Metals and their functions

Team presentation here

Research Activities

Organometallic chemistry and catalysis

Supramolecular chemistry, material chemistry

Bioinorganic and medicinal chemistry

Team members

Chargé de Recherche, Organic Materials (DMO)thierry.achard@ipcms.unistra.fr
Station: +33(0)3 88 10 71 62Office: 2041
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Directeur de Recherche, Organic Materials (DMO)stephane.bellemin@ipcms.unistra.fr
Station: +33(0)3 88 10 71 66Office: 2045
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Doctorante, Organic Materials (DMO)anna.bonfiglio@ipcms.unistra.fr
Station: +33(0)3 88 10 71 57Office: 2036
CDD IT, Organic Materials (DMO)julien.egly@ipcms.unistra.fr
Station: /Office: 2050
Maîtresse de conférences, Organic Materials (DMO)aline.maisse@ipcms.unistra.fr
Station: +33(0)3 88 10 71 66Office: 2045
Maître de conférences, Organic Materials (DMO)matteo.mauro@ipcms.unistra.fr
Station: +33(0)3 88 10 72 07Office: 2034
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Recent publications

[1]
T. Achard, S. Bellemin-Laponnaz, Recent Advances on Catalytic Osmium-Free Olefin syn-Dihydroxylation, European Journal of Organic Chemistry. 2021 (2021) 877–896. https://doi.org/10.1002/ejoc.202001209.
[1]
Z. Asbai, A. Bonfiglio, P. Mercandelli, F. Polo, M. Mauro, Cationic rhenium(I) complexes bearing a pi-accepting pyridoannulated N-heterocyclic carbene ligand: Synthesis, photophysical, electrochemical and theoretical investigation, Polyhedron. 197 (2021) 115025. https://doi.org/10.1016/j.poly.2021.115025.
[1]
A. Bonfiglio, C. McCartin, U. Carrillo, C. Cebrian, P.C. Gros, S. Fournel, A. Kichler, C. Daniel, M. Mauro, Ir-III-Pyridoannelated N-Heterocyclic Carbene Complexes: Potent Theranostic Agents via Mitochondria Targeting, European Journal of Inorganic Chemistry. (2021) 1551–1564. https://doi.org/10.1002/ejic.202100132.
[1]
H. Chen, Y. Zhang, A. Bonfiglio, F. Morlet-Savary, M. Mauro, J. Lalevee, Rhenium(I) N-Heterocyclic Carbene Complexes in Photoinitiating Systems for Polymerization upon Visible Light: Development of Photosensitive Resins for 3D and 4D Applications, ACS Applied Polymer Materials. 3 (2021) 464–473. https://doi.org/10.1021/acsapm.0c01207.
[1]
R. De Marco, M. Dal Grande, M. Baron, L. Orian, C. Graiff, T. Achard, S. Bellemin-Laponnaz, A. Pothig, C. Tubaro, Synthesis, Structural Characterization and Antiproliferative Activity of Gold(I) and Gold(III) Complexes Bearing Thioether-Functionalized N-Heterocyclic Carbenes, European Journal of Inorganic Chemistry. (2021) 1–12. https://doi.org/10.1002/ejic.202100495.
[1]
J. Egly, D. Bissessar, T. Achard, B. Heinrich, P. Steffanut, M. Mauro, S. Bellemin-Laponnaz, Copper(I) complexes with remotely functionalized phosphine ligands: Synthesis, structural variety, photophysics and effect onto the optical properties, Inorganica Chimica Acta. 514 (2021) 119971. https://doi.org/10.1016/j.ica.2020.119971.
[1]
Y. Geiger, T. Achard, A. Maisse-Francois, S. Bellemin-Laponnaz, Absence of Non-Linear Effects Despite Evidence for Catalyst Aggregation, European Journal of Organic Chemistry. early (2021). https://doi.org/10.1002/ejoc.202100183.
[1]
F. Hammoud, M. Rahal, J. Egly, F. Morlet-Savary, A. Hijazi, S. Bellemin-Laponnaz, M. Mauro, J. Lalevee, Cubane Cu4I4(phosphine)(4) complexes as new co-initiators for free radical photopolymerization: towards aromatic amine-free systems, Polymer Chemistry. 12 (2021) 2848–2859. https://doi.org/10.1039/d1py00277e.
[1]
M. Marinova, A. Bonnefont, T. Achard, A. Maisse-Francois, S. Bellemin-Laponnaz, Polymerization/depolymerization of chiral metallo-supramolecular assembly induced by redox change, Chirality. (2021) 1–8. https://doi.org/10.1002/chir.23342.
[1]
M. Mauro, Phosphorescent multinuclear complexes for optoelectronics: tuning of the excited-state dynamics, Chemical Communications. early (2021). https://doi.org/10.1039/d1cc01077h.
[1]
M. Paolino, A. Reale, G. Magrini, V. Razzano, M. Saletti, G. Giuliani, A. Donati, F. Samperi, A. Scamporrino, M. Canetti, M. Mauro, F. Villafiorita-Monteleone, E. Fois, C. Botta, A. Cappelli, Synthesis and UV-light induced oligomerization of a benzofulvene-based neutral platinum(II) complex, European Polymer Journal. 156 (2021) 110597. https://doi.org/10.1016/j.eurpolymj.2021.110597.
[1]
S. Bellemin-Laponnaz, N-Heterocyclic Carbene Platinum Complexes: A Big Step Forward for Effective Antitumor Compounds, European Journal of Inorganic Chemistry. 2020 (2020) 10–20. https://doi.org/10.1002/ejic.201900960.
[1]
A. Bonfiglio, M. Mauro, PhosphorescentTris-Bidentate Ir(III)Complexes with N-Heterocyclic Carbene Scaffolds: Structural Diversity and Optical Properties, European Journal of Inorganic Chemistry. early (2020). https://doi.org/10.1002/ejic.202000509.
[1]
A. Bonfiglio, K. Magra, C. Cebrian, F. Polo, P.C. Gros, P. Mercandelli, M. Mauro, Red-emitting neutral rhenium(I) complexes bearing a pyridyl pyridoannelated N-heterocyclic carbene, Dalton Transactions. 49 (2020) 3102–3111. https://doi.org/10.1039/c9dt04890a.
[1]
A. Bonfiglio, L. Pallova, V. Cesar, C. Gourlaouen, S. Bellemin-Laponnaz, C. Daniel, F. Polo, M. Mauro, Phosphorescent Cationic Heterodinuclear Ir-III/M(I)Complexes (M=Cu-I, Au-I) with a Hybrid Janus-Type N-Heterocyclic Carbene Bridge, Chemistry-a European Journal. 26 (2020) 1–17. https://doi.org/10.1002/chem.202002767.
[1]
M. Bouche, B. Vincent, T. Achard, S. Bellemin-Laponnaz, N-Heterocyclic Carbene Platinum(IV) as Metallodrug Candidates: Synthesis and(195)Pt NMR Chemical Shift Trend, Molecules. 25 (2020) 3148. https://doi.org/10.3390/molecules25143148.
[1]
E. Charignon, M. Bouche, C. Clave-Darcissac, G. Dahm, G. Ichim, A. Clotagatide, H.C. Mertani, P. Telouk, J. Caramel, J.-J. Diaz, S. Bellemin-Laponnaz, P. Bouvet, C. Billotey, In Cellulo Evaluation of the Therapeutic Potential of NHC Platinum Compounds in Metastatic Cutaneous Melanoma, International Journal of Molecular Sciences. 21 (2020) 7626. https://doi.org/10.3390/ijms21217826.
[1]
W. Chen, J. Egly, A. Pobtador-Bahamonde I., A. Maisse-Francois, S. Bellemin-Laponnaz, T. Achard, Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (kappa 2-C,S)-thioether-functionalised NHC ligands, Dalton Transactions. 49 (2020) 3243–3252. https://doi.org/10.1039/c9dt04825a.
[1]
Y. Geiger, T. Achard, A. Maisse-Francois, S. Bellemin-Laponnaz, Hyperpositive nonlinear effects in asymmetric catalysis, Nature Catalysis. (2020). https://doi.org/10.1038/s41929-020-0441-1.
[1]
Y. Geiger, T. Achard, A. Maisse-Francois, S. Bellemin-Laponnaz, Observation of hyperpositive non-linear effect in catalytic asymmetric organozinc additions to aldehydes, Chirality. (2020) 1–7. https://doi.org/10.1002/chir.23271.
[1]
Y. Geiger, T. Achard, A. Maisse-Francois, S. Bellemin-Laponnaz, Hyperpositive non-linear effects: enantiodivergence and modelling, Chemical Science. 11 (2020) 12453–12463. https://doi.org/10.1039/d0sc04724d.
[1]
K.S. Kumar, I. Salitros, B. Heinrich, S. Moldovan, M. Mauro, M. Ruben, Spin-crossover in iron(II)-phenylene ethynylene-2,6-di(pyrazol-1-yl) pyridine hybrids: toward switchable molecular wire-like architectures, Journal of Physics-Condensed Matter. 32 (2020) 204002. https://doi.org/10.1088/1361-648X/ab6cc2.
[1]
M. Marinova, A. Bonnefont, T. Achard, A. Maisse-Francois, S. Bellemin-Laponnaz, Chiral stimuli-responsive metallo-supramolecular assembly induced by Cu-II/Cu(I)redox change, Chemical Communications. 56 (2020) 8703–8706. https://doi.org/10.1039/d0cc01716g.
[1]
M. Paolino, A. Reale, G. Magrini, V. Razzano, G. Giuliani, A. Donati, G. Giorgi, F. Samperi, M. Canetti, M. Mauro, F. Villafiorita-Monteleone, E. Fois, C. Botta, A. Cappelli, UV-light-induced polymerization in the amorphous solid-state of a spontaneously non-polymerizing 3-phenylbenzofulvene monomer, European Polymer Journal. 137 (2020) 109923. https://doi.org/10.1016/j.eurpolymj.2020.109923.
[1]
C. Romain, S. Bellemin-Laponnaz, S. Dagorne, Recent progress on NHC-stabilized early transition metal (group 3-7) complexes: Synthesis and applications, Coordination Chemistry Reviews. 422 (2020) 213411. https://doi.org/10.1016/j.ccr.2020.213411.
[1]
R. Verron, T. Achard, C. Seguin, S. Fournel, S. Bellemin-Laponnaz, Synthesis and Characterization of N-Heterocyclic Carbene Dithiocarbamate Platinum Complexes with Antitumoral Activity, European Journal of Inorganic Chemistry. (2020). https://doi.org/10.1002/ejic.202000329.