1839302
2DH6J37C
2024
surface-science-reports
50
creator
asc
22419
https://www.ipcms.fr/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-9ed74a97d5e53d2bb4f7dcad6325a67b%22%2C%22meta%22%3A%7B%22request_last%22%3A0%2C%22request_next%22%3A0%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%227RMU8JMF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Appleton%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.L.%20Appleton%2C%20L.%20Ballerini%2C%20S.%20Choua%2C%20C.%20Gourlaouen%2C%20R.%20Ruppert%2C%20M.%20Mauro%2C%20Cooperative%2C%20Close%20and%20Remote%20Steric%20Effects%20on%20the%20Structural%20and%20Optical%20Properties%20of%20Copper%28I%29%20Bis-Phenanthroline%20Complexes%2C%20European%20Journal%20of%20Inorganic%20Chemistry%2027%20%282024%29%20e202400278.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.202400278%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.202400278%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Cooperative%2C%20Close%20and%20Remote%20Steric%20Effects%20on%20the%20Structural%20and%20Optical%20Properties%20of%20Copper%28I%29%20Bis-Phenanthroline%20Complexes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jordan%20L.%22%2C%22lastName%22%3A%22Appleton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lavinia%22%2C%22lastName%22%3A%22Ballerini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22Choua%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Romain%22%2C%22lastName%22%3A%22Ruppert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22The%20synthesis%20as%20well%20as%20the%20structural%2C%20optical%20and%20computational%20characterization%20of%20seven%20new%20highly%20hindered%20homoleptic%20copper%28I%29%20phenanthroline%20complexes%20%28namely%20C1-C7%29%20is%20reported%20along%20with%20the%20comparison%20with%20the%20benchmark%20derivatives.%20Despite%20limited%20steric%20hindrance%20in%20direct%20proximity%20of%20the%20copper%28I%29%20coordination%20site%2C%20X-ray%20structures%20show%20that%20the%20higher%20hindered%20derivatives%20of%20the%20series%20display%20a%20more%20optimal%20tetrahedral%20geometry%20with%20minimal%20D2%20symmetry%20distortion.%20A%20novel%20remote%20control%20of%20the%20geometry%2C%20with%20steric%20hindrance%20away%20from%20the%20coordination%20site%2C%20leads%20to%20a%20favorable%20arrangement%20as%20demonstrated%20by%20structural%20and%20computational%20data.%20In%20addition%2C%20electrochemical%20and%20steady-state%20and%20time-resolved%20photophysical%20studies%20are%20presented%20which%20further%20support%20the%20beneficial%20effects%20on%20the%20ground-state%20redox%20and%20excited-state%20properties%20when%20both%20remote%20and%20close%20steric%20effects%20are%20exploited.%20Indeed%2C%20both%20an%20increase%20of%20the%20photoluminescence%20quantum%20yield%20and%20a%20prolongation%20of%20the%20excited%20state%20lifetime%20is%20observed%20for%20the%20highly-substituted%20derivative%20C6%20compared%20to%20benchmark%20counterparts%20on%20account%20of%20the%20reduced%20excited-state%20flattening%20distortions%20imparted%20by%20the%20additional%20steric%20constraints.Seven%20copper%28I%29%20phenanthroline%20complexes%20have%20been%20synthesized%20with%20steric%20hindrance%20present%20at%20and%20away%20from%20the%20coordination%20site%2C%20coined%20as%20remote%20control.%20This%20technique%20allowed%20for%20the%20synthesis%20of%20highly%20hindered%20stable%20homoleptic%20complexes%20which%20presented%20interesting%20ground%20and%20excited%20state%20properties%20that%20were%20corroborated%20by%20DFT%20calculations.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fejic.202400278%22%2C%22ISSN%22%3A%221434-1948%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fejic.202400278%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-09-13T09%3A14%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22M3XBAN5I%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Ballerini%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20Ballerini%2C%20W.-M.%20Zhang%2C%20T.%20Groizard%2C%20C.%20Gourlaouen%2C%20F.%20Polo%2C%20A.%20Jouaiti%2C%20H.-C.%20Su%2C%20M.%20Mauro%2C%20Binuclear%20iridium%28iii%29%20complexes%20for%20efficient%20near-infrared%20light-emitting%20electrochemical%20cells%20with%20electroluminescence%20up%20to%20800%20nm%2C%20Journal%20of%20Materials%20Chemistry%20C%20Early%20access%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4tc02040e%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4tc02040e%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Binuclear%20iridium%28iii%29%20complexes%20for%20efficient%20near-infrared%20light-emitting%20electrochemical%20cells%20with%20electroluminescence%20up%20to%20800%20nm%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lavinia%22%2C%22lastName%22%3A%22Ballerini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wei-Min%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomaz%22%2C%22lastName%22%3A%22Groizard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Gourlaouen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdelaziz%22%2C%22lastName%22%3A%22Jouaiti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hai-Ching%22%2C%22lastName%22%3A%22Su%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%5D%2C%22abstractNote%22%3A%22Near%20infrared%20%28NIR%29%20emitting%20optoelectronic%20devices%20have%20great%20potential%20for%20applications%20in%20communication%2C%20encryption%20technologies%2C%20night-vision%20display%20and%20photodynamic%20biomedical%20devices.%20Nevertheless%2C%20their%20development%20is%20currently%20hampered%20by%20the%20lack%20of%20efficient%20NIR-emissive%20materials.%20Herein%2C%20a%20novel%20class%20of%20cationic%20binuclear%20Ir%28iii%29%20emitters%20%28Ir-D1%20and%20Ir-D2%29%20based%20on%20a%20ditopic%20coordinating%20scaffold%20featuring%20the%20pi-deficient%20thiazolo%5B5%2C4-d%5Dthiazole%20and%20pi-accepting%20moiety%20%28either%20pyridine%20or%20pyrazine%29%2C%20is%20described%20and%20fully%20characterized%20using%20photophysical%20and%20computational%20techniques.%20Comparison%20with%20the%20parental%20mononuclear%20derivatives%20Ir-M1%20and%20Ir-M2%20is%20provided%20as%20well.%20Remarkably%2C%20the%20binuclear%20complexes%20display%20NIR%20photoluminescence%20in%20solution%20with%20a%20maximum%20up%20to%20lambda%28em%29%20%3D%20ca.%20840%20nm%2C%20which%20represent%20some%20rare%20examples%20of%20metal%20complexes%20emitting%20in%20this%20spectral%20region.%20Interestingly%2C%20NIR%20photoluminescence%20is%20retained%20in%20polymer-matrix%20thin-film%20for%20the%20binuclear%20counterparts.%20These%20findings%20prompt%20the%20successful%20use%20of%20these%20NIR%20emitters%20as%20electroactive%20materials%20in%20light%20emitting%20electrochemical%20cells%20%28LECs%29.%20Binuclear%20complexes%20Ir-D1%20and%20Ir-D2%20yield%20electroluminescence%20peaking%20at%20lambda%28EL%29%20%3D%20750%20and%20800%20nm%2C%20respectively%2C%20and%20device%20performances%20that%20are%20the%20highest%20reported%20for%20LECs%20in%20this%20spectral%20region%20to%20date%20for%20molecular%20%28i.e.%20non-excimer%29%20emitters.%20This%20work%20demonstrates%20the%20superior%20performances%20of%20the%20binuclear%20design%20strategy%20for%20achieving%20efficient%20NIR%20electroluminescence.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4tc02040e%22%2C%22ISSN%22%3A%222050-7526%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4tc02040e%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222024-08-22T06%3A59%3A28Z%22%7D%7D%2C%7B%22key%22%3A%22VAMNXKNE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Brouillac%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Brouillac%2C%20N.%20McIntosh%2C%20B.%20Heinrich%2C%20O.%20Jeannin%2C%20O.%20De%20Sagazan%2C%20N.%20Coulon%2C%20J.%20Rault-Berthelot%2C%20J.%20Cornil%2C%20E.%20Jacques%2C%20C.%20Quinton%2C%20C.%20Poriel%2C%20Grafting%20Electron-Accepting%20Fragments%20on%20%5B4%5Dcyclo-2%2C7-carbazole%20Scaffold%3A%20Tuning%20the%20Structural%20and%20Electronic%20Properties%20of%20Nanohoops%2C%20Advanced%20Science%20%282024%29%202309115.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadvs.202309115%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadvs.202309115%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Grafting%20Electron-Accepting%20Fragments%20on%20%5B4%5Dcyclo-2%2C7-carbazole%20Scaffold%3A%20Tuning%20the%20Structural%20and%20Electronic%20Properties%20of%20Nanohoops%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Brouillac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nemo%22%2C%22lastName%22%3A%22McIntosh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Jeannin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22De%20Sagazan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Coulon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joelle%22%2C%22lastName%22%3A%22Rault-Berthelot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Cornil%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuel%22%2C%22lastName%22%3A%22Jacques%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cassandre%22%2C%22lastName%22%3A%22Quinton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cyril%22%2C%22lastName%22%3A%22Poriel%22%7D%5D%2C%22abstractNote%22%3A%22Since%20the%20first%20applications%20of%20nanohoops%20in%20organic%20electronics%20appear%20promising%2C%20the%20time%20has%20come%20to%20go%20deeper%20into%20their%20rational%20design%20in%20order%20to%20reach%20high-efficiency%20materials.%20To%20do%20so%2C%20systematic%20studies%20dealing%20with%20the%20incorporation%20of%20electron-rich%20and%5C%2For%20electron-poor%20functional%20units%20on%20nanohoops%20have%20to%20be%20performed.%20Herein%2C%20the%20synthesis%2C%20the%20electrochemical%2C%20photophysical%2C%20thermal%2C%20and%20structural%20properties%20of%20two%20%5B4%5Dcyclo-2%2C7-carbazoles%2C%20%5B4%5DC-Py-Cbz%2C%20and%20%5B4%5DC-Pm-Cbz%2C%20possessing%20electron-withdrawing%20units%20on%20their%20nitrogen%20atoms%20%28pyridine%20or%20pyrimidine%29%20are%20reported.%20The%20synthesis%20of%20these%20nanohoops%20is%20first%20optimized%20and%20a%20high%20yield%20above%2050%25%20is%20reached.%20Through%20a%20structure-properties%20relationship%20study%2C%20it%20is%20shown%20that%20the%20substituent%20has%20a%20significant%20impact%20on%20some%20physicochemical%20properties%20%28eg%20HOMO%5C%2FLUMO%20levels%29%20while%20others%20are%20kept%20unchanged%20%28eg%20fluorescence%29.%20Incorporation%20in%20electronic%20devices%20shows%20that%20the%20most%20electrically%20efficient%20Organic%20Field-Effect%20transistors%20are%20obtained%20with%20%5B4%5DC-Py-Cbz%20although%20this%20compound%20does%20not%20present%20the%20best-organized%20semiconductor%20layer.%20These%20experimental%20data%20are%20finally%20confronted%20with%20the%20electronic%20couplings%20between%20the%20nanohoops%20determined%20at%20the%20DFT%20level%20and%20have%20highlighted%20the%20origin%20in%20the%20difference%20of%20charge%20transport%20properties.%20%5B4%5DC-Py-Cbz%20has%20the%20advantage%20of%20a%20more%202D-like%20transport%20character%20than%20%5B4%5DC-Pm-Cbz%2C%20which%20alleviates%20the%20impact%20of%20defects%20and%20structural%20organization.The%20synthesis%2C%20the%20electrochemical%2C%20photophysical%2C%20thermal%2C%20and%20structural%20properties%20of%20two%20%5B4%5Dcyclo-2%2C7-carbazoles%2C%20%5B4%5DC-Py-Cbz%20and%20%5B4%5DC-Pm-Cbz%2C%20possessing%20electron-withdrawing%20units%20on%20their%20nitrogen%20atoms%20%28i.e.%2C%20pyridine%20and%20pyrimidine%29%20are%20reported.%20Incorporation%20in%20electronic%20devices%20shows%20that%20the%20most%20electrically%20efficient%20OFETs%20are%20obtained%20with%20%5B4%5DC-Py-Cbz%20although%20this%20compound%20does%20not%20present%20the%20best-organized%20semiconductor%20layer.image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadvs.202309115%22%2C%22ISSN%22%3A%222198-3844%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadvs.202309115%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222024-06-20T13%3A17%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22C5QLFTG6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Brouillac%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Brouillac%2C%20A.%20Serez%2C%20N.%20Mcintosh%2C%20J.%20Rault-Berthelot%2C%20O.%20Jeannin%2C%20B.%20Heinrich%2C%20C.%20Quinton%2C%20O.%20De%20Sagazan%2C%20E.%20Jacques%2C%20J.%20Cornil%2C%20C.%20Poriel%2C%20Importance%20of%20the%20curvature%20in%20electronic%2C%20structural%20and%20charge%20transport%20properties%3A%20oligomers%20of%20N-pyridine%20carbazole%2C%20Journal%20of%20Materials%20Chemistry%20C%2012%20%282024%29%2012598%26%23x2013%3B12607.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4tc02304h%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4tc02304h%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Importance%20of%20the%20curvature%20in%20electronic%2C%20structural%20and%20charge%20transport%20properties%3A%20oligomers%20of%20N-pyridine%20carbazole%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Brouillac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ari%22%2C%22lastName%22%3A%22Serez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nemo%22%2C%22lastName%22%3A%22Mcintosh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joelle%22%2C%22lastName%22%3A%22Rault-Berthelot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Jeannin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cassandre%22%2C%22lastName%22%3A%22Quinton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22De%20Sagazan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuel%22%2C%22lastName%22%3A%22Jacques%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Cornil%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cyril%22%2C%22lastName%22%3A%22Poriel%22%7D%5D%2C%22abstractNote%22%3A%22The%20recent%20development%20of%20pi-conjugated%20nanohoops%20in%20organic%20electronics%20has%20opened%20new%20perspectives%20for%20this%20family%20of%20curved%20materials.%20Addressing%20the%20difference%20arising%20from%20curved%20vs.%20non-curved%20materials%20is%20an%20important%20concern%20in%20order%20to%20highlight%20the%20specific%20properties%20of%20curved%20materials.%20Herein%2C%20we%20discuss%20the%20significant%20differences%20arising%20between%20%5B4%5D-cyclo-N-pyridine-2%2C7-carbazole%20%5B4%5DC-Py-Cbz%20and%20its%20linear%20counterpart%2C%20N-pyridine-2%2C7-tetracarbazole%20%5B4%5DL-Py-Cbz.%20This%20study%20gathers%20optical%2C%20electrochemical%2C%20structural%2C%20morphological%20and%20charge%20transport%20properties%20and%20highlights%20the%20key%20role%20played%20by%20the%20curvature.%20We%20notably%20show%20how%20the%20electronic%20effects%20of%20the%20pending%20pyridines%20differently%20affect%20the%20molecular%20orbitals%20energies.%20We%20have%20also%20shown%20how%20structural%20rearrangements%20between%20ground%20and%20first%20excited%20states%20can%20be%20at%20the%20origin%20of%20the%20peculiar%20emission%20of%20nanohoops.%20Finally%2C%20the%20huge%20difference%20in%20terms%20of%20charge%20transport%20properties%20was%20discussed.%20Nanohoop%20%5B4%5DC-Py-Cbz%20displays%20a%20field-effect%20mobility%20in%20the%20saturated%20regime%20mu%28FEsat%29%20of%203.4%20x%2010%28-6%29%20cm%282%29%20V-1%20s%28-1%29%2C%20six%20times%20higher%20than%20that%20of%20its%20linear%20analogue%20%5B4%5DL-Py-Cbz%20%285.7%20x%2010%28-7%29%20cm%282%29%20V-1%20s%28-1%29%29.%20However%2C%20the%20detailed%20study%20of%20the%20charge%20transport%20properties%20shows%20that%20the%20linear%20analogue%20forms%20a%20semi-conducting%20layer%20with%20a%20lower%20trap%20density%2C%20more%20favourable%20to%20the%20charge%20hopping%20processes.%20Theoretical%20calculations%20have%20provided%20clues%20on%20the%20origin%20of%20these%20differences%2C%20revealing%20that%20despite%20the%20intensity%20of%20electronic%20couplings%20is%20significantly%20in%20favor%20of%20%5B4%5DL-Py-Cbz%2C%20their%20highly%20anisotropic%20character%20renders%20them%20more%20sensitive%20to%20defects%20and%20disorder.%20This%20is%20consistent%20with%20the%20fact%20that%20%5B4%5DC-Py-Cbz%20displays%20experimentally%20better%20charge%20transport%20properties%20than%20%5B4%5DL-Py-Cbz.%20Such%20a%20type%20of%20structure-property%20relationship%20study%20provides%20fundamental%20findings%20of%20interest%20for%20the%20future%20design%20of%20high-performance%20nanohoops.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4tc02304h%22%2C%22ISSN%22%3A%222050-7526%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4tc02304h%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-09-13T09%3A15%3A22Z%22%7D%7D%2C%7B%22key%22%3A%22DKPTL9QP%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Chen%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EY.%20Chen%2C%20J.%20He%2C%20H.%20Lin%2C%20H.-F.%20Wang%2C%20P.%20Hu%2C%20B.-Q.%20Wang%2C%20K.-Q.%20Zhao%2C%20B.%20Donnio%2C%20Efficient%20synthesis%20of%20fluorinated%20triphenylenes%20with%20enhanced%20arene-perfluoroarene%20interactions%20in%20columnar%20mesophases%2C%20Beilstein%20Journal%20of%20Organic%20Chemistry%2020%20%282024%29%203263%26%23x2013%3B3273.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3762%5C%2Fbjoc.20.270%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3762%5C%2Fbjoc.20.270%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Efficient%20synthesis%20of%20fluorinated%20triphenylenes%20with%20enhanced%20arene-perfluoroarene%20interactions%20in%20columnar%20mesophases%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yang%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiao%22%2C%22lastName%22%3A%22He%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hang%22%2C%22lastName%22%3A%22Lin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Hai-Feng%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ping%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bi-Qin%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22The%20high%20potential%20of%20non-covalent%20arene-fluoroarene%20intermolecular%20interactions%20in%20the%20design%20of%20liquid%20crystals%20lies%20in%20their%20ability%20to%20strongly%20promote%20self-assembly%2C%20improve%20the%20order%20and%20stability%20of%20the%20supramolecular%20mesophases%2C%20and%20enable%20tuneability%20of%20the%20optical%20and%20electronic%20properties%2C%20which%20can%20potentially%20be%20exploited%20for%20advanced%20applications%20in%20display%20technologies%2C%20photonic%20devices%2C%20sensors%2C%20and%20organic%20electronics.%20We%20recently%20successfully%20reported%20the%20straightforward%20synthesis%20of%20several%20mesogens%20containing%20four%20lateral%20aliphatic%20chains%20and%20derived%20from%20the%20classical%20triphenylene%20core%20self-assembling%20in%20columnar%20mesophases%20based%20on%20this%20paradigm.%20These%20mesogenic%20compounds%20were%20simply%20obtained%20in%20good%20yields%20by%20the%20nucleophilic%20substitution%20%28SNFAr%29%20of%20various%20types%20of%20commercially%20available%20fluoroarenes%20with%20the%20electrophilic%20organolithium%20derivatives%202%2C2%27-dilithio-4%2C4%27%2C5%2C5%27tetraalkoxy-1%2C1%27-biphenyl%20%282Li-BPn%29.%20In%20a%20continuation%20of%20this%20study%2C%20aiming%20at%20testing%20the%20limits%20of%20the%20reaction%20and%20providing%20a%20large%20diversity%20of%20structures%2C%20a%20structurally%20related%20series%20of%20compounds%20is%20reported%20here%2C%20namely%201%2C2%2C4-trifluoro-6%2C7%2C10%2C11tetraalkoxy-3-%28perfluorophenyl%29triphenylenes%20%28Fn%29.%20They%20were%20obtained%20by%20reacting%20the%20above%20mentioned%202%2C2%27-dilithiobiphenyl%20derivatives%20with%20decafluorobiphenyl%2C%20C6F5-C6F5.%20These%20compounds%20differ%20from%20the%20previously%20reported%20series%2C%201%2C2%2C4-trifluoro6%2C7%2C10%2C11-tetraalkoxy-3-aryltriphenylenes%20%28PHn%29%2C%20solely%20by%20the%20substitution%20of%20the%20terminal%20phenyl%20ring%20with%20a%20pentafluorophenyl%20ring.%20Thus%2C%20as%20expected%2C%20they%20display%20a%20Colhex%20mesophase%20over%20large%20temperature%20ranges%2C%20with%20only%20small%20differences%20in%20the%20mesophase%20stability%20and%20transition%20temperatures.%20Furthermore%2C%20the%20presence%20of%20the%20terminal%20fluorophenyl%20group%20enables%20a%20subsequent%20second%20annulation%2C%20yielding%20a%20new%20series%20of%20extended%20polyaromatic%20mesomorphic%20compounds%2C%20i.e.%2C%201%2C1%27%2C3%2C3%27%2C4%2C4%27-hexafluoro6%2C6%27%2C7%2C7%27%2C10%2C10%27%2C11%2C11%27-octaalkoxy-2%2C2%27-bitriphenylene%20%28Gnm%29%20which%20were%20found%20to%20display%20a%20Colrec%20mesophase.%20The%20specific%20nucleo%20philic%20substitution%20patterns%20of%20the%20F%20n%20derivatives%20and%20the%20antiparallel%20stacking%20mode%20into%20columnar%20structures%20stabilized%20by%20arene-perfluoroarene%20intermolecular%20interactions%20were%20confirmed%20by%20the%20single-crystal%20structure%20of%20the%20alkoxy-free%20side%20chain%20analog%2C%20i.e.%2C%201%2C2%2C4-trifluoro-3-%28perfluorophenyl%29triphenylene%20%28F%29.%20UV-vis%20absorption%20and%20fluorescence%20emission%20spectroscopies%20reveal%20green%20photoluminescence%20with%20fluorescence%20quantum%20yields%20of%20up%20to%2033%25%20for%20the%20F%20n%20derivatives.%20The%20J-aggregation%20for%20the%20inner%20fluorine-substituted%20dimers%20G%20nm%20is%20energetically%20and%20stereoelectronically%20more%20favorable%20and%20G%2066%20exhibits%20thin-film%20fluores-%20cence%20with%20a%20large%20red-shift%20of%20the%20emission%20peak.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3762%5C%2Fbjoc.20.270%22%2C%22ISSN%22%3A%221860-5397%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222025-01-09T13%3A16%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22NYIUY7CX%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Del%20Giudice%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Del%20Giudice%2C%20G.%20Voegeli%2C%20J.-M.%20Strub%2C%20B.%20Heinrich%2C%20L.%20Douce%2C%20Ionic%20Liquid%20Crystals%20Based%20on%20Loop-Shaped%20Copper%28I%29%20Complexes.%2C%20Inorganic%20Chemistry%2063%20%282024%29%206103%26%23x2013%3B6110.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.4c00728%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.inorgchem.4c00728%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ionic%20Liquid%20Crystals%20Based%20on%20Loop-Shaped%20Copper%28I%29%20Complexes.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Del%20Giudice%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Voegeli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Strub%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Douce%22%7D%5D%2C%22abstractNote%22%3A%22This%20paper%20describes%20the%20synthesis%20and%20characterization%20of%20liquid%20crystals%20based%20on%20loop-shaped%20cationic%20copper%28I%29%20complexes%20of%20a%20multidentate%20ligand.%20Their%20synthesis%20involves%20the%20one-pot%20reaction%20of%20an%20alkyloxy-decorated%20pyridine-aldehyde%20unit%20with%20a%20diamine%20%282%2C2%27-%28ethylenedioxy%29bis%28ethylamine%29%29%20spacer%20to%20form%20in%20situ%20a%20pyridine-imine%20quadridentate-N4-donor%20ligand%2C%20L%2C%20which%20is%20able%20to%20chelate%20a%20copper%28I%29%20center%20associated%20with%20various%20noncoordinating%20anions.%20All%20of%20these%20compounds%20were%20characterized%20by%20NMR%2C%20IR%2C%20and%20electronic%20absorption%20spectroscopy%2C%20and%20more%20particularly%20by%20X-ray%20diffraction%20and%20mass%20spectroscopy%2C%20enabling%20unambiguous%20assignment%20of%20the%20%5BML%5D%2B%20mononuclear%20nature%20of%20the%20cationic%20components.%20The%20presence%20of%20six%20flexible%20alkyloxy%20chains%20at%20each%20end%20of%20the%20ligand%20associated%20with%20the%20rigidity%20of%20the%20core%20complex%20causes%20induction%20of%20a%20liquid%20crystal%20state%20with%20a%20columnar%20self-organized%20architecture%2C%20where%20the%20columns%20are%20packed%20in%20a%20hexagonal%20two-dimensional%20network.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.inorgchem.4c00728%22%2C%22ISSN%22%3A%221520-510X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.inorgchem.4c00728%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22VYTETDZF%22%5D%2C%22dateModified%22%3A%222024-06-20T13%3A21%3A39Z%22%7D%7D%2C%7B%22key%22%3A%22VYM5PRIQ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Diaa%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.A.%20Diaa%2C%20N.%20El-Mahallawy%2C%20M.%20Shoeib%2C%20F.%20Mouillard%2C%20T.%20Fert%26%23xE9%3B%2C%20P.%20Masson%2C%20A.%20Carrad%26%23xF2%3B%2C%20Biodegradable%20PMMA%20coated%20Zn-Mg%20alloy%20with%20bimodal%20grain%20structure%20for%20orthopedic%20applications%20-%20A%20promising%20alternative.%2C%20Bioactive%20Materials%2039%20%282024%29%20479%26%23x2013%3B491.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bioactmat.2024.05.031%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bioactmat.2024.05.031%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Biodegradable%20PMMA%20coated%20Zn-Mg%20alloy%20with%20bimodal%20grain%20structure%20for%20orthopedic%20applications%20-%20A%20promising%20alternative.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alia%20A%22%2C%22lastName%22%3A%22Diaa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nahed%22%2C%22lastName%22%3A%22El-Mahallawy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Madiha%22%2C%22lastName%22%3A%22Shoeib%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Flavien%22%2C%22lastName%22%3A%22Mouillard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tom%22%2C%22lastName%22%3A%22Fert%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Masson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Adele%22%2C%22lastName%22%3A%22Carrad%5Cu00f2%22%7D%5D%2C%22abstractNote%22%3A%22The%20study%20examines%20the%20impact%20of%20microstructure%20and%20polymethyl%20methacrylate%20%28PMMA%29%20grafting%20on%20the%20degradability%20of%20Zn-Mg%20alloys.%20The%20mechanical%20properties%20of%20a%20Zn%20alloy%20containing%200.68wt%25%20Mg%20and%20extruded%20at%20200%5Cu00b0C%20are%20enhanced%20for%20degradable%20load-bearing%20applications%2C%20addressing%20a%20crucial%20need%20in%20the%20field.%20The%20material%20exhibits%20a%20bimodal%20grain%20size%20distribution%20that%20is%20random%20texture%2C%20consisting%20of%20secondary%20phases%2C%20grains%2C%20and%20sub-grains.%20With%20an%20elongation%20to%20failure%20of%2016%25%2C%20the%20yield%20and%20ultimate%20tensile%20strengths%20are%20325.9%20and%20414.5MPa%2C%20respectively%2C%20and%20the%20compressive%20yield%20strength%20is%20450.5MPa.%20The%20%5C%22grafting-from%5C%22%20method%20was%20used%20to%20coat%20a%20few%20micrometers%20thick%20of%20PMMA%20on%20both%20bulk%20and%20scaffold%20Zn%20alloys%20to%20mitigate%20the%20corrosion%20rate.%20The%20last%20one%20is%20a%20porous%20structure%2C%20with%20a%20porosity%20of%2065.8%20%25%2C%20considered%20as%20in%20the%20first%20approach%20of%20an%20orthopedic%20implant.%20After%20being%20immersed%20for%20720h%2C%20the%20PMMA-grafted%20bulk%20alloy%27s%20corrosion%20rate%20decreased%20from%200.43%20to%200.25mm%5C%2Fy.%20Similarly%2C%20the%20scaffold%20alloy%27s%20corrosion%20rate%20reduced%20from%201.24%20to%200.49mm%5C%2Fy.%20These%20results%20indicate%20that%20the%20method%20employed%20could%20be%20used%20for%20future%20orthopedic%20applications.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.bioactmat.2024.05.031%22%2C%22ISSN%22%3A%222452-199X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.bioactmat.2024.05.031%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22DEB5KWFS%22%2C%22MKAFAH44%22%2C%226739WBV7%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A13%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22MJLBL6LK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Durand%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Durand%2C%20H.%20Zeng%2C%20B.%20Jismy%2C%20O.%20Boyron%2C%20B.%20Heinrich%2C%20L.%20Herrmann%2C%20O.%20Bardagot%2C%20I.%20Moutsios%2C%20A.V.%20Mariasevskaia%2C%20A.P.%20Melnikov%2C%20D.A.%20Ivanov%2C%20M.%20Brinkmann%2C%20N.%20Leclerc%2C%20Controlling%20conjugated%20polymer%20morphology%20by%20precise%20oxygen%20position%20in%20single-ether%20side%20chains.%2C%20Materials%20Horizons%20Early%20Access%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4mh00492b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4mh00492b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Controlling%20conjugated%20polymer%20morphology%20by%20precise%20oxygen%20position%20in%20single-ether%20side%20chains.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pablo%22%2C%22lastName%22%3A%22Durand%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Huiyan%22%2C%22lastName%22%3A%22Zeng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Badr%22%2C%22lastName%22%3A%22Jismy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Boyron%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Herrmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Bardagot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ioannis%22%2C%22lastName%22%3A%22Moutsios%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alina%20V%22%2C%22lastName%22%3A%22Mariasevskaia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexey%20P%22%2C%22lastName%22%3A%22Melnikov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dimitri%20A%22%2C%22lastName%22%3A%22Ivanov%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martin%22%2C%22lastName%22%3A%22Brinkmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Leclerc%22%7D%5D%2C%22abstractNote%22%3A%22Recently%2C%20polar%20side%20chains%20have%20emerged%20as%20a%20functional%20tool%20to%20enhance%20conjugated%20polymer%20doping%20properties%20by%20improving%20the%20polymer%20miscibility%20with%20polar%20chemical%20dopants%20and%20facilitate%20solvated%20ion%20uptake.%20In%20this%20work%2C%20we%20design%20and%20investigate%20a%20novel%20family%20of%20side%20chains%20containing%20a%20single%20ether%20function%2C%20enabling%20the%20modulation%20of%20the%20oxygen%20atom%20position%20along%20the%20side%20chain.%20A%20meticulous%20investigation%20of%20this%20new%20polymer%20series%20by%20differential%20scanning%20calorimetry%2C%20fast%20scanning%20chip%20calorimetry%20and%20X-ray%20scattering%20shows%20that%20polymers%20bearing%20single-ether%20side%20chains%20can%20show%20high%20degree%20of%20crystallinity%20under%20proper%20conditions.%20Importantly%2C%20due%20to%20a%20gauche%20effect%20allowing%20the%20side%20chain%20to%20bend%20at%20the%20oxygen%20atom%2C%20the%20degree%20of%20crystallinity%20of%20polymers%20can%20be%20controlled%20by%20the%20position%20of%20the%20oxygen%20atom%20along%20the%20side%20chain.%20The%20further%20the%20oxygen%20atom%20is%20from%20the%20conjugated%20backbone%2C%20the%20more%20crystalline%20the%20polymer%20becomes.%20In%20addition%2C%20for%20all%20new%20polymers%2C%20high%20thermomechanical%20properties%20are%20demonstrated%2C%20leading%20to%20remarkable%20electrical%20conductivities%20and%20thermoelectric%20power%20factors%20in%20rub-aligned%20and%20sequentially%20doped%20thin%20films.%20This%20work%20confirms%20the%20potential%20of%20single-ether%20side%20chains%20to%20be%20used%20as%20polar%20solubilizing%20side%20chains%20for%20the%20design%20of%20a%20next%20generation%20of%20p-%20and%20n-type%20semiconducting%20polymers%20with%20increased%20affinity%20to%20polar%20dopants%20while%20maintaining%20high%20molecular%20order.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4mh00492b%22%2C%22ISSN%22%3A%222051-6355%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4mh00492b%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222024-08-22T07%3A03%3A04Z%22%7D%7D%2C%7B%22key%22%3A%2224NNYNZV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dussart%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Dussart%2C%20A.%20Maisse-Francois%2C%20S.%20Bellemin-Laponnaz%2C%20Chiral%20Self-Sorting%20Process%20With%20C2%20Symmetric%20Bisimidazoline%20Ligands%2C%20Chirality%2036%20%282024%29%20e23720.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchir.23720%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchir.23720%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Chiral%20Self-Sorting%20Process%20With%20C2%20Symmetric%20Bisimidazoline%20Ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Caitlyn%22%2C%22lastName%22%3A%22Dussart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aline%22%2C%22lastName%22%3A%22Maisse-Francois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22We%20have%20studied%20the%20coordination%20chemistry%20of%20chiral%20imidazoline-based%20C-2-symmetric%20ligands%20with%20zinc%20%28II%29%20and%20copper%20%28II%29.%20Two%20types%20of%20bisimidazoline%20ligands%20were%20studied%2C%20one%20with%20the%20free%20amine%20%28BIM-H%29%20and%20the%20other%20with%20the%20amine%20protected%20by%20a%20toluene%20sulfonyl%20group%20in%20position%206%20%28BIM-Ts%29.%20The%20complexes%20formed%20were%20isolated%2C%20purified%2C%20and%20characterized%2C%20in%20particular%20by%20X-ray%20diffraction%20studies%20and%20CD%20in%20the%20case%20of%20the%20enantiopure%20complexes.%20By%20playing%20with%20the%20choice%20of%20ligand%20system%20%28enantiopure%20or%20racemate%29%2C%20we%20were%20able%20to%20show%20that%20the%20selective%20formation%20of%20homoleptic%20and%20heteroleptic%20metal%20complexes%20can%20be%20controlled%20by%20means%20of%20the%20chiral%20molecular%20instruction%20of%20bisimidazoline%20ligands.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchir.23720%22%2C%22ISSN%22%3A%220899-0042%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchir.23720%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-11-08T10%3A37%3A11Z%22%7D%7D%2C%7B%22key%22%3A%22JNNK79VJ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dussart%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Dussart%2C%20A.%20Bonnefont%2C%20S.%20Bellemin-Laponnaz%2C%20Cu%26lt%3BSUP%26gt%3BI%26lt%3B%5C%2FSUP%26gt%3B%5C%2FCu%26lt%3BSUP%26gt%3BII%26lt%3B%5C%2FSUP%26gt%3B%20Chiral%20Homoleptic%20Complexes%3A%20Study%20of%20Self-Recognition%20and%20Self-Discrimination%2C%20European%20Journal%20of%20Inorganic%20Chemistry%2027%20%282024%29%20e202400527.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.202400527%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fejic.202400527%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Cu%3CSUP%3EI%3C%5C%2FSUP%3E%5C%2FCu%3CSUP%3EII%3C%5C%2FSUP%3E%20Chiral%20Homoleptic%20Complexes%3A%20Study%20of%20Self-Recognition%20and%20Self-Discrimination%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Caitlyn%22%2C%22lastName%22%3A%22Dussart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antoine%22%2C%22lastName%22%3A%22Bonnefont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22The%20formation%20of%20ML2%20homoleptic%20copper%28I%29%20and%20copper%28II%29%20complexes%20from%20bidentate%20chiral%20ligands%20with%20C2%20symmetry%2C%20comprising%20three%20types%20of%20substituents%20%28namely%20benzyl%2C%20indanyl%20and%20phenyl%20groups%29%2C%20was%20investigated.%20The%20formation%20of%20homochiral%20or%20heterochiral%20complexes%20can%20be%20influenced%20by%20the%20nature%20of%20the%20substituents%20and%20the%20geometry%20induced%20by%20the%20oxidation%20state%20of%20the%20metal.%20All%20the%20complexes%20were%20isolated%20and%20characterized%2C%20in%20particular%20in%20the%20solid%20state%20by%20X-ray%20diffraction%20studies.%20In%20solution%2C%20cyclic%20voltammetry%20was%20used%20to%20study%20ligand%20association%20and%20discrimination%20induced%20by%20the%20CuI%5C%2FCuII%20transition.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fejic.202400527%22%2C%22ISSN%22%3A%221434-1948%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fejic.202400527%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222025-01-13T14%3A08%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22RDEU4IEG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guchait%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Guchait%2C%20S.%20Oummouch%2C%20P.%20Durand%2C%20N.%20Kamatham%2C%20B.%20Jismy%2C%20L.%20Herrmann%2C%20S.%20M%26%23xE9%3Bry%2C%20N.%20Leclerc%2C%20M.%20Brinkmann%2C%20Impact%20of%20Side%20Chain%20Chemical%20Structure%20on%20Doping%20and%20Thermoelectric%20Properties%20of%20Oriented%20PBTTT%20Thin%20Films.%2C%20Small%20%282024%29%20e2410073.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.202410073%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmll.202410073%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Impact%20of%20Side%20Chain%20Chemical%20Structure%20on%20Doping%20and%20Thermoelectric%20Properties%20of%20Oriented%20PBTTT%20Thin%20Films.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shubhradip%22%2C%22lastName%22%3A%22Guchait%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Said%22%2C%22lastName%22%3A%22Oummouch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pablo%22%2C%22lastName%22%3A%22Durand%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Narayanaswamy%22%2C%22lastName%22%3A%22Kamatham%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Badr%22%2C%22lastName%22%3A%22Jismy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Herrmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22M%5Cu00e9ry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Leclerc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martin%22%2C%22lastName%22%3A%22Brinkmann%22%7D%5D%2C%22abstractNote%22%3A%22In%20this%20contribution%2C%20doping%20of%20oriented%20thin%20films%20is%20investigated%20for%20three%20PBTTT%20polymers%20bearing%20different%20side%20chains%20including%20linear%20alkyl%20%5Cu2500%28CH2%2912%5Cu2500H%2C%20single%20ether%20%5Cu2500%28CH2%297%5Cu2500O%5Cu2500%28CH2%294%5Cu2500H%20and%20alkyl-siloxane%20%5Cu2500%28CH2%295%5Cu2500%28Si%28CH3%292O%292%5Cu2500Si%28CH3%293%20A%20combination%20of%20transmission%20electron%20microscopy%2C%20polarized%20UV-vis-NIR%20spectroscopy%20and%20transport%20measurements%20helps%20uncover%20the%20essential%20role%20of%20the%20chemical%20nature%20of%20side%20chains%20on%20the%20efficacy%20of%20the%20doping%20and%20on%20the%20resulting%20thermoelectric%20performances%20in%20oriented%20PBTTT%20films.%20Siloxane%20side%20chains%20help%20to%20reach%20record%20alignment%20level%20of%20PBTTT%20with%20dichroic%20ratio%20beyond%2050%20for%20an%20optimized%20rubbing%20temperature%20but%20they%20impede%20effective%20doping%20of%20PBTTT%20crystals%20with%20F6TCNNQ%2C%20resulting%20in%20very%20poor%20TE%20properties.%20By%20contrast%2C%20doping%20the%20amorphous%20phase%20of%20all%20three%20PBTTTs%20with%20magic%20blue%20%28MB%29%20results%20in%20excellent%20TE%20performances.%20Both%2C%20chemical%20nature%20of%20side%20chains%20and%20semi-crystalline%20structure%20of%20the%20polymer%20determine%20the%20efficacy%20of%20doping.%20The%20use%20of%20siloxane%20side%20chains%20further%20impacts%20the%20scaling%20laws%20Ssigma-1%5C%2Fs%20between%20the%20Seebeck%20coefficient%20S%20and%20the%20charge%20conductivity%20sigma.%20An%20unexpected%20s%20%3D%202%20exponent%20is%20observed%20and%20tentatively%20attributed%20to%20the%20dimensionality%20of%20charge%20transport%20in%20the%20highly%20oriented%20mesophase%20of%20PBTTT.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fsmll.202410073%22%2C%22ISSN%22%3A%221613-6829%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22VYTETDZF%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222025-01-09T13%3A17%3A03Z%22%7D%7D%2C%7B%22key%22%3A%22QU5MFQKL%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hemmerle%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Hemmerle%2C%20N.%20Aubert%2C%20T.%20Moreno%2C%20P.%20Kekicheff%2C%20B.%20Heinrich%2C%20S.%20Spagnoli%2C%20M.%20Goldmann%2C%20G.%20Ciatto%2C%20P.%20Fontaine%2C%20Opportunities%20and%20new%20developments%20for%20the%20study%20of%20surfaces%20and%20interfaces%20in%20soft%20condensed%20matter%20at%20the%20SIRIUS%20beamline%20of%20Synchrotron%20SOLEIL.%2C%20Journal%20of%20Synchrotron%20Radiation%2031%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600577523008810%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600577523008810%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Opportunities%20and%20new%20developments%20for%20the%20study%20of%20surfaces%20and%20interfaces%20in%20soft%20condensed%20matter%20at%20the%20SIRIUS%20beamline%20of%20Synchrotron%20SOLEIL.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arnaud%22%2C%22lastName%22%3A%22Hemmerle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Aubert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Moreno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Kekicheff%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22Spagnoli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Michel%22%2C%22lastName%22%3A%22Goldmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gianluca%22%2C%22lastName%22%3A%22Ciatto%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Fontaine%22%7D%5D%2C%22abstractNote%22%3A%22The%20SIRIUS%20beamline%20of%20Synchrotron%20SOLEIL%20is%20dedicated%20to%20X-ray%20scattering%20and%20spectroscopy%20of%20surfaces%20and%20interfaces%2C%20covering%20the%20tender%20to%20mid-hard%20X-ray%20range%20%281.1-13%5Cu2005keV%29.%20The%20beamline%20has%20hosted%20a%20wide%20range%20of%20experiments%20in%20the%20field%20of%20soft%20interfaces%20and%20beyond%2C%20providing%20various%20grazing-incidence%20techniques%20such%20as%20diffraction%20and%20wide-angle%20scattering%20%28GIXD%5C%2FGIWAXS%29%2C%20small-angle%20scattering%20%28GISAXS%29%20and%20X-ray%20fluorescence%20in%20total%20reflection%20%28TXRF%29.%20SIRIUS%20also%20offers%20specific%20sample%20environments%20tailored%20for%20in%20situ%20complementary%20experiments%20on%20solid%20and%20liquid%20surfaces.%20Recently%2C%20the%20beamline%20has%20added%20compound%20refractive%20lenses%20associated%20with%20a%20transfocator%2C%20allowing%20for%20the%20X-ray%20beam%20to%20be%20focused%20down%20to%2010%5Cu2005m%20%2A%2010%5Cu2005m%20while%20maintaining%20a%20reasonable%20flux%20on%20the%20sample.%20This%20new%20feature%20opens%20up%20new%20possibilities%20for%20faster%20GIXD%20measurements%20at%20the%20liquid-air%20interface%20and%20for%20measurements%20on%20samples%20with%20narrow%20geometries.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1107%5C%2FS1600577523008810%22%2C%22ISSN%22%3A%221600-5775%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1107%5C%2FS1600577523008810%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222024-06-20T13%3A26%3A22Z%22%7D%7D%2C%7B%22key%22%3A%228KC66DAT%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Henning%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EX.%20Henning%2C%20K.%20Alhada-Lahbabi%2C%20D.%20Deleruyelle%2C%20B.%20Gautier%2C%20L.%20Schlur%2C%20T.%20Fix%2C%20S.%20Colis%2C%20A.%20Dinia%2C%20M.V.%20Rastei%2C%20Oxygen%20vacancy%20effects%20on%20polarization%20switching%20of%20ferroelectric%20Bi%3Csub%3E2%3C%5C%2Fsub%3EFeCrO%3Csub%3E6%3C%5C%2Fsub%3E%20thin%20films%2C%20Physical%20Review%20Materials%208%20%282024%29%20054416.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.8.054416%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.8.054416%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Oxygen%20vacancy%20effects%20on%20polarization%20switching%20of%20ferroelectric%20Bi%3Csub%3E2%3C%5C%2Fsub%3EFeCrO%3Csub%3E6%3C%5C%2Fsub%3E%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Henning%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Alhada-Lahbabi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Deleruyelle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Gautier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Fix%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silviu%22%2C%22lastName%22%3A%22Colis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aziz%22%2C%22lastName%22%3A%22Dinia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mircea%20V.%22%2C%22lastName%22%3A%22Rastei%22%7D%5D%2C%22abstractNote%22%3A%22The%20controlled%20switching%20of%20spontaneous%20polarization%20in%20ferroelectrics%20by%20applying%20an%20external%20electric%20field%20is%20essential%20for%20many%20device%20operations.%20Oxygen%20vacancy%20defects%20commonly%20found%20in%20oxide%20ferroelectrics%20offer%20a%20tempting%20means%20for%20polarization%20switching%20regulation%20at%20an%20atomic%20scale.%20This%20study%20presents%20a%20method%20involving%20a%20series%20of%20annealing%20cycles%20under%20various%20environments%20to%20modulate%20the%20amount%20of%20oxygen%20vacancies%20in%20ferroelectric%20Bi2FeCrO6%20thin%20films.%20By%20performing%20a%20piezoresponse%20force%20microscopy%20study%20after%20each%20annealing%20cycle%2C%20it%20is%20shown%20that%20a%20high%20content%20of%20oxygen%20vacancies%20induces%20specific%20fingerprints%20on%20polarization%20hysteresis%20loops.%20Reducing%20oxygen%20vacancy%20density%20by%20annealing%20in%20oxygen-rich%20environments%20results%20in%20hysteresis%20loops%20being%20wider%20and%20displaying%20less%20imprint%2C%20while%20increasing%20oxygen%20vacancy%20density%20by%20annealing%20in%20oxygen-poor%20environments%20results%20in%20thinner%20and%20more%20imprinted%20hysteresis%20loops.%20The%20process%20is%20largely%20reversible%2C%20constituting%20an%20alternative%20method%20for%20polarization%20switching%20control%20at%20specific%20electric%20fields.%20Ferroelectric%20phase-field%20calculations%20and%20energy%20level%20diagrams%20obtained%20through%20ellipsometry%2C%20Kelvin%20probe%2C%20and%20photoemission%20spectroscopy%20indicate%20a%20combined%20switching%20mechanism%20based%20on%20a%20doping%20effect%20due%20to%20oxygen%20vacancies%20and%20a%20built-in%20electric%20field%20originating%20from%20the%20interface.%20Our%20study%20is%20helpful%20for%20designing%20ferroelectric%20films%20with%20a%20precise%20imprint%20or%2C%20more%20generally%2C%20for%20understanding%20the%20impact%20of%20charged%20defects%20on%20the%20polarization%20states%20in%20ferroelectric%20films.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevMaterials.8.054416%22%2C%22ISSN%22%3A%222475-9953%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevMaterials.8.054416%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222024-06-20T12%3A08%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22J29GWZSV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Hoffmann%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EN.%20Hoffmann%2C%20M.A.G.%20Fernandez%2C%20A.%20Desvals%2C%20C.%20Lefebvre%2C%20C.%20Michelin%2C%20M.%20Latrache%2C%20Photochemical%20reactions%20of%20biomass%20derived%20platform%20chemicals%2C%20Frontiers%20in%20Chemistry%2012%20%282024%29%201485354.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3389%5C%2Ffchem.2024.1485354%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3389%5C%2Ffchem.2024.1485354%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Photochemical%20reactions%20of%20biomass%20derived%20platform%20chemicals%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Norbert%22%2C%22lastName%22%3A%22Hoffmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%20Andres%20Gomez%22%2C%22lastName%22%3A%22Fernandez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arthur%22%2C%22lastName%22%3A%22Desvals%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corentin%22%2C%22lastName%22%3A%22Lefebvre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Michelin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohammed%22%2C%22lastName%22%3A%22Latrache%22%7D%5D%2C%22abstractNote%22%3A%22Platform%20chemicals%20obtained%20from%20biomass%20will%20play%20an%20important%20role%20in%20chemical%20industry.%20Already%20existing%20compounds%20or%20not%20yet%20established%20chemicals%20are%20produced%20from%20this%20renewable%20feedstock.%20Using%20photochemical%20reactions%20as%20sustainable%20method%20for%20the%20conversion%20of%20matter%20furthermore%20permits%20to%20develop%20processes%20that%20are%20interesting%20from%20the%20ecological%20and%20economical%20point%20of%20view.%20Furans%20or%20levoglucosenone%20are%20thus%20obtained%20from%20carbohydrate%20containing%20biomass.%20Photochemical%20rearrangements%2C%20photooxygenation%20reactions%20or%20photocatalytic%20radical%20reactions%20can%20be%20carried%20out%20with%20such%20compounds.%20Also%2C%20sugars%20such%20pentoses%20or%20hexoses%20can%20be%20more%20easily%20transformed%20into%20heterocyclic%20target%20compounds%20when%20such%20photochemical%20reactions%20are%20used.%20Lignin%20is%20an%20important%20source%20for%20aromatic%20compounds%20such%20as%20vanillin.%20Photocycloaddition%20of%20these%20compounds%20with%20alkenes%20or%20the%20use%20light%20supported%20multicomponent%20reactions%20yield%20interesting%20target%20molecules.%20Dyes%2C%20surfactants%20or%20compounds%20possessing%20a%20high%20degree%20of%20molecular%20diversity%20and%20complexity%20have%20been%20synthesized%20with%20photochemical%20key%20steps.%20Alkenes%20as%20platform%20chemicals%20are%20also%20produced%20by%20fermentation%20processes%2C%20for%20example%2C%20with%20cyanobacteria%20using%20biological%20photosynthesis.%20Such%20alkenes%20as%20well%20as%20terpenes%20may%20further%20be%20transformed%20in%20photochemical%20reactions%20yielding%2C%20for%20example%2C%20precursors%20of%20jet%20fuels.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3389%5C%2Ffchem.2024.1485354%22%2C%22ISSN%22%3A%222296-2646%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3389%5C%2Ffchem.2024.1485354%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222025-01-13T14%3A08%3A17Z%22%7D%7D%2C%7B%22key%22%3A%2288CR5QRA%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jankovic%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ED.%20Jankovic%2C%20J.-G.%20Hartmann%2C%20M.%20Ruben%2C%20P.-A.%20Hervieux%2C%20Noisy%20qudit%20vs%20multiple%20qubits%3A%20conditions%20on%20gate%20efficiency%20for%20enhancing%20fidelity%2C%20NPJ%20Quantum%20Information%2010%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41534-024-00829-6%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41534-024-00829-6%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Noisy%20qudit%20vs%20multiple%20qubits%3A%20conditions%20on%20gate%20efficiency%20for%20enhancing%20fidelity%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Denis%22%2C%22lastName%22%3A%22Jankovic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Gabriel%22%2C%22lastName%22%3A%22Hartmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul-Antoine%22%2C%22lastName%22%3A%22Hervieux%22%7D%5D%2C%22abstractNote%22%3A%22As%20qubit-based%20platforms%20face%20near-term%20technical%20challenges%20in%20terms%20of%20scalability%2C%20qudits%2C%20d-level%20bases%20of%20quantum%20information%2C%20are%20being%20implemented%20in%20multiple%20platforms%20as%20an%20alternative%20for%20Quantum%20Information%20Processing%20%28QIP%29.%20We%20compare%20the%20infidelity%20scalings%20of%20single%20qudit%20and%20multiqubit%20systems%20within%20identical%20Hilbert%20space%20dimensions%20and%20noisy%20environments%20in%20the%20Lindblad%20formalism.%20We%20find%20them%20to%20be%20gate-independent%20to%20first-order%20and%20present%20an%20analytically-derived%20critical%20curve%20%28%20d%202%20-%201%20%29%20%5C%2F%203%20log%202%20%28%20d%20%29%20%5C%5Cdocumentclass%5B12pt%5D%7Bminimal%7D%20%5C%5Cusepackage%7Bamsmath%7D%20%5C%5Cusepackage%7Bwasysym%7D%20%5C%5Cusepackage%7Bamsfonts%7D%20%5C%5Cusepackage%7Bamssymb%7D%20%5C%5Cusepackage%7Bamsbsy%7D%20%5C%5Cusepackage%7Bmathrsfs%7D%20%5C%5Cusepackage%7Bupgreek%7D%20%5C%5Csetlength%7B%5C%5Coddsidemargin%7D%7B-69pt%7D%20%5C%5Cbegin%7Bdocument%7D%24%24%28%7Bd%7D%3C%5E%3E%7B2%7D-1%29%5C%2F3%7B%5C%5Clog%20%7D_%7B2%7D%28d%29%24%24%5C%5Cend%7Bdocument%7D%20that%20benchmarks%20the%20operational%20time%20efficiency%20of%20qudits%20and%20qubits%20relative%20to%20their%20decoherence%20times.%20This%20comparison%20reveals%20conditions%20under%20which%20qudits%20offer%20competitive%20gate%20efficiencies%20compared%20to%20leading%20qubit%20platforms.%20Our%20findings%2C%20supported%20by%20numerical%20simulations%20testing%20the%20applicability%20and%20limits%20of%20the%20linear%20response%20formalism%2C%20highlight%20the%20relevance%20of%20qudits%20in%20near-term%20QIP.%20This%20provides%20a%20benchmark%20for%20evaluating%20qudit%20platforms%2C%20specifically%20those%20with%20lower%20dimensionality%2C%20in%20terms%20of%20their%20operational%20efficiency%20relative%20to%20the%20qubit%20state-of-the-art.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41534-024-00829-6%22%2C%22ISSN%22%3A%222056-6387%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41534-024-00829-6%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%2288PVNMDA%22%2C%22CHW2VGSR%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A50%3A12Z%22%7D%7D%2C%7B%22key%22%3A%22NUD7ZH2R%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Jebnouni%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Jebnouni%2C%20S.%20Teka%2C%20B.%20Heinrich%2C%20M.%20Majdoub%2C%20N.S.%20Jaballah%2C%20N.%20Leclerc%2C%20Molecular%20semiconductors%20with%20Carbazole%20versus%20Triazatruxene%20endcaps%3A%20A%20matter%20of%20self-assembly%2C%20Journal%20of%20Molecular%20Structure%201318%20%282024%29%20139241.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.molstruc.2024.139241%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.molstruc.2024.139241%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Molecular%20semiconductors%20with%20Carbazole%20versus%20Triazatruxene%20endcaps%3A%20A%20matter%20of%20self-assembly%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Achref%22%2C%22lastName%22%3A%22Jebnouni%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Safa%22%2C%22lastName%22%3A%22Teka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mustapha%22%2C%22lastName%22%3A%22Majdoub%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nejmeddine%20Smida%22%2C%22lastName%22%3A%22Jaballah%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Leclerc%22%7D%5D%2C%22abstractNote%22%3A%22In%20this%20work%2C%20we%20describe%20the%20design%20and%20synthesis%20of%20a%20novel%20soluble%20conjugated%20molecule%2C%20CAR-TzDPP%2C%20consisting%20of%20a%20central%20diketopyrrolopyrrole%20core%20%28DPP%29%20connected%20to%20carbazole%20endcaps%20through%20thiazole%20rings.%20To%20evaluate%20its%20properties%2C%20a%20triazatruxene-based%20molecule%20%28TAT-TzDPP%29%20was%20used%20as%20a%20model%20for%20comparison.%20The%20electrochemical%20and%20the%20in-solution%20optical%20properties%20are%20in%20good%20agreement%20with%20those%20obtained%20from%20DFT%20calculations.%20However%2C%20the%20thin-film%20self-assemblies%20of%20CAR-TzDPP%20exhibited%20distinct%20differences%2C%20forming%20a%20more%20standard%20crystalline%20structure%20including%20insulating%20side-chains%20layers%20that%20disallowed%20side%20interactions%20between%20aromatic%20rings.%20This%20resulted%20in%20a%20reduced%20charge%20transport%20ability%20to%20a%20two-dimensional%20%282D%29%20ambipolar%20charge%20transport%20in%20CAR-TzDPP%2C%20compared%20to%20the%20nearly%20isotropic%20unipolar%20charge%20transport%20in%20TAT-TzDPP.%20Despite%20this%2C%20CAR-TzDPP%20can%20be%20considered%20a%20viable%20alternative%20for%20device%20configurations%20requiring%20semiconducting%20pathways%20aligned%20in%20the%20substrate%20plane%20due%20to%20its%20simplified%20and%20high%20yield%20synthesis%20route%2C%20ease%20of%20processing%2C%20and%20reliable%20charge%20mobility%20in%20OFETs.%20This%20research%20highlights%20the%20significance%20of%20molecular%20units%20in%20small%20semiconducting%20organic%20molecules%2C%20not%20only%20in%20terms%20of%20their%20individual%20optoelectronic%20properties%20but%20also%20in%20terms%20of%20their%20selfassembly%20capabilities%2C%20which%20ultimately%20influence%20their%20charge%20transport%20properties.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.molstruc.2024.139241%22%2C%22ISSN%22%3A%220022-2860%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.molstruc.2024.139241%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A22%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22A79NUSYE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22K%5Cu00e9kicheff%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20K%26%23xE9%3Bkicheff%2C%20B.%20Heinrich%2C%20A.%20Hemmerle%2C%20P.%20Fontaine%2C%20C.%20Lambour%2C%20N.%20Beyer%2C%20D.%20Favier%2C%20A.%20Egele%2C%20K.A.%20Emelyanenko%2C%20E.%20Modin%2C%20A.M.%20Emelyanenko%2C%20L.B.%20Boinovich%2C%20Condensation%20or%20Desublimation%3A%20Nanolevel%20Structural%20Look%20on%20Two%20Frost%20Formation%20Pathways%20on%20Surfaces%20with%20Different%20Wettabilities%2C%20ACS%20Nano%20Early%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.4c02192%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.4c02192%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Condensation%20or%20Desublimation%3A%20Nanolevel%20Structural%20Look%20on%20Two%20Frost%20Formation%20Pathways%20on%20Surfaces%20with%20Different%20Wettabilities%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22K%5Cu00e9kicheff%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Beno%5Cu00eet%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Arnaud%22%2C%22lastName%22%3A%22Hemmerle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Fontaine%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lambour%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Beyer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Favier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antoine%22%2C%22lastName%22%3A%22Egele%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kirill%20A.%22%2C%22lastName%22%3A%22Emelyanenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Evgeny%22%2C%22lastName%22%3A%22Modin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%20M.%22%2C%22lastName%22%3A%22Emelyanenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ludmila%20B.%22%2C%22lastName%22%3A%22Boinovich%22%7D%5D%2C%22abstractNote%22%3A%22Processes%20of%20water%20condensation%20and%20desublimation%20on%20solid%20surfaces%20are%20ubiquitous%20in%20nature%20and%20essential%20for%20various%20industrial%20applications%2C%20which%20are%20crucial%20for%20their%20performance.%20Despite%20their%20significance%2C%20these%20processes%20are%20not%20well%20understood%20due%20to%20the%20lack%20of%20methods%20that%20can%20provide%20insight%20at%20the%20nanolevel%20into%20the%20very%20first%20stages%20of%20phase%20transitions.%20Taking%20advantage%20of%20synchrotron%20grazing-incidence%20wide-angle%20X-ray%20scattering%20%28GIWAXS%29%20and%20environmental%20scanning%20electron%20microscopy%20%28ESEM%29%2C%20two%20pathways%20of%20the%20frosting%20process%20from%20supersaturated%20vapors%20were%20studied%20in%20real%20time%20for%20substrates%20with%20different%20wettabilities%20ranging%20from%20highly%20hydrophilic%20to%20superhydrophobic.%20Within%20GIWAXS%2C%20a%20fully%20quantitative%20structural%20and%20orientational%20characterization%20of%20the%20undergoing%20phase%20transition%20reveals%20the%20information%20on%20degree%20of%20crystallinity%20of%20the%20new%20phase%20and%20determines%20the%20ordering%20at%20the%20surfaces%20and%20inside%20the%20films%20at%20the%20initial%20stages%20of%20water%5C%2Fice%20nucleation%20from%20vapor%20onto%20the%20substrates.%20The%20diversity%20of%20frosting%20scenarios%2C%20including%20direct%20desublimation%20from%20the%20vapor%20and%20two-stage%20condensation%5Cu2013freezing%20processes%2C%20was%20observed%20by%20both%20GIWAXS%20and%20ESEM%20for%20different%20combinations%20of%20substrate%20wettability%20and%20vapor%20supersaturations.%20The%20classical%20nucleation%20theory%20straightforwardly%20predicts%20the%20pathway%20of%20the%20phase%20transition%20for%20hydrophobic%20and%20superhydrophobic%20substrates.%20The%20case%20of%20hydrophilic%20substrates%20is%20more%20intricate%20because%20the%20barriers%20in%20Gibbs%20free%20energy%20for%20nucleating%20both%20liquid%20and%20solid%20embryos%20are%20close%20to%20each%20other%20and%20comparable%20to%20thermal%20energy%20kBT.%20At%20that%20end%2C%20classical%20nucleation%20theory%20allows%20concluding%20a%20relation%20between%20contact%20angles%20for%20ice%20and%20water%20embryos%20on%20the%20basis%20of%20the%20observed%20frosting%20pathway.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsnano.4c02192%22%2C%22ISSN%22%3A%221936-0851%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsnano.4c02192%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22JUERTWNS%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222024-06-20T13%3A27%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22RYI343ST%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kuppusamy%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.K.%20Kuppusamy%2C%20A.%20Mizuno%2C%20L.%20K%26%23xE4%3Bmmerer%2C%20S.%20Salamon%2C%20B.%20Heinrich%2C%20C.%20Bailly%2C%20I.%20%26%23x160%3Balitro%26%23x161%3B%2C%20H.%20Wende%2C%20M.%20Ruben%2C%20Lattice%20solvent-%20and%20substituent-dependent%20spin-crossover%20in%20isomeric%20iron%28ii%29%20complexes%2C%20Dalton%20Transactions%2053%20%282024%29%2010851%26%23x2013%3B10865.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD4DT00429A%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2FD4DT00429A%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Lattice%20solvent-%20and%20substituent-dependent%20spin-crossover%20in%20isomeric%20iron%28ii%29%20complexes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Senthil%20Kumar%22%2C%22lastName%22%3A%22Kuppusamy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Asato%22%2C%22lastName%22%3A%22Mizuno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lea%22%2C%22lastName%22%3A%22K%5Cu00e4mmerer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Soma%22%2C%22lastName%22%3A%22Salamon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Beno%5Cu00eet%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bailly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ivan%22%2C%22lastName%22%3A%22%5Cu0160alitro%5Cu0161%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Heiko%22%2C%22lastName%22%3A%22Wende%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%5D%2C%22abstractNote%22%3A%22Spin-state%20switching%20in%20iron%28ii%29%20complexes%20composed%20of%20ligands%20featuring%20moderate%20ligand-field%20strength%5Cu2014for%20example%2C%202%2C6-bi%281H-pyrazol-1-yl%29pyridine%20%28BPP%29%5Cu2014is%20dependent%20on%20many%20factors.%20Herein%2C%20we%20show%20that%20spin-state%20switching%20in%20isomeric%20iron%28ii%29%20complexes%20composed%20of%20BPP-based%20ligands%5Cu2014ethyl%202%2C6-bis%281H-pyrazol-1-yl%29isonicotinate%20%28BPP-COOEt%2C%20L1%29%20and%20%282%2C6-di%281H-pyrazol-1-yl%29pyridin-4-yl%29methylacetate%20%28BPP-CH2OCOMe%2C%20L2%29%5Cu2014is%20dependent%20on%20the%20nature%20of%20the%20substituent%20at%20the%20BPP%20skeleton.%20Bi-stable%20spin-state%20switching%5Cu2014with%20a%20thermal%20hysteresis%20width%20%28%5Cu0394T1%5C%2F2%29%20of%2044%20K%20and%20switching%20temperature%20%28T1%5C%2F2%29%20%3D%20298%20K%20in%20the%20first%20cycle%5Cu2014is%20observed%20for%20complex%201%5Cu00b7CH3CN%20composed%20of%20L1%20and%20BF4%5Cu2212%20counter%20anions.%20Conversely%2C%20the%20solvent-free%20isomeric%20counterpart%20of%201%5Cu00b7CH3CN%5Cu2014complex%202a%2C%20composed%20of%20L2%20and%20BF4%5Cu2212%20counter%20anions%5Cu2014was%20trapped%20in%20the%20high-spin%20%28HS%29%20state.%20For%20one%20of%20the%20polymorphs%20of%20complex%202b%5Cu00b7CH3CN%5Cu20142b%5Cu00b7CH3CN-Y%2C%20Y%20denotes%20yellow%20colour%20of%20the%20crystals%5Cu2014composed%20of%20L2%20and%20ClO4%5Cu2212%20counter%20anions%2C%20a%20gradual%20and%20non-hysteretic%20SCO%20is%20observed%20with%20T1%5C%2F2%20%3D%20234%20K.%20Complexes%201%5Cu00b7CH3CN%20and%202b%5Cu00b7CH3CN-Y%20also%20underwent%20light-induced%20spin-state%20switching%20at%205%20K%20due%20to%20the%20light-induced%20excited%20spin-state%20trapping%20%28LIESST%29%20effect.%20Structures%20of%20the%20low-spin%20%28LS%29%20and%20HS%20forms%20of%20complex%201%5Cu00b7CH3CN%20revealed%20that%20spin-state%20switching%20goes%20hand-in-hand%20with%20pronounced%20distortion%20of%20the%20trans-Npyridyl-Fe%5Cu2013Npyridyl%20angle%20%28%5Cu03d5%29%2C%20whereas%20such%20distortion%20is%20not%20observed%20for%202b%5Cu00b7CH3CN-Y.%20This%20observation%20points%20that%20distortion%20is%20one%20of%20the%20factors%20making%20the%20spin-state%20switching%20of%201%5Cu00b7CH3CN%20hysteretic%20in%20the%20solid%20state.%20The%20observation%20of%20bi-stable%20spin-state%20switching%20with%20T1%5C%2F2%20centred%20at%20room%20temperature%20for%201%5Cu00b7CH3CN%20indicates%20that%20technologically%20relevant%20spin-state%20switching%20profiles%20based%20on%20mononuclear%20iron%28ii%29%20complexes%20can%20be%20obtained.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2FD4DT00429A%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2FD4DT00429A%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%5D%2C%22dateModified%22%3A%222024-08-22T07%3A04%3A21Z%22%7D%7D%2C%7B%22key%22%3A%226A2XKMEE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Le%20Dot%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Le%20Dot%2C%20M.A.G.%20Fernandez%2C%20A.%20Langovist%2C%20B.%20Charriere%2C%20P.%20Gerard%2C%20F.%20Dumur%2C%20N.%20Hoffmann%2C%20J.%20Lalevee%2C%20New%20monomers%20or%20co-monomers%20based%20on%20the%20alkoxyfuranone%20Scaffold%3A%20Toward%20new%20alternatives%20to%20Petroleum-Based%20structures%2C%20European%20Polymer%20Journal%20215%20%282024%29%20113259.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.eurpolymj.2024.113259%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.eurpolymj.2024.113259%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22New%20monomers%20or%20co-monomers%20based%20on%20the%20alkoxyfuranone%20Scaffold%3A%20Toward%20new%20alternatives%20to%20Petroleum-Based%20structures%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marie%22%2C%22lastName%22%3A%22Le%20Dot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%20Andres%20Gomez%22%2C%22lastName%22%3A%22Fernandez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne%22%2C%22lastName%22%3A%22Langovist%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bruno%22%2C%22lastName%22%3A%22Charriere%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Gerard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frederic%22%2C%22lastName%22%3A%22Dumur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Norbert%22%2C%22lastName%22%3A%22Hoffmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacques%22%2C%22lastName%22%3A%22Lalevee%22%7D%5D%2C%22abstractNote%22%3A%22Over%20the%20past%20decade%2C%20the%20circular%20economy%20has%20become%20a%20key%20component%20of%20sustainability%20due%20to%20environmental%20issues%20and%20more%20stringent%20environmental%20regulations.%20In%20this%20connection%2C%20the%20valuation%20of%20bio-based%20monomers%20possessing%20innovative%20structures%20remains%20an%20important%20challenge.%20Furthermore%2C%20several%20goals%20must%20be%20achieved%3A%201%29%20the%20homopolymerization%20of%20such%20bio-based%20monomers%20by%20free%20radical%20photopolymerization%20which%20requires%20small%20energy%20inputs%20with%20limited%20emission%20of%20volatile%20organic%20compounds%20%28COV%29%20and%202%29%20their%20copolymerization%20with%20Elium%20%28R%29%20thermoplastic%20resins%20to%20increase%20biogenic%20carbon%20in%20these%20novel%20low-viscosity%20methacrylic%20resins%20developed%20by%20Arkema.%20The%20challenge%20will%20be%2C%20in%20this%20context%2C%20to%20maximize%20the%20biomass%20carbon%20content%20while%20maintaining%20or%20even%20surpassing%20the%20properties%20exhibited%20by%20their%20petrochemical%20counterpart.%20In%20this%20work%2C%20a%20series%20of%20alkoxyfuranones%20derived%20from%20furfural%20have%20been%20synthesized.%20The%20four%20alkoxyfuranones%20%28%20AF%201%20%2C%20AF%202%20%2C%20AF%203%20and%20AF%204%20%29%20varying%20by%20the%20functionality%20of%20the%20side%20chains%20%28but-3-en-1-yl%2C%20acrylate%2C%20isopropyl%20and%20ethyl%29%20attached%20via%20acetalization%20of%20the%205-hydroxy-2%285H%29-furanone%20were%20studied%20as%20potential%20monomers%20or%20co-monomers%20for%20free%20radical%20polymerization.%20The%20synthesis%20of%20AF%201%20and%20AF%202%20has%20never%20been%20reported%20in%20the%20literature.%20The%20homopolymerization%20of%20two%20of%20them%20%28%20AF%201%20and%20AF%202%20%29%20was%20successfully%20achieved%2C%20but%20only%20one%20led%20to%20a%20high%20-glass%20transition%20temperature%20%28T%20g%20%29%20bio-based%20polymer.%20On%20the%20other%20hand%2C%20copolymerization%20with%20Elium%20%28R%29%20thermoplastic%20resins%20was%20obtained%20with%20different%20ratios%20of%20AF%202%20as%20a%20co-monomer.%20As%20a%20result%2C%20the%20expected%20gain%20value%2C%20such%20as%20faster%20photopolymerization%20was%20successfully%20obtained.%20Nevertheless%2C%20the%20copolymerization%20doesn%20%27t%20lead%20to%20obtaining%20high%20-T%20g%20polymers.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.eurpolymj.2024.113259%22%2C%22ISSN%22%3A%220014-3057%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.eurpolymj.2024.113259%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A20%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22LMGRUTHU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lyu%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EY.%20Lyu%2C%20F.%20Gao%2C%20P.%20Cheng%2C%20L.%20Chen%2C%20S.%20Klyatskaya%2C%20M.%20Ruben%2C%20J.%20Rosen%2C%20J.V.%20Barth%2C%20J.%20Bjoerk%2C%20K.%20Wu%2C%20Y.-Q.%20Zhang%2C%20Unraveling%20Enyne%20Bonding%20via%20Dehydrogenation-Hydrogenation%20Processes%20in%20On-Surface%20Synthesis%20with%20Terminal%20Alkynes%2C%20Advanced%20Materials%20Interfaces%20%282024%29%202400222.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmi.202400222%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmi.202400222%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unraveling%20Enyne%20Bonding%20via%20Dehydrogenation-Hydrogenation%20Processes%20in%20On-Surface%20Synthesis%20with%20Terminal%20Alkynes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuanhao%22%2C%22lastName%22%3A%22Lyu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Feng%22%2C%22lastName%22%3A%22Gao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Peng%22%2C%22lastName%22%3A%22Cheng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lan%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Svetlana%22%2C%22lastName%22%3A%22Klyatskaya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Rosen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johannes%20V.%22%2C%22lastName%22%3A%22Barth%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jonas%22%2C%22lastName%22%3A%22Bjoerk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kehui%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yi-Qi%22%2C%22lastName%22%3A%22Zhang%22%7D%5D%2C%22abstractNote%22%3A%22On-surface%20reactions%20of%20terminal%20alkynes%20in%20ultrahigh%20vacuum%20have%20attracted%20widespread%20attention%20due%20to%20their%20high%20technological%20promise.%20However%2C%20employing%20different%20precursors%20and%20substrate%20materials%20often%20intricate%20reaction%20schemes%20appear%20far%20from%20being%20well-understood.%20Thus%2C%20recent%20investigations%20of%20alkyne%20coupling%20on%20noble%20metal%20surfaces%20suggest%20non-dehydrogenative%20scenarios%2C%20contradicting%20earlier%20reports.%20Herein%2C%20the%20study%20employs%20noncontact%20atomic%20force%20microscopy%20%28nc-AFM%29%20with%20high%20spatial%20resolution%20to%20conclusively%20characterize%20exemplary%20alkyne%20coupling%20products.%20Contrary%20to%20initial%20interpretations%20proposing%20dehydrogenative%20homocoupling%20on%20Ag%28111%29%2C%20bond-resolved%20AFM%20imaging%20reveals%20the%20expression%20of%20enyne%20motifs.%20Based%20on%20complementary%2C%20extensive%20density%20functional%20theory%20calculations%2C%20the%20pertaining%20reaction%20mechanisms%20are%20explored.%20It%20is%20proposed%20that%20enyne%20formation%20initiates%20with%20a%20direct%20carbon-carbon%20coupling%20between%20two%20alkyne%20groups%2C%20followed%20by%20surface-assisted%20dehydrogenation-hydrogenation%20processes.%20Thereby%20consecutive%20steps%20of%20atomic%20hydrogen%20cleavage%2C%20surface%20migration%20and%20recombination%20to%20a%20different%20carbon%20atom%20enable%20bridging%20via%20carbon-carbon%20double%20bonding.%20The%20new%20results%20shed%20light%20on%20subtle%2C%20but%20crucial%20surface-mediated%20hydrogen%20transfer%20processes%20involved%20in%20the%20chemical%20bond%20formation%2C%20which%20are%20suggested%20to%20be%20of%20general%20relevance%20in%20on-surface%20synthesis.%20Terminal%20alkyne%20coupling%20on%20Ag%28111%29%20in%20ultrahigh%20vacuum%20is%20conclusively%20examined%20by%20bond-resolved%20atomic%20force%20microscopy%20and%20density%20functional%20theory%20modeling.%20The%20prevailing%20bonding%20motif%20is%20the%20enyne%20moiety%2C%20originating%20from%20a%20distinct%20surface-mediated%20dehydrogenation-hydrogenation%20reaction%20pathway.%20The%20findings%20highlight%20the%20important%20role%20of%20hydrogen%20transfer%20in%20the%20course%20of%20on-surface%20synthesis%20procedures.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadmi.202400222%22%2C%22ISSN%22%3A%222196-7350%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadmi.202400222%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22BMA9GKQT%22%5D%2C%22dateModified%22%3A%222024-06-20T13%3A32%3A50Z%22%7D%7D%2C%7B%22key%22%3A%22CYI7T969%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Matsushima%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Matsushima%2C%20C.%20Qin%2C%20T.%20Teng%2C%20N.%20Kamatham%2C%20L.S.%20Vargas%2C%20D.%20Kreher%2C%20B.%20Heinrich%2C%20T.%20Ishii%2C%20S.%20Terakawa%2C%20M.R.%20Leyden%2C%20A.S.D.%20Sandanayaka%2C%20F.%20Bencheikh%2C%20K.%20Miyata%2C%20K.%20Onda%2C%20Y.%20Kanemitsu%2C%20F.%20Mathevet%2C%20C.%20Adachi%2C%20Efficient%20Electroluminescence%20from%20Organic%20Fluorophore-Containing%20Perovskite%20Films%2C%20Advanced%20Materials%20%282024%29%202408775.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202408775%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202408775%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Efficient%20Electroluminescence%20from%20Organic%20Fluorophore-Containing%20Perovskite%20Films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Toshinori%22%2C%22lastName%22%3A%22Matsushima%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chuanjiang%22%2C%22lastName%22%3A%22Qin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Teng%22%2C%22lastName%22%3A%22Teng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Narayanaswamy%22%2C%22lastName%22%3A%22Kamatham%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lydia%20Sosa%22%2C%22lastName%22%3A%22Vargas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Kreher%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomohiro%22%2C%22lastName%22%3A%22Ishii%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Shinobu%22%2C%22lastName%22%3A%22Terakawa%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthew%20R.%22%2C%22lastName%22%3A%22Leyden%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Atula%20S.%20D.%22%2C%22lastName%22%3A%22Sandanayaka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fatima%22%2C%22lastName%22%3A%22Bencheikh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kiyoshi%22%2C%22lastName%22%3A%22Miyata%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ken%22%2C%22lastName%22%3A%22Onda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yoshihiko%22%2C%22lastName%22%3A%22Kanemitsu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Mathevet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chihaya%22%2C%22lastName%22%3A%22Adachi%22%7D%5D%2C%22abstractNote%22%3A%22Two-dimensional%20perovskites%20containing%20an%20organic%20fluorophore%20can%20be%20a%20unique%20emitter%20for%20light-emitting%20diodes%20%28LEDs%29.%20However%2C%20external%20quantum%20efficiencies%20%28EQEs%29%20of%20fluorophore-containing%20perovskite%20LEDs%20reported%20thus%20far%20are%20still%20very%20low.%20In%20this%20study%2C%20these%20are%20able%20to%20boost%20the%20EQE%20to%20approximate%20to%2010%25%20by%20choosing%20an%20organic%20fluorophore%20with%20appropriate%20energy%20levels%20for%20the%20perovskite%20structure%20organization.%20In%20the%20fluorophore-containing%20perovskite%20LEDs%2C%20carrier%20transport%20and%20exciton%20formation%20take%20place%20in%20the%20perovskite%27s%20metal%20halide%20framework%2C%20thereby%20avoiding%20the%20direct%20formation%20of%20nonradiative%20triplet%20excitons%20on%20the%20organic%20fluorophores.%20Subsequently%2C%20the%20bright%20triplet%20excitons%20formed%20in%20the%20metal%20halide%20framework%20are%20transferred%20to%20form%20the%20radiative%20singlet%20states%20of%20the%20organic%20fluorophores%2C%20leading%20to%20efficient%20electroluminescence%20%28EL%29%20from%20the%20organic%20fluorophores%20regularly%20dispersed%20inside%20the%20perovskite%20structure.%20Unexpectedly%20higher%20light-outcoupling%20efficiency%2C%20which%20is%20caused%20by%20the%20light%20scattering%20in%20the%20polycrystalline%20perovskite%20layer%2C%20will%20be%20another%20reason%20for%20efficient%20EL.%20These%20findings%20will%20contribute%20toward%20the%20fabrication%20of%20LED-based%20products%20with%20high%20performance%20at%20a%20low%20cost.In%20light-emitting%20diodes%20using%20an%20organic%20fluorophore-containing%202D%20perovskite%20as%20the%20emitter%2C%20carrier%20transport%2C%20and%20exciton%20formation%20take%20place%20in%20the%20metal%20halide%20sheets.%20Then%2C%20the%20bright%20triplet%20excitons%20formed%20in%20the%20metal%20halide%20sheets%20are%20transferred%20to%20singlet%20states%20of%20the%20organic%20fluorophores.%20With%20these%20processes%2C%20efficient%20electroluminescence%20is%20observed%20from%20the%20organic%20fluorophores%20inside%20the%20perovskite.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadma.202408775%22%2C%22ISSN%22%3A%220935-9648%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadma.202408775%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-11-08T10%3A43%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22G3EUMQBF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mechrouk%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EV.%20Mechrouk%2C%20B.%20Leforestier%2C%20W.%20Chen%2C%20A.I.%20Poblador-Bahamonde%2C%20A.%20Maisse-Francois%2C%20S.%20Bellemin-Laponnaz%2C%20T.%20Achard%2C%20Diastereoselective%20Synthesis%20of%20Sulfoxide-Functionalized%20N-Heterocyclic%20Carbene%20Ruthenium%20Complexes%3A%20An%20Experimental%20and%20Computational%20Study%2C%20Chemistry-a%20European%20Journal%2030%20%282024%29%20e202401390.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202401390%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202401390%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Diastereoselective%20Synthesis%20of%20Sulfoxide-Functionalized%20N-Heterocyclic%20Carbene%20Ruthenium%20Complexes%3A%20An%20Experimental%20and%20Computational%20Study%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Victoria%22%2C%22lastName%22%3A%22Mechrouk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Baptiste%22%2C%22lastName%22%3A%22Leforestier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Weighang%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Amalia%20I.%22%2C%22lastName%22%3A%22Poblador-Bahamonde%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aline%22%2C%22lastName%22%3A%22Maisse-Francois%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Achard%22%7D%5D%2C%22abstractNote%22%3A%22The%20synthesis%20of%20sulfoxide-functionalized%20NHC%20ligand%20precursors%20were%20carried%20out%20by%20direct%20and%20mild%20oxidation%20from%20corresponding%20thioether%20precursors%20with%20high%20selectivity.%20Using%20these%20salts%2C%20a%20series%20of%20cationic%20%5BRu%28II%29%28eta%206-p-cymene%29%28NHC-SO%29Cl%5D%2B%20complexes%20were%20obtained%20in%20excellent%20yields%20by%20the%20classical%20Ag2O%20transmetallation%20route.%20NMR%20analyses%20suggested%20a%20chelate%20structure%20for%20the%20metal%20complexes%2C%20and%20X-ray%20diffractometry%20studies%20of%20complexes%204%20b%2C%204%20c%2C%204dBArF%20and%204%20e%20unambiguously%20confirmed%20the%20preference%20for%20the%20bidentate%20%28kappa%202-C%2CS%29%20coordination%20mode%20of%20the%20NHC-SO%20ligands.%20Interestingly%2C%20only%20one%20diastereomer%2C%20in%20the%20form%20of%20an%20enantiomeric%20pair%2C%20was%20observed%20both%20in%201H%20NMR%20and%20in%20the%20solid%20state%20for%20the%20complexes.%20DFT%20calculations%20showed%20a%20possible%20intrinsic%20energy%20difference%20between%20the%20two%20pairs%20of%20diastereomer.%20The%20calculated%20energy%20barriers%20suggested%20that%20inversion%20of%20the%20sulfoxide%20is%20only%20plausible%20from%20the%20higher%20energy%20diastereomer%20together%20with%20bulky%20substituents.%20Inverting%20the%20configuration%20at%20the%20Ru%20center%20instead%20shows%20a%20lower%20and%20accessible%20activation%20barrier%20to%20provide%20the%20most%20stable%20diastereomer%20through%20thermodynamic%20control%2C%20consistent%20with%20the%20observation%20of%20a%20single%20species%20by%201H%20NMR%20as%20a%20pair%20of%20enantiomers.%20All%20these%20complexes%20catalyse%20the%20beta-alkylation%20of%20secondary%20alcohols.%20Complex%204dPF6%20bearing%20an%20NHC-functionalised%20S-Ad%20group%20has%20been%20further%20studied%20with%20different%20primary%20and%20secondary%20alcohols%20as%20substrates%2C%20showing%20high%20reactivity%20and%20high%20to%20moderate%20beta-ol-selectivities.Diastereoselective%20synthesis%3A%20A%20new%20family%20of%20sulfoxide-functionalized%20NHCs%20was%20created%20by%20a%20simple%20oxidation%20protocol%20from%20thioether-NHC.%20Associated%20with%20Ru%28p-cymene%29%2C%20these%20NHC-SO%20ligands%20allow%20the%20formation%20of%20a%20single%20diastereomer%20in%20the%20form%20of%20an%20enantiomeric%20couple.%20This%20interesting%20selectivity%20is%20discussed%20by%20means%20of%20DFT%20calculations%20and%20experiments.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchem.202401390%22%2C%22ISSN%22%3A%220947-6539%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchem.202401390%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A17%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22AAYNQMFT%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Mechrouk%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EV.%20Mechrouk%2C%20D.%20Bissessar%2C%20J.%20Egly%2C%20J.%20Parmentier%2C%20S.%20Bellemin-Laponnaz%2C%20Synthesis%20and%20Characterization%20of%20Transition%20Metal%20Complexes%20Supported%20by%20Phosphorus%20Ligands%20Obtained%20Using%20Hydrophosphination%20of%20Cyclic%20Internal%20Alkenes.%2C%20Molecules%2029%20%282024%29%203946.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules29163946%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules29163946%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synthesis%20and%20Characterization%20of%20Transition%20Metal%20Complexes%20Supported%20by%20Phosphorus%20Ligands%20Obtained%20Using%20Hydrophosphination%20of%20Cyclic%20Internal%20Alkenes.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Victoria%22%2C%22lastName%22%3A%22Mechrouk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Bissessar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Julien%22%2C%22lastName%22%3A%22Egly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jordan%22%2C%22lastName%22%3A%22Parmentier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22The%20design%20and%20study%20of%20rich%2C%20bulky%20phosphorus%20ligands%20is%20a%20key%20area%20of%20research%20for%20homogeneous%20catalysis.%20Here%2C%20we%20describe%20an%20original%20strategy%20using%20a%20hydrophosphination%20reaction%20to%20produce%20phosphines%20of%20interest%20for%20coordination%20chemistry%20and%20homogenous%20catalysis.%20In%20particular%2C%20the%20phosphine%20obtained%20by%20reacting%20diphenylphosphine%20with%20acenaphthylene%20%28ligand%202%29%20gives%20a%20ligand%20that%20adopts%20an%20unusual%20spatial%20geometry.%20The%20coordination%20chemistry%20of%20the%20ligand%20has%20been%20investigated%20with%20Au%28I%29%2C%20Ag%28I%29%2C%20Cu%28I%29%2C%20and%20Pd%28II%29%2C%20for%20which%20a%20complete%20characterization%20could%20be%20made%2C%20particularly%20in%20X-ray%20diffraction%20studies.%20The%20reactivity%20of%20some%20of%20these%20complexes%20has%20been%20demonstrated%2C%20particularly%20in%20Pd-catalyzed%20cross-coupling%20reactions%20and%20Au-catalyzed%20hydroaminations%20and%20in%20the%20hydration%20of%20alkynes.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.3390%5C%2Fmolecules29163946%22%2C%22ISSN%22%3A%221420-3049%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fmolecules29163946%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-09-13T09%3A16%3A38Z%22%7D%7D%2C%7B%22key%22%3A%22MFZSQ8NV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Piquero-Zulaica%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EI.%20Piquero-Zulaica%2C%20W.%20Hu%2C%20A.P.%20Seitsonen%2C%20F.%20Haag%2C%20J.%20Kuechle%2C%20F.%20Allegretti%2C%20Y.%20Lyu%2C%20L.%20Chen%2C%20K.%20Wu%2C%20Z.M.%20Abd%20El-Fattah%2C%20E.%20Aktuerk%2C%20S.%20Klyatskaya%2C%20M.%20Ruben%2C%20M.%20Muntwiler%2C%20J.V.%20Barth%2C%20Y.-Q.%20Zhang%2C%20Unconventional%20Band%20Structure%20via%20Combined%20Molecular%20Orbital%20and%20Lattice%20Symmetries%20in%20a%20Surface-Confined%20Metallated%20Graphdiyne%20Sheet%2C%20Advanced%20Materials%20%282024%29%202405178.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202405178%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadma.202405178%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unconventional%20Band%20Structure%20via%20Combined%20Molecular%20Orbital%20and%20Lattice%20Symmetries%20in%20a%20Surface-Confined%20Metallated%20Graphdiyne%20Sheet%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ignacio%22%2C%22lastName%22%3A%22Piquero-Zulaica%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wenqi%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ari%20Paavo%22%2C%22lastName%22%3A%22Seitsonen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Felix%22%2C%22lastName%22%3A%22Haag%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johannes%22%2C%22lastName%22%3A%22Kuechle%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francesco%22%2C%22lastName%22%3A%22Allegretti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuanhao%22%2C%22lastName%22%3A%22Lyu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lan%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kehui%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zakaria%20M.%22%2C%22lastName%22%3A%22Abd%20El-Fattah%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ethem%22%2C%22lastName%22%3A%22Aktuerk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Svetlana%22%2C%22lastName%22%3A%22Klyatskaya%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mario%22%2C%22lastName%22%3A%22Ruben%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthias%22%2C%22lastName%22%3A%22Muntwiler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johannes%20V.%22%2C%22lastName%22%3A%22Barth%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yi-Qi%22%2C%22lastName%22%3A%22Zhang%22%7D%5D%2C%22abstractNote%22%3A%22Graphyne%20%28GY%29%20and%20graphdiyne%20%28GDY%29-based%20monolayers%20represent%20the%20next%20generation%202D%20carbon-rich%20materials%20with%20tunable%20structures%20and%20properties%20surpassing%20those%20of%20graphene.%20However%2C%20the%20detection%20of%20band%20formation%20in%20atomically%20thin%20GY%5C%2FGDY%20analogues%20has%20been%20challenging%2C%20as%20both%20long-range%20order%20and%20atomic%20precision%20have%20to%20be%20fulfilled%20in%20the%20system.%20The%20present%20work%20reports%20direct%20evidence%20of%20band%20formation%20in%20on-surface%20synthesized%20metallated%20Ag-GDY%20sheets%20with%20mesoscopic%20%28approximate%20to%201%20mu%20m%29%20regularity.%20Employing%20scanning%20tunneling%20and%20angle-resolved%20photoemission%20spectroscopies%2C%20energy-dependent%20transitions%20of%20real-space%20electronic%20states%20above%20the%20Fermi%20level%20and%20formation%20of%20the%20valence%20band%20are%20respectively%20observed.%20Furthermore%2C%20density%20functional%20theory%20%28DFT%29%20calculations%20corroborate%20the%20observations%20and%20reveal%20that%20doubly%20degenerate%20frontier%20molecular%20orbitals%20on%20a%20honeycomb%20lattice%20give%20rise%20to%20flat%2C%20Dirac%20and%20Kagome%20bands%20close%20to%20the%20Fermi%20level.%20DFT%20modeling%20also%20indicates%20an%20intrinsic%20band%20gap%20for%20the%20pristine%20sheet%20material%2C%20which%20is%20retained%20for%20a%20bilayer%20with%20h-BN%2C%20whereas%20adsorption-induced%20in-gap%20electronic%20states%20evolve%20at%20the%20synthesis%20platform%20with%20Ag-GDY%20decorating%20the%20%28111%29%20facet%20of%20silver.%20These%20results%20illustrate%20the%20tremendous%20potential%20for%20engineering%20novel%20band%20structures%20via%20molecular%20orbital%20and%20lattice%20symmetries%20in%20atomically%20precise%202D%20carbon%20materials.%20ToC%20Figure%20illustrates%20the%20emergence%20of%20unconventional%20band%20structure%20in%20mesoscopically%20%28approximate%20to%201%20mu%20m%29%20ordered%20metallated-graphdiyne%20single%20sheet%20due%20to%20combined%20frontier%20molecular%20orbital%20and%20lattice%20symmetries.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadma.202405178%22%2C%22ISSN%22%3A%220935-9648%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadma.202405178%22%2C%22collections%22%3A%5B%222DH6J37C%22%5D%2C%22dateModified%22%3A%222024-06-20T12%3A08%3A00Z%22%7D%7D%2C%7B%22key%22%3A%22TU887C4Q%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Rammal%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.M.%20Rammal%2C%20P.%20Nizet%2C%20G.%20Layrac%2C%20S.%20Swaraj%2C%20B.%20Heinrich%2C%20J.%20Jing%2C%20E.%20Steveler%2C%20T.%20Heiser%2C%20N.%20Leclerc%2C%20P.%20Leveque%2C%20A.%20Hebraud%2C%20Aqueous%20inks%20for%20ecofriendly%20processing%20of%20organic%20solar%20cells%3A%20Investigation%20of%20morphological%20changes%2C%20Synthetic%20Metals%20305%20%282024%29%20117599.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.synthmet.2024.117599%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.synthmet.2024.117599%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Aqueous%20inks%20for%20ecofriendly%20processing%20of%20organic%20solar%20cells%3A%20Investigation%20of%20morphological%20changes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%20M.%22%2C%22lastName%22%3A%22Rammal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Paul%22%2C%22lastName%22%3A%22Nizet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geraldine%22%2C%22lastName%22%3A%22Layrac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sufal%22%2C%22lastName%22%3A%22Swaraj%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jiang%22%2C%22lastName%22%3A%22Jing%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emilie%22%2C%22lastName%22%3A%22Steveler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Heiser%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Leclerc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Leveque%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne%22%2C%22lastName%22%3A%22Hebraud%22%7D%5D%2C%22abstractNote%22%3A%22Aqueous%20dispersions%20of%20organic%20semiconducting%20nanoparticles%20%28NPs%29%20are%20particularly%20attractive%20as%20inks%20for%20the%20environmentally%20friendly%20preparation%20of%20organic%20solar%20cells.%20The%20internal%20morphology%20of%20the%20NPs%2C%20which%20depends%20on%20their%20elaboration%20process%2C%20is%20a%20key%20parameter%2C%20which%20has%20a%20significant%20influence%20on%20the%20final%20morphology%20of%20the%20active%20layer%20and%20therefore%20its%20effectiveness.%20In%20the%20present%20study%2C%20core%20-shell%20%28PF2%3APC71BM%29%20NPs%20were%20prepared%20by%20miniemulsion.%20Their%20internal%20morphology%20including%20the%20composition%20of%20the%20two%20phases%20was%20characterized%20by%20scanning%20transmission%20X-ray%20microscopy%20%28STXM%29%20showing%20a%20core%20composed%20of%2077%25%20PC71BM%20and%20a%20shell%20composed%20of%2075%25%20PF2.%20It%20was%20found%20that%20thermal%20annealing%20promotes%20PC71BM%20diffusion%20from%20the%20core%20to%20the%20shell%2C%20increasing%20its%20proportion%20in%20the%20shell%20from%2025%25%20to%2042%25.%20This%20annealing%2C%20when%20applied%20after%20NPs%20deposition%20by%20spincoating%2C%20allows%20partial%20coalescence%20of%20the%20NPs%2C%20reducing%20the%20roughness%20of%20the%20active%20layer%2C%20and%20increases%20electron%20mobility%2C%20thus%20demonstrating%20the%20formation%20of%20PC71BM%20percolation%20paths%20for%20electron%20transport.%20A%20PCE%20of%201.6%25%20could%20thus%20be%20obtained%20after%2010%20min%20of%20thermal%20annealing%20at%20100%20degrees%20C.%20At%20higher%20temperature%2C%20GrazingIncidence%20Wide%20-Angle%20X%20-Ray%20Scattering%20%28GIWAXS%29%20analyses%20demonstrate%20the%20modification%20of%20the%20PF2%20structuration%20from%20randomly%20oriented%20lamella%20after%20deposition%20to%20edge%20-on%20orientation%20after%20annealing%2C%20leading%20to%20an%20unfavorable%20decrease%20of%20the%20hole%20mobility%20in%20the%20direction%20perpendicular%20to%20the%20substrate%2C%20while%20increasing%20the%20hole%20mobility%20in%20the%20substrate%20plane.%20This%20study%20demonstrates%20the%20need%20to%20systematically%20characterize%20the%20internal%20morphology%20of%20NPs%20in%20order%20to%20rationalize%20the%20morphology%20of%20the%20active%20layer%20and%20optimize%20its%20properties.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.synthmet.2024.117599%22%2C%22ISSN%22%3A%220379-6779%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.synthmet.2024.117599%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-11-08T10%3A43%3A45Z%22%7D%7D%2C%7B%22key%22%3A%22IRNUE5EH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sleczkowski%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Sleczkowski%2C%20Y.%20Xiao%2C%20J.W.%20Wu%2C%20C.%20Adachi%2C%20L.S.%20Vargas%2C%20D.%20Kreher%2C%20B.%20Heinrich%2C%20J.-C.%20Ribierre%2C%20F.%20Mathevet%2C%20Electron%20Transport%20in%20Soft-Crystalline%20Thin%20Films%20of%20Perylene%20Diimide%20Substituted%20with%20Swallow-Tail%20Terminal%20Alkyl%20Chains%2C%20Journal%20of%20Physical%20Chemistry%20C%20128%20%282024%29%2021826%26%23x2013%3B21835.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.4c06222%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.4c06222%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Electron%20Transport%20in%20Soft-Crystalline%20Thin%20Films%20of%20Perylene%20Diimide%20Substituted%20with%20Swallow-Tail%20Terminal%20Alkyl%20Chains%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Piotr%22%2C%22lastName%22%3A%22Sleczkowski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yiming%22%2C%22lastName%22%3A%22Xiao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jeong%20Weon%22%2C%22lastName%22%3A%22Wu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chihaya%22%2C%22lastName%22%3A%22Adachi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lydia%20Sosa%22%2C%22lastName%22%3A%22Vargas%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Kreher%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Heinrich%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Charles%22%2C%22lastName%22%3A%22Ribierre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fabrice%22%2C%22lastName%22%3A%22Mathevet%22%7D%5D%2C%22abstractNote%22%3A%22We%20have%20examined%20the%20structural%20and%20electron%20transport%20properties%20of%20a%20swallow-tailed%20N%2CN%27-bis%281-heptyloctyl%29-perylene-3%2C4%3A9%2C10-bis%28dicarboximide%29%20%28PDI-C8%2C7%29%20in%20thin%20films.%20A%20comprehensive%20analysis%20of%20material%20with%20the%20use%20of%20X-ray%20scattering%20methods%20evidenced%20the%20appearance%20of%20a%20new%20soft-crystalline%20mesophase%20that%20was%20induced%20by%20thermal%20processing%20of%20the%20swallow-tail%20PDI%20derivative.%20By%20combining%20electrical%20measurements%20with%20grazing-incidence%20wide-angle%20X-ray%20scattering%20%28GIWAXS%29%2C%20we%20show%20that%20these%20morphological%20changes%20of%20thin%20films%20boost%20their%20charge%20transport%20in%20the%20organic%20field-effect%20transistor%20%28OFET%29%20configuration.%20The%20systematic%20device%20engineering%20of%20OFETs%2C%20including%20device%20architecture%2C%20thermal%20history%2C%20and%20preparation%20method%20of%20the%20active%20layer%2C%20resulted%20in%20a%20significant%20improvement%20in%20the%20electron%20field-effect%20mobility%20and%20the%20related%20performance%20parameters.%20In%20particular%2C%20the%20results%20demonstrate%20a%20strong%20improvement%20in%20the%20charge%20transport%20of%20PDI-C8%2C7%20films%20in%20their%20soft-crystalline%20phase%2C%20which%20originates%20from%20the%20N-substitution%20by%20swallow-tails.%20In%20addition%2C%20our%20study%20demonstrates%20that%20the%20melt-processing%20route%2C%20a%20solvent-free%20and%20vacuum-free%20method%20for%20the%20fabrication%20of%20organic%20thin%20films%2C%20represents%20an%20efficient%20strategy%20for%20the%20fabrication%20of%20high-performance%20air-stable%20n-type%20OFETs.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpcc.4c06222%22%2C%22ISSN%22%3A%221932-7447%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22TK3HH32E%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222025-01-09T13%3A17%3A09Z%22%7D%7D%2C%7B%22key%22%3A%22U39EMR5B%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Strzelecki%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Strzelecki%2C%20A.%20Shpiruk%2C%20G.M.%20Cech%2C%20A.%20Kloska%2C%20P.%20H%26%23xE9%3Bbraud%2C%20N.%20Beyer%2C%20F.%20Busi%2C%20W.%20Grange%2C%20Robust%2C%20high-yield%2C%20rapid%20fabrication%20of%20DNA%20constructs%20for%20Magnetic%20Tweezers%2C%20Biochemical%20and%20Biophysical%20Research%20Communications%20731%20%282024%29%20150370.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bbrc.2024.150370%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2Fhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bbrc.2024.150370%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Robust%2C%20high-yield%2C%20rapid%20fabrication%20of%20DNA%20constructs%20for%20Magnetic%20Tweezers%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patryk%22%2C%22lastName%22%3A%22Strzelecki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anastasiia%22%2C%22lastName%22%3A%22Shpiruk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Grzegorz%20M.%22%2C%22lastName%22%3A%22Cech%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Kloska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pascal%22%2C%22lastName%22%3A%22H%5Cu00e9braud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Beyer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florent%22%2C%22lastName%22%3A%22Busi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wilfried%22%2C%22lastName%22%3A%22Grange%22%7D%5D%2C%22abstractNote%22%3A%22Single-molecule%20techniques%20are%20highly%20sensitive%20tools%20that%20can%20reveal%20reaction%20intermediates%20often%20obscured%20in%20experiments%20involving%20large%20ensembles%20of%20molecules.%20Therefore%2C%20they%20provide%20unprecedented%20information%20on%20the%20mechanisms%20that%20control%20biomolecular%20reactions.%20Currently%2C%20one%20of%20the%20most%20significant%20single-molecule%20assays%20is%20Magnetic%20Tweezers%20%28MT%29%2C%20which%20probes%20enzymatic%20reactions%20at%20high%20spatio-temporal%20resolutions%20on%20tens%2C%20if%20not%20hundreds%2C%20of%20molecules%20simultaneously.%20For%20high-resolution%20MT%20experiments%2C%20a%20short%20double-stranded%20DNA%20molecule%20%28less%20than%202%2C000%20base%20pairs%29%20is%20typically%20attached%20between%20a%20micron-sized%20superparamagnetic%20bead%20and%20a%20surface.%20The%20fabrication%20of%20such%20a%20substrate%20is%20key%20for%20successful%20single-molecule%20assays%2C%20and%20several%20papers%20have%20discussed%20the%20possibility%20of%20improving%20the%20fabrication%20of%20short%20DNA%20constructs.%20However%2C%20reported%20yields%20are%20usually%20low%20and%20require%20additional%20time-consuming%20purification%20steps%20%28e.g.%2C%20gel%20purification%29.%20In%20this%20paper%2C%20we%20propose%20the%20use%20of%20a%20Golden%20Gate%20Assembly%20assay%20that%20allows%20for%20the%20production%20of%20DNA%20constructs%20within%20minutes%20%28starting%20from%20PCR%20products%29.%20We%20discuss%20how%20relevant%20parameters%20may%20affect%20the%20yield%20and%20offer%20single-molecule%20experimentalists%20a%20simple%20yet%20robust%20approach%20to%20fabricate%20DNA%20constructs.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.bbrc.2024.150370%22%2C%22ISSN%22%3A%220006-291X%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0006291X24009069%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22CHW2VGSR%22%2C%22JUERTWNS%22%2C%22TK3HH32E%22%2C%22TFVWSVG3%22%5D%2C%22dateModified%22%3A%222024-08-21T09%3A45%3A16Z%22%7D%7D%2C%7B%22key%22%3A%22IX7URXAS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20Y.%20Geiger%2C%20S.%20Bellemin-Laponnaz%2C%20Divergence%20of%20catalytic%20systems%20in%20the%20zinc-catalysed%20alkylation%20of%20benzaldehyde%20mediated%20by%20chiral%20proline-based%20ligands%2C%20Nature%20Synthesis%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs44160-024-00491-y%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs44160-024-00491-y%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Divergence%20of%20catalytic%20systems%20in%20the%20zinc-catalysed%20alkylation%20of%20benzaldehyde%20mediated%20by%20chiral%20proline-based%20ligands%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yannick%22%2C%22lastName%22%3A%22Geiger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22Asymmetric%20catalysis%20has%20expanded%20the%20range%20of%20chiral%20products%20readily%20accessible%20through%20increasingly%20efficient%20synthetic%20catalysts.%20The%20development%20of%20these%20catalysts%20often%20starts%20with%20a%20result%20obtained%20by%20systematic%20screening%20of%20known%20privileged%20chiral%20structures%20and%20assumes%20that%20the%20active%20species%20would%20be%20an%20isolated%20monomolecular%20species.%20Here%20we%20report%20the%20study%20of%20three%20proline-derived%20ligands%2C%20diphenyl-N-methyl-prolinol%2C%20diphenylprolinol%20and%205-%28hydroxydiphenylmethyl%29-2-pyrrolidinone%2C%20in%20the%20zinc-catalysed%20alkylation%20of%20benzaldehyde.%20The%20three%20ligands%20exhibit%20different%20system-level%20behaviour%2C%20characterized%20by%20multiple%20levels%20of%20aggregation%20that%20may%20be%20catalytically%20active%20simultaneously.%20While%20diphenyl-N-methyl-prolinol%20behaves%20as%20expected%20from%20a%20mechanistic%20point%20of%20view%2C%20diphenylprolinol%20shows%20enantiodivergence%20during%20the%20reaction%20due%20to%20an%20asymmetric%20autoinduction%20process.%20With%205-%28hydroxydiphenylmethyl%29-2-pyrrolidinone%2C%20we%20were%20able%20to%20establish%20the%20possibility%20of%20at%20least%20trimeric%20active%20species%20in%20equilibrium%20with%20less%20aggregated%20active%20species.%20Simulations%20using%20a%20mathematical%20model%20confirm%20the%20possibility%20of%20such%20systems-level%20behaviour.%20Parallel%20study%20of%20the%20three%20systems%20reveals%20three%20distinct%20system-level%20behaviours%20that%20are%20central%20to%20the%20efficiency%20of%20the%20catalytic%20reaction.Three%20closely%20related%20proline-based%20ligands%20give%20rise%20to%20different%20catalytic%20systems%20in%20asymmetric%20dialkylzinc%20addition%20reactions.%20Mechanistic%20studies%20reveal%20that%20monomeric%2C%20dimeric%20and%20product-catalyst%20complexes%20and%20aggregates%20larger%20than%20dimers%20are%20all%20catalytically%20active.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs44160-024-00491-y%22%2C%22ISSN%22%3A%222731-0582%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs44160-024-00491-y%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222024-06-03T09%3A40%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22EJIQ7DCY%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20J.%20Frey%2C%20Y.%20Geiger%2C%20S.%20Bellemin-Laponnaz%2C%20Les%20effets%20non%20lin%26%23xE9%3Baires%20en%20catalyse%20asym%26%23xE9%3Btrique%2C%20L%26%23x2019%3Bactualit%26%23xE9%3B%20Chimique%20%282024%29%2040%26%23x2013%3B49.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fnew.societechimiquedefrance.fr%5C%2Fnumero%5C%2Fles-effets-non-lineaires-en-catalyse-asymetrique-p40-n491%5C%2F%27%3Ehttps%3A%5C%2F%5C%2Fnew.societechimiquedefrance.fr%5C%2Fnumero%5C%2Fles-effets-non-lineaires-en-catalyse-asymetrique-p40-n491%5C%2F%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22magazineArticle%22%2C%22title%22%3A%22Les%20effets%20non%20lin%5Cu00e9aires%20en%20catalyse%20asym%5Cu00e9trique%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Frey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yannick%22%2C%22lastName%22%3A%22Geiger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22St%5Cu00e9phane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22french%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fnew.societechimiquedefrance.fr%5C%2Fnumero%5C%2Fles-effets-non-lineaires-en-catalyse-asymetrique-p40-n491%5C%2F%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222024-06-20T14%3A02%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22ZZEQIZ86%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20V.%20Giuso%2C%20F.%20Polo%2C%20P.%20Mercandelli%2C%20Y.-T.%20Chen%2C%20C.-H.%20Chang%2C%20M.%20Mauro%2C%20S.%20Bellemin-Laponnaz%2C%20A%20stable%20and%20true-blue%20emissive%20hexacoordinate%20Si%28iv%29%20N-heterocyclic%20carbene%20complex%20and%20its%20use%20in%20organic%20light-emitting%20diodes%2C%20Dalton%20Transactions%2053%20%282024%29%206445%26%23x2013%3B6450.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4dt00420e%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd4dt00420e%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20stable%20and%20true-blue%20emissive%20hexacoordinate%20Si%28iv%29%20N-heterocyclic%20carbene%20complex%20and%20its%20use%20in%20organic%20light-emitting%20diodes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerio%22%2C%22lastName%22%3A%22Giuso%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Federico%22%2C%22lastName%22%3A%22Polo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierluigi%22%2C%22lastName%22%3A%22Mercandelli%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yi-Ting%22%2C%22lastName%22%3A%22Chen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chih-Hao%22%2C%22lastName%22%3A%22Chang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matteo%22%2C%22lastName%22%3A%22Mauro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22A%20neutral%20hexacoordinate%20Si%28iv%29%20complex%20containing%20two%20tridentate%20N-heterocyclic%20carbene%20ligands%20is%20synthesised%20and%20characterized%20by%20X-ray%20crystallography%2C%20optical%20spectroscopy%2C%20electrochemistry%20and%20computational%20methods.%20The%20stable%20compound%20exhibits%20remarkable%20deep-blue%20photoluminescence%20particularly%20in%20the%20solid%20state%2C%20which%20enables%20its%20use%20as%20an%20electroluminescent%20material%20in%20organic%20light-emitting%20diodes.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd4dt00420e%22%2C%22ISSN%22%3A%221477-9226%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd4dt00420e%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%5D%2C%22dateModified%22%3A%222024-06-20T14%3A03%3A08Z%22%7D%7D%2C%7B%22key%22%3A%22TXMA7N72%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thierry%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ET.%20Thierry%2C%20Y.%20Geiger%2C%20S.%20Bellemin-Laponnaz%2C%20Correction%3A%20Thierry%20et%20al.%20Observation%20of%20Hyperpositive%20Non-Linear%20Effect%20in%20Asymmetric%20Organozinc%20Alkylation%20in%20Presence%20of%20N-Pyrrolidinyl%20Norephedrine.%20%28Molecules%202022%2C%2027%2C%203780.%29%2C%20Molecules%20%28Basel%2C%20Switzerland%29%2029%20%282024%29%204265.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules29174265%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fmolecules29174265%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Correction%3A%20Thierry%20et%20al.%20Observation%20of%20Hyperpositive%20Non-Linear%20Effect%20in%20Asymmetric%20Organozinc%20Alkylation%20in%20Presence%20of%20N-Pyrrolidinyl%20Norephedrine.%20%28Molecules%202022%2C%2027%2C%203780.%29%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thibault%22%2C%22lastName%22%3A%22Thierry%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yannick%22%2C%22lastName%22%3A%22Geiger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Bellemin-Laponnaz%22%7D%5D%2C%22abstractNote%22%3A%22The%20authors%20wish%20to%20make%20the%20following%20correction%20to%20their%20paper%20%5B...%5D.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3390%5C%2Fmolecules29174265%22%2C%22ISSN%22%3A%221420-3049%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fmolecules29174265%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22ITCCYZMF%22%2C%22ZMH8G5EH%22%5D%2C%22dateModified%22%3A%222024-11-08T10%3A46%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22WJYXUXS6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zeng%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.-Y.%20Zeng%2C%20W.-J.%20Deng%2C%20K.-Q.%20Zhao%2C%20C.%20Redshaw%2C%20B.%20Donnio%2C%20Phenanthrothiophene-Triazine%20Star-Shaped%20Discotic%20Liquid%20Crystals%3A%20Synthesis%2C%20Self-Assembly%2C%20and%20Stimuli-Responsive%20Fluorescence%20Properties%2C%20Chemistry-a%20European%20Journal%20%282024%29%20e202400296.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202400296%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fchem.202400296%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Phenanthrothiophene-Triazine%20Star-Shaped%20Discotic%20Liquid%20Crystals%3A%20Synthesis%2C%20Self-Assembly%2C%20and%20Stimuli-Responsive%20Fluorescence%20Properties%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chong-Yang%22%2C%22lastName%22%3A%22Zeng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wen-Jing%22%2C%22lastName%22%3A%22Deng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Carl%22%2C%22lastName%22%3A%22Redshaw%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22Lipophilic%20biphenylthiophene-%20and%20phenanthrothiophene-triazine%20compounds%2C%20BPTTn%20and%20CPTTn%2C%20respectively%2C%20were%20prepared%20by%20a%20tandem%20procedure%20involving%20successive%20Suzuki-Miyaura%20coupling%20and%20Scholl%20cyclodehydrogenation%20reactions.%20These%20compounds%20display%20photoluminescence%20in%20solution%20and%20in%20thin%20film%20state%2C%20solvatochromism%20with%20increasing%20solvent%27s%20polarity%2C%20as%20well%20as%20acidochromism%20and%20metal%20ion%20recognition%20stimuli-responsive%20fluorescence.%20Protonation%20of%20BPTT10%20and%20CPTT10%20by%20trifluoroacetic%20acid%20results%20in%20fluorescence%20quenching%2C%20which%20is%20reversibly%20restored%20once%20treated%20with%20triethylamine%20%28ON-OFF%20switch%29.%20DFT%20computational%20studies%20show%20that%20intramolecular%20charge%20transfer%20%28ICT%29%20phenomena%20occurs%20for%20both%20molecules%2C%20and%20reveal%20that%20protonation%20enhances%20the%20electron-withdrawing%20ability%20of%20the%20triazine%20core%20and%20reduces%20the%20band%20gap.%20This%20acidochromic%20behavior%20was%20applied%20to%20a%20prototype%20fluorescent%20anti-counterfeiting%20device.%20They%20also%20specifically%20recognize%20Fe3%2B%20through%20coordination%2C%20and%20the%20recognition%20mechanism%20is%20closely%20related%20to%20the%20photoinduced%20electron%20transfer%20between%20Fe3%2B%20and%20BPTT10%5C%2FCPTT10.%20CPTTn%20self-assemble%20into%20columnar%20rectangular%20%28Colrec%29%20mesophase%2C%20which%20can%20be%20modulated%20by%20oleic%20acid%20via%20the%20formation%20of%20a%20hydrogen-bonded%20supramolecular%20liquid%20crystal%20hexagonal%20Colhex%20mesophase.%20Finally%2C%20CPTTn%20also%20form%20organic%20gels%20in%20alkanes%20at%20low%20critical%20gel%20concentration%20%283.0%20mg%5C%2FmL%29.%20Therefore%2C%20these%20star-shaped%20triazine%20molecules%20possess%20many%20interesting%20features%20and%20thus%20hold%20great%20promises%20for%20information%20processing%2C%20liquid%20crystal%20semiconductors%20and%20organogelators.Triazine-based%20mesogens%20with%20three%20pending%20discoid%20arms%20have%20been%20shown%20to%20self-organize%20into%20rectangular%20columnar%20mesophases%20and%20form%20gels%20in%20various%20solvents.%20The%20solvatochromic-%2C%20acidochromic-%20and%20metal%20recognition-response%20photoluminescence%20of%20these%20mesogens%20offer%20applications%20in%20stimuli-responsive%20fluorescence%20anti-counterfeiting%20and%20as%20selective%20metal-ion%20recognition.%20image%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fchem.202400296%22%2C%22ISSN%22%3A%220947-6539%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fchem.202400296%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222024-06-20T15%3A19%3A03Z%22%7D%7D%2C%7B%22key%22%3A%2254SSWAVU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zeng%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Zeng%2C%20H.%20Wang%2C%20B.-Q.%20Wang%2C%20P.%20Hu%2C%20K.-Q.%20Zhao%2C%20B.%20Donnio%2C%20Dual-State%20Fluorescence%20in%20Some%20Salicylaldehyde-triphenylene%20Discotic%20Liquid%20Crystal%20Derivatives%20Induced%20by%20Excited%20State%20Intramolecular%20Proton%20Transfer%2C%20Chemistry%20of%20Materials%2036%20%282024%29%207306%26%23x2013%3B7316.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.4c01213%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.4c01213%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Dual-State%20Fluorescence%20in%20Some%20Salicylaldehyde-triphenylene%20Discotic%20Liquid%20Crystal%20Derivatives%20Induced%20by%20Excited%20State%20Intramolecular%20Proton%20Transfer%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chongyang%22%2C%22lastName%22%3A%22Zeng%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Haifeng%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bi-Qin%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ping%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22A%20new%20family%20of%20excited%20state%20intramolecular%20proton%20transfer%20%28ESIPT%29%20molecules%20based%20on%20the%20enol%5C%2Fketone%20tautomerism%20is%20reported.%20The%20molecules%20were%20designed%20to%20display%20columnar%20mesophases%20and%20consist%20of%20the%20archetypical%203%2C6%2C7%2C10%2C11-penta%28alkoxy%29triphenylene%20discotic%20core%20functionalized%20in%20the%20vacant%20%5C%222-position%5C%22%20by%20a%20salicylaldehyde%20group%20%28TPn-SA%29.%20For%20comparison%20and%20confirmation%20that%20the%20ESIPT%20effect%20is%20solely%20due%20to%20the%20salicylaldehyde%20group%2C%20structurally%20related%20triphenylene%20derivatives%20bearing%20benzaldehyde%20%28TPn-S%29%20or%20aldehyde%20%28TPS6%29%20side%20groups%20were%20also%20synthesized.%20These%20molecules%20were%20synthesized%20either%20by%20Suzuki-Miyaura%20cross-coupling%20%28TPn-SA%2C%20TPn-S%29%20or%20by%20the%20Bouveault%20aldehyde%20synthesis%20%28Ar-Li%20and%20DMF%2C%20TPS6%29%20in%20overall%20good%20yields.%20All%20triphenylene%20compounds%20show%20an%20enantiotropic%20columnar%20hexagonal%20mesophase%20over%20large%20temperature%20range.%20Furthermore%2C%20TPn-SA%20compounds%20undergo%20a%20mesophase%20to%20crystalline%20phase%20transformation%20upon%20UV%20light%20irradiation%20at%20365%20nm%2C%20caused%20by%20ESIPT-induced%20enol-ketone%20tautomerism.%20TP12-SA%20also%20self-assembles%20into%20room%20temperature%20gels%20in%20toluene%20and%20ethyl%20acetate%20at%20rather%20low%20critical%20gel%20concentration.%20TPn-SA%20and%20TPn-S%20present%20strong%20fluorescence%20in%20both%20solution%20and%20solid%20state%2C%20with%20fluorescence%20quantum%20yields%20for%20the%20TPn-SA%20compounds%20around%20similar%20to%2020%25%3B%20TPS6%2C%20in%20contrast%2C%20does%20not%20show%20fluorescence%20in%20solid%20state%20because%20of%20aggregation-caused%20quenching.%20The%20dual%20emission%20observed%20for%20TPn-SA%20was%20supported%20by%20DFT%20calculation.%20The%20ketone%20emission%20is%20dominant%20in%20nonpolar%20solvents%20and%20aggregated%20states%2C%20while%20the%20enol%20emission%20is%20dominant%20in%20polar%20solvents%20or%20in%20dilute%20solutions.%20Finally%2C%20the%20performances%20of%20TP6-SA%20and%20TP6-S%20in%20solid-state%20lighting%20LED%20devices%20have%20been%20investigated.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.4c01213%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.chemmater.4c01213%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A15%3A19Z%22%7D%7D%2C%7B%22key%22%3A%22MAQSKNWN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Zhang%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.-L.%20Zhang%2C%20W.-H.%20Yu%2C%20K.-Q.%20Zhao%2C%20P.%20Hu%2C%20B.-Q.%20Wang%2C%20B.%20Donnio%2C%20Mesomorphism%20Modulation%20of%20Perfluorinated%20Janus%20Triphenylenes%20by%20Inhomogeneous%20Chain%20Substitution%20Patterns%2C%20Chemistry-an%20Asian%20Journal%2019%20%282024%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fasia.202301080%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fasia.202301080%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Mesomorphism%20Modulation%20of%20Perfluorinated%20Janus%20Triphenylenes%20by%20Inhomogeneous%20Chain%20Substitution%20Patterns%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kai-Li%22%2C%22lastName%22%3A%22Zhang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Wen-Hao%22%2C%22lastName%22%3A%22Yu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ke-Qing%22%2C%22lastName%22%3A%22Zhao%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ping%22%2C%22lastName%22%3A%22Hu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bi-Qin%22%2C%22lastName%22%3A%22Wang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bertrand%22%2C%22lastName%22%3A%22Donnio%22%7D%5D%2C%22abstractNote%22%3A%22Two%20isomeric%20series%20of%20compounds%20with%20%5C%22inverted%5C%22%20chains%27%20substitution%20patterns%2C%207%2C10-dialkoxy-1%2C2%2C3%2C4-tetrafluoro-6%2C11-dimethoxytriphenylene%20and%206%2C11-dialkoxy-1%2C2%2C3%2C4-tetrafluoro-7%2C10-dimethoxytriphenylene%2C%20labelled%20respectively%20p-TPFn%20and%20m-TPFn%2C%20and%20two%20non-fluorinated%20homologous%20isomers%2C%203%2C6-dibutoxy-2%2C7-dimethoxytriphenylene%20and%202%2C7-dibutoxy-3%2C6-dimethoxytriphenylene%2C%20p-TP4%20and%20m-TP4%2C%20respectively%2C%20were%20synthesized%20in%20three%20steps%20and%20obtained%20in%20good%20yields%20by%20the%20efficient%20transition-metal-free%2C%20fluoroarene%20nucleophilic%20substitution%20via%20the%20reaction%20of%20appropriate%202%2C2%27-dilithium%20biphenylenes%20with%20either%20perfluorobenzene%2C%20C6F6%2C%20to%20yield%20p-TPFn%20and%20m-TPFn%2C%20or%20o-difluorobenzene%2C%20C6H4F2%2C%20for%20p-TP4%20and%20m-TP4%2C%20respectively.%20The%20single-crystal%20structures%20of%20p-TPF4%2C%20m-TPF4%20and%20p-TP4%2C%20unequivocally%20confirmed%20that%20the%20cyclization%20reactions%20occurred%20at%20the%20expected%20positions%2C%20and%20that%20the%20fluorinated%20molecules%20stack%20up%20into%20columns%20with%20short%20separation%2C%20a%20propitious%20situation%20for%20the%20emergence%20of%20columnar%20mesophases.%20The%20mesomorphous%20properties%20were%20found%20to%20be%20greatly%20affected%20by%20both%20chains%27%20length%20and%20positional%20isomerism%3A%20a%20Col%28hex%29%20phase%20is%20found%20for%20p-TPF4%20and%20m-TPF4%2C%20but%20mesomorphism%20vanishes%20in%20p-TP%3Cbold%3EF%3C%5C%2Fbold%3E6%2C%20and%20changes%20for%20the%20isomeric%20homologs%20m-TPFn%2C%20with%20the%20induction%20for%20n%20%3E%3D%206%20of%20a%20lamello-columnar%20phase%2C%20LamCol%28rec%29.%20As%20expected%2C%20both%20non-fluorinated%20compounds%20are%20deprived%20of%20mesomorphism.%20These%20compounds%20emit%20blue-violet%20colour%20in%20solution%2C%20independently%20of%20the%20chains%27%20substitution%20pattern%2C%20and%20the%20absolute%20fluorescence%20quantum%20yields%20can%20reach%20up%20to%2046%20%25.%20In%20thin%20films%2C%20fluorescence%20is%20slightly%20redshifted.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fasia.202301080%22%2C%22ISSN%22%3A%221861-4728%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fasia.202301080%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22IEGKATUQ%22%5D%2C%22dateModified%22%3A%222024-06-20T15%3A19%3A34Z%22%7D%7D%5D%7D
[1]
J.L. Appleton, L. Ballerini, S. Choua, C. Gourlaouen, R. Ruppert, M. Mauro, Cooperative, Close and Remote Steric Effects on the Structural and Optical Properties of Copper(I) Bis-Phenanthroline Complexes, European Journal of Inorganic Chemistry 27 (2024) e202400278. https://doi.org/10.1002/ejic.202400278.
[1]
L. Ballerini, W.-M. Zhang, T. Groizard, C. Gourlaouen, F. Polo, A. Jouaiti, H.-C. Su, M. Mauro, Binuclear iridium(iii) complexes for efficient near-infrared light-emitting electrochemical cells with electroluminescence up to 800 nm, Journal of Materials Chemistry C Early access (2024). https://doi.org/10.1039/d4tc02040e.
[1]
C. Brouillac, N. McIntosh, B. Heinrich, O. Jeannin, O. De Sagazan, N. Coulon, J. Rault-Berthelot, J. Cornil, E. Jacques, C. Quinton, C. Poriel, Grafting Electron-Accepting Fragments on [4]cyclo-2,7-carbazole Scaffold: Tuning the Structural and Electronic Properties of Nanohoops, Advanced Science (2024) 2309115. https://doi.org/10.1002/advs.202309115.
[1]
C. Brouillac, A. Serez, N. Mcintosh, J. Rault-Berthelot, O. Jeannin, B. Heinrich, C. Quinton, O. De Sagazan, E. Jacques, J. Cornil, C. Poriel, Importance of the curvature in electronic, structural and charge transport properties: oligomers of N-pyridine carbazole, Journal of Materials Chemistry C 12 (2024) 12598–12607. https://doi.org/10.1039/d4tc02304h.
[1]
Y. Chen, J. He, H. Lin, H.-F. Wang, P. Hu, B.-Q. Wang, K.-Q. Zhao, B. Donnio, Efficient synthesis of fluorinated triphenylenes with enhanced arene-perfluoroarene interactions in columnar mesophases, Beilstein Journal of Organic Chemistry 20 (2024) 3263–3273. https://doi.org/10.3762/bjoc.20.270.
[1]
N. Del Giudice, G. Voegeli, J.-M. Strub, B. Heinrich, L. Douce, Ionic Liquid Crystals Based on Loop-Shaped Copper(I) Complexes., Inorganic Chemistry 63 (2024) 6103–6110. https://doi.org/10.1021/acs.inorgchem.4c00728.
[1]
A.A. Diaa, N. El-Mahallawy, M. Shoeib, F. Mouillard, T. Ferté, P. Masson, A. Carradò, Biodegradable PMMA coated Zn-Mg alloy with bimodal grain structure for orthopedic applications - A promising alternative., Bioactive Materials 39 (2024) 479–491. https://doi.org/10.1016/j.bioactmat.2024.05.031.
[1]
P. Durand, H. Zeng, B. Jismy, O. Boyron, B. Heinrich, L. Herrmann, O. Bardagot, I. Moutsios, A.V. Mariasevskaia, A.P. Melnikov, D.A. Ivanov, M. Brinkmann, N. Leclerc, Controlling conjugated polymer morphology by precise oxygen position in single-ether side chains., Materials Horizons Early Access (2024). https://doi.org/10.1039/d4mh00492b.
[1]
C. Dussart, A. Maisse-Francois, S. Bellemin-Laponnaz, Chiral Self-Sorting Process With C2 Symmetric Bisimidazoline Ligands, Chirality 36 (2024) e23720. https://doi.org/10.1002/chir.23720.
[1]
C. Dussart, A. Bonnefont, S. Bellemin-Laponnaz, Cu<SUP>I</SUP>/Cu<SUP>II</SUP> Chiral Homoleptic Complexes: Study of Self-Recognition and Self-Discrimination, European Journal of Inorganic Chemistry 27 (2024) e202400527. https://doi.org/10.1002/ejic.202400527.
[1]
S. Guchait, S. Oummouch, P. Durand, N. Kamatham, B. Jismy, L. Herrmann, S. Méry, N. Leclerc, M. Brinkmann, Impact of Side Chain Chemical Structure on Doping and Thermoelectric Properties of Oriented PBTTT Thin Films., Small (2024) e2410073. https://doi.org/10.1002/smll.202410073.
[1]
A. Hemmerle, N. Aubert, T. Moreno, P. Kekicheff, B. Heinrich, S. Spagnoli, M. Goldmann, G. Ciatto, P. Fontaine, Opportunities and new developments for the study of surfaces and interfaces in soft condensed matter at the SIRIUS beamline of Synchrotron SOLEIL., Journal of Synchrotron Radiation 31 (2024). https://doi.org/10.1107/S1600577523008810.
[1]
X. Henning, K. Alhada-Lahbabi, D. Deleruyelle, B. Gautier, L. Schlur, T. Fix, S. Colis, A. Dinia, M.V. Rastei, Oxygen vacancy effects on polarization switching of ferroelectric Bi2FeCrO6 thin films, Physical Review Materials 8 (2024) 054416. https://doi.org/10.1103/PhysRevMaterials.8.054416.
[1]
N. Hoffmann, M.A.G. Fernandez, A. Desvals, C. Lefebvre, C. Michelin, M. Latrache, Photochemical reactions of biomass derived platform chemicals, Frontiers in Chemistry 12 (2024) 1485354. https://doi.org/10.3389/fchem.2024.1485354.
[1]
D. Jankovic, J.-G. Hartmann, M. Ruben, P.-A. Hervieux, Noisy qudit vs multiple qubits: conditions on gate efficiency for enhancing fidelity, NPJ Quantum Information 10 (2024). https://doi.org/10.1038/s41534-024-00829-6.
[1]
A. Jebnouni, S. Teka, B. Heinrich, M. Majdoub, N.S. Jaballah, N. Leclerc, Molecular semiconductors with Carbazole versus Triazatruxene endcaps: A matter of self-assembly, Journal of Molecular Structure 1318 (2024) 139241. https://doi.org/10.1016/j.molstruc.2024.139241.
[1]
P. Kékicheff, B. Heinrich, A. Hemmerle, P. Fontaine, C. Lambour, N. Beyer, D. Favier, A. Egele, K.A. Emelyanenko, E. Modin, A.M. Emelyanenko, L.B. Boinovich, Condensation or Desublimation: Nanolevel Structural Look on Two Frost Formation Pathways on Surfaces with Different Wettabilities, ACS Nano Early (2024). https://doi.org/10.1021/acsnano.4c02192.
[1]
S.K. Kuppusamy, A. Mizuno, L. Kämmerer, S. Salamon, B. Heinrich, C. Bailly, I. Šalitroš, H. Wende, M. Ruben, Lattice solvent- and substituent-dependent spin-crossover in isomeric iron(ii) complexes, Dalton Transactions 53 (2024) 10851–10865. https://doi.org/10.1039/D4DT00429A.
[1]
M. Le Dot, M.A.G. Fernandez, A. Langovist, B. Charriere, P. Gerard, F. Dumur, N. Hoffmann, J. Lalevee, New monomers or co-monomers based on the alkoxyfuranone Scaffold: Toward new alternatives to Petroleum-Based structures, European Polymer Journal 215 (2024) 113259. https://doi.org/10.1016/j.eurpolymj.2024.113259.
[1]
Y. Lyu, F. Gao, P. Cheng, L. Chen, S. Klyatskaya, M. Ruben, J. Rosen, J.V. Barth, J. Bjoerk, K. Wu, Y.-Q. Zhang, Unraveling Enyne Bonding via Dehydrogenation-Hydrogenation Processes in On-Surface Synthesis with Terminal Alkynes, Advanced Materials Interfaces (2024) 2400222. https://doi.org/10.1002/admi.202400222.
[1]
T. Matsushima, C. Qin, T. Teng, N. Kamatham, L.S. Vargas, D. Kreher, B. Heinrich, T. Ishii, S. Terakawa, M.R. Leyden, A.S.D. Sandanayaka, F. Bencheikh, K. Miyata, K. Onda, Y. Kanemitsu, F. Mathevet, C. Adachi, Efficient Electroluminescence from Organic Fluorophore-Containing Perovskite Films, Advanced Materials (2024) 2408775. https://doi.org/10.1002/adma.202408775.
[1]
V. Mechrouk, B. Leforestier, W. Chen, A.I. Poblador-Bahamonde, A. Maisse-Francois, S. Bellemin-Laponnaz, T. Achard, Diastereoselective Synthesis of Sulfoxide-Functionalized N-Heterocyclic Carbene Ruthenium Complexes: An Experimental and Computational Study, Chemistry-a European Journal 30 (2024) e202401390. https://doi.org/10.1002/chem.202401390.
[1]
V. Mechrouk, D. Bissessar, J. Egly, J. Parmentier, S. Bellemin-Laponnaz, Synthesis and Characterization of Transition Metal Complexes Supported by Phosphorus Ligands Obtained Using Hydrophosphination of Cyclic Internal Alkenes., Molecules 29 (2024) 3946. https://doi.org/10.3390/molecules29163946.
[1]
I. Piquero-Zulaica, W. Hu, A.P. Seitsonen, F. Haag, J. Kuechle, F. Allegretti, Y. Lyu, L. Chen, K. Wu, Z.M. Abd El-Fattah, E. Aktuerk, S. Klyatskaya, M. Ruben, M. Muntwiler, J.V. Barth, Y.-Q. Zhang, Unconventional Band Structure via Combined Molecular Orbital and Lattice Symmetries in a Surface-Confined Metallated Graphdiyne Sheet, Advanced Materials (2024) 2405178. https://doi.org/10.1002/adma.202405178.
[1]
M.M. Rammal, P. Nizet, G. Layrac, S. Swaraj, B. Heinrich, J. Jing, E. Steveler, T. Heiser, N. Leclerc, P. Leveque, A. Hebraud, Aqueous inks for ecofriendly processing of organic solar cells: Investigation of morphological changes, Synthetic Metals 305 (2024) 117599. https://doi.org/10.1016/j.synthmet.2024.117599.
[1]
P. Sleczkowski, Y. Xiao, J.W. Wu, C. Adachi, L.S. Vargas, D. Kreher, B. Heinrich, J.-C. Ribierre, F. Mathevet, Electron Transport in Soft-Crystalline Thin Films of Perylene Diimide Substituted with Swallow-Tail Terminal Alkyl Chains, Journal of Physical Chemistry C 128 (2024) 21826–21835. https://doi.org/10.1021/acs.jpcc.4c06222.
[1]
P. Strzelecki, A. Shpiruk, G.M. Cech, A. Kloska, P. Hébraud, N. Beyer, F. Busi, W. Grange, Robust, high-yield, rapid fabrication of DNA constructs for Magnetic Tweezers, Biochemical and Biophysical Research Communications 731 (2024) 150370. https://doi.org/https://doi.org/10.1016/j.bbrc.2024.150370.
[1]
T. Thierry, Y. Geiger, S. Bellemin-Laponnaz, Divergence of catalytic systems in the zinc-catalysed alkylation of benzaldehyde mediated by chiral proline-based ligands, Nature Synthesis (2024). https://doi.org/10.1038/s44160-024-00491-y.
[1]
T. Thierry, J. Frey, Y. Geiger, S. Bellemin-Laponnaz, Les effets non linéaires en catalyse asymétrique, L’actualité Chimique (2024) 40–49. https://new.societechimiquedefrance.fr/numero/les-effets-non-lineaires-en-catalyse-asymetrique-p40-n491/.
[1]
T. Thierry, V. Giuso, F. Polo, P. Mercandelli, Y.-T. Chen, C.-H. Chang, M. Mauro, S. Bellemin-Laponnaz, A stable and true-blue emissive hexacoordinate Si(iv) N-heterocyclic carbene complex and its use in organic light-emitting diodes, Dalton Transactions 53 (2024) 6445–6450. https://doi.org/10.1039/d4dt00420e.
[1]
T. Thierry, Y. Geiger, S. Bellemin-Laponnaz, Correction: Thierry et al. Observation of Hyperpositive Non-Linear Effect in Asymmetric Organozinc Alkylation in Presence of N-Pyrrolidinyl Norephedrine. (Molecules 2022, 27, 3780.), Molecules (Basel, Switzerland) 29 (2024) 4265. https://doi.org/10.3390/molecules29174265.
[1]
C.-Y. Zeng, W.-J. Deng, K.-Q. Zhao, C. Redshaw, B. Donnio, Phenanthrothiophene-Triazine Star-Shaped Discotic Liquid Crystals: Synthesis, Self-Assembly, and Stimuli-Responsive Fluorescence Properties, Chemistry-a European Journal (2024) e202400296. https://doi.org/10.1002/chem.202400296.
[1]
C. Zeng, H. Wang, B.-Q. Wang, P. Hu, K.-Q. Zhao, B. Donnio, Dual-State Fluorescence in Some Salicylaldehyde-triphenylene Discotic Liquid Crystal Derivatives Induced by Excited State Intramolecular Proton Transfer, Chemistry of Materials 36 (2024) 7306–7316. https://doi.org/10.1021/acs.chemmater.4c01213.
[1]
K.-L. Zhang, W.-H. Yu, K.-Q. Zhao, P. Hu, B.-Q. Wang, B. Donnio, Mesomorphism Modulation of Perfluorinated Janus Triphenylenes by Inhomogeneous Chain Substitution Patterns, Chemistry-an Asian Journal 19 (2024). https://doi.org/10.1002/asia.202301080.