. 2008, 10, 305-308.

44) Gade, L. H. ; Bellemin-Laponnaz, S. Exploiting Threefold Symmetry in Asymmetric Catalysis : The Case of Tris(oxazolinyl)ethanes (“Trisox”). Chem. Eur. J. 2008, 14, 4142-4152.

43) Foltz, C. ; Stecker, B. ; Marconi, G. ; Bellemin-Laponnaz, S. ; Wadepohl, H. ; Gade L. H. Stereochemical Consequences of Threefold Symmetry in Asymmetric Catalysis : Distorting C3 Chiral 1,1,1-Tris(oxazolinyl)ethanes ( Trisox ) in CuII Lewis Acid Catalysts. Chem. Eur. J. 2007, 13, 9912-9923.

42) Lukešová, L. ; Ward, B. D. ; Bellemin-Laponnaz, S. ; Wadepohl, H. ; Gade, L. H. C3-symmetric chiral organolanthanide complexes : synthesis, characterization, and stereospecific polymerization of α-olefins. Organometallics 2007, 26, 4652-4657.

41) Suisse, J. M. ; Douce, L. ; Bellemin-Laponnaz, S. ; Maisse-François, A. ; Welter, R. ; Miyake, Y. ; Shimizu, Y. Liquid crystal imidazolium salts : towards materials for catalysis and molecular electronics. Eur. J. Inorg. Chem. 2007, 3899-3905.

40) Foltz, C. ; Enders, M ; Bellemin-Laponnaz, S. ; Wadepohl, H. ; Gade, L. H. Using a Tripod as a Chiral Chelating Ligand : Chemical Exchange Between Equivalent Molecular Structure in Palladium Catalysis with 1,1,1-Tris(oxazolinyl)ethane (« Trisox »). Chem. Eur. J. 2007, 13, 5994-6008.

39) Bellemin-Laponnaz, S. ; Gade, L. H. 1,1,1-tris(4S)-4-isopropyloxazolin-2-ylethane. The Encyclopedia of Reagents for Organic Synthesis [EROS] 2007, DOI : 10.1002/047084289-X.rn00794.

38) Dagorne, S. ; Bellemin-Laponnaz, S. ; Maisse-François, A. Metal Complexes Incorporating Monoanionic Bisoxazolinate Ligands : Synthesis, Structures, Reactivity and Applications in Asymmetric Catalysis. Eur. J. Inorg. Chem. 2007, 913-925.

37) Lukešová, L. ; Ward, B. D. ; Bellemin-Laponnaz, S. ; Wadepohl, H. ; Gade, L. H. High tacticity control in organolanthanide polymerization catalysis : formation of isotactic poly(α-alkenes) with a chiral C3-symmetric thulium complex. Dalton Trans. 2007, 920-922.

36) Bellemin-Laponnaz, S.; Gade, L. H. Symétrie C3 et catalyse : application de ligands tris(oxazolines) dans des réactions énantiosélectives. L’actualité chimique 2007, 307, 16-20

35) Gade, L. H.; Marconi, G.; Dro, C.; Ward, B. D.; Poyatos, M.; Bellemin-Laponnaz, S.; Wadepohl, H.; Sorace, L.; Poneti, G. Shaping and Enforcing Coordination Spheres: The Implications of C3 and C1 Chirality in the Coordination Chemistry of 1,1,1-Tris(oxazolinyl)ethane (“Trisox”). Chem. Eur. J. 2007, 13, 3058-3075.

34) Dagorne, S.; Le Bideau, F.; Welter, R.; Bellemin-Laponnaz, S.; Maisse-François, A. Well-defined Low-coordinate alkyl and Alkoxides Cationic Al Complexes Incorporating an Aminophenolate Bidentate Ligand and their reactivity with ε-caprolactone and Lactides. Chem. Eur. J. 2007, 13, 3202-3217.

33) Fliedel, C.; Maisse-François, A.; Bellemin-Laponnaz S. Palladium(II) Complexes of a Bis-2-aminobiphenyl N-Heterocyclic Carbene : Synthesis, Structural Studies and catalytic Activity. Inorg. Chim. Acta 2007, 360, 143-148.

32) Gade, L. H.; Bellemin-Laponnaz S. Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric catalysis. Top. Organomet. Chem. 2007, 21, 117-157.

31) Gade, L. H.; Bellemin-Laponnaz S. Mixed Oxazoline-Carbenes as Stereodirecting Ligands for Asymmetric Catalysis. Coord. Chem. Rev. 2007, 251, 718-725.

30) Ward, B. D.; Risler, H.; Weitershaus, K.; Bellemin-Laponnaz, S.; Wadepohl, H.; Gade, L. H. 2-Aminopyrrolines: New Chiral Amidinate Ligands with a Rigid, Well Defined Molecular Structure and their Coordination to TiIV. Inorg. Chem. 2006, 45, 7777-7787.

29) Issenhuth, J. T. ; Dagorne, S. ; Bellemin-Laponnaz, S. Efficient Enantioselective Hydrosilylation of Aryl Ketones Catalyzed by a Chiral BINAP-Copper(I) Catalyst – Phenyl Methyl Silane System. Adv. Synth. Catal. 2006, 348, 1991-1994.

28) Alaaeddine, A.; Amgoune, A.; Thomas, C.; Dagorne, S.; Bellemin-Laponnaz, S.; Carpentier, J. F. Bis[bis(oxazolinato)] Complexes of Yttrium and Lanthanum: Molecular Structure and Use in Polymerization of (D,L)-Lactide and (D,L)-Butyrolactone. Eur. J. Inorg. Chem. 2006, 3652-3658.

27) Seitz, M. ; Capacchione, C. ; Bellemin-Laponnaz, S. ; Wadepohl, H. ; Ward, B. D. ; Gade, L. H. Bisoxazolines with one and two sidearms : stereodirecting ligands for copper-catalysed asymmetric allylic oxidations of alkenes. Dalton Trans. 2006, 193-202.

26) Poyatos, M.; Maisse-François, A.; Bellemin-Laponnaz, S.; Peris, E.; Gade, L. H. Synthesis and Structural Chemistry of Arene-Ruthenium Halfsandwich Complexes Bearing an Oxazolinyl-Carbene Ligand. J. Organomet. Chem. 2006, 691, 2713-2720.

25) Poyatos, M.; Maisse-François, A.; Bellemin-Laponnaz, S.; Gade, L. H. Coordination Chemistry of a Modular N,C-Chelating Oxazole-Carbene Ligand and Its Applications in Hydrosilylation Catalysis. Organometallics 2006, 25, 2634-2641.

24) Foltz, C.; Stecker, B.; Marconi, G.; Bellemin-Laponnaz, S.; Wadepohl, H.; Gade, L. H. Exploiting C3-symmetry in the dynamic coordination of a chiral trisoxazoline to copper(II): improved enantioselectivity, and catalyst stability in asymmetric lewis acid catalysis. Chem. Commun. 2005, 5115-5117.

23) Schneider, N.; César, V.; Bellemin-Laponnaz, S.; Gade, L. H. Modular Assembly of a Chiral Bis(oxazolinyl)carbene: A New Meridionally Coordinating Tridentate Spectator Ligand. Organometallics 2005, 24, 4886-4888.

22) Dagorne, S.; Bellemin-Laponnaz, S.; Maisse-François, A.; Rager, M. N.; Welter, R. Synthesis and Structure of Neutral and Cationic Gallium Complexes Incorporating Bis(oxazolinato) Ligands. Eur. J. Inorg. Chem. 2005, 4206-4214.

21) Schneider, N.; César, V.; Bellemin-Laponnaz, S.; Gade, L. H. Synthesis and Structural Chemistry of Oxazolinyl-Carbene Copper(I) Complexes. J. Organomet. Chem. 2005, 690, 5556-5561.

20) Moïse, J. M.; Bellemin-Laponnaz, S.; Douce, L.; Maisse-François, A.; Welter, R. A new liquid crystal compound based on a ionic imidazolium salt. Tetrahedron Letters 2005, 46, 4303-4305.

19) César, V.; Bellemin-Laponnaz, S.; Wadepohl, H.; Gade, L.H. Designing the “Search Pathway” in the Development of a New Class of Highly Efficient Stereoselective Hydrosilylation Catalysts. Chem. Eur. J. 2005, 11, 2862-2873.

18) Ward B. D.; Bellemin-Laponnaz, S.; Gade, L.H. C3 Chirality in Polymerization Catalysis: A Highly Active Dicationic Scandium(III) Catalyst for the Isoselective Polymerization of 1-Hexene. Angew. Chem. Int. Ed. 2005, 44, 1668-1671.

17) César, V.; Bellemin-Laponnaz, S.; Gade, L.H. Chiral N-Heterocyclic Carbenes as Stereodirecting Ligands in Asymmetric catalysis. Chem. Soc. Rev. 2004, 33, 619-636.

16) Dro, C.; Bellemin-Laponnaz, S.; Welter, R., Gade L. H. A C3-symmetrical Chiral Trisoxazoline Zinc Complex as a Functional Model for Zinc Hydrolases: Kinetic Resolution of Racemic Chiral Esters by Transesterification. Angew. Chem. Int. Ed. 2004, 43, 4479-4482.

15) César, V.; Bellemin-Laponnaz, S.; Gade, L.H. Cationic and Neutral Oxazoline-Carbene-Rhodium(I) Complexes. Eur. J. Inorg. Chem. 2004, 3436-3444.

14) Dagorne, S.; Bellemin-Laponnaz, S.; Welter, R. Synthesis and Structure of neutral and cationic aluminium complexes incorporating bis-oxazolinato ligands. Organometallics 2004, 23,.3053-3061.

13) César, V.; Bellemin-Laponnaz, S.; Gade, L.H. A Modular Assembly of Chiral Oxazolinylcarbene-Rhodium Complexes: Efficient Non-Phosphine Based Catalysts in the Asymmetric Hydrosilylation of Dialkylketones. Angew. Chem. Int. Ed. 2004, 43, 1014-1017.

12) César, V.; Bellemin-Laponnaz, S.; Gade, L.H. Direct Coupling of Oxazolines and N-Heterocyclic Carbenes : A Modular Approach to a New Class of C-N Donor Ligands for Homogeneous Catalysis. Organometallics 2002, 21, 5204-5208.

11) Bellemin-Laponnaz, S.; Gade, L.H. A Modular Approach to C1 and C3-Chiral N-Tripod Ligands for Asymmetric Catalysis. Angew. Chem. Int. Ed. 2002, 41, 3473-3475.

10) Bellemin-Laponnaz, S.; Le Ny, J. P. Metal Oxo Complexes as Catalysts for the Isomerization of Allylic Alcohols. C. R. Chimie 2002, 5, 217-224.

9) Bellemin-Laponnaz, S.; Gade, L.H. Three 2-Oxazolyl Rings on One Quaternary Carbon Atom: Preparation of a Novel Tripodal Trisoxazoline Ligand and the Tetrameric Molecular Structure of it CuI Complex. Chem. Commun. 2002, 1286-1287

8) Bellemin-Laponnaz, S.; Lo, M. M.-C.; Peterson, T. H.; Allen, J. M.; Fu, G. C. Synthesis, Structure, and Reactivity of C2-Symmetric Bis(phospholyl)zirconium and Bis(phospholyl)hafnium Complexes. Organometallics 2001, 20(16), 3453-3458

7) Arai, S.; Bellemin-Laponnaz, S.; Fu, G. C. Kinetic resolution of amines by a nonenzymatic acylation catalyst. Angew. Chem. Int. Ed. 2001, 40(1), 234-236

6) Bellemin-Laponnaz, S.; Coleman, K. S.; Dierkes, P.; Masson, J. P.; Osborn, J. A. Synthesis and coordination of the new chiral tridentate O,N,O ligand 2,6-bis[(1S,2S,5R)-1-hydroxy-(-)-menthyl]pyridine to molybdenum(VI) and vanadium(V) oxo complexes: crystal structures of [(2,6-bis{1-hydroxy-(-)-menthyl}pyridine)MoO2] and [(2,6-bis{1-hydroxy-(-)-menthyl}pyridine)VO]2(O). Eur. J. Inorg. Chem. 2000, (7), 1645-1649

5) Bellemin-Laponnaz, S.; Tweddell, J.; Ruble, J. C.; Breitling, F. M.; Fu, G. C. The kinetic resolution of allylic alcohols by a non-enzymatic acylation catalyst; application to natural product synthesis. Chem. Commun. 2000, (12), 1009-1010

4) Bellemin-Laponnaz, S.; Le Ny, J.P.; Osborn, J. A. Isomerization of allylic silyl ethers catalyzed by ReO3(OSiR3) complexes. Tetrahedron Letters 2000, 41(10), 1549-1552

3) Bellemin-Laponnaz S., Coleman K. S., Osborn J. A. Co-ordination of the chiral N,O-ligand 2-[(1S, 2S, 5R)(-)-menthol]pyridine to molybdenum(VI) and vanadium(IV) oxo complexes – Crystal structures of [MoO2{2-(-)-menthol-pyridine}2] and [VO{2-(-)menthol-pyridine}2]. Polyhedron 2000, 18 (19), 2533-2536.

2) Bellemin-Laponnaz S., Le Ny J. P., Dedieu A. Mechanism of the allylic rearrangement of allyloxo metal oxo complexes: An ab initio theoretical investigation. Chem. Eur. J. 1999, 5 (1), 57-64.

1) Bellemin-Laponnaz S., Gisie H., Le Ny J. P., Osborn J. A. Mechanistic Insights into the Very Efficient [ReO3OSiR3]-Catalyzed Isomerization of Allyl Alcohols. Angew. Chem. Int. Ed. 1997, 36 (9), 976-978.