Christophe LEFEVRE
Researcher, Inorganic Materials Chemistry (DCMI)Christophe.Lefevre@ipcms.unistra.frPhone: +33(0)3 88 10 71 28Office: 2008
Research background
click on pictures/logos for links
Academic background
click on pictures/logos for links
Current researches
click on pictures/logos for links
• Synthesis and characterisation of functional oxides | |
---|---|
The CoFe2O4 and FeV2O4 spinel compounds | |
The multiferroic Ga2-xFexO3[/latex] compounds |
• Partnership and Valorization | |
---|---|
Collaboration with Dassault-Aviation | |
Joint Research Lab Moliere |
Expertise & Software Development
click on pictures/logos for links
• X-rays Diffraction | |
---|---|
Le Bail & Rietveld Analyses | |
Resonant diffraction |
• Development | |
---|---|
FitREXS : simulation and refinement of DANES spectra |
Other / Networks
click on pictures/logos for links
Other :
CRPP (Competent Radiological Protection Person)
Networks : | |||
---|---|---|---|
Blender : |
Publications
1839302
lefèvre
surface-science-reports
50
creator
desc
year
6939
https://www.ipcms.fr/wp-content/plugins/zotpress/
%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3A%22zotpress-3b0680fa8df27bf77701f1a7fb933c8d%22%2C%22meta%22%3A%7B%22request_last%22%3A50%2C%22request_next%22%3A50%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%228Q3KQBQJ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Werckmann%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Werckmann%2C%20J.%20Cypriano%2C%20C.T.%20Lef%26%23xE8%3Bvre%2C%20K.%20Dembele%2C%20O.%20Ersen%2C%20D.A.%20Bazylinski%2C%20U.%20Lins%2C%20M.%20Farina%2C%20Localized%20iron%20accumulation%20precedes%20nucleation%20and%20growth%20of%20magnetite%20crystals%20in%20magnetotactic%20bacteria%2C%20Scientific%20Reports%207%20%282017%29%208291.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-017-08994-9%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1038%5C%2Fs41598-017-08994-9%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Localized%20iron%20accumulation%20precedes%20nucleation%20and%20growth%20of%20magnetite%20crystals%20in%20magnetotactic%20bacteria%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacques%22%2C%22lastName%22%3A%22Werckmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jefferson%22%2C%22lastName%22%3A%22Cypriano%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christopher%20T.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kassioge%22%2C%22lastName%22%3A%22Dembele%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dennis%20A.%22%2C%22lastName%22%3A%22Bazylinski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ulysses%22%2C%22lastName%22%3A%22Lins%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcos%22%2C%22lastName%22%3A%22Farina%22%7D%5D%2C%22abstractNote%22%3A%22Many%20magnetotactic%20bacteria%20%28MTB%29%20biomineralize%20magnetite%20crystals%20that%20nucleate%20and%20grow%20inside%20intracellular%20membranous%20vesicles%20that%20originate%20from%20invaginations%20of%20the%20cytoplasmic%20membrane.%20The%20crystals%20together%20with%20their%20surrounding%20membranes%20are%20referred%20to%20magnetosomes.%20Magnetosome%20magnetite%20crystals%20nucleate%20and%20grow%20using%20iron%20transported%20inside%20the%20vesicle%20by%20specific%20proteins.%20Here%20we%20address%20the%20question%3A%20can%20iron%20transported%20inside%20MTB%20for%20the%20production%20of%20magnetite%20crystals%20be%20spatially%20mapped%20using%20electron%20microscopy%3F%20Cultured%20and%20uncultured%20MTB%20from%20brackish%20and%20freshwater%20lagoons%20were%20studied%20using%20analytical%20transmission%20electron%20microscopy%20in%20an%20attempt%20to%20answer%20this%20question.%20Scanning%20transmission%20electron%20microscopy%20was%20used%20at%20sub-nanometric%20resolution%20to%20determine%20the%20distribution%20of%20elements%20by%20implementing%20high%20sensitivity%20energy%20dispersive%20X-ray%20%28EDS%29%20mapping%20and%20electron%20energy%20loss%20spectroscopy%20%28EELS%29.%20EDS%20mapping%20showed%20that%20magnetosomes%20are%20enmeshed%20in%20a%20magnetosomal%20matrix%20in%20which%20iron%20accumulates%20close%20to%20the%20magnetosome%20forming%20a%20continuous%20layer%20visually%20appearing%20as%20a%20corona.%20EELS%2C%20obtained%20at%20high%20spatial%20resolution%2C%20confirmed%20that%20iron%20was%20present%20close%20to%20and%20inside%20the%20lipid%20bilayer%20magnetosome%20membrane.%20This%20study%20provides%20important%20clues%20to%20magnetite%20formation%20in%20MTB%20through%20the%20discovery%20of%20a%20mechanism%20where%20iron%20ions%20accumulate%20prior%20to%20magnetite%20biomineralization.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1038%5C%2Fs41598-017-08994-9%22%2C%22ISSN%22%3A%222045-2322%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1038%5C%2Fs41598-017-08994-9%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%5D%2C%22dateModified%22%3A%222021-12-08T13%3A16%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22ASVHVBUI%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Walter%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Walter%2C%20C.%20Billotey%2C%20A.%20Garofalo%2C%20C.%20Ulhaq-Bouillet%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20J.%20Taleb%2C%20S.%20Laurent%2C%20L.%20Vander%20Elst%2C%20R.N.%20Muller%2C%20L.%20Lartigue%2C%20F.%20Gazeau%2C%20D.%20Felder-Flesch%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Mastering%20the%20Shape%20and%20Composition%20of%20Dendronized%20Iron%20Oxide%20Nanoparticles%20To%20Tailor%20Magnetic%20Resonance%20Imaging%20and%20Hyperthermia%2C%20Chemistry%20of%20Materials%2026%20%282014%29%205252%26%23x2013%3B5264.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcm5019025%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcm5019025%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Mastering%20the%20Shape%20and%20Composition%20of%20Dendronized%20Iron%20Oxide%20Nanoparticles%20To%20Tailor%20Magnetic%20Resonance%20Imaging%20and%20Hyperthermia%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aurelie%22%2C%22lastName%22%3A%22Walter%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Claire%22%2C%22lastName%22%3A%22Billotey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Garofalo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Ulhaq-Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jacqueline%22%2C%22lastName%22%3A%22Taleb%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Laurent%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Luce%22%2C%22lastName%22%3A%22Vander%20Elst%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Robert%20N.%22%2C%22lastName%22%3A%22Muller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lenaic%22%2C%22lastName%22%3A%22Lartigue%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Florence%22%2C%22lastName%22%3A%22Gazeau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Delphine%22%2C%22lastName%22%3A%22Felder-Flesch%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22The%20current%20challenge%20in%20the%20field%20of%20nano-medicine%20is%20the%20design%20of%20multifunctional%20nano-objects%20effective%20both%20for%20the%20diagnosis%20and%20treatment%20of%20diseases.%20Here%2C%20dendronized%20FeO1-x%40Fe3-xO4%20nanoparticles%20with%20spherical%2C%20cubic%2C%20and%20octopode%20shapes%20and%20oxidized%20Fe3-xO4%20nanocubes%20have%20been%20synthesized%20and%20structurally%20and%20magnetically%20characterized.%20Strong%20exchange%20bias%20properties%20are%20highlighted%20in%20core%20shell%20nanoparticles%20%28NPs%29%20due%20to%20magnetic%20interactions%20between%20their%20antiferromagnetic%20core%20and%20ferrimagnetic%20shell.%20Both%20in%20vitro%20relaxivity%20measurements%20and%20nuclear%20magnetic%20resonance%20%28NMR%29%20distribution%20profiles%20have%20confirmed%20the%20very%20good%20in%20vitro%20magnetic%20resonance%20imaging%20%28Mm%29%20properties%20of%20core%20shell%20and%20cubic%20shape%20NPs%2C%20especially%20at%20low%20concentration.%20This%20might%20be%20related%20to%20the%20supplementary%20anisotropy%20introduced%20by%20the%20exchange%20bias%20properties%20and%20the%20cubic%20shape.%20The%20high%20heating%20values%20of%20core%20shell%20NPs%20and%20oxidized%20nanocubes%20at%20low%20concentration%20are%20attributed%20to%20dipolar%20interactions%20inducing%20different%20clustering%20states%2C%20as%20a%20function%20of%20concentration.%20In%20vivo%20MRI%20studies%20have%20also%20evidenced%20a%20clustering%20effect%20at%20the%20injection%20point%2C%20depending%20on%20the%20concentration%2C%20and%20confirmed%20the%20very%20good%20in%20vivo%20MRI%20properties%20of%20core%20shell%20NPs%20and%20oxidized%20nanocubes%20in%20particular%20at%20low%20concentration.%20These%20results%20show%20that%20these%20core%20shell%20and%20cubic%20shape%20dendronized%20nano-objects%20are%20very%20suitable%20to%20combine%20MRI%20and%20hyperthermia%20properties%20at%20low%20injected%20doses.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Fcm5019025%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fcm5019025%22%2C%22collections%22%3A%5B%222DH6J37C%22%2C%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22BMA9GKQT%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A16%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22Z5EQERJG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Valenzuela%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EL.%20Valenzuela%2C%20F.-B.%20Yimbou%2C%20A.%20Ewin%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20R.%20Manzorro%2C%20N.%20Keller%2C%20Ru-modified%20graphitic%20carbon%20nitride%20for%20the%20solar%20light-driven%20photocatalytic%20H2O2%20synthesis%2C%20Catalysis%20Today%20441%20%282024%29%20114881.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.cattod.2024.114881%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.cattod.2024.114881%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ru-modified%20graphitic%20carbon%20nitride%20for%20the%20solar%20light-driven%20photocatalytic%20H2O2%20synthesis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laura%22%2C%22lastName%22%3A%22Valenzuela%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Frael-Benjamin%22%2C%22lastName%22%3A%22Yimbou%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antoine%22%2C%22lastName%22%3A%22Ewin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ramon%22%2C%22lastName%22%3A%22Manzorro%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%5D%2C%22abstractNote%22%3A%22Hydrogen%20peroxide%20%28H2O2%29%20is%20an%20efficient%20and%20environmentally%20friendly%20oxidant%20as%20well%20as%20a%20promising%20energycarrier%20alternative%20to%20hydrogen.%20Its%20solar%20light-driven%20photocatalytic%20synthesis%20from%20H2O%20and%20O2%20is%20a%20highprospect%20sustainable%20alternative%20to%20the%20industrial%20anthraquinone%20process.%20Hybrid%20Ru-modified%20graphitic%20carbon%20nitride%20%28g-C3N4%29%20catalysts%20were%20prepared%20by%20thermal%20polymerisation%20of%20melamine%5C%2FRu%28III%29%20acetylacetonate%20mixtures%2C%20and%20subsequent%20thermal%20exfoliation.%20Simultaneous%20Ru%20incorporation%20and%20thermal%20exfoliation%20impacted%20the%20morphology%20and%20the%20structure%20of%20the%20g-C3N4%20sheets%2C%20and%20low-atomicity%20Ru%20species%20with%20small%20nanoclusters%20and%20single%20atoms%20were%20observed%20only%20in%20the%20Ru-modified%20exfoliated%20g-C3N4%20photocatalysts.%20We%20demonstrated%20the%20potential%20of%20a%20joint%20thermal%20exfoliation%20and%20modification%20with%20Ru%20to%20enhance%20the%20H2O2%20synthesis%20efficiency%20of%20the%20g-C3N4%20photocatalyst%20under%20simulated%20sunlight.%20A%20volcano-type%20behavior%20was%20observed%20with%20increasing%20the%20Ru%20content%2C%20and%20the%20best%20performance%20was%20obtained%20for%20exfoliated%20g-C3N4%20with%20an%20ultra-low%20Ru%20content%20of%200.019%20wt.%20%25%2C%20that%20outperformed%20both%20its%20bulk%20counterpart%20and%20the%20pristine%20exfoliated%20reference%20in%20terms%20of%20initial%20H2O2%20synthesis%20rate%20and%20H2O2%20formation%20rate%20constant.%20The%20enhanced%20performance%20was%20attributed%20to%20the%20presence%20of%20highly%20dispersed%20low%20atomicity%20Ru%20as%20well%20as%20to%20more%20accessible%20active%20sites%20and%20carrier%20migration%20channels.%20Quenching%20experiments%20revealed%20a%20mixed%20reactional%20pathway%20involving%20both%20two-step%20one-electron%20and%20one-step%20two-electron%20O2%20reduction%20in%20the%20photocatalytic%20H2O2%20production.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.cattod.2024.114881%22%2C%22ISSN%22%3A%220920-5861%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.cattod.2024.114881%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222024-08-21T12%3A14%3A37Z%22%7D%7D%2C%7B%22key%22%3A%22UKGKD22I%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thomasson%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Thomasson%2C%20F.%20Ibrahim%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20E.%20Autissier%2C%20F.%20Roulland%2C%20C.%20M%26%23xE9%3Bny%2C%20C.%20Leuvrey%2C%20S.%20Choi%2C%20W.%20Jo%2C%20O.%20Cr%26%23xE9%3Bgut%2C%20G.%20Versini%2C%20S.%20Barre%2C%20M.%20Alouani%2C%20N.%20Viart%2C%20Effects%20of%20iron%20concentration%20and%20cationic%20site%20disorder%20on%20the%20optical%20properties%20of%20magnetoelectric%20gallium%20ferrite%20thin%20films%2C%20RSC%20Advances%203%20%282013%29%203124%26%23x2013%3B3130.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc2ra22681b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc2ra22681b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Effects%20of%20iron%20concentration%20and%20cationic%20site%20disorder%20on%20the%20optical%20properties%20of%20magnetoelectric%20gallium%20ferrite%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Ibrahim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Autissier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Choi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22W.%22%2C%22lastName%22%3A%22Jo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22O.%22%2C%22lastName%22%3A%22Cr%5Cu00e9gut%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Alouani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Room-temperature%20dielectric%20function%20epsilon%20%3D%20epsilon%281%29%20%2B%20i%20epsilon%282%29%20spectra%20of%20magnetoelectric%20Ga2-xFexO3%20%28x%20%3D%200.9%2C%201.0%2C%20and%201.4%29%20thin%20films%20are%20determined%20by%20spectroscopic%20ellipsometry%20%28SE%29%20as%20a%20function%20of%20Fe%20concentration%20x.%20The%20SE%20data%20are%20analysed%20by%20a%20multilayer%20model%20with%20a%20series%20of%20Tauc-Lorentz%20oscillators.%20While%20the%20threshold%20energies%20slightly%20decrease%20as%20x%20increases%2C%20the%20oscillator%20strength%20shows%20a%20strong%20composition-dependence%20for%20the%20major%20optical%20structure%20at%20similar%20to%203.5%20eV.%20The%20experimental%20data%20are%20compared%20to%20the%20epsilon%20spectra%20obtained%20by%20density%20functional%20theory%20%28%20DFT%29%20calculations.%20Even%20though%20the%20overall%20shape%20of%20epsilon%20spectra%20is%20consistent%2C%20the%20experimental%20data%20and%20calculated%20spectra%20show%20a%20clear%20discrepancy%20in%20the%20oscillator%27s%20strength%20ratio%20of%20the%20two%20optical%20structures%20at%20similar%20to%203.5%20and%20similar%20to%206.0%20eV.%20The%20DFT%20calculations%20suggest%20that%20a%20significant%20disordering%20in%20the%20cationic%20%28Ga%20and%20Fe%29%20sites%20in%20Ga2-xFexO3%20is%20present%20in%20thin%20films%2C%20which%20influences%20their%20optical%20properties.%20This%20work%20demonstrates%20a%20successful%20application%20of%20optical%20characterization%20for%20determining%20the%20cationic%20sites%20occupation%20in%20thin%20films%2C%20which%20in%20turn%20improves%20our%20understanding%20of%20Physics%20and%20Chemistry%20in%20Ga2-xFexO3%20thin%20films%20and%20paves%20a%20pathway%20to%20the%20development%20of%20new%20multifunctional%20devices.%22%2C%22date%22%3A%222013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fc2ra22681b%22%2C%22ISSN%22%3A%222046-2069%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc2ra22681b%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%222A2F8AAB%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222021-11-17T14%3A56%3A56Z%22%7D%7D%2C%7B%22key%22%3A%22EBGATJIP%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thomasson%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Thomasson%2C%20S.%20Cherifi%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20B.%20Gautier%2C%20D.%20Albertini%2C%20C.%20M%26%23xE9%3Bny%2C%20N.%20Viart%2C%20Room%20temperature%20multiferroicity%20in%20Ga0.6Fe1.4O3%3AMg%20thin%20films%2C%20Journal%20of%20Applied%20Physics%20113%20%282013%29%20214101.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4808349%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4808349%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Room%20temperature%20multiferroicity%20in%20Ga0.6Fe1.4O3%3AMg%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Cherifi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Gautier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.%22%2C%22lastName%22%3A%22Albertini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20on%20the%20multiferroic%20behavior%20of%202%25-magnesium-doped%20Ga0.6Fe1.4O3%20thin%20film%20at%20room%20temperature.%20The%20sample%20was%20grown%20by%20pulsed%20laser%20deposition%20on%20a%20Pt-coated%20Yttrium-Stabilized%20Zirconia%20substrate.%20Magnetic%20measurements%20indicate%20a%20net%20magnetization%20of%20105%20emu%5C%2Fcm%283%29%20at%20295%20K%2C%20and%20the%20persistence%20of%20magnetic%20ordering%20above%20room%20temperature.%20Ferroelectric%20measurements%20show%20clear%20polarization%20switching%20with%20negligible%20contribution%20from%20leakage%20currents%2C%20with%20a%20polarization%20of%200.2%20mu%20C%5C%2Fcm%28-2%29%20and%20a%20coercive%20field%20of%20133%20kV%5C%2Fcm.%20Scanning%20probe%20microscopy%20confirms%20the%20low%20leakage%20current%20and%20detects%20a%20stable%20piezoelectric%20signal.%20This%20could%20open%20original%20perspectives%20for%20the%20application%20of%20single-phased%20multiferroic%20systems.%20%28C%29%202013%20AIP%20Publishing%20LLC.%22%2C%22date%22%3A%222013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4808349%22%2C%22ISSN%22%3A%220021-8979%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F1.4808349%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22MKAFAH44%22%2C%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222017-04-04T09%3A31%3A42Z%22%7D%7D%2C%7B%22key%22%3A%22WHVKGI4F%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Thomasson%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Thomasson%2C%20J.%20Kreisel%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20G.%20Versini%2C%20S.%20Barre%2C%20N.%20Viart%2C%20Raman%20scattering%20of%20magnetoelectric%20gallium%20ferrite%20thin%20films%2C%20Journal%20of%20Physics-Condensed%20Matter%2025%20%282013%29%20045401.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-8984%5C%2F25%5C%2F4%5C%2F045401%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F0953-8984%5C%2F25%5C%2F4%5C%2F045401%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Raman%20scattering%20of%20magnetoelectric%20gallium%20ferrite%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Kreisel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Gallium%20ferrite%2C%20Ga2-xFexO3%20%28GFO%29%2C%20is%20a%20promising%20magnetoelectric%20material%20as%20it%20exhibits%20both%20magnetic%20and%20electric%20orders%20close%20to%20room%20temperature.%20Here%2C%20we%20report%20a%20temperature-dependent%20investigation%20of%20GFO%20thin%20films%20with%20x%20%3D%201.0%20and%201.4%20by%20using%20Raman%20scattering.%20Our%20investigation%20suggests%20the%20absence%20of%20a%20structural%20phase%20transition%20of%20both%20films%20in%20the%20investigated%2090-500%20K%20temperature%20range%2C%20which%20is%20similar%20to%20earlier%20observations%20on%20bulk%20samples.%20We%20note%2C%20however%2C%20the%20occurrence%20of%20weak%20anomalies%20in%20the%20temperature-dependent%20band%20position%20of%20some%20phonons%2C%20which%20we%20attribute%20to%20spin-phonon%20coupling%20as%20the%20anomalies%20occur%20close%20to%20the%20Neel%20temperature%20of%20the%20materials.%22%2C%22date%22%3A%222013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1088%5C%2F0953-8984%5C%2F25%5C%2F4%5C%2F045401%22%2C%22ISSN%22%3A%220953-8984%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1088%5C%2F0953-8984%5C%2F25%5C%2F4%5C%2F045401%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222016-09-09T06%3A38%3A33Z%22%7D%7D%2C%7B%22key%22%3A%224NZHAQRK%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Soszka%20et%20al.%22%2C%22parsedDate%22%3A%222022%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EE.%20Soszka%2C%20M.%20Jedrzejczyk%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Ihiawakrim%2C%20N.%20Keller%2C%20A.M.%20Ruppert%2C%20TiO2-supported%20Co%20catalysts%20for%20the%20hydrogenation%20of%20gamma-valerolactone%20to%202-methyltetrahydrofuran%3A%20influence%20of%20the%20support%2C%20Catalysis%20Science%20%26amp%3B%20Technology%20Early%20Access%20%282022%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd2cy01044e%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd2cy01044e%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22TiO2-supported%20Co%20catalysts%20for%20the%20hydrogenation%20of%20gamma-valerolactone%20to%202-methyltetrahydrofuran%3A%20influence%20of%20the%20support%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emilia%22%2C%22lastName%22%3A%22Soszka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcin%22%2C%22lastName%22%3A%22Jedrzejczyk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Agnieszka%20M.%22%2C%22lastName%22%3A%22Ruppert%22%7D%5D%2C%22abstractNote%22%3A%222-Methyltetrahydrofuran%20%28MTHF%29%20is%20considered%20as%20one%20of%20the%20most%20promising%20green%20fuel%20alternatives%20that%20could%20be%20obtained%20from%20renewable%20lignocellulosic%20biomass%20through%20the%20catalytic%20hydrogenation%20of%20the%20gamma-valerolactone%20%28GVL%29%20platform%20molecule.%20In%20the%20current%20work%2C%20we%20report%20on%20the%20ability%20of%20earth-abundant%20non-noble%20metal%20Co%20catalysts%20supported%20on%20TiO2%20to%20be%20used%20efficiently%20for%20the%20synthesis%20of%20MTHF.%20The%20activity%20of%20TiO2-supported%20Co%20catalysts%20in%20the%20hydrogenation%20of%20GVL%20to%202-MTHF%20was%20investigated%2C%20and%20several%20key%20factors%20with%20significant%20influence%20on%20the%20reaction%20have%20been%20identified%20and%20discussed.%20Among%20them%2C%20we%20pointed%20out%20the%20crucial%20role%20of%20the%20titania%20support%20as%20a%20versatile%20tool%20able%20to%20drive%20the%20properties%20of%20the%20supported%20metallic%20cobalt%20nanoparticles%20and%20consequently%20the%20activity%20of%20the%20catalysts.%20In%20addition%20to%20the%20necessary%20catalyst%20acidity%2C%20we%20showed%20that%20the%20catalyst%20performances%20were%20related%20to%20the%20Co%20particle%20size%20and%20to%20the%20metal-support%20interaction%2C%20both%20properties%20being%20highly%20dependent%20on%20the%20composition%20of%20the%20titania%20support.%20We%20demonstrated%20the%20beneficial%20co-presence%20of%20both%20anatase%20and%20rutile%20crystalline%20phases%20within%20the%20TiO2%20support%2C%20and%20we%20proposed%20that%20the%20nature%20of%20the%20crystalline%20phase%20not%20only%20influences%20the%20Co%20particle%20size%20and%20the%20catalyst%20acidity%20but%20also%20allows%20tuning%20the%20SMSI%20effect%20for%20achieving%20optimum%20performances%20in%202-MTHF%20synthesis.%22%2C%22date%22%3A%222022%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd2cy01044e%22%2C%22ISSN%22%3A%222044-4753%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd2cy01044e%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-11-16T15%3A13%3A00Z%22%7D%7D%2C%7B%22key%22%3A%226D8L9PEN%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Sartori%20et%20al.%22%2C%22parsedDate%22%3A%222022%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EK.%20Sartori%2C%20D.%20Ihiawakrim%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20S.%20Reguer%2C%20C.%20Mocuta%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20F.%20Choueikani%2C%20B.P.%20Pichon%2C%20A%20detailed%20investigation%20of%20the%20core%40shell%20structure%20of%20exchanged%20coupled%20magnetic%20nanoparticles%20after%20performing%20solvent%20annealing%2C%20Materials%20Advances%20Early%20access%20%282022%29.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd2ma00629d%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fd2ma00629d%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20detailed%20investigation%20of%20the%20core%40shell%20structure%20of%20exchanged%20coupled%20magnetic%20nanoparticles%20after%20performing%20solvent%20annealing%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kevin%22%2C%22lastName%22%3A%22Sartori%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Solenn%22%2C%22lastName%22%3A%22Reguer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristian%22%2C%22lastName%22%3A%22Mocuta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fadi%22%2C%22lastName%22%3A%22Choueikani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%5D%2C%22abstractNote%22%3A%22Thanks%20to%20important%20advances%20in%20synthesis%20techniques%2C%20a%20wide%20collection%20of%20bimagnetic%20core-shell%20nanoparticles%20with%20tunable%20properties%20was%20reported%20in%20the%20literature.%20Such%20nanoparticles%20may%20combine%20two%20phases%20with%20different%20intrinsic%20magnetic%20properties%20%28magnetization%2C%20anisotropy%2C%20coercive%20field%2C%20etc.%29.%20Core-shell%20structures%20with%20large%20interfaces%20usually%20favor%20efficient%20exchange%20coupling%20between%20both%20phases%20that%20may%20result%20in%20the%20enhancement%20of%20the%20effective%20magnetic%20anisotropy%20energy%20and%20of%20the%20coercive%20field.%20In%20this%20context%2C%20the%20chemical%20composition%20and%20the%20crystal%20structure%20of%20the%20core%5C%2Fshell%20interface%20in%20nanoparticles%20are%20crucial%20parameters%20to%20modulate%20efficiently%20their%20magnetic%20properties.%20Here%2C%20we%20report%20on%20the%20solvent%20mediated%20thermal%20annealing%20of%20Fe3-delta%20O4%40CoO%20nanoparticles%20in%20a%20high%20boiling%20point%20solvent.%20The%20structure%20of%20nanoparticles%20was%20investigated%20before%20and%20after%20thermal%20annealing%20by%20advanced%20characterization%20techniques%20such%20as%20high%20resolution%20transmission%20electron%20microscopy%20%28HR-TEM%29%2C%20X-ray%20absorption%20spectroscopy%20%28XAS%29%2C%20X-ray%20magnetic%20circular%20dichroism%20%28XMCD%29%20and%20diffraction%20anomalous%20near%20edge%20structure%20%28DANES%29.%20The%20combination%20of%20DANES%20and%20XAS%5C%2FXMCD%20allowed%20studying%20the%20cationic%20distribution%20in%20spinel%20and%20wustite%20crystal%20structures%20as%20a%20function%20of%20site%20occupancy%20and%20oxidation%20state.%20To%20the%20best%20of%20our%20knowledge%2C%20it%20is%20the%20first%20time%20that%20DANES%20is%20performed%20to%20quantitatively%20investigate%20the%20chemical%20composition%20of%20biphasic%20metal%20oxide%20nanoparticles.%20Hence%2C%20we%20have%20investigated%20precisely%20the%20chemical%20composition%20of%20the%20spinel%20phase%20and%20that%20of%20the%20wustite%20phase.%20Besides%20the%20partial%20solubilisation%20of%20the%20CoO%20shell%20observed%20by%20HR-TEM%2C%20thermal%20annealing%20favors%20the%20formation%20of%20a%20thicker%20intermediate%20Co-doped%20ferrite%20layer%20at%20the%20spinel%5C%2Fwustite%20interface.%20Such%20significant%20modifications%20of%20the%20core%40shell%20structure%20markedly%20influence%20interfacial%20coupling%20phenomena%20between%20the%20core%20and%20the%20shell%2C%20hence%20offering%20wide%20perspectives%20towards%20nanoparticles%20with%20tunable%20magnetic%20properties%20for%20a%20variety%20of%20applications.%22%2C%22date%22%3A%222022%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fd2ma00629d%22%2C%22ISSN%22%3A%222633-5409%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fd2ma00629d%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222022-11-21T10%3A23%3A32Z%22%7D%7D%2C%7B%22key%22%3A%22K82RTZDI%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Salian%20et%20al.%22%2C%22parsedDate%22%3A%222018%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.D.%20Salian%2C%20B.M.%20Koo%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20T.%20Cottineau%2C%20C.%20Lebouin%2C%20A.T.%20Tesfaye%2C%20P.%20Knauth%2C%20V.%20Keller%2C%20T.%20Djenizian%2C%20Niobium%20Alloying%20of%20Self-Organized%20TiO2%20Nanotubes%20as%20an%20Anode%20for%20Lithium-Ion%20Microbatteries%2C%20Advanced%20Materials%20Technologies%203%20%282018%29%201700274.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmt.201700274%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fadmt.201700274%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Niobium%20Alloying%20of%20Self-Organized%20TiO2%20Nanotubes%20as%20an%20Anode%20for%20Lithium-Ion%20Microbatteries%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Girish%20D.%22%2C%22lastName%22%3A%22Salian%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Bon%20Min%22%2C%22lastName%22%3A%22Koo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thomas%22%2C%22lastName%22%3A%22Cottineau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chrystelle%22%2C%22lastName%22%3A%22Lebouin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexander%20T.%22%2C%22lastName%22%3A%22Tesfaye%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Knauth%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valerie%22%2C%22lastName%22%3A%22Keller%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Thierry%22%2C%22lastName%22%3A%22Djenizian%22%7D%5D%2C%22abstractNote%22%3A%22Self-supported%20titanium%20dioxide%20nanotube%20is%20explored%20as%20a%20potential%20negative%20electrode%20for%203D%20Li-ion%20%28micro%29%20batteries.%20Apart%20from%20the%20direct%20contact%20of%20the%20nanotubes%20with%20the%20substrate%2C%20the%201D%20porous%20structure%20effectively%20facilitates%20the%20flow%20of%20electrolyte%20into%20the%20bulk%2C%20alleviates%20any%20volume%20expansion%20during%20cycling%2C%20and%20provides%20a%20short%20lithium-ion%20diffusion%20length.%20The%20fabrication%20of%20self-supported%20Nb%20rich%20titanium%20dioxide%20nanotubes%20by%20electrochemical%20anodization%20of%20Ti-Nb%20alloys%20is%20reported.%20The%20structure%2C%20morphology%2C%20and%20the%20composition%20of%20the%20Nb%20alloyed%20TiO2%20nanotubes%20are%20studied%20using%20scanning%20electron%20microscopy%2C%20X-ray%20diffraction%2C%20and%20X-ray%20photoelectron%20spectroscopy.%20The%20electrochemical%20behavior%20of%20the%20alloyed%20and%20the%20pristine%20TiO2%20nanotubes%20is%20investigated%20by%20cyclic%20voltammetry%2C%20chronopotentiometry%2C%20and%20electrochemical%20impedance%20spectroscopy.%20The%20electrochemical%20performance%20of%20the%20pristine%20and%20the%20alloyed%20titania%20nanotubes%20reveals%20that%20as%20the%20niobium%20concentration%20increases%20the%20capacity%20increases.%20The%20titania%20nanotubes%20containing%2010%20wt%25%20of%20Nb%20deliver%20a%20higher%20capacity%2C%20with%20good%20capacity%20retention%20and%20coulombic%20efficiency.%20Electrochemical%20impedance%20spectroscopy%20analysis%20shows%20that%20Nb%20alloying%20can%20decrease%20the%20overall%20cell%20impedance%20by%20reducing%20the%20charge%20transfer%20resistance.%22%2C%22date%22%3A%222018%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fadmt.201700274%22%2C%22ISSN%22%3A%222365-709X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fadmt.201700274%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-03-14T13%3A29%3A50Z%22%7D%7D%2C%7B%22key%22%3A%22L3T9W9A4%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Roulland%20et%20al.%22%2C%22parsedDate%22%3A%222022%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EF.%20Roulland%2C%20G.%20Roseau%2C%20A.P.%20Corredor%2C%20L.%20Wendling%2C%20G.%20Krieger%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20M.%20Trassin%2C%20G.%20Pourroy%2C%20N.%20Viart%2C%20Promoting%20the%20magnetic%20exchanges%20in%20PLD%20deposited%20strained%20films%20of%20FeV2O4%20thin%20films%2C%20Materials%20Chemistry%20and%20Physics%20276%20%282022%29%20125360.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2021.125360%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2021.125360%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Promoting%20the%20magnetic%20exchanges%20in%20PLD%20deposited%20strained%20films%20of%20FeV2O4%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fran%5Cu00e7ois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Roseau%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20Pena%22%2C%22lastName%22%3A%22Corredor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurianne%22%2C%22lastName%22%3A%22Wendling%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Guillaume%22%2C%22lastName%22%3A%22Krieger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Morgan%22%2C%22lastName%22%3A%22Trassin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genevieve%22%2C%22lastName%22%3A%22Pourroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Transition%20metal%20complex%20oxides%20are%20remarkable%20for%20the%20richness%20of%20tunable%20physical%20properties%20their%20strongly%20correlated%20electrons%20allow.%20We%20have%20undertaken%20the%20pulsed%20laser%20deposition%20of%20epitaxial%20thin%20films%20of%20the%20magnetically%20frustrated%20FeV2O4%20spinel%20vanadate%20compound.%20A%20precise%20optimization%20of%20the%20oxygen%20pressure%20deposition%20conditions%20was%20necessary%20to%20avoid%20the%20presence%20of%20volatile%20over-oxidated%20vanadium%20while%20avoiding%20the%20presence%20of%20oxygen%20vacancies.%20We%20report%20the%20effect%20of%20the%20epitaxial%20compressive%20stress%20induced%20by%20the%20MgO%20substrates%20on%20the%20structural%20and%20magnetic%20properties%20of%20the%20films.%20The%20surprising%20films%20lattice%20parameters%20reduction%20in%20all%20directions%20lead%20to%20an%20unusual%20auxetic%20behaviour.%20The%20reduced%20volume%20of%20the%20cell%20results%20in%20a%20decrease%20of%20the%20V-V%20distances.%20This%20allows%20a%2050%20K%20increase%20of%20the%20magnetic%20transition%20temperature%2C%20which%20now%20reaches%20160%20K.%20The%20epitaxial%20strain%20tuning%20of%20the%20magnetic%20order%20in%20the%20iron-based%20vanadates%20open%20new%20degrees%20of%20freedom%20towards%20the%20integration%20of%20the%20films%20in%20oxide%20electronics.%22%2C%22date%22%3A%222022%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.matchemphys.2021.125360%22%2C%22ISSN%22%3A%220254-0584%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.matchemphys.2021.125360%22%2C%22collections%22%3A%5B%22NZSFH59F%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222022-01-07T14%3A58%3A23Z%22%7D%7D%2C%7B%22key%22%3A%228QGB3TFE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Roulland%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EF.%20Roulland%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20A.%20Thomasson%2C%20N.%20Viart%2C%20Study%20of%20Ga%282-x%29FexO3%20solid%20solution%3A%20Optimisation%20of%20the%20ceramic%20processing%2C%20in%3A%20Journal%20of%20the%20European%20Ceramic%20Society%2C%202013%3A%20pp.%201029%26%23x2013%3B1035.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2012.11.014%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2012.11.014%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Study%20of%20Ga%282-x%29FexO3%20solid%20solution%3A%20Optimisation%20of%20the%20ceramic%20processing%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Magnetoelectrics%20are%20experiencing%20a%20renewal%20of%20interest%20in%20the%20recent%20years.%20These%20materials%20can%20be%20used%20as%20new%20data%20storage%20applications.%20The%20MeRAMs%20%28Magnetoelectric%20Random%20Access%20Memories%29%20actually%20combine%20the%20advantages%20of%20the%20magnetic%20random%20access%20memories%20%28MRAMs%29%20in%20terms%20of%20access%20time%20and%20endurance%20with%20those%20of%20the%20ferroelectric%20ones%20%28FeRAMs%29%20in%20terms%20of%20writing%20energy.%20Ga2-xFexO3%20%28GFO%29%20represents%20a%20good%20alternative%20to%20the%20perovskites%20usually%20studied%20for%20magnetoelectric%20applications%20as%20it%20is%20known%20to%20be%20polar%2C%20ferrimagnetic%20above%20room%20temperature%20for%20x%20%3E%3D%201.4%2C%20and%20magnetoelectric.%20The%20proposed%20work%20is%20to%20establish%20a%20complete%20study%20of%20the%20Ga2-xFexO3%20ceramic%20processing%20for%20x%20from%200.7%20to%201.4%2C%20optimising%20each%20fabrication%20step%20to%20obtain%20high%20quality%20materials.%20A%20diagram%20highlighting%20the%20opposing%20compounds%20in%20GFO%20solid%20solution%20has%20been%20established%20depending%20on%20the%20Fe%5C%2FGa%20ratio%20and%20the%20calcination%20temperature.%20Moreover%20the%20optimised%20ceramics%20exhibit%20significant%20improvements%20of%20the%20magnetic%20order%20temperatures.%20%28C%29%202012%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222013%22%2C%22proceedingsTitle%22%3A%22Journal%20of%20the%20European%20Ceramic%20Society%22%2C%22conferenceName%22%3A%22Electroceramics%20XIII%2C%20Enschede%2C%20Pays-Bas%2C%2024-27%20juin%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jeurceramsoc.2012.11.014%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2012.11.014%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A11%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22CSTIQJRW%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Raolison%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EZ.%20Raolison%2C%20Q.%20Clement%2C%20A.-L.%20Adenot-Engelvin%2C%20N.%20Mallejac%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20G.%20Pourroy%2C%20F.%20Boust%2C%20N.%20Vukadinovic%2C%20Broadband%20Permeability%20Spectra%20of%20Flake-Shaped%20Ferromagnetic%20Particle%20Composites%2C%20in%3A%20IEEE%20Transactions%20on%20Magnetics%2C%202017%3A%20p.%202801704.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2FTMAG.2017.2735943%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2FTMAG.2017.2735943%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Broadband%20Permeability%20Spectra%20of%20Flake-Shaped%20Ferromagnetic%20Particle%20Composites%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zo%22%2C%22lastName%22%3A%22Raolison%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Q.%22%2C%22lastName%22%3A%22Clement%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20-L.%22%2C%22lastName%22%3A%22Adenot-Engelvin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Mallejac%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genevi%5Cu00e8ve%22%2C%22lastName%22%3A%22Pourroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Boust%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Vukadinovic%22%7D%5D%2C%22abstractNote%22%3A%22Broadband%20permeability%20spectra%20of%20aligned%20ferromagnetic%20flakes%20embedded%20in%20a%20nonmagnetic%20polymer%20matrix%20have%20been%20measured%20using%20an%20APC-7%20coaxial%20line%20within%20the%20frequency%20range%2010%20MHz%20-18%20GHz.%20These%20spectra%20reveal%20two%20well-defined%20resonance%20lines.%20The%20low-frequency%20one%20%28sub-GHz%20range%29%20has%20previously%20been%20attributed%20to%20the%20fundamental%20vortex%20translation%20mode%20in%20a%20multidomain%20magnetic%20structure%2C%20whereas%20the%20high-frequency%20resonance%20%28beyond%201%20GHz%29%20is%20assigned%20to%20the%20natural%20spin%20resonance.%20A%20two-level%20analytical%20model%20combining%20a%20spin%20dynamics%20description%20including%20these%20two%20contributions%20at%20the%20flake%20scale%20and%20a%20Maxwell-Garnett%20mixing%20rule%20at%20the%20composite%20scale%20has%20been%20developed%20and%20reproduces%20very%20satisfactorily%20the%20experimental%20spectra%20in%20terms%20of%20resonance%20frequencies%2C%20resonance%20linewidths%2C%20and%20resonance%20mode%20amplitudes.%22%2C%22date%22%3A%222017%22%2C%22proceedingsTitle%22%3A%22IEEE%20Transactions%20on%20Magnetics%22%2C%22conferenceName%22%3A%22IEEE%20International%20Magnetics%20Conference%20%28Intermag%29%2C%20Dublin%2C%20IRELAND%2C%2024-28%20avril%202017%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1109%5C%2FTMAG.2017.2735943%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1109%5C%2FTMAG.2017.2735943%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222022-01-13T16%3A51%3A04Z%22%7D%7D%2C%7B%22key%22%3A%22NUNJM2XU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Raolison%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EZ.%20Raolison%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20J.%20Neige%2C%20A.-L.%20Adenot-Engelvin%2C%20J.M.%20Greneche%2C%20N.%20Vukadinovic%2C%20G.%20Pourroy%2C%20Structural%20and%20microwave%20properties%20of%20silica-coated%20NiFeMo%20flakes%5C%2Fpolymer%20composites%2C%20Materials%20Research%20Express%202%20%282015%29%20026101.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2053-1591%5C%2F2%5C%2F2%5C%2F026101%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1088%5C%2F2053-1591%5C%2F2%5C%2F2%5C%2F026101%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Structural%20and%20microwave%20properties%20of%20silica-coated%20NiFeMo%20flakes%5C%2Fpolymer%20composites%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Zo%22%2C%22lastName%22%3A%22Raolison%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Neige%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A-L%22%2C%22lastName%22%3A%22Adenot-Engelvin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20M.%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Vukadinovic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genevi%5Cu00e8ve%22%2C%22lastName%22%3A%22Pourroy%22%7D%5D%2C%22abstractNote%22%3A%22The%20microwave%20properties%20of%20sheets%20containing%20silica-coated%20NiFeMo%20flakes%20are%20investigated%20and%20discussed%20according%20to%20the%20sheet%20structure%2C%20the%20silica%20layer%20uniformity%20and%20thickness.%20Commercial%20NiFeMo%20flakes%20are%20coated%20using%20the%20Stoeber%20method%20and%20embedded%20in%20polymer%20using%20the%20doctor%20blade%20process.%20The%20silica%20layer%20thickness%20is%20estimated%20by%20transmission%20electron%20microscopy%20%28TEM%29%20and%20the%20coating%20quality%20is%20probed%20by%20scanning%20electron%20microscopy%20%28SEM%29.%20The%20in-plane%20orientation%20of%20magnetic%20moments%20within%20the%20sheet%20is%20evidenced%20by%20Fe-57%20Mossbauer%20spectrometry.%20As%20a%20result%2C%20the%20permittivity%20of%20composites%20is%20strongly%20reduced%20when%20the%20NiFeMo%20flakes%20are%20completely%20coated%2C%20whereas%20the%20permeability%20level%20is%20weakly%20and%20progressively%20altered%20when%20the%20silica%20thickness%20increases.%20We%20show%20that%20the%20frequency%20range%20for%20microwave%20absorption%20can%20be%20tuned%20according%20to%20the%20silica%20thickness%20and%20the%20flake%20loading.%20Reflection%20losses%20of%20-13%20dB%20are%20obtained%20in%20the%201-2%20GHz%20range%20for%20a%20normal%20incident%20electromagnetic%20wave%20interacting%20with%203%20mm%20sheets%20backed%20by%20a%20perfect%20conductor%20and%20loaded%20with%20silica%20%2890%20nm%20width%29-coated%20NiFeMo%20flakes.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1088%5C%2F2053-1591%5C%2F2%5C%2F2%5C%2F026101%22%2C%22ISSN%22%3A%222053-1591%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1088%5C%2F2053-1591%5C%2F2%5C%2F2%5C%2F026101%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A27%3A39Z%22%7D%7D%2C%7B%22key%22%3A%222AS4V5B6%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Raolison%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EZ.%20Raolison%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20J.%20Neige%2C%20A.L.%20Adenot-Engelvin%2C%20G.%20Pourroy%2C%20N.%20Vukadinovic%2C%20Preparation%20and%20Microwave%20Properties%20of%20Silica%20Coated%20Ni-Fe-Mo%20Flakes%20Composites%2C%20in%3A%20IEEE%20Transactions%20on%20Magnetics%2C%202013%3A%20pp.%20986%26%23x2013%3B989.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2Ftmag.2012.2225025%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2Ftmag.2012.2225025%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22conferencePaper%22%2C%22title%22%3A%22Preparation%20and%20Microwave%20Properties%20of%20Silica%20Coated%20Ni-Fe-Mo%20Flakes%20Composites%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Z.%22%2C%22lastName%22%3A%22Raolison%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Neige%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%20L.%22%2C%22lastName%22%3A%22Adenot-Engelvin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Pourroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Vukadinovic%22%7D%5D%2C%22abstractNote%22%3A%22Fabrication%20of%20silica%20coated%20permalloy-like%20flaky%20particles%20and%20microwave%20properties%20of%20uncoated%20and%20coated%20particles%20dispersed%20in%20a%20polymer%20matrix%20are%20presented.%20The%20silica%20layer%20is%20successfully%20obtained%20through%20the%20Stober%20process%20and%20its%20thickness%20is%20about%2050%20nm.%20Permeability%20and%20permittivity%20measurements%20are%20carried%20out%20using%20an%20APC7%20coaxial%20line.%20It%20is%20demonstrated%20that%20composites%20with%20an%20insulating%20layer%20exhibit%20the%20same%20permeability%20levels%20as%20the%20ones%20filled%20with%20uncoated%20permalloy-like%20flakes%20but%20lower%20permittivity%20levels%20which%20improves%20its%20impedance%20matching%20and%20thus%20enhances%20its%20microwave%20absorbing%20properties.%20Calculated%20reflection%20loss%20of%201%20mm%20composite%20layer%20shows%20that%20peak%20frequencies%20are%20shifted%20to%20higher%20frequencies%20while%20their%20intensities%20are%20slightly%20increased%20when%20composites%20are%20filled%20with%20coated%20flaky%20particles%20%28-4.26%20dB%20at%201.89%20GHz%20for%20the%20uncoated%20flakes%20and%20-4.53%20dB%20at%202.57%20GHz%20for%20the%20coated%20ones%20at%20the%20same%20volume%20content%20of%2021%25%29.%20Composites%20filled%20with%20higher%20volume%20contents%20are%20expected%20to%20be%20promising%20candidates%20as%20absorbing%20materials%20above%20the%20GHz%20range.%22%2C%22date%22%3A%222013%22%2C%22proceedingsTitle%22%3A%22IEEE%20Transactions%20on%20Magnetics%22%2C%22conferenceName%22%3A%22IEEE%20International%20Conference%20on%20Microwave%20Magnetics%20%28ICMM%29%20Kaiserslautern%2C%20Allemagne%2C%2026-29%20ao%5Cu00fbt%202012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1109%5C%2Ftmag.2012.2225025%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1109%5C%2Ftmag.2012.2225025%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222017-11-16T13%3A54%3A57Z%22%7D%7D%2C%7B%22key%22%3A%22RYMRUSBC%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Preziosi%20et%20al.%22%2C%22parsedDate%22%3A%222021%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ED.%20Preziosi%2C%20S.%20Homkar%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20M.%20Salluzzo%2C%20N.%20Viart%2C%20Unusual%20anisotropic%20magnetic%20orbital%20moment%20obtained%20from%20x-ray%20magnetic%20circular%20dichroism%20in%20a%20multiferroic%20oxide%20system%2C%20Physical%20Review%20B%20103%20%282021%29%20184420.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.103.184420%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.103.184420%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unusual%20anisotropic%20magnetic%20orbital%20moment%20obtained%20from%20x-ray%20magnetic%20circular%20dichroism%20in%20a%20multiferroic%20oxide%20system%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Homkar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Salluzzo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222021%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.103.184420%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Flink.aps.org%5C%2Fdoi%5C%2F10.1103%5C%2FPhysRevB.103.184420%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-05-09T07%3A20%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22ARWZJ4V4%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pichon%20et%20al.%22%2C%22parsedDate%22%3A%222011%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.P.%20Pichon%2C%20O.%20Gerber%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20I.%20Florea%2C%20S.%20Fleutot%2C%20W.%20Baaziz%2C%20M.%20Pauly%2C%20M.%20Ohlmann%2C%20C.%20Ulhaq%2C%20O.%20Ersen%2C%20V.%20Pierron-Bohnes%2C%20P.%20Panissod%2C%20M.%20Drillon%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Microstructural%20and%20Magnetic%20Investigations%20of%20W%26%23xFC%3Bstite-Spinel%20Core-Shell%20Cubic-Shaped%20Nanoparticles%2C%20Chemistry%20of%20Materials%2023%20%282011%29%202886%26%23x2013%3B2900.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcm2003319%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fcm2003319%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Microstructural%20and%20Magnetic%20Investigations%20of%20W%5Cu00fcstite-Spinel%20Core-Shell%20Cubic-Shaped%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Gerber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ileana%22%2C%22lastName%22%3A%22Florea%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Solenne%22%2C%22lastName%22%3A%22Fleutot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Walid%22%2C%22lastName%22%3A%22Baaziz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthias%22%2C%22lastName%22%3A%22Pauly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maxime%22%2C%22lastName%22%3A%22Ohlmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Ulhaq%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V%5Cu00e9ronique%22%2C%22lastName%22%3A%22Pierron-Bohnes%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pierre%22%2C%22lastName%22%3A%22Panissod%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Drillon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222011%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Fcm2003319%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fcm2003319%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22M244N6AF%22%2C%22UVN4N32C%22%2C%22WJDNKBGA%22%2C%22ZN5EITAC%22%2C%226739WBV7%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A15%3A04Z%22%7D%7D%2C%7B%22key%22%3A%22FVJZPPVU%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pena%20Corredor%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Pena%20Corredor%2C%20M.%20Gamarde%2C%20L.%20El%20Khabchi%2C%20M.J.V.%20Bernardez%2C%20M.%20Lenertz%2C%20C.%20Leuvrey%2C%20L.%20Schlur%2C%20F.%20Roulland%2C%20N.%20Viart%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20Room-temperature%20magnetism%20and%20controlled%20cation%20distribution%20in%20vanadium%20ferrite%20thin%20films%2C%20Materials%20Chemistry%20and%20Physics%20314%20%282024%29%20128856.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2023.128856%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.matchemphys.2023.128856%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Room-temperature%20magnetism%20and%20controlled%20cation%20distribution%20in%20vanadium%20ferrite%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Pena%20Corredor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Matthieu%22%2C%22lastName%22%3A%22Gamarde%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lamiae%22%2C%22lastName%22%3A%22El%20Khabchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Jose%20Vazquez%22%2C%22lastName%22%3A%22Bernardez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%5D%2C%22abstractNote%22%3A%22Spinel%20oxides%20demonstrate%20significant%20technological%20promise%20due%20to%20the%20vast%20array%20of%20interrelated%20physical%20properties%20that%20their%20unique%20structure%20supports.%20Specifically%2C%20the%20Fe1%2BxV2-xO4%20spinel%20system%20garners%20extensive%20interest%20due%20to%20the%20presence%20of%20orbitally%20ordered%20states%20and%20multiferroism.%20This%20study%20focuses%20on%20the%20elaboration%20of%20high-quality%20Fe2VO4%20%28x%20%3D%201%29%20thin%20films%20on%20MgO%20substrates%20via%20pulsed%20laser%20deposition%20from%20a%20bulk%20ceramic%20target.%20X-ray%20diffraction%20structural%20analyses%20confirm%20the%20epitaxial%20growth%20of%20the%20films%2C%20their%20high%20crystallinity%20and%20fully%20strained%20nature.%20The%20cationic%20distribution%20and%20stoichiometry%20were%20investigated%20using%20Resonant%20Elastic%20X-ray%20Scattering%20experiments%2C%20in%20conjunction%20with%20comprehensive%20characterization%20of%20the%20films%27%20magnetic%20and%20electrical%20properties.%20The%20films%20exhibit%20room-temperature%20magnetism%2C%20with%20a%20magnetization%20consistent%20with%20the%20%28Fe3%2B%29Td%5BFe2%2BV3%2B%202%20%5DOhO4%20inverse%20spinel%20structure%20unveiled%20by%20anomalous%20diffraction.%20This%20work%20represents%20the%20inaugural%20successful%20deposition%20of%20Fe2VO4%20thin%20films%2C%20thereby%20expanding%20the%20family%20of%20spinel%20vanadium%20oxide%20thin%20films%20with%20a%20new%20member%20that%20demonstrates%20room-temperature%20magnetic%20properties.%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.matchemphys.2023.128856%22%2C%22ISSN%22%3A%220254-0584%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.matchemphys.2023.128856%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22GA3EX26X%22%5D%2C%22dateModified%22%3A%222024-09-11T07%3A02%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22G36PFTTW%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pena%20Corredor%20et%20al.%22%2C%22parsedDate%22%3A%222023%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Pena%20Corredor%2C%20N.%20Viart%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20inserexs%3A%20reflection%20choice%20software%20for%20resonant%20elastic%20X-ray%20scattering.%2C%20Journal%20of%20Applied%20Crystallography%2056%20%282023%29%20854%26%23x2013%3B859.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576723002212%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576723002212%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22inserexs%3A%20reflection%20choice%20software%20for%20resonant%20elastic%20X-ray%20scattering.%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%22%2C%22lastName%22%3A%22Pena%20Corredor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chistophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%5D%2C%22abstractNote%22%3A%22This%20paper%20presents%20inserexs%2C%20an%20open-source%20computer%20program%20that%20aims%20to%20pre-evaluate%20the%20different%20reflections%20for%20resonant%20elastic%20X-ray%20scattering%20%28REXS%29%20diffraction%20experiments.%20REXS%20is%20an%20extremely%20versatile%20technique%20that%20can%20provide%20positional%20and%20occupational%20information%20about%20the%20atoms%20present%20in%20a%20crystal.%20inserexs%20was%20conceived%20to%20help%20REXS%20experimentalists%20know%20beforehand%20which%20reflections%20to%20choose%20to%20determine%20a%20parameter%20of%20interest.%20Prior%20work%20has%20already%20proven%20this%20to%20be%20useful%20in%20the%20determination%20of%20atomic%20positions%20in%20oxide%20thin%20films.%20inserexs%20allows%20generalization%20to%20any%20given%20system%20and%20aims%20to%20popularize%20resonant%20diffraction%20as%20an%20alternative%20technique%20to%20improve%20the%20resolution%20of%20crystalline%20structures.%22%2C%22date%22%3A%222023%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1107%5C%2FS1600576723002212%22%2C%22ISSN%22%3A%221600-5767%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576723002212%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222023-08-09T13%3A37%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22BK999ZF5%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Oh%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.H.%20Oh%2C%20R.H.%20Shin%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20A.%20Thomasson%2C%20F.%20Roulland%2C%20Y.%20Shin%2C%20D.-H.%20Kim%2C%20J.-Y.%20Kim%2C%20A.%20Demchenko%2C%20C.%20Leuvrey%2C%20C.%20M%26%23xE9%3Bny%2C%20W.%20Jo%2C%20N.%20Viart%2C%20Incorporation%20of%20cobalt%20ions%20into%20magnetoelectric%20gallium%20ferrite%20epitaxial%20films%3A%20tuning%20of%20conductivity%20and%20magnetization%2C%20RSC%20Advances%205%20%282015%29%2034265%26%23x2013%3B34271.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc5ra03609g%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc5ra03609g%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Incorporation%20of%20cobalt%20ions%20into%20magnetoelectric%20gallium%20ferrite%20epitaxial%20films%3A%20tuning%20of%20conductivity%20and%20magnetization%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20H.%22%2C%22lastName%22%3A%22Oh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%20H.%22%2C%22lastName%22%3A%22Shin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Shin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D-H.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J-Y.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Demchenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22W.%22%2C%22lastName%22%3A%22Jo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Thin%20films%20of%20Ga0.6Fe1.4O3%20show%20ferrimagnetism%20with%20a%20transition%20temperature%20at%20around%20360%20K%20but%20suffer%20from%20large%20charge%20conduction.%20Substituting%20Fe2%2B%20with%20non-magnetic%20Mg2%2B%20ions%20reduces%20the%20charge%20conduction%20but%20also%20lowers%20the%20magnetic%20transition%20temperature.%20Doping%20Ga0.6Fe1.4O3%20thin%20films%20with%20magnetic%20Co2%2B%20ions%20leads%20to%20a%20similar%20reduction%20in%20the%20charge%20conduction%2C%20which%20is%20significant%20by%20two%20orders%20of%20magnitude%2C%20and%2C%20on%20the%20other%20hand%2C%20does%20not%20lead%20to%20any%20modification%20of%20the%20ferrimagnetic%20transition.%20The%20remnant%20magnetization%20of%20the%20leakage%20currents%20free%20Co-doped%20Ga0.6Fe1.4O3%20thin%20films%20is%20of%2053%20emu%20cm%28-3%29%20at%20300%20K.%20These%20films%2C%20therefore%2C%20are%20promising%20materials%20with%20potential%20uses%20in%20magnetoelectric%20and%20multiferroic%20devices.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc5ra03609g%22%2C%22ISSN%22%3A%222046-2069%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc5ra03609g%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A11%3A43Z%22%7D%7D%2C%7B%22key%22%3A%22M9EIKEXG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Miyako%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EE.%20Miyako%2C%20B.P.%20Pichon%2C%20C.%20Menard-Moyon%2C%20I.A.%20Vacchi%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20A.%20Bianco%2C%20Design%2C%20synthesis%2C%20characterization%20and%20properties%20of%20magnetic%20nanoparticle-nanocarbon%20hybrids%2C%20Carbon%2096%20%282016%29%2049%26%23x2013%3B56.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.carbon.2015.09.045%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.carbon.2015.09.045%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Design%2C%20synthesis%2C%20characterization%20and%20properties%20of%20magnetic%20nanoparticle-nanocarbon%20hybrids%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Eijiro%22%2C%22lastName%22%3A%22Miyako%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cecilia%22%2C%22lastName%22%3A%22Menard-Moyon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Isabella%20Anna%22%2C%22lastName%22%3A%22Vacchi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Bianco%22%7D%5D%2C%22abstractNote%22%3A%22Carbon%20nanostructured%20materials%20such%20as%20carbon%20nanotubes%20and%20graphene%20oxide%20are%20attracting%20much%20attention%20due%20to%20their%20outstanding%20chemical%20and%20physical%20properties.%20Metal%20nanoparticle-decoration%20can%20provide%20additional%20functionalities%20to%20these%20nanocarbons.%20Many%20chemical%20methods%20are%20being%20used%20for%20the%20synthesis%20of%20these%20metal%20nanoparticle-functionalized%20nanocarbon%20hybrids.%20On%20the%20other%20hand%2C%20the%20outstanding%20properties%20of%20spinelle%20iron%20oxide%20magnetic%20%28MAG%29%20nanoparticles%20have%20been%20efficiently%20used%20for%20a%20variety%20of%20applications%20such%20as%20manipulation%20of%20biomolecules%20and%20cells%2C%20cancer%20hyperthermia%2C%20and%20medical%20devices.%20Therefore%2C%20MAG%20nanoparticle%20decoration%20of%20carbon%20nanotubes%20and%20graphene%20oxide%20can%20provide%20promising%20nanohybrid%20materials%20for%20nanobiotechnological%20applications.%20In%20this%20work%2C%20we%20present%20a%20straightforward%20chemical%20route%20for%20MAG%20nanopartide%20decoration%20of%20nanocarbon%20supports%20including%20carbon%20nanotubes%20and%20graphene%20oxide%20using%20in%20situ%20high-temperature%20decomposition%20method.%20This%20chemical%20methodology%20allows%20precisely%20controlling%20the%20MAG%20nanoparticle%20content%2C%20the%20MAG%20nanopartide%20size%20leading%20to%20a%20uniform%20coating%20on%20the%20different%20carbon%20supports.%20The%20properties%20of%20these%20new%20hybrids%20have%20been%20thoroughly%20evaluated.%20Our%20results%20show%20that%20the%20MAG%20nanoparticle%20decoration%20process%20strongly%20affects%20the%20structural%20and%20magnetic%20characteristics%20of%20the%20hybrids.%20The%20combination%20of%20MAG%20nanopartide%20and%20nanocarbon%20materials%20will%20open%20the%20door%20to%20their%20use%20in%20different%20domains%20including%20nanocomposites%2C%20wastewater%20treatment%2C%20sensors%2C%20biomaterials%2C%20and%20cancer%20therapy.%20%28C%29%202015%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.carbon.2015.09.045%22%2C%22ISSN%22%3A%220008-6223%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.carbon.2015.09.045%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A14%3A38Z%22%7D%7D%2C%7B%22key%22%3A%22Q83U4EK3%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Meunier%20et%20al.%22%2C%22parsedDate%22%3A%222022%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.%20Meunier%2C%20S.%20Homkar%2C%20F.%20Choueikani%2C%20M.G.%20Silly%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20C.%20Leuvrey%2C%20J.%20Robert%2C%20D.%20Preziosi%2C%20N.%20Viart%2C%20Nonmonotonous%20temperature%20fluctuations%20of%20the%20orbital%20moment%20and%20spin-orbit%20coupling%20in%20multiferroic%20gallium%20ferrite%20thin%20films%2C%20Physical%20Review%20B%20106%20%282022%29%20184410.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.106.184410%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevB.106.184410%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nonmonotonous%20temperature%20fluctuations%20of%20the%20orbital%20moment%20and%20spin-orbit%20coupling%20in%20multiferroic%20gallium%20ferrite%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Meunier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Suvidyakumar%22%2C%22lastName%22%3A%22Homkar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fadi%22%2C%22lastName%22%3A%22Choueikani%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mathieu%20G.%22%2C%22lastName%22%3A%22Silly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222022%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevB.106.184410%22%2C%22ISSN%22%3A%222469-9950%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevB.106.184410%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-12-09T10%3A27%3A54Z%22%7D%7D%2C%7B%22key%22%3A%22XVDGFS8F%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Martin%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EE.%20Martin%2C%20F.%20Roulland%2C%20S.%20Grenier%2C%20F.%20Appert%2C%20J.%20Juraszek%2C%20M.%20Trassin%2C%20C.%20Bouillet%2C%20E.%20Chikoidze%2C%20C.%20Arnold%2C%20B.%20Berini%2C%20Y.%20Dumont%2C%20S.%20Colis%2C%20S.%20Barre%2C%20G.%20Versini%2C%20D.%20Preziosi%2C%20C.%20Leuvrey%2C%20N.%20Blanc%2C%20N.%20Boudet%2C%20G.%20Pourroy%2C%20N.%20Viart%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20Non-auxeticiauxetic%20transitions%20inducing%20modifications%20of%20the%20magnetic%20anisotropy%20in%20CoFe2O4%20thin%20films%2C%20Journal%20of%20Alloys%20and%20Compounds%20836%20%282020%29%20155425.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2020.155425%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jallcom.2020.155425%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Non-auxeticiauxetic%20transitions%20inducing%20modifications%20of%20the%20magnetic%20anisotropy%20in%20CoFe2O4%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Martin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fran%5Cu00e7ois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Grenier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Appert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Juraszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Trassin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Chikoidze%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Arnold%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Berini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Dumont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Silviu%22%2C%22lastName%22%3A%22Colis%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C%5Cu00e9dric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Blanc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Boudet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genevi%5Cu00e8ve%22%2C%22lastName%22%3A%22Pourroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%5D%2C%22abstractNote%22%3A%22An%20auxetic%20behaviour%20is%20evidenced%20in%20CoFe2O4%20thin%20films%20grown%20by%20pulsed%20laser%20deposition%20on%20%28100%29%20MgO%20substrates%20under%20various%20O-2%5C%2FN-2%20pressures.%20This%20rare%20behaviour%20for%20an%20intrinsic%20material%20is%20observed%20for%20intermediate%20oxidation%20conditions%2C%20in%20between%20two%20non%20auxetic%20domains%20delimited%20by%20high%20%28%3E0.05%20mbar%29%20and%20low%20%28%3C0.03%20mbar%29%20O-2%5C%2FN-2%20deposition%20pressures.%20Combining%20X-ray%20resonant%20diffraction%20and%20Mossbauer%20spectroscopy%2C%20we%20experimentally%20prove%20that%20the%20auxetic%20behaviour%20is%20related%20to%20the%20presence%20of%20cobalt%20ions%20in%20the%20tetrahedral%20sites.%20The%20impact%20of%20the%20structural%20modifications%20caused%20by%20the%20various%20oxidation%20conditions%20on%20the%20electronic%20and%20magnetic%20properties%20are%20studied%20for%20the%20various%20oxidation%20domains.%20Variations%20as%20important%20as%20a%20transition%20from%20a%20p-type%20semiconducting%20to%20an%20insulating%20behaviour%2C%20or%20from%20an%20in-plane%20to%20an%20out-of-plane%20magnetization%20are%20observed%20when%20spanning%20from%20the%20lowest%20%280.01%20mbar%29%20to%20the%20highest%20%281%20mbar%29%20studied%20oxidation%20pressures.%20%28C%29%202020%20Elsevier%20B.V.%20All%20rights%20reserved.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jallcom.2020.155425%22%2C%22ISSN%22%3A%220925-8388%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jallcom.2020.155425%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A29%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22UTRGARXX%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Liu%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EX.%20Liu%2C%20B.P.%20Pichon%2C%20C.%20Ulhaq%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20J.-M.%20Greneche%2C%20D.%20Begin%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Systematic%20Study%20of%20Exchange%20Coupling%20in%20Core%20Shell%20Fe3-delta%20O4%40CoO%20Nanoparticles%2C%20Chemistry%20of%20Materials%2027%20%282015%29%204073%26%23x2013%3B4081.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.5b01103%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.5b01103%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Systematic%20Study%20of%20Exchange%20Coupling%20in%20Core%20Shell%20Fe3-delta%20O4%40CoO%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xiaojie%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Ulhaq%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dominique%22%2C%22lastName%22%3A%22Begin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22Although%20single%20magnetic%20domain%20nanoparticles%20are%20very%20promising%20for%20many%20applications%2C%20size%20reduction%20usually%20results%20in%20low%20magnetic%20anisotropy%20and%20unblocked%20domain%20at%20room%20temperature%2C%20e.g.%2C%20superparamagnetism.%20An%20alternative%20approach%20is%20core-shell%20nanoparticles%20featured%20by%20exchange%20bias%20coupling%20between%20ferro%28i%29magnetic%20%5BF%28i%29M%5D%20and%20antiferromagnetic%20%28AFM%29%20phases.%20Although%20exchange%20bias%20coupling%20has%20been%20reported%20for%20very%20diverse%20coreshell%20nanoparticles%2C%20it%20is%20difficult%20to%20compare%20these%20studies%20to%20rationalize%20the%20effect%20of%20many%20structural%20parameters%20on%20the%20magnetic%20properties.%20Herein%2C%20we%20report%20on%20a%20systematic%20study%20which%20consists%20of%20the%20modulation%20of%20the%20shell%20structure%20and%20its%20influence%20on%20the%20exchange%20bias%20coupling.%20A%20series%20of%20Fe-3-O-delta%284%29%40CoO%20core-shell%20nanoparticles%20has%20been%20synthesized%20by%20seed-mediated%20growth%20based%20on%20the%20thermal%20decomposition%20technique.%20The%20variation%20of%20Co%20reactant%20concentration%20resulted%20in%20the%20modulation%20of%20the%20shell%20structure%20for%20which%20thickness%2C%20crystallinity%2C%20and%20interface%20with%20the%20iron%20oxide%20core%20strongly%20affect%20the%20magnetic%20properties.%20The%20thickest%20CoO%20shell%20and%20the%20largest%20F%28i%29M%5C%2FAFM%20interface%20led%20to%20the%20largest%20exchange%20bias%20coupling.%20Very%20high%20values%20of%20coercive%20field%20%2819%3F000%20Oe%29%20and%20M-R%5C%2FM-S%20ratio%20%280.86%29%20were%20obtained.%20The%20most%20stricking%20results%20consist%20of%20the%20increase%20of%20the%20coercive%20field%20while%20exchange%20field%20vanishes%20when%20the%20CoO%20thickness%20decreases%3A%20it%20is%20ascribed%20to%20the%20diffusion%20of%20Co%20species%20in%20the%20surface%20layer%20of%20iron%20oxide%20which%20generates%20to%20some%20extent%20cobalt%20ferrite%20and%20induces%20hard%5C%2Fsoft%20exchange%20coupling%20between%20ferrimagnetic%20phases.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.5b01103%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.chemmater.5b01103%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A14%3A35Z%22%7D%7D%2C%7B%22key%22%3A%229JDG6IIJ%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lef%5Cu00e8vre%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Lef%26%23xE8%3Bvre%2C%20A.%20Demchenko%2C%20C.%20Bouillet%2C%20M.%20Luysberg%2C%20X.%20Devaux%2C%20F.%20Roulland%2C%20G.%20Versini%2C%20S.%20Barre%2C%20Y.%20Wakabayashi%2C%20N.%20Boudet%2C%20C.%20Leuvrey%2C%20M.%20Acosta%2C%20C.%20M%26%23xE9%3Bny%2C%20E.%20Martin%2C%20S.%20Grenier%2C%20V.%20Favre-Nicolin%2C%20N.%20Viart%2C%20Nondestructive%20Method%20for%20the%20Determination%20of%20the%20Electric%20Polarization%20Orientation%20in%20Thin%20Films%3A%20Illustration%20on%20Gallium%20Ferrite%20Thin%20Films%2C%20Small%20Methods%201%20%282017%29%201700234.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmtd.201700234%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmtd.201700234%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nondestructive%20Method%20for%20the%20Determination%20of%20the%20Electric%20Polarization%20Orientation%20in%20Thin%20Films%3A%20Illustration%20on%20Gallium%20Ferrite%20Thin%20Films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chistophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Demchenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Martina%22%2C%22lastName%22%3A%22Luysberg%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Devaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fran%5Cu00e7ois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yusuke%22%2C%22lastName%22%3A%22Wakabayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Boudet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C%5Cu00e9dric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Manuel%22%2C%22lastName%22%3A%22Acosta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elodie%22%2C%22lastName%22%3A%22Martin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22St%5Cu00e9phane%22%2C%22lastName%22%3A%22Grenier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Favre-Nicolin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20The%20knowledge%20and%20control%20of%20the%20electric%20polarization%20in%20multiferroic%20thin%20films%20is%20currently%20the%20subject%20of%20extensive%20research%20efforts.%20This%20is%20the%20key%20toward%20a%20possible%20transformation%20into%20devices%20of%20the%20exciting%20phenomena%20such%20as%20conductance%20modification%20or%20polarity%20observed%20at%20ferroelectric%20domain%20walls.%20The%20main%20methods%20currently%20available%20to%20determine%20the%20polarization%20characteristics%20in%20thin%20films%20suffer%20from%20being%20local%2C%20time%20demanding%2C%20potentially%20vitiated%20by%20artefacts%2C%20or%20even%20blinded%20in%20some%20cases.%20A%20nondestructive%20method%20based%20on%20resonant%20diffraction%20is%20proposed%20for%20the%20determination%20of%20the%20polarization%20orientation%20in%20multiferroic%2C%20ferroelectric%2C%20or%20pyroelectric%20thin%20films.%20The%20method%20is%20experimentally%20illustrated%20for%20multiferroic%20gallium%20ferrite%20thin%20films.%20Its%20validity%20is%20also%20theoretically%20shown%20for%20the%20perovskite-based%20structure%20of%20the%20emblematic%20ferroelectric%20Pb%28Zr%2CTi%29O3%2C%20which%20augurs%20numerous%20prospects%20for%20its%20potential%20applications.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fsmtd.201700234%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fsmtd.201700234%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22DEB5KWFS%22%2C%22UVN4N32C%22%2C%22WJDNKBGA%22%2C%22ZN5EITAC%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222022-01-24T13%3A34%3A23Z%22%7D%7D%2C%7B%22key%22%3A%2288IUP77A%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lef%5Cu00e8vre%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Lef%26%23xE8%3Bvre%2C%20A.%20Thomasson%2C%20F.%20Roulland%2C%20V.%20Favre-Nicolin%2C%20Y.%20Joly%2C%20Y.%20Wakabayashi%2C%20G.%20Versini%2C%20S.%20Barre%2C%20C.%20Leuvrey%2C%20A.%20Demchenko%2C%20N.%20Boudet%2C%20N.%20Viart%2C%20Determination%20of%20the%20cationic%20distribution%20in%20oxidic%20thin%20films%20by%20resonant%20X-ray%20diffraction%3A%20the%20magnetoelectric%20compound%20Ga%24%5C%5Csb%202%24-%24%26%23x131%3Bt%20x%24Fe%24%5C%5Csb%20%26%23x131%3Bt%20x%24O%24%5C%5Csb%203%24%2C%20Journal%20of%20Applied%20Crystallography%2049%20%282016%29%201308%26%23x2013%3B1314.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576716010001%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576716010001%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Determination%20of%20the%20cationic%20distribution%20in%20oxidic%20thin%20films%20by%20resonant%20X-ray%20diffraction%3A%20the%20magnetoelectric%20compound%20Ga%24%5C%5Csb%202%24-%24%5Cu0131t%20x%24Fe%24%5C%5Csb%20%5Cu0131t%20x%24O%24%5C%5Csb%203%24%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Vincent%22%2C%22lastName%22%3A%22Favre-Nicolin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yves%22%2C%22lastName%22%3A%22Joly%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yusuke%22%2C%22lastName%22%3A%22Wakabayashi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Demchenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Boudet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22The%20cationic%20distribution%20is%20decisive%20for%20both%20the%20magnetic%20and%20electric%20properties%20of%20complex%20oxides.%20While%20it%20can%20be%20easily%20determined%20in%20bulk%20materials%20using%20classical%20methods%20such%20as%20X-ray%20or%20neutron%20diffraction%2C%20difficulties%20arise%20for%20thin%20films%20owing%20to%20the%20relatively%20small%20amount%20of%20material%20to%20probe.%20It%20is%20shown%20here%20that%20a%20full%20determination%20of%20the%20cationic%20site%20distribution%20in%20thin%20films%20is%20possible%20through%20an%20optimized%20processing%20of%20resonant%20elastic%20X-ray%20scattering%20experiments.%20The%20method%20is%20illustrated%20using%20gallium%20ferrite%20Ga%24%5C%5Csb%202%24-%24%5Cu0131t%20x%24Fe%24%5C%5Csb%20%5Cu0131t%20x%24O%24%5C%5Csb%203%24%20samples%20which%20have%20been%20the%20focus%20of%20an%20increasing%20number%20of%20studies%20this%20past%20decade.%20They%20indeed%20represent%20an%20alternative%20to%20the%2C%20to%20date%2C%20only%20room-temperature%20magnetoelectric%20compound%20BiFeO%24%5C%5Csb%203%24.%20The%20methodology%20can%20be%20applied%20to%20determine%20the%20element%20distribution%20over%20the%20various%20crystallographic%20sites%20in%20any%20crystallized%20system.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1107%5C%2FS1600576716010001%22%2C%22ISSN%22%3A%221600-5767%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1107%5C%2FS1600576716010001%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A28%3A06Z%22%7D%7D%2C%7B%22key%22%3A%22EK3QERAR%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lef%5Cu00e8vre%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Lef%26%23xE8%3Bvre%2C%20R.H.%20Shin%2C%20J.H.%20Lee%2C%20S.H.%20Oh%2C%20F.%20Roulland%2C%20A.%20Thomasson%2C%20E.%20Autissier%2C%20C.%20M%26%23xE9%3Bny%2C%20W.%20Jo%2C%20N.%20Viart%2C%20Reduced%20leakage%20currents%20and%20possible%20charge%20carriers%20tuning%20in%20Mg-doped%20Ga0.6Fe1.4O3%20thin%20films%2C%20Applied%20Physics%20Letters%20100%20%282012%29%20262904%20%5C%2Fp.1%26%23x2013%3B4.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4729872%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1063%5C%2F1.4729872%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Reduced%20leakage%20currents%20and%20possible%20charge%20carriers%20tuning%20in%20Mg-doped%20Ga0.6Fe1.4O3%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%20H.%22%2C%22lastName%22%3A%22Shin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20H.%22%2C%22lastName%22%3A%22Lee%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%20H.%22%2C%22lastName%22%3A%22Oh%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fran%5Cu00e7ois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Autissier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22W.%22%2C%22lastName%22%3A%22Jo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Ga0.6Fe1.4O3%20is%20predicted%20to%20be%20magnetoelectric%20with%20non%20zero%20magnetization%20at%20room%20temperature.%20However%2C%20in%20thin%20films%2C%20electric%20properties%20are%20overshadowed%20by%20strong%20leakage%20currents.%20In%20this%20Letter%2C%20we%20show%20that%20Mg%20doping%20in%20Ga0.6Fe1.4O3%20thin%20films%20grown%20by%20pulsed%20laser%20deposition%20allows%20decreasing%20the%20leakage%20current%20density%20by%20four%20orders%20of%20magnitude%20and%20might%20simultaneously%20allow%20tuning%20the%20carriers%27%20nature.%20These%20results%20suggest%20the%20possibility%20to%20develop%20a%20new%20class%20of%20material%20exhibiting%20room%20temperature%20magnetization%2C%20tunable%20transport%20properties%2C%20and%20magnetoelectric%20properties.%20%28C%29%202012%20American%20Institute%20of%20Physics.%20%5Bhttp%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F1.4729872%5D%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1063%5C%2F1.4729872%22%2C%22ISSN%22%3A%220003-6951%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1063%5C%2F1.4729872%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-04-08T12%3A07%3A24Z%22%7D%7D%2C%7B%22key%22%3A%22H6UHWFCC%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lef%5Cu00e8vre%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20A.%20Thomasson%2C%20E.%20Autissier%2C%20C.%20Leuvrey%2C%20S.%20Barre%2C%20G.%20Versini%2C%20N.%20Viart%2C%20G.%20Pourroy%2C%20Stabilization%20of%20scandium%20rich%20spinel%20ferrite%20CoFe%282-x%29Sc%28x%29O4%20%28x%20%26lt%3B%3D%201%29%20in%20thin%20films%2C%20Journal%20of%20Solid%20State%20Chemistry%20232%20%282015%29%20118%26%23x2013%3B122.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jssc.2015.09.012%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jssc.2015.09.012%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Stabilization%20of%20scandium%20rich%20spinel%20ferrite%20CoFe%282-x%29Sc%28x%29O4%20%28x%20%3C%3D%201%29%20in%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Emmanuel%22%2C%22lastName%22%3A%22Autissier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genevieve%22%2C%22lastName%22%3A%22Pourroy%22%7D%5D%2C%22abstractNote%22%3A%22Scandium%20rich%20cobalt%20ferrites%20CoyFe3-x-yScxO4%20with%20y-1%20never%20obtained%20in%20bulk%20could%20be%20stabilized%20in%20pulsed%20laser%20deposited%20thin%20films.%20Scandium%20contents%20of%20up%20to%20x%3D1%20are%20reached.%20The%20cell%20parameter%20increases%20versus%20x%20as%20awaited%20when%20considering%20the%20size%20of%20scandium.%20It%20is%20equal%20to%200.8620%20nm%20for%20x%3D1%2C%20significantly%20higher%20than%20that%20of%20CoFe2O4%20%280.8396%20nm%29.%20The%20lattice%20mismatch%20between%20the%20MgO%20%28100%29%20substrate%20and%20the%20scandium-containing%20spinel%20leads%20to%20an%20increased%20roughness.%20Cobalt%20is%20displaced%20from%20the%20octahedral%20site%20by%20Sc%20and%20mainly%20occupies%20the%20tetrahedral%20sites%20for%20high%20x%20values.%20%28C%29%202015%20Elsevier%20Inc.%20All%20rights%20reserved.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jssc.2015.09.012%22%2C%22ISSN%22%3A%220022-4596%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jssc.2015.09.012%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A11%3A37Z%22%7D%7D%2C%7B%22key%22%3A%222EMIB29D%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Lef%5Cu00e8vre%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EC.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20A.%20Thomasson%2C%20C.%20M%26%23xE9%3Bny%2C%20F.%20Porcher%2C%20G.%20Andre%2C%20N.%20Viart%2C%20Magnetic%20and%20Polar%20Properties%26%23x2019%3B%20Optimization%20in%20the%20Magnetoelectric%20Ga2-xFexO3%20Compounds%2C%20Journal%20of%20Physical%20Chemistry%20C%20117%20%282013%29%2014832%26%23x2013%3B14839.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjp403733b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Fjp403733b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetic%20and%20Polar%20Properties%27%20Optimization%20in%20the%20Magnetoelectric%20Ga2-xFexO3%20Compounds%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Porcher%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Andre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22The%20influence%20of%20the%20iron%20content%20on%20the%20magnetic%2C%20polar%2C%20and%20magnetoelectric%20properties%20of%20Ga2-xFexO3%20%28x%20%3D%201.0%3B%20x%20%3D%201.4%29%20polycrystalline%20samples%20was%20studied%20by%20a%20combined%20magnetic%20%28SQUID%29%20and%20structural%20%28X-ray%20and%20temperature-dependent%20neutrons%20diffraction%29%20study.%20As%20expected%2C%20the%20samples%20showed%20a%20ferrimagnetic%20structure%2C%20with%20moments%20aligned%20along%20the%20c%20axis.%20The%20Neel%20temperature%20increases%20with%20x%2C%20from%20210%20K%20for%20GaFeO3%20to%20360%20K%20for%20Ga0.6Fe1.4O3.%20The%20magnetic%20moment%20is%20close%20to%203.8%20mu%20B%20per%20iron%20atom%20for%20all%20compositions.%20The%20structural%20investigations%20show%20a%20decrease%20in%20the%20distortion%20parameters%20with%20increasing%20iron%20content%2C%20and%20computation%20of%20the%20polarization%20with%20a%20point-charge%20model%20gives%20a%20similar%20significant%20and%20temperature-independent%20value%20of%20approximate%20to%2020%20mu%20C%5C%2Fcm%282%29%20for%20both%20compositions.%20This%20study%20clearly%20indicates%20that%20magnetic%20properties%20can%20be%20strongly%20enhanced%20by%20increasing%20the%20Fe%20content%20in%20the%20cell%2C%20while%20the%20non-negligible%20polarization%20value%20is%20preserved.%20Because%20the%20magnetoelectric%20coupling%20is%20also%20predicted%20to%20be%20preserved%20when%20increasing%20the%20iron%20content%20to%20x%20%3D%201.4%2C%20this%20composition%20is%20the%20most%20appropriate%20for%20applications.%22%2C%22date%22%3A%222013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fjp403733b%22%2C%22ISSN%22%3A%221932-7447%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Fjp403733b%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A11%3A23Z%22%7D%7D%2C%7B%22key%22%3A%22WHBM925V%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kundys%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.%20Kundys%2C%20F.%20Roulland%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20C.%20M%26%23xE9%3Bny%2C%20A.%20Thomasson%2C%20N.%20Viart%2C%20Room%20temperature%20polarization%20in%20the%20ferrimagnetic%20Ga2-xFexO3%20ceramics%2C%20Journal%20of%20the%20European%20Ceramic%20Society%2035%20%282015%29%202277%26%23x2013%3B2281.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2015.02.029%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2015.02.029%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Room%20temperature%20polarization%20in%20the%20ferrimagnetic%20Ga2-xFexO3%20ceramics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Kundys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Thomasson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22The%20effect%20of%20the%20Fe%5C%2FGa%20ratio%20on%20the%20magnetic%20and%20electric%20properties%20of%20the%20multiferroic%20Ga2-xFexO3%20compound%20has%20been%20studied%20in%20order%20to%20determine%20the%20composition%20range%20exhibiting%20magnetic%20and%20electric%20orders%20coexistence%20and%20their%20critical%20temperatures.%20A%20magnetoelectric%20phase%20diagram%2C%20showing%20the%20evolution%20of%20both%20the%20Neel%20magnetic%20ordering%20temperature%20T-N%20and%20the%20electric%20ordering%20temperature%20T-c%2C%20versus%20the%20iron%20content%20has%20been%20established%20for%200.9%20%3C%3D%20x%20%3C%3D%201.4.%20While%20the%20ferrimagnetic%20Neel%20temperature%20increases%20with%20the%20iron%20content%2C%20the%20electric%20ordering%20temperature%20shows%20an%20opposite%20trend.%20The%20electric%20polarization%20has%20been%20found%20to%20exist%20far%20above%20room%20temperature%20for%20the%20x%20%3D%201.1%20composition%20which%20shows%20the%20highest%20observed%20electric%20ordering%20temperature%20of%20T-c%20approximate%20to%20580%20K.%20The%20x%20%3D%201.3%20and%201.4%20compounds%20are%20ferrimagnetic-electric%20relaxors%20with%20both%20properties%20coexisting%20at%20room%20temperature.%20%28C%29%202015%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jeurceramsoc.2015.02.029%22%2C%22ISSN%22%3A%220955-2219%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.jeurceramsoc.2015.02.029%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22N8397DCZ%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222017-04-04T09%3A40%3A49Z%22%7D%7D%2C%7B%22key%22%3A%22739725TF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Homkar%20et%20al.%22%2C%22parsedDate%22%3A%222021%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Homkar%2C%20E.%20Martin%2C%20B.%20Meunier%2C%20A.%20Anadon-Barcelona%2C%20C.%20Bouillet%2C%20J.%20Gorchon%2C%20K.%20Dumesnil%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20O.%20Copie%2C%20D.%20Preziosi%2C%20S.%20Petit-Watelot%2C%20J.-C.%20Rojas-Sanchez%2C%20N.%20Viart%2C%20Spin%20Current%20Transport%20in%20Hybrid%20Pt%5C%2FMultifunctional%20Magnetoelectric%20Ga0.6Fe1.4O3%20Bilayers%2C%20ACS%20Applied%20Electronic%20Materials%203%20%282021%29%204433%26%23x2013%3B4440.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.1c00586%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsaelm.1c00586%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Spin%20Current%20Transport%20in%20Hybrid%20Pt%5C%2FMultifunctional%20Magnetoelectric%20Ga0.6Fe1.4O3%20Bilayers%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Suvidyakumar%22%2C%22lastName%22%3A%22Homkar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elodie%22%2C%22lastName%22%3A%22Martin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benjamin%22%2C%22lastName%22%3A%22Meunier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alberto%22%2C%22lastName%22%3A%22Anadon-Barcelona%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jon%22%2C%22lastName%22%3A%22Gorchon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Karine%22%2C%22lastName%22%3A%22Dumesnil%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Copie%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%22%2C%22lastName%22%3A%22Petit-Watelot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Juan-Carlos%22%2C%22lastName%22%3A%22Rojas-Sanchez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22The%20low%20power%20manipulation%20of%20magnetization%20is%20currently%20a%20highly%20sought-after%20objective%20in%20spintronics.%20Non-ferromagnetic%20large%20spin-orbit%20coupling%20heavy%20metal%20%28NM%29%5C%2Fferromagnet%20%28FM%29%20heterostructures%20offer%20interesting%20elements%20of%20response%20to%20this%20issue%20by%20granting%20the%20manipulation%20of%20the%20FM%20magnetization%20by%20the%20NM%20spin%20Hall%20effect-generated%20spin%20current.%20Additional%20functionalities%2C%20such%20as%20the%20electric%20field%20control%20of%20the%20spin%20current%20generation%2C%20can%20be%20offered%20using%20multifunctional%20FMs.%20We%20have%20studied%20the%20spin%20current-transfer%20processes%20between%20Pt%20and%20the%20multifunctional%20magnetoelectric%20Ga0.6Fe1.4O3%20%28GFO%29.%20In%20particular%2C%20via%20angular-dependent%20magnetotransport%20measurements%2C%20we%20were%20able%20to%20differentiate%20between%20magnetic%20proximity%20effect-induced%20anisotropic%20magnetoresistance%20and%20spin%20Hall%20magnetoresistance%20%28SMR%29.%20Our%20analysis%20shows%20that%20SMR%20is%20the%20dominant%20phenomenon%20at%20all%20temperatures%20and%20is%20the%20only%20one%20to%20be%20considered%20near%20room%20temperature%2C%20with%20a%20magnitude%20comparable%20to%20those%20observed%20in%20Pd%5C%2FYIG%20or%20Pt%5C%2FYIG%20heterostructures.%20These%20results%20indicate%20that%20magnetoelectric%20GFO%20thin%20films%20show%20promises%20for%20achieving%20an%20electric-field%20control%20of%20the%20spin%20current%20generation%20in%20NM%5C%2FFM%20oxide-based%20heterostructures.%22%2C%22date%22%3A%222021%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsaelm.1c00586%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsaelm.1c00586%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-01-06T10%3A20%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22F9D4IECE%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Homkar%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3ES.%20Homkar%2C%20D.%20Preziosi%2C%20X.%20Devaux%2C%20C.%20Bouillet%2C%20J.%20Nordlander%2C%20M.%20Trassin%2C%20F.%20Roulland%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20G.%20Versini%2C%20S.%20Barre%2C%20C.%20Leuvrey%2C%20M.%20Lenertz%2C%20M.%20Fiebig%2C%20G.%20Pourroy%2C%20N.%20Viart%2C%20Ultrathin%20regime%20growth%20of%20atomically%20flat%20multiferroic%20gallium%20ferrite%20films%20with%20perpendicular%20magnetic%20anisotropy%2C%20Physical%20Review%20Materials%203%20%282019%29%20124416.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.3.124416%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1103%5C%2FPhysRevMaterials.3.124416%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ultrathin%20regime%20growth%20of%20atomically%20flat%20multiferroic%20gallium%20ferrite%20films%20with%20perpendicular%20magnetic%20anisotropy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Suvidyakumar%22%2C%22lastName%22%3A%22Homkar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Devaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Johanna%22%2C%22lastName%22%3A%22Nordlander%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Morgan%22%2C%22lastName%22%3A%22Trassin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marc%22%2C%22lastName%22%3A%22Lenertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Manfred%22%2C%22lastName%22%3A%22Fiebig%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Genevieve%22%2C%22lastName%22%3A%22Pourroy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Room%20temperature%20magnetoelectric%20multiferroic%20thin%20films%20offer%20great%20promises%20for%20the%20spintronics%20industry.%20The%20actual%20development%20of%20devices%2C%20however%2C%20requires%20the%20production%20of%20ultrathin%20atomically%20smooth%20films%20of%20high%20crystalline%20quality%20in%20order%20to%20increase%20spin%20transfer%20efficiency.%20Using%20both%20high-resolution%20transmission%20electron%20microscopy%20and%20atomically%20resolved%20electron%20energy%20loss%20spectroscopy%2C%20we%20unveil%20the%20complex%20growth%20mechanism%20of%20a%20promising%20candidate%2C%20gallium%20ferrite.%20This%20material%2C%20with%20its%20net%20room-temperature%20magnetization%20of%20approximately%20100%20emu%5C%2Fcm%283%29%2C%20is%20an%20interesting%20challenger%20to%20the%20antiferromagnetic%20bismuth%20ferrite.%20We%20obtained%20atomically%20flat%20gallium%20ferrite%20ultrathin%20films%20with%20a%20thickness%20control%20down%20to%20one%20fourth%20of%20a%20unit%20cell.%20Films%20with%20thicknesses%20as%20low%20as%207%20nm%20are%20polar%20and%20show%20a%20perpendicular%20magnetic%20anisotropy%20of%203%20x%2010%283%29%20J%5C%2Fm%283%29%20at%20300%20K%2C%20which%20makes%20them%20particularly%20attractive%20for%20spin%20current%20transmission%20in%20spintronic%20devices%2C%20such%20as%20spin%20Hall%20effect%20based%20heavy-metal%20%5C%2F%20ferrimagnetic%20oxide%20heterostructures.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1103%5C%2FPhysRevMaterials.3.124416%22%2C%22ISSN%22%3A%222475-9953%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1103%5C%2FPhysRevMaterials.3.124416%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A28%3A48Z%22%7D%7D%2C%7B%22key%22%3A%22RFT4I7WT%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guardia%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Guardia%2C%20S.%20Nitti%2C%20M.E.%20Materia%2C%20G.%20Pugliese%2C%20N.%20Yaacoub%2C%20J.-M.%20Greneche%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20L.%20Manna%2C%20T.%20Pellegrino%2C%20Gold-iron%20oxide%20dimers%20for%20magnetic%20hyperthermia%3A%20the%20key%20role%20of%20chloride%20ions%20in%20the%20synthesis%20to%20boost%20the%20heating%20efficiency%2C%20Journal%20of%20Materials%20Chemistry%20B%205%20%282017%29%204587%26%23x2013%3B4594.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc7tb00968b%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc7tb00968b%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Gold-iron%20oxide%20dimers%20for%20magnetic%20hyperthermia%3A%20the%20key%20role%20of%20chloride%20ions%20in%20the%20synthesis%20to%20boost%20the%20heating%20efficiency%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Guardia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Nitti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%20E.%22%2C%22lastName%22%3A%22Materia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Pugliese%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Yaacoub%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%20-M.%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.%22%2C%22lastName%22%3A%22Manna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.%22%2C%22lastName%22%3A%22Pellegrino%22%7D%5D%2C%22abstractNote%22%3A%22With%20the%20aim%20of%20producing%20Au-FexOy%20dimers%20with%20outstanding%20heating%20performances%20under%20magnetic%20hyperthermia%20conditions%20applicable%20to%20human%20patients%2C%20here%20we%20report%20two%20synthesis%20routes%2C%20a%20two-pot%20and%20a%20one-pot%20method.%20The%20addition%20of%20chloride%20ions%20and%20the%20absence%20of%201%2C2-hexadecanediol%20%28HDDOL%29%2C%20a%20commonly%20used%20chemical%20in%20this%20synthesis%2C%20are%20the%20key%20factors%20that%20enable%20us%20to%20produce%20dimers%20at%20low%20temperature%20with%20crystalline%20iron%20oxide%20domains%20in%20the%20size%20range%20between%2018-39%20nm%20that%20is%20ideal%20for%20magnetic%20hyperthermia.%20In%20the%20case%20of%20two-pot%20synthesis%2C%20in%20which%20no%20chloride%20ions%20are%20initially%20present%20in%20the%20reaction%20pot%2C%20dimers%20are%20obtained%20only%20at%20300%20degrees%20C.%20In%20order%20to%20lower%20the%20reaction%20temperature%20to%20200%20degrees%20C%20and%20to%20tune%20the%20size%20of%20the%20iron%20oxide%20domain%2C%20the%20addition%20of%20chloride%20ions%20becomes%20the%20crucial%20parameter.%20In%20the%20one-pot%20method%2C%20the%20presence%20of%20chloride%20ions%20from%20the%20start%20of%20the%20synthesis%20%28as%20counter%20ions%20of%20the%20gold%20salt%20precursor%29%20enables%20a%20prompt%20formation%20of%20dimers%20directly%20at%20200%20degrees%20C.%20In%20this%20case%2C%20the%20reaction%20time%20is%20the%20main%20parameter%20used%20to%20tune%20the%20iron%20oxide%20size.%20A%20record%20value%20of%20specific%20absorption%20rates%20%28SARs%29%20up%20to%201300%20W%20g%28Fe%29%28-1%29%20at%20330%20kHz%20and%2024%20kA%20m%28-1%29%20was%20measured%20for%20dimers%20with%20an%20iron%20oxide%20domain%20of%2024%20nm%20in%20size.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc7tb00968b%22%2C%22ISSN%22%3A%222050-750X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc7tb00968b%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A28%3A17Z%22%7D%7D%2C%7B%22key%22%3A%22JWP3BMGS%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Guardia%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Guardia%2C%20A.%20Riedinger%2C%20S.%20Nitti%2C%20G.%20Pugliese%2C%20S.%20Marras%2C%20A.%20Genovese%2C%20M.E.%20Materia%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20L.%20Manna%2C%20T.%20Pellegrino%2C%20One%20pot%20synthesis%20of%20monodisperse%20water%20soluble%20iron%20oxide%20nanocrystals%20with%20high%20values%20of%20the%20specific%20absorption%20rate%2C%20Journal%20of%20Materials%20Chemistry%20B%202%20%282014%29%204426%26%23x2013%3B4434.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc4tb00061g%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc4tb00061g%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22One%20pot%20synthesis%20of%20monodisperse%20water%20soluble%20iron%20oxide%20nanocrystals%20with%20high%20values%20of%20the%20specific%20absorption%20rate%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pablo%22%2C%22lastName%22%3A%22Guardia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andreas%22%2C%22lastName%22%3A%22Riedinger%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Simone%22%2C%22lastName%22%3A%22Nitti%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Giammarino%22%2C%22lastName%22%3A%22Pugliese%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sergio%22%2C%22lastName%22%3A%22Marras%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alessandro%22%2C%22lastName%22%3A%22Genovese%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Elena%22%2C%22lastName%22%3A%22Materia%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Liberato%22%2C%22lastName%22%3A%22Manna%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Teresa%22%2C%22lastName%22%3A%22Pellegrino%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20a%20highly%20reproducible%20route%20to%20synthesize%20iron%20oxide%20nanoparticles%20%28IONPs%29%20with%20control%20over%20size%20and%20shape%20and%20with%20size%20dispersions%20around%2010%25.%20By%20tuning%20the%20relative%20ratio%20of%20squalane%20to%20dibenzyl%20ether%2C%20which%20were%20used%20as%20solvents%20in%20the%20synthesis%2C%20the%20size%20of%20the%20particles%20could%20be%20varied%20from%2014%20to%20around%20100%20nm%2C%20while%20their%20shape%20evolved%20from%20cubic%20%28for%20size%20ranges%20up%20to%2035%20nm%29%20to%20truncated%20octahedra%20and%20octahedra%20%28for%20sizes%20from%2040%20nm%20up%20to%20100%20nm%29.%20Fine%20tuning%20of%20the%20size%20within%20each%20of%20these%20ranges%20could%20be%20achieved%20by%20varying%20the%20heating%20ramp%20and%20the%20iron%20precursor%20to%20decanoic%20acid%20ratio.%20We%20also%20demonstrate%20direct%20water%20transfer%20of%20the%20as-synthesized%20IONPs%20via%20in%20situ%20ligand%20exchange%20with%20gallol%20polyethylene%20glycol%20molecules%2C%20the%20latter%20simply%20added%20to%20the%20crude%20nanocrystal%20mixture%20at%2070%20degrees%20C.%20The%20specific%20absorption%20rate%20%28SAR%29%20values%20measured%20on%20the%20water%20transferred%20IONPs%2C%20at%20frequencies%20and%20applied%20magnetic%20fields%20that%20are%20considered%20safe%20for%20patients%2C%20confirmed%20their%20high%20heating%20performance.%20Finally%2C%20this%20method%20allows%20the%20transfer%20of%2035%20nm%20nanocubes%20as%20individually%20coated%20and%20stable%20particles%20to%20the%20water%20phase.%20For%20the%20first%20time%2C%20the%20heating%20performance%20of%20such%20large%20IONPs%20has%20been%20studied.%20This%20work%20uncovers%20the%20possibility%20of%20using%20large%20IONPs%20for%20magnetic%20hyperthermia%20in%20tumor%20therapy.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc4tb00061g%22%2C%22ISSN%22%3A%222050-750X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc4tb00061g%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A11%3A29Z%22%7D%7D%2C%7B%22key%22%3A%22XKAV7RJF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Goetz%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EJ.%20Goetz%2C%20A.%20Nonat%2C%20A.%20Diallo%2C%20M.%20Sy%2C%20I.%20Sera%2C%20A.%20Lecointre%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20C.F.%20Chan%2C%20K.-L.%20Wong%2C%20L.J.%20Charbonni%26%23xE8%3Bre%2C%20Ultrabright%20Lanthanide%20Nanoparticles%2C%20ChemPlusChem%2081%20%282016%29%20526%26%23x2013%3B534.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcplu.201600007%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fcplu.201600007%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ultrabright%20Lanthanide%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Joan%22%2C%22lastName%22%3A%22Goetz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Aline%22%2C%22lastName%22%3A%22Nonat%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Abdoulaye%22%2C%22lastName%22%3A%22Diallo%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mohamadou%22%2C%22lastName%22%3A%22Sy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ildan%22%2C%22lastName%22%3A%22Sera%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Alexandre%22%2C%22lastName%22%3A%22Lecointre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chi%20Fai%22%2C%22lastName%22%3A%22Chan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ka-Leung%22%2C%22lastName%22%3A%22Wong%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Lo%5Cu00efc%20J.%22%2C%22lastName%22%3A%22Charbonni%5Cu00e8re%22%7D%5D%2C%22abstractNote%22%3A%22Tb-doped%20La0.9Tb0.1F3%20nanoparticles%20were%20prepared%20by%20a%20simple%20and%20reproducible%20microwave-assisted%20synthetic%20protocol%20in%20water.%20The%20nanoparticles%20were%20characterized%20by%20XRD%2C%20TEM%2C%20dynamic%20light%20scattering%20and%20inductively%20coupled%20plasma%20atomic%20emission%20spectroscopy%20elemental%20analysis.%20Eleven%20ligands%20with%20varying%20coordination%20and%20photosensitizing%20abilities%20were%20designed%20to%20bind%20at%20the%20surface%20of%20the%20Tb-doped%20nanoparticles.%20The%20photosensitizing%20behavior%20was%20monitored%20by%20electronic%20absorption%20spectroscopy%20and%20steady-state%20and%20time-resolved%20emission%20spectroscopy.%20The%20two%20most%20effective%20photosensitizing%20ligands%20were%20used%20to%20isolate%20and%20purify%20the%20capped%20nanoparticles.%20The%20composition%20and%20spectroscopic%20properties%20of%20these%20nanoparticles%20were%20measured%2C%20which%20revealed%20either%202660%20and%205240%20ligands%20per%20nanoparticle%2C%20molar%20absorptivities%20of%207.6%5Cu00d7106%20and%201.6%5Cu00d7107%20m%5Cu22121%20cm%5Cu22121%20and%20luminescence%20quantum%20yields%20of%200.29%20and%200.13%20in%20water%2C%20respectively.%20These%20data%20correspond%20to%20exceptional%20brightness%20values%20of%202.2%5Cu00d7106%20and%202.1%5Cu00d7106%20m%5Cu22121%20cm%5Cu22121%2C%20respectively.%20The%20as-prepared%20nanoparticles%20were%20imaged%20in%20HeLa%20cells%20by%20fluorescence%20microscopy%2C%20which%20showed%20their%20specific%20localization%20in%20lysosomes.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fcplu.201600007%22%2C%22ISSN%22%3A%222192-6506%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fcplu.201600007%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-08-18T11%3A43%3A51Z%22%7D%7D%2C%7B%22key%22%3A%22NNTPJSAH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Gerber%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EO.%20Gerber%2C%20B.P.%20Pichon%2C%20C.%20Ulhaq%2C%20J.-M.%20Greneche%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20I.%20Florea%2C%20O.%20Ersen%2C%20D.%20Begin%2C%20S.%20Lemonnier%2C%20E.%20Barraud%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Low%20Oxidation%20State%20and%20Enhanced%20Magnetic%20Properties%20Induced%20by%20Raspberry%20Shaped%20Nanostructures%20of%20Iron%20Oxide%2C%20Journal%20of%20Physical%20Chemistry%20C%20119%20%282015%29%2024665%26%23x2013%3B24673.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.5b08164%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.jpcc.5b08164%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Low%20Oxidation%20State%20and%20Enhanced%20Magnetic%20Properties%20Induced%20by%20Raspberry%20Shaped%20Nanostructures%20of%20Iron%20Oxide%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Olivier%22%2C%22lastName%22%3A%22Gerber%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%20P.%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Ulhaq%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ileana%22%2C%22lastName%22%3A%22Florea%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dominique%22%2C%22lastName%22%3A%22Begin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sebastien%22%2C%22lastName%22%3A%22Lemonnier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Elodie%22%2C%22lastName%22%3A%22Barraud%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22Nanostructures%20with%20controlled%20size%2C%20morphology%2C%20and%20composition%20represent%20a%20main%20challenge%20in%20materials%20science%20because%20controlling%20these%20parameters%20is%20fundamental%20to%20optimizing%20the%20subsequent%20functional%20properties.%20Aggregated%20nanostructures%2C%20combining%20both%20individual%20and%20collective%20properties%20of%20nanocrystals%2C%20offer%20interesting%20perspectives%20to%20design%20new%20magnetic%20nanomaterials.%20In%20that%20context%2C%20original%20porous%20raspberry%20shaped%20nanostructures%20consisting%20of%20oriented%20aggregates%20of%20ferrite%20nanocrystals%20have%20been%20synthesized%20by%20an%20one-pot%20polyol%20solvothermal%20method.%20Synthesis%20conditions%20have%20been%20optimized%20to%20obtain%20nanostructures%20featured%20by%20similar%20sizes%20of%20about%20250%20nm%20and%20nanocrystal%20sizes%20modulated%20from%205%20to%2060%20nm%2C%20leading%20to%20porous%20structures%20with%20tunable%20specific%20surface%20area.%20Structural%20and%20magnetic%20studies%20of%20nanostructures%20as%20a%20function%20of%20the%20nanocrystal%20size%20evidenced%20their%20low%20oxidation%20state%20and%20enhanced%20magnetic%20properties.%20Indeed%2C%20the%20oriented%20aggregation%20of%20nanocrystals%20leads%20to%20high%20interface%20between%20nanograins%20reducing%20significantly%20their%20surface%20oxidation%20and%20enhancing%20their%20saturation%20magnetization%20in%20comparison%20to%20individual%20nanoparticles%20of%20similar%20sizes.%20Magnetic%20moments%20of%20each%20grain%20are%20also%20consequently%20strongly%20coupled%20by%20dipolar%20interactions%20which%20led%20to%20superspin%20glass%20effects.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.jpcc.5b08164%22%2C%22ISSN%22%3A%221932-7447%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.jpcc.5b08164%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226739WBV7%22%2C%22CF4ZI7HM%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A14%3A00Z%22%7D%7D%2C%7B%22key%22%3A%22WP4B7SND%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Garcia-Munoz%20et%20al.%22%2C%22parsedDate%22%3A%222023%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Garcia-Munoz%2C%20F.%20Fresno%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Robert%2C%20N.%20Keller%2C%20Influence%20of%20the%20solid%20titanium%20source%20on%20the%20activity%20of%20La1_xTixFeO3%20photo-CWPO%20catalysts%20under%20UV-A%20light%2C%20Catalysis%20Today%20413%26%23x2013%3B415%20%282023%29%20113974.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.cattod.2022.12.005%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.cattod.2022.12.005%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Influence%20of%20the%20solid%20titanium%20source%20on%20the%20activity%20of%20La1_xTixFeO3%20photo-CWPO%20catalysts%20under%20UV-A%20light%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patricia%22%2C%22lastName%22%3A%22Garcia-Munoz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fernando%22%2C%22lastName%22%3A%22Fresno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Chistophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Didier%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%5D%2C%22abstractNote%22%3A%22In%20the%20search%20for%20more%20efficient%20low-temperature%20catalysts%20able%20to%20oxidise%20biorecalcitrant%20pollutants%20in%20water%2C%20the%20selective%20substitution%20of%20La3%2B%20by%20Ti3%2B%20cations%20was%20reported%20to%20boost%20the%20UV-A%20light%20driven%20activity%20of%20LaFeO3%20orthoferrites%20as%20H2O2-mediated%20photo-CWPO%20catalysts.%20La1_xTixFeO3%20catalysts%20with%200%20%3C%20x%20%3C%200.11%20were%20obtained%20by%20a%20modified%20Pechini%20sol-gel%20route%20via%20the%20addition%20of%20a%20solid%20source%20of%20titanium%20during%20the%20synthesis.%20By%20using%20a%20span%20of%20crystallized%20and%20amorphous%20TiO2%2C%20the%20influence%20of%20the%20titanium%20source%20on%20the%20substitution%20rate%20in%20the%20orthoferrite%20network%20and%20on%20the%20performances%20of%20the%20catalysts%20under%20UV-A%20light%20was%20demonstrated%20using%20the%20degradation%20of%204-chlorophenol%20as%20test%20reaction.%20The%20amorphous%20content%20of%20the%20TiO2%20precursor%20is%20proposed%20to%20be%20the%20key%20factor%20driving%20the%20substitution%20of%20La3%2B%2C%20the%20largest%20substitution%20of%2011%20%25%20being%20obtained%20using%20a%20dried%20sol-gel%20TiO2%20precursor.%20We%20suggest%20that%20the%20substitution%20proceeds%20during%20the%20thermal%20treatment%20via%20a%20solid-solid%20diffusion%20between%20TiO2%20and%20the%20amorphous%20LaFeO3%20before%20it%20crystallises.%20The%20catalyst%20robustness%20was%20influ-enced%20by%20the%20TiO2%20nature.%20Small%20size%20Ti-LaFeO3%20crystallites%20strongly%20lowered%20or%20blocked%20the%20Fe%20release%2C%20while%20no%20improvement%20was%20observed%20for%20large%20size%20crystallites%20vs.%20the%20pristine%20material%2C%20what%20was%20associated%20to%20a%20poor%20homogenization%20of%20the%20titanium%20in%20the%20network.%20We%20showed%20that%20the%20mineralization%20activity%20was%20proportional%20to%20the%20substitution%20rate%20of%20La1_xTixFeO3%20catalysts%2C%20while%20a%20similar%20relationship%20could%20be%20drawn%20for%20the%20degradation%20activity%20only%20in%20the%20case%20of%20highly%20robust%20catalysts%20with%20pure%20heterogeneous%20surface%20reactions.%22%2C%22date%22%3A%222023%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.cattod.2022.12.005%22%2C%22ISSN%22%3A%220920-5861%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.cattod.2022.12.005%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222023-06-15T14%3A47%3A28Z%22%7D%7D%2C%7B%22key%22%3A%225NXX849Q%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Garcia-Munoz%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Garcia-Munoz%2C%20F.%20Fresno%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Robert%2C%20N.%20Keller%2C%20Ti-%20-Modified%20LaFeO3%5C%2Fbeta-SiC%20Alveolar%20Foams%20as%20Immobilized%20Dual%20Catalysts%20with%20Combined%20Photo-Fenton%20and%20Photocatalytic%20Activity%2C%20ACS%20Applied%20Materials%20%26amp%3B%20Interfaces%2012%20%282020%29%2057025%26%23x2013%3B57037.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.0c16647%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facsami.0c16647%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ti-%20-Modified%20LaFeO3%5C%2Fbeta-SiC%20Alveolar%20Foams%20as%20Immobilized%20Dual%20Catalysts%20with%20Combined%20Photo-Fenton%20and%20Photocatalytic%20Activity%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patricia%22%2C%22lastName%22%3A%22Garcia-Munoz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fernando%22%2C%22lastName%22%3A%22Fresno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Didier%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%5D%2C%22abstractNote%22%3A%22Ti-modified%20LaFeO3%5C%2Fbeta-SiC%20alveolar%20foams%20were%20used%20as%20immobilized%2C%20highly%20robust%20dual%20catalysts%20with%20combined%20photocatalytic%20wet%20peroxide%20oxidation%20and%20photocatalytic%20activity%20under%20UV-A%20light.%20They%20were%20prepared%20by%20incipient%20wetness%20impregnation%20of%20a%20beta-SiC%20foam%20support%2C%20by%20implementing%20a%20sol-gel%20Pechini%20synthesis%20at%20the%20foam%20surface%20in%20the%20presence%20of%20dried%20amorphous%20sol-gel%20titania%20as%20a%20titanium%20source.%20The%20physicochemical%20and%20catalytic%20features%20suggest%20the%20stabilization%20at%20the%20foam%20surface%20of%20a%20substituted%20La1-xTixFeO3%20catalyst%20analogous%20to%20its%20powdery%20counterpart.%20Taking%204-chlorophenol%20removal%20in%20water%20as%20a%20model%20reaction%2C%20its%20dual%20nature%20enables%20both%20high%20reaction%20rates%20and%20full%20total%20organic%20carbon%20%28TOC%29%20conversion%20because%20of%20a%20synergy%20effect%2C%20while%20its%20macroscopic%20structure%20overcomes%20the%20drawback%20of%20working%20with%20powdery%20catalysts.%20Further%2C%20it%20yields%20photonic%20efficiencies%20for%20degradation%20and%20mineralization%20of%20ca.%209.4%20and%2038%25%2C%20respectively%2C%20that%20strongly%20outperform%20those%20obtained%20with%20a%20reference%20TiO%282%29P25%5C%2Fbeta-SiC%20foam%20photocatalyst.%20The%20enhancement%20of%20the%20catalyst%20robustness%20upon%20Ti%20modification%20prevents%20any%20Fe%20leaching%20to%20the%20solution%2C%20and%20therefore%2C%20the%20optimized%20macroscopic%20foam%20catalyst%20with%2010%20wt%20%25%20catalyst%20loading%20operates%20through%20pure%20heterogeneous%20surface%20reactions%2C%20without%20any%20activity%20loss%20during%20reusability%20test%20cycles.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facsami.0c16647%22%2C%22ISSN%22%3A%221944-8244%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facsami.0c16647%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A29%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22FJ657CAF%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Garcia-Munoz%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Garcia-Munoz%2C%20F.%20Fresno%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Robert%2C%20N.%20Keller%2C%20Synergy%20effect%20between%20photocatalysis%20and%20heterogeneous%20photo-Fenton%20catalysis%20on%20Ti-doped%20LaFeO3%20perovskite%20for%20high%20efficiency%20light-assisted%20water%20treatment%2C%20Catalysis%20Science%20%26amp%3B%20Technology%2010%20%282020%29%201299%26%23x2013%3B1310.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9cy02269d%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc9cy02269d%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synergy%20effect%20between%20photocatalysis%20and%20heterogeneous%20photo-Fenton%20catalysis%20on%20Ti-doped%20LaFeO3%20perovskite%20for%20high%20efficiency%20light-assisted%20water%20treatment%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patricia%22%2C%22lastName%22%3A%22Garcia-Munoz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fernando%22%2C%22lastName%22%3A%22Fresno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Didier%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%5D%2C%22abstractNote%22%3A%22A%20strategy%20combining%20both%20heterogenized%20photo-Fenton%20and%20photocatalysis%20advanced%20oxidation%20processes%20for%20a%20single%20dual%20catalyst%20is%20developed%20simultaneously%20benefiting%20from%20the%20higher%20reaction%20rate%20of%20photo-Fenton%20and%20the%20higher%20mineralization%20yield%20of%20photocatalysis%20in%20water%20treatment%2C%20while%20overcoming%20the%20strong%20drawbacks%20still%20limiting%20their%20viability%20as%20single%20processes.%20We%20prepared%20via%20a%20facile%20Pechini%20sol-gel%20route%20a%20highly%20efficient%20and%20stable%20Ti-substituted%20LaFeO3%20dual%20catalyst%2C%20acting%20simultaneously%20as%20a%20reusable%20photo-Fenton%20solid%20catalyst%20and%20a%20photocatalyst%20in%20water%20treatment.%20The%20partial%20substitution%20of%20La%20by%20Ti%20ions%20in%20the%20crystalline%20network%20led%20to%20pure%20heterogeneous%20surface%20reactions%20with%20an%20increase%20in%20the%20catalyst%20robustness%20by%20more%20than%20two%20orders%20of%20magnitude%2C%20indicating%20the%20absence%20of%20any%20Fe%20released%20and%20the%20stability%20of%20catalytic%20performance%20with%20test%20cycles.%20It%20further%20strongly%20enhanced%20the%20reaction%20rates%2C%20due%20to%20both%20increased%20availability%20of%20the%20photogenerated%20charge%20carriers%20at%20the%20surface%20and%20the%20electronic%20enrichment%20of%20surface%20Fe%2C%20and%20allowed%20full%20mineralization%20of%20a%20pollutant%20to%20be%20achieved%20at%20circumneutral%20pH%20through%20combined%20advanced%20oxidation%20processes.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9cy02269d%22%2C%22ISSN%22%3A%222044-4753%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc9cy02269d%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A29%3A13Z%22%7D%7D%2C%7B%22key%22%3A%22HENAXSRH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Garcia-Munoz%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Garcia-Munoz%2C%20F.%20Fresno%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Robert%2C%20N.%20Keller%2C%20Highly%20robust%20La1-xTixFeO3%20dual%20catalyst%20with%20combined%20photocatalytic%20and%20photo-CWPO%20activity%20under%20visible%20light%20for%204-chlorophenol%20removal%20in%20Chock%20for%20water%2C%20Applied%20Catalysis%20B-Environmental%20262%20%282020%29%20118310.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apcatb.2019.118310%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apcatb.2019.118310%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Highly%20robust%20La1-xTixFeO3%20dual%20catalyst%20with%20combined%20photocatalytic%20and%20photo-CWPO%20activity%20under%20visible%20light%20for%204-chlorophenol%20removal%20in%20Chock%20for%20water%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patricia%22%2C%22lastName%22%3A%22Garcia-Munoz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fernando%22%2C%22lastName%22%3A%22Fresno%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Didier%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%5D%2C%22abstractNote%22%3A%22A%20highly%20robust%20Ti-substituted%20LaFeO3%20dual%20catalyst%20was%20synthesized%20via%20a%20facile%20Pechini%20sol-gel%20route%20using%20a%20dried%20amorphous%20sol-gel%20titania%20as%20titanium%20source%20and%20a%20final%20calcination%20at%20800%20degrees%20C%20that%20enabled%20solid-solid%20diffusion%20of%20titanium%20atoms%20within%20the%20perovskite%20network.%20Using%20an%20amorphous%20precursor%20instead%20of%20crystallized%20titania%20nanocrystals%20increased%20the%20Ti%20-%3E%20La%20atomic%20substitution%20degree%20in%20the%20crystalline%20network%20from%205%20at%25%20to%2011%20at%25%2C%20together%20with%20a%20strong%20increase%20in%20the%20catalytic%20activity.%20The%20partially%20substituted%20La1-xTixFeO3%20catalyst%20with%20a%2011%20at%25%20substitution%20degree%20allowed%20pure%20heterogeneous%20surface%20reactions%20to%20take%20place%20under%20pure%20visible%20light%20%28lambda%20%3E%20420%20nm%29%2C%20with%20an%20increase%20in%20the%20catalyst%20robustness%20by%20more%20than%20two%20orders%20of%20magnitude%20compared%20to%20the%20unmodified%20LaFeO3%20counterpart%2C%20evidenced%20by%20the%20absence%20of%20any%20Fe%20release%2C%20the%20structural%20stability%20of%20the%20substituted%20catalyst%20and%20the%20absence%20of%20any%20loss%20of%20catalytic%20activity%20with%20test%20cycles.%20Further%2C%20the%20strategy%20of%20combining%20both%20photocatalysis%20and%20H2O2%20-mediated%20heterogeneous%20photo-Fenton%20advanced%20oxidation%20processes%20within%20one%20single%20heterogeneous%20catalyst%20allowed%20the%20dual%20La1-xTixFeO3%20catalyst%20to%20simultaneously%20take%20advantage%20from%20the%20higher%20reaction%20rate%20of%20photo-Fenton%20and%20from%20the%20higher%20mineralization%20yield%20of%20photocatalysis%20in%20water%20treatment.%20As%20a%20result%2C%20the%20dual%2011%20at%25%20Ti-substituted%20La1-xTixFeO3%20catalyst%20clearly%20outperformed%20its%20unmodified%20LaFeO3%20counterpart%20and%20led%20to%20a%20complete%20mineralization%20of%20the%204-chlorophenol%20substrate%20under%20pure%20visible%20light%2C%20with%20strongly%20enhanced%20H2O2%20decomposition%2C%204-chlorophenol%20and%20TOC%20conversion%20rates.%20Finally%2C%20the%20activity%20of%20the%20La1-xTixFeO3%20catalyst%20under%20visible%20light%20contributed%20significantly%20to%20its%20overall%20activity%20obtained%20using%20the%20full%20solar%20spectra.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apcatb.2019.118310%22%2C%22ISSN%22%3A%220926-3373%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.apcatb.2019.118310%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A29%3A07Z%22%7D%7D%2C%7B%22key%22%3A%22XV4PV8SG%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Garcia-Munoz%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EP.%20Garcia-Munoz%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Robert%2C%20N.%20Keller%2C%20Ti-substituted%20LaFeO3%20perovskite%20as%20photoassisted%20CWPO%20catalyst%20for%20water%20treatment%2C%20Applied%20Catalysis%20B-Environmental%20248%20%282019%29%20120%26%23x2013%3B128.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apcatb.2019.02.030%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apcatb.2019.02.030%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ti-substituted%20LaFeO3%20perovskite%20as%20photoassisted%20CWPO%20catalyst%20for%20water%20treatment%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patricia%22%2C%22lastName%22%3A%22Garcia-Munoz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Didier%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Keller%22%7D%5D%2C%22abstractNote%22%3A%22New%20Ti-substituted%20LaFeO3%20perovskites%20have%20been%20synthesized%20via%20a%20sol-gel%20method%20with%20partial%20substitution%20of%20La%20by%20Ti%20and%20used%20as%20catalyst%20in%20the%20photoassisted%20CWPO%20for%20the%20removal%20of%204-Cl-Phenol%20in%20water.%20The%20influence%20of%20the%20calcination%20temperature%20and%20the%20Ti%20at.%25%20content%20was%20evaluated%20in%20terms%20of%20activity%20and%20stability.%20The%20Ti-substituted%20LaFeO3%20catalyst%20calcined%20at%20800%20degrees%20C%20showed%20an%20activity%20optimum%20for%20a%203.2%20at.%25%20content%20of%20Ti%20in%20the%20presence%20of%20the%20stoichiometric%20dose%20of%20H2O2%20%2C%20with%20a%20higher%20mineralization%20rate%20and%20yield%20than%20its%20LaFeO3%20counterpart%2C%20while%20achieving%20complete%20Cl-phenol%20removal%20and%20100%25%20mineralization%20at%20circumneutral%20pH%2C%20ambient%20pressure%20and%20temperature.%20The%20La%20partial%20substitution%20by%20Ti%20and%20the%20increase%20in%20the%20calcination%20temperature%20strongly%20improved%20the%20catalyst%20stability%20in%20terms%20of%20Fe%20leaching%2C%20and%20the%20Ti-substituted%20LaFeO3%20catalyst%20calcined%20at%20800%20degrees%20C%20displayed%20stable%20performances%20over%205%20cycles%20of%20reaction%2C%20with%20a%20limited%20Fe%20leaching%20lower%20than%200.1%25%20of%20its%20total%20content.%20The%20catalyst%20was%20active%20simultaneously%20in%20both%20photoassisted%20CWPO%20and%20photocatalysis%20under%20UV-A%20light.%20Thus%2C%20the%20photoassisted%20CWPO%20with%20Ti-substituted%20LaFeO3%20catalysts%20may%20overcome%20some%20drawbacks%20of%20single%20AOPs%20by%20combining%20higher%20rates%20at%20complete%20mineralization.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apcatb.2019.02.030%22%2C%22ISSN%22%3A%220926-3373%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.apcatb.2019.02.030%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A28%3A41Z%22%7D%7D%2C%7B%22key%22%3A%22NM5XX958%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Demchenko%20et%20al.%22%2C%22parsedDate%22%3A%222022%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Demchenko%2C%20S.%20Homkar%2C%20C.%20Bouillet%2C%20C.T.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20D.%20Preziosi%2C%20G.%20Versini%2C%20C.%20Leuvrey%2C%20P.%20Boullay%2C%20X.%20Devaux%2C%20N.%20Viart%2C%20Unveiling%20unconventional%20ferroelectric%20switching%20in%20multiferroic%20Ga-0.6%20Fe1.4O3%20thin%20films%20through%20multiscale%20electron%20microscopy%20investigations%2C%20Acta%20Materialia%20240%20%282022%29%20118337.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.actamat.2022.118337%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.actamat.2022.118337%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unveiling%20unconventional%20ferroelectric%20switching%20in%20multiferroic%20Ga-0.6%20Fe1.4O3%20thin%20films%20through%20multiscale%20electron%20microscopy%20investigations%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Demchenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Suvidyakumar%22%2C%22lastName%22%3A%22Homkar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christopher%20T.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Boullay%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Xavier%22%2C%22lastName%22%3A%22Devaux%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Understanding%20the%20polarization%20switching%20mechanisms%20at%20play%20in%20ferroelectric%20materials%20is%20crucial%20for%20their%20exploitation%20in%20electronic%20devices.%20The%20conventional%20centrosymmetric%20reference%20structure-based%20mechanism%20which%20accounts%20for%20ferroelectricity%20in%20most%20of%20the%20usual%20displacive%20ferroelectric%20materi-als%20is%20too%20energy-demanding%20for%20some%20newly%20diagnosed%20ferroelectric%20materials%20such%20as%20the%20Ga2-xFexO3%20%280.8%20%3C%3D%20x%20%3C%3D%201.4%29%20compounds.%20Some%20alternative%20theoretical%20propositions%20have%20been%20made%20and%20need%20ex-perimental%20confirmation.%20A%20dual-scale%20electron%20microscopy%20study%20is%20performed%20on%20thin%20films%20of%20the%20Ga0.6Fe1.4O3%20multiferroic%20compound.%20A%20wide%20scale%20precession-assisted%20electron%20diffraction%20tomography%20study%20first%20allows%20the%20determination%20of%20the%20structure%20the%20compound%20adopts%20in%20thin%20films%2C%20and%20even%20permits%20the%20refinement%20of%20the%20atomic%20positions%20within%20this%20structure.%20Cationic%20mobility%20is%20suggested%20for%20two%20of%20the%20atomic%20positions%20through%20the%20existence%20of%20extra%20electronic%20density.%20A%20local%20in%20situ%20high%20resolution%20scanning%20transmission%20electron%20microscopy%20study%20then%20allows%20confirming%20these%20mobilities%20by%20directly%20spotting%20the%20cationic%20displacements%20on%20successively%20acquired%20images.%20The%20whole%20study%20confirms%20an%20unconventional%20switching%20mechanism%20via%20local%20domain%20wall%20motion%20in%20this%20compound.%20%28c%29%202022%20Acta%20Materialia%20Inc.%20Published%20by%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222022%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.actamat.2022.118337%22%2C%22ISSN%22%3A%221359-6454%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.actamat.2022.118337%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222022-11-21T09%3A57%3A46Z%22%7D%7D%2C%7B%22key%22%3A%22KMP3XGWH%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Demchenko%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.%20Demchenko%2C%20Y.%20Chang%2C%20E.%20Chikoidze%2C%20B.%20Berini%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20F.%20Roulland%2C%20C.%20Ulhaq-Bouillet%2C%20G.%20Versini%2C%20S.%20Barre%2C%20C.%20Leuvrey%2C%20V.%20Favre-Nicolin%2C%20N.%20Boudet%2C%20S.%20Zafeiratos%2C%20Y.%20Dumont%2C%20N.%20Viart%2C%20Tuning%20the%20conductivity%20type%20in%20a%20room%20temperature%20magnetic%20oxide%3A%20Ni-doped%20Ga0.6Fe1.4O3%20thin%20films%2C%20RSC%20Advances%206%20%282016%29%2028248%26%23x2013%3B28256.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc6ra01540a%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1039%5C%2Fc6ra01540a%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Tuning%20the%20conductivity%20type%20in%20a%20room%20temperature%20magnetic%20oxide%3A%20Ni-doped%20Ga0.6Fe1.4O3%20thin%20films%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ana%22%2C%22lastName%22%3A%22Demchenko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Chang%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Chikoidze%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Berini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Fran%5Cu00e7ois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Ulhaq-Bouillet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Gilles%22%2C%22lastName%22%3A%22Versini%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sophie%22%2C%22lastName%22%3A%22Barre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C%5Cu00e9dric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Favre-Nicolin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Boudet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Zafeiratos%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Dumont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%5D%2C%22abstractNote%22%3A%22Ni-Doped%20thin%20films%20of%20the%20room%20temperature%20ferrimagnetic%20oxide%20Ga0.6Fe1.4O3%20were%20deposited%20by%20pulsed%20laser%20deposition%20and%20their%20electronic%20transport%20and%20structural%20and%20magnetic%20properties%20were%20studied.%20The%20actual%20insertion%20of%20the%20Ni%20cations%20within%20the%20Ga0.6Fe1.4O3%20structure%20has%20been%20checked%20by%20resonant%20X-ray%20scattering.%20A%20clear%20extremum%20is%20noticed%20for%20all%20properties%20for%20the%202%25%20Ni%20doping%3A%20extrema%20in%20the%20crystallographic%20cell%20parameters%20of%20the%20films%2C%20maximum%20in%20the%20Curie%20temperature%2C%20and%20maximum%20in%20the%20electric%20resistivity.%20We%20also%20observed%20a%20change%20of%20conductivity%20type%20for%20this%20dopant%20concentration%2C%20from%20n-type%20for%20Ni%20contents%20below%202%25%20to%20p-type%20for%20Ni%20contents%20above%202%25.%20We%20explain%20this%20behavior%20by%20the%20existence%20of%20oxygen%20vacancies%20in%20the%20pulsed%20laser%20deposited%20Ga0.6Fe1.4O3%20thin%20films%2C%20which%20results%20in%20the%20reduction%20of%20some%20of%20the%20Fe3%2B%20into%20Fe2%2B%20cations%2C%20and%20n-type%20conduction%20via%20a%20hopping%20mechanism.%20The%20insertion%20of%20Ni2%2B%20cations%20first%20deals%20with%20the%20presence%20of%20oxygen%20vacancies%20and%20reduces%20the%20number%20of%20n-type%20carriers%20in%20the%20films%2C%20in%20a%20compensation-like%20mechanism.%20When%20the%20number%20of%20introduced%20Ni2%2B%20cations%20dominates%20the%20number%20of%20oxygen%20vacancies%2C%20conductivity%20becomes%20p-type%20and%20starts%20to%20increase%20again.%20We%20believe%20that%20the%20tunability%20of%20the%20conduction%20type%20and%20magnitude%20in%20thin%20films%20of%20a%20room%20temperature%20ferrimagnetic%20material%20paves%20the%20way%20towards%20new%20all%20oxide%20electronic%20devices.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1039%5C%2Fc6ra01540a%22%2C%22ISSN%22%3A%222046-2069%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1039%5C%2Fc6ra01540a%22%2C%22collections%22%3A%5B%22CHW2VGSR%22%2C%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22TBP4QFHK%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A27%3A50Z%22%7D%7D%2C%7B%22key%22%3A%22QSG64UKV%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22de%20Tymowski%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EB.%20de%20Tymowski%2C%20Y.%20Liu%2C%20C.%20M%26%23xE9%3Bny%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Begin%2C%20P.%20Nguyen%2C%20C.%20Pham%2C%20D.%20Edouard%2C%20F.%20Luck%2C%20C.%20Pham-Huu%2C%20Co-Ru%5C%2FSiC%20impregnated%20with%20ethanol%20as%20an%20effective%20catalyst%20for%20the%20Fischer-Tropsch%20synthesis%2C%20Applied%20Catalysis%20A-General%20419%20%282012%29%2031%26%23x2013%3B40.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apcata.2012.01.004%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1016%5C%2Fj.apcata.2012.01.004%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Co-Ru%5C%2FSiC%20impregnated%20with%20ethanol%20as%20an%20effective%20catalyst%20for%20the%20Fischer-Tropsch%20synthesis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22de%20Tymowski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Yuefeng%22%2C%22lastName%22%3A%22Liu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christian%22%2C%22lastName%22%3A%22M%5Cu00e9ny%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dominique%22%2C%22lastName%22%3A%22Begin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Patrick%22%2C%22lastName%22%3A%22Nguyen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Charlotte%22%2C%22lastName%22%3A%22Pham%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22David%22%2C%22lastName%22%3A%22Edouard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francis%22%2C%22lastName%22%3A%22Luck%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cuong%22%2C%22lastName%22%3A%22Pham-Huu%22%7D%5D%2C%22abstractNote%22%3A%22Silicon%20carbide%20containing%20cobalt%20%2830%20wt.%25%29%20doped%20with%200.1%20wt.%25%20of%20ruthenium%20catalysts%20prepared%20by%20incipient%20wetness%20impregnation%20of%20cobalt%20nitrate%20with%20either%20ethanol%20or%20water%20were%20tested%20in%20the%20Fischer-Tropsch%20synthesis%20%28FTS%29%20in%20a%20fixed-bed%20configuration.%20The%20catalyst%20prepared%20with%20ethanol%20exhibits%20a%20higher%20FTS%20performance%20compared%20to%20the%20one%20prepared%20with%20water%20and%20especially%20at%20high%20reaction%20temperature%2C%20i.e.%20230%20degrees%20C.%20The%20FTS%20performance%20of%20the%20cobalt-based%20catalyst%20impregnated%20with%20ethanol%20further%20increases%2C%20under%20high%20temperature%20and%20high%20space%20velocity%2C%20to%20reach%20a%20steady%20state%20reaction%20rate%20of%200.54%20g%28CH2%29%20g%28catalyst%29%28-1%29h%28-1%29%2C%20and%20a%20relatively%20high%20C5%2B%20selectivity%20of%20about%2090%25.%20In%20addition%2C%20the%20catalyst%20also%20exhibits%20a%20relatively%20high%20stability%20as%20a%20function%20of%20time%20on%20stream.%20Co-59%20zero%20field%20NMR%20analysis%20has%20indicates%20that%20the%20proportion%20of%20cobalt%20atoms%20engaged%20in%20the%20small%20hcp%20cobalt%20particles%20%28%3C8%20nm%29%20was%20higher%20for%20the%20ethanol%20impregnated%20catalyst%20and%20also%20to%20the%20more%20homogeneous%20dispersion%20of%20the%20ruthenium%20atoms%20within%20the%20cobalt%20network%20forming%20an%20alloy.%20%28C%29%202012%20Elsevier%20B.V.%20All%20rights%20reserved.%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apcata.2012.01.004%22%2C%22ISSN%22%3A%220926-860X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1016%5C%2Fj.apcata.2012.01.004%22%2C%22collections%22%3A%5B%22UVN4N32C%22%2C%22ZN5EITAC%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222016-04-08T09%3A11%3A02Z%22%7D%7D%2C%7B%22key%22%3A%22XCIW9QMA%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Darcheville%20et%20al.%22%2C%22parsedDate%22%3A%222024%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Darcheville%2C%20A.-L.%20Adenot-Engelvin%2C%20C.%20Boscher%2C%20J.-M.%20Greneche%2C%20C.T.%20Lef%26%23xE8%3Bvre%2C%20J.%20Robert%2C%20O.%20Ersen%2C%20J.M.G.%20Calbet%2C%20M.L.R.%20Gonzalez%2C%20A.%20Thiaville%2C%20C.%20Sanchez%2C%20Magnetism%20of%20Iron%20Oxide%20Nanoparticles%3A%20From%20Atomic%20Order%20to%20Complexity%20at%20the%20Mesoscopic%20Scale%2C%20Physica%20Status%20Solidi-Rapid%20Research%20Letters%20Early%20access%20%282024%29%202400059.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fpssr.202400059%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1002%5C%2Fpssr.202400059%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Magnetism%20of%20Iron%20Oxide%20Nanoparticles%3A%20From%20Atomic%20Order%20to%20Complexity%20at%20the%20Mesoscopic%20Scale%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marie%22%2C%22lastName%22%3A%22Darcheville%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Lise%22%2C%22lastName%22%3A%22Adenot-Engelvin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Boscher%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christopher%20T.%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jerome%22%2C%22lastName%22%3A%22Robert%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jose%20Maria%20Gonzalez%22%2C%22lastName%22%3A%22Calbet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Maria%20Luisa%20Ruiz%22%2C%22lastName%22%3A%22Gonzalez%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andre%22%2C%22lastName%22%3A%22Thiaville%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Sanchez%22%7D%5D%2C%22abstractNote%22%3A%22Zn-substituted%20iron%20oxide%20nanoparticles%20of%20approximate%20to%205%20nm%20in%20diameter%20are%20synthetized%20by%20a%20microwave-assisted%20thermal%20decomposition%20method.%20The%20addition%20of%20ethylene%20glycol%20results%20in%20a%20size%20increase%20to%2022%20nm.%20Cationic%20disorder%20has%20been%20observed%20by%20electron%20energy%20loss%20spectroscopy-scanning%20transmission%20electron%20microscopy.%20Using%20M%20%26%20ouml%3Bssbauer%20spectrometry%20combined%20with%20Rietveld%20analysis%2C%20the%20complete%20cationic%20and%20vacancies%20repartition%20in%20the%20lattice%20is%20determined%2C%20as%20well%20as%20the%20canting%20of%20magnetic%20moments.%20This%20allows%20the%20magnetic%20moment%20to%20be%20calculated%2C%20in%20good%20agreement%20with%20that%20measured.%20The%20alternating%20current%20magnetic%20susceptibility%20is%20modeled%20by%20the%20N%20%26%20eacute%3Bel-Brown%20and%20the%20Coffey%20models%2C%20showing%20some%20discrepancy%20between%20these%20two%20approaches%20which%20is%20discussed.%20The%20largest%20particles%20show%20a%20complex%20morphology%20involving%20an%20oriented%20attachment%20mechanism%20of%20smaller%20units.%20Their%20cationic%20disorder%20and%20internal%20porosity%20have%20been%20evidenced%20and%20quantified%2C%20and%20the%20work%20shows%20that%20despite%20these%20defects%20they%20behave%20rather%20as%20magnetically%20blocked%20nanoparticles.How%20does%20the%20structural%20and%20chemical%20complexity%20commonly%20encountered%20in%20iron%20oxide%20nanoparticles%20influence%20their%20magnetic%20behavior%3F%20First%2C%20%5C%22small%5C%22%20nanoparticles%2C%20with%20only%20cationic%20disorder%2C%20are%20studied%20as%20a%20simple%20case.%20Then%20larger%20nanoparticles%20are%20showing%20in%20addition%20inner%20porosity%20and%20partial%20crystalline%20order%20as%20source%20of%20defects.%20At%20the%20end%2C%20they%20can%20magnetically%20be%20described%20as%20dense%20nanoparticles%21image%20%28c%29%202024%20WILEY-VCH%20GmbH%22%2C%22date%22%3A%222024%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1002%5C%2Fpssr.202400059%22%2C%22ISSN%22%3A%221862-6254%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1002%5C%2Fpssr.202400059%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%226739WBV7%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222024-08-22T07%3A02%3A42Z%22%7D%7D%2C%7B%22key%22%3A%224TSQG6I2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Darcheville%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EM.%20Darcheville%2C%20A.-L.%20Adenot-Engelvin%2C%20C.%20Boscher%2C%20N.%20Vukadinovic%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20A.%20Thiaville%2C%20C.%20Sanchez%2C%20Evidence%20of%20the%20Superparamagnetic%20State%20in%20the%20Zero-Field%20Microwave%20Susceptibility%20Spectra%20of%20Ferrimagnetic%20Nanoparticles%2C%20IEEE%20Magnetics%20Letters%2011%20%282020%29%206105305.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2FLMAG.2020.3026228%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1109%5C%2FLMAG.2020.3026228%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Evidence%20of%20the%20Superparamagnetic%20State%20in%20the%20Zero-Field%20Microwave%20Susceptibility%20Spectra%20of%20Ferrimagnetic%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marie%22%2C%22lastName%22%3A%22Darcheville%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anne-Lise%22%2C%22lastName%22%3A%22Adenot-Engelvin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Boscher%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nicolas%22%2C%22lastName%22%3A%22Vukadinovic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andre%22%2C%22lastName%22%3A%22Thiaville%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Clement%22%2C%22lastName%22%3A%22Sanchez%22%7D%5D%2C%22abstractNote%22%3A%22We%20investigated%20the%20static%20and%20dynamic%20magnetic%20properties%20of%20Zn%3Csub%3E0.4%3C%5C%2Fsub%3EFe%3Csub%3E2.6%3C%5C%2Fsub%3EO%3Csub%3E4%3C%5C%2Fsub%3E%20nanoparticles%20synthesized%20by%20thermal%20decomposition.%20Two%20ranges%20of%20diameter%20were%20used%3A%20small%20particles%20%28diameter%20about%206.2%20nm%29%20and%20larger%20ones%20%28diameter%20about%2022.4%20nm%29.%20The%20nanoparticle%20microstructure%20was%20characterized%20by%20transmission%20electron%20microscopy.%20The%20temperature%20dependence%20of%20the%20zero-field%20dynamic%20permeability%20for%20both%20nanoparticle%20sizes%20was%20studied%2C%20revealing%20a%20superparamagnetic%20state%20for%20the%20small%20ones.%20Effects%20of%20the%20nanoparticle%20size%20on%20the%20dynamic%20permeability%20were%20analyzied%2C%20and%20linked%20to%20the%20superparamagnetic%20state.%20A%20dynamic%20susceptibility%20model%20was%20found%20to%20reproduce%20the%20experimental%20behavior%20as%20well%20as%20its%20temperature%20dependence.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1109%5C%2FLMAG.2020.3026228%22%2C%22ISSN%22%3A%221949-307X%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1109%5C%2FLMAG.2020.3026228%22%2C%22collections%22%3A%5B%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222021-06-09T09%3A29%3A02Z%22%7D%7D%2C%7B%22key%22%3A%22VC37G3S2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cotin%20et%20al.%22%2C%22parsedDate%22%3A%222018%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Cotin%2C%20C.%20Kiefer%2C%20F.%20Perton%2C%20D.%20Ihiawakrim%2C%20C.%20Blanco-Andujar%2C%20S.%20Moldovan%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20O.%20Ersen%2C%20B.%20Pichon%2C%20D.%20Mertz%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Unravelling%20the%20Thermal%20Decomposition%20Parameters%20for%20The%20Synthesis%20of%20Anisotropic%20Iron%20Oxide%20Nanoparticles%2C%20Nanomaterials%208%20%282018%29%20881.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fnano8110881%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.3390%5C%2Fnano8110881%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Unravelling%20the%20Thermal%20Decomposition%20Parameters%20for%20The%20Synthesis%20of%20Anisotropic%20Iron%20Oxide%20Nanoparticles%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geoffrey%22%2C%22lastName%22%3A%22Cotin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Celine%22%2C%22lastName%22%3A%22Kiefer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francis%22%2C%22lastName%22%3A%22Perton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dris%22%2C%22lastName%22%3A%22Ihiawakrim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cristina%22%2C%22lastName%22%3A%22Blanco-Andujar%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Simona%22%2C%22lastName%22%3A%22Moldovan%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ovidiu%22%2C%22lastName%22%3A%22Ersen%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Mertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22Iron%20oxide%20nanoparticles%20are%20widely%20used%20as%20a%20contrast%20agent%20in%20magnetic%20resonance%20imaging%20%28MRI%29%2C%20and%20may%20be%20used%20as%20therapeutic%20agent%20for%20magnetic%20hyperthermia%20if%20they%20display%20in%20particular%20high%20magnetic%20anisotropy.%20Considering%20the%20effect%20of%20nanoparticles%20shape%20on%20anisotropy%2C%20a%20reproducible%20shape%20control%20of%20nanoparticles%20is%20a%20current%20synthesis%20challenge.%20By%20investigating%20reaction%20parameters%2C%20such%20as%20the%20iron%20precursor%20structure%2C%20its%20water%20content%2C%20but%20also%20the%20amount%20of%20the%20surfactant%20%28sodium%20oleate%29%20reported%20to%20control%20the%20shape%2C%20iron%20oxide%20nanoparticles%20with%20different%20shape%20and%20composition%20were%20obtained%2C%20in%20particular%2C%20iron%20oxide%20nanoplates.%20The%20effect%20of%20the%20surfactant%20coming%20from%20precursor%20was%20taking%20into%20account%20by%20using%20in%20house%20iron%20stearates%20bearing%20either%20two%20or%20three%20stearate%20chains%20and%20the%20negative%20effect%20of%20water%20on%20shape%20was%20confirmed%20by%20considering%20these%20precursors%20after%20their%20dehydration.%20Iron%20stearates%20with%20three%20chains%20in%20presence%20of%20a%20ratio%20sodium%20oleate%5C%2Foleic%20acid%201%3A1%20led%20mainly%20to%20nanocubes%20presenting%20a%20core-shell%20Fe1-xO%40Fe3-xO4%20composition.%20Nanocubes%20with%20straight%20faces%20were%20only%20obtained%20with%20dehydrated%20precursors.%20Meanwhile%2C%20iron%20stearates%20with%20two%20chains%20led%20preferentially%20to%20the%20formation%20of%20nanoplates%20with%20a%20ratio%20sodium%20oleate%5C%2Foleic%20acid%204%3A1.%20The%20rarely%20reported%20flat%20shape%20of%20the%20plates%20was%20confirmed%20with%203D%20transmission%20electronic%20microscopy%20%28TEM%29%20tomography.%20The%20investigation%20of%20the%20synthesis%20mechanisms%20confirmed%20the%20major%20role%20of%20chelating%20ligand%20and%20of%20the%20heating%20rate%20to%20drive%20the%20cubic%20shape%20of%20nanoparticles%20and%20showed%20that%20the%20nanoplate%20formation%20would%20depend%20mainly%20on%20the%20nucleation%20step%20and%20possibly%20on%20the%20presence%20of%20a%20given%20ratio%20of%20oleic%20acid%20and%20chelating%20ligand%20%28oleate%20and%5C%2For%20stearate%29.%22%2C%22date%22%3A%222018%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.3390%5C%2Fnano8110881%22%2C%22ISSN%22%3A%222079-4991%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.3390%5C%2Fnano8110881%22%2C%22collections%22%3A%5B%22DEB5KWFS%22%2C%22WJDNKBGA%22%2C%226739WBV7%22%2C%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222021-10-20T12%3A54%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22JI6YKCJ2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Cotin%20et%20al.%22%2C%22parsedDate%22%3A%222020%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EG.%20Cotin%2C%20F.%20Perton%2C%20C.%20Petit%2C%20S.%20Sall%2C%20C.%20Kiefer%2C%20V.%20Begin%2C%20B.%20Pichon%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20D.%20Mertz%2C%20J.-M.%20Greneche%2C%20S.%20B%26%23xE9%3Bgin-Colin%2C%20Harnessing%20Composition%20of%20Iron%20Oxide%20Nanoparticle%3A%20Impact%20of%20Solvent-Mediated%20Ligand-Ligand%20Interaction%20and%20Competition%20between%20Oxidation%20and%20Growth%20Kinetics%2C%20Chemistry%20of%20Materials%2032%20%282020%29%209245%26%23x2013%3B9259.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.0c03041%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.chemmater.0c03041%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Harnessing%20Composition%20of%20Iron%20Oxide%20Nanoparticle%3A%20Impact%20of%20Solvent-Mediated%20Ligand-Ligand%20Interaction%20and%20Competition%20between%20Oxidation%20and%20Growth%20Kinetics%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Geoffrey%22%2C%22lastName%22%3A%22Cotin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francis%22%2C%22lastName%22%3A%22Perton%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Corinne%22%2C%22lastName%22%3A%22Petit%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Secou%22%2C%22lastName%22%3A%22Sall%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Celine%22%2C%22lastName%22%3A%22Kiefer%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Valentin%22%2C%22lastName%22%3A%22Begin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Benoit%22%2C%22lastName%22%3A%22Pichon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Damien%22%2C%22lastName%22%3A%22Mertz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jean-Marc%22%2C%22lastName%22%3A%22Greneche%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Sylvie%22%2C%22lastName%22%3A%22B%5Cu00e9gin-Colin%22%7D%5D%2C%22abstractNote%22%3A%22The%20composition%20of%20metal%20oxide%20nanoparticles%20is%20of%20great%20importance%20for%20their%20applications%20because%20defects%20and%5C%2For%20deviation%20from%20stoichiometry%20strongly%20affect%20their%20physical%20properties.%20We%20report%20here%20on%20the%20crucial%20role%20of%20synthesis%20parameters%20such%20as%20solvent%2C%20ligand%2C%20and%20iron%20precursors%20on%20the%20composition%20of%20spinel%20iron%20oxide%20nanoparticles%20synthesized%20by%20the%20thermal%20decomposition%20method.%20At%20first%2C%20the%20investigation%20of%20the%20thermal%20decomposition%20of%20iron%20stearates%20bearing%20either%20two%20or%20three%20stearate%20chains%20by%20thermogravimetric%20analysis%2C%20infrared%20spectroscopy%2C%20and%20Mossbauer%20spectrometry%20as%20a%20function%20of%20temperature%20and%20syntheses%20with%20only%20oleic%20acid%20and%20iron%20stearate%20confirmed%20that%20the%20composition%20of%20the%20first%20nuclei%20is%20wustite%20Fe1-xO.%20The%20synthesis%20of%20nanoparticles%20with%20high%20sizes%20requires%20the%20use%20of%20very%20high%20boiling%20point%20solvents%20to%20ensure%20an%20effective%20growth%20step.%20We%20observed%20that%20when%20the%20grain%20growth%20and%20oxidation%20kinetics%20are%20similar%2C%20nanoparticles%20with%20a%20spinel%20composition%20and%20no%20defects%20are%20produced.%20An%20oxidation%20rate%20slower%20than%20the%20nuclei%20growth%20rate%20favors%20the%20formation%20of%20core-shell%20Fe1-xO%40Fe3-xO4%20NPs.%20The%20oxidation%20kinetics%20is%20shown%20to%20be%20influenced%20by%20surfactant%20and%20solvent%20natures.%20Indeed%2C%20surfactants%20such%20as%20oleic%20acid%20form%20a%20dense%20monolayer%20at%20the%20nuclei%20surface%2C%20and%20oxidation%20kinetics%20will%20depend%20on%20this%20monolayer%20permeability.%20Temperature%2C%20solvents%20with%20high%20surfactant%20affinity%2C%20deprotonated%20surfactants%2C%20or%20decomposition%20products%20of%20solvents%20affect%20the%20monolayer%20stability%20and%20thus%20the%20nanoparticle%20composition.%20The%20solvents%27%20nature%20and%20solvent-mediated%20ligand-ligand%20interactions%20are%20thus%20evidenced%20to%20be%20important%20parameters%20to%20control%20the%20formation%20of%20defect-free%20and%20stoichiometric%20oxide%20nanoparticles.%22%2C%22date%22%3A%222020%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.chemmater.0c03041%22%2C%22ISSN%22%3A%220897-4756%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1021%5C%2Facs.chemmater.0c03041%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%2C%22UBUT97QT%22%5D%2C%22dateModified%22%3A%222021-09-06T12%3A41%3A26Z%22%7D%7D%2C%7B%22key%22%3A%22G4CJ7PP2%22%2C%22library%22%3A%7B%22id%22%3A1839302%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Corredor%20et%20al.%22%2C%22parsedDate%22%3A%222022%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%3Cdiv%20class%3D%5C%22csl-bib-body%5C%22%20style%3D%5C%22line-height%3A%201.35%3B%20%5C%22%3E%5Cn%20%20%3Cdiv%20class%3D%5C%22csl-entry%5C%22%20style%3D%5C%22clear%3A%20left%3B%20%5C%22%3E%5Cn%20%20%20%20%3Cdiv%20class%3D%5C%22csl-left-margin%5C%22%20style%3D%5C%22float%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%5C%22%3E%5B1%5D%3C%5C%2Fdiv%3E%3Cdiv%20class%3D%5C%22csl-right-inline%5C%22%20style%3D%5C%22margin%3A%200%20.4em%200%201.5em%3B%5C%22%3EA.P.%20Corredor%2C%20L.%20Wendling%2C%20D.%20Preziosi%2C%20L.%20Schlur%2C%20C.%20Leuvrey%2C%20D.%20Thiaudiere%2C%20E.%20Elklaim%2C%20N.%20Blanc%2C%20S.%20Grenier%2C%20F.%20Roulland%2C%20N.%20Viart%2C%20C.%20Lef%26%23xE8%3Bvre%2C%20Oxygen%20crystallographic%20positions%20in%20thin%20films%20by%20non-destructive%20resonant%20elastic%20X-ray%20scattering%2C%20Journal%20of%20Applied%20Crystallography%2055%20%282022%29%20526%26%23x2013%3B532.%20%3Ca%20href%3D%27https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576722003673%27%3Ehttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1107%5C%2FS1600576722003673%3C%5C%2Fa%3E.%3C%5C%2Fdiv%3E%5Cn%20%20%3C%5C%2Fdiv%3E%5Cn%3C%5C%2Fdiv%3E%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Oxygen%20crystallographic%20positions%20in%20thin%20films%20by%20non-destructive%20resonant%20elastic%20X-ray%20scattering%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Antonio%20Pena%22%2C%22lastName%22%3A%22Corredor%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurianne%22%2C%22lastName%22%3A%22Wendling%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Daniele%22%2C%22lastName%22%3A%22Preziosi%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Laurent%22%2C%22lastName%22%3A%22Schlur%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Cedric%22%2C%22lastName%22%3A%22Leuvrey%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dominique%22%2C%22lastName%22%3A%22Thiaudiere%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Erik%22%2C%22lastName%22%3A%22Elklaim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nils%22%2C%22lastName%22%3A%22Blanc%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Stephane%22%2C%22lastName%22%3A%22Grenier%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Francois%22%2C%22lastName%22%3A%22Roulland%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Nathalie%22%2C%22lastName%22%3A%22Viart%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Christophe%22%2C%22lastName%22%3A%22Lef%5Cu00e8vre%22%7D%5D%2C%22abstractNote%22%3A%22Precisely%20locating%20oxygen%20atoms%20in%20nanosized%20systems%20is%20a%20real%20challenge.%20The%20traditional%20strategies%20used%20for%20bulk%20samples%20fail%20at%20probing%20samples%20with%20much%20less%20matter.%20Resonant%20elastic%20X-ray%20scattering%20%28REXS%29%20experiments%20in%20the%20X-ray%20absorption%20near-edge%20structure%20%28XANES%29%20domain%20have%20already%20proved%20their%20efficiency%20in%20probing%20transition%20metal%20cations%20in%20thin%20films%2C%20but%20it%20is%20not%20feasible%20to%20perform%20such%20experiments%20at%20the%20low-energy%20edges%20of%20lighter%20atoms%20-%20such%20as%20oxygen.%20In%20this%20study%2C%20the%20adequacy%20of%20using%20REXS%20in%20the%20extended%20X-ray%20absorption%20fine%20structure%20%28EXAFS%29%20domain%2C%20also%20known%20as%20extended%20diffraction%20absorption%20fine%20structure%20%28EDAFS%29%2C%20to%20solve%20this%20issue%20is%20shown.%20The%20technique%20has%20been%20validated%20on%20a%20bulk%20FeV2O4%20sample%2C%20through%20comparison%20with%20results%20obtained%20with%20conventional%20X-ray%20diffraction%20measurements.%20Subsequently%2C%20the%20positions%20of%20oxygen%20atoms%20in%20a%20thin%20film%20were%20unveiled%20by%20using%20the%20same%20strategy.%20The%20approach%20described%20in%20this%20study%20can%20henceforth%20be%20applied%20to%20solve%20the%20crystallographic%20structure%20of%20oxides%2C%20and%20will%20help%20in%20better%20understanding%20the%20properties%20and%20functionalities%20which%20are%20dictated%20by%20the%20positions%20of%20the%20oxygen%20atoms%20in%20functional%20nanosized%20materials.%22%2C%22date%22%3A%222022%22%2C%22language%22%3A%22English%22%2C%22DOI%22%3A%2210.1107%5C%2FS1600576722003673%22%2C%22ISSN%22%3A%221600-5767%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fdx.doi.org%5C%2F10.1107%5C%2FS1600576722003673%22%2C%22collections%22%3A%5B%226IWM732K%22%2C%22CF4ZI7HM%22%2C%22SB8Q592R%22%5D%2C%22dateModified%22%3A%222022-07-21T09%3A00%3A56Z%22%7D%7D%5D%7D
[1]
J. Werckmann, J. Cypriano, C.T. Lefèvre, K. Dembele, O. Ersen, D.A. Bazylinski, U. Lins, M. Farina, Localized iron accumulation precedes nucleation and growth of magnetite crystals in magnetotactic bacteria, Scientific Reports 7 (2017) 8291. https://doi.org/10.1038/s41598-017-08994-9.
[1]
A. Walter, C. Billotey, A. Garofalo, C. Ulhaq-Bouillet, C. Lefèvre, J. Taleb, S. Laurent, L. Vander Elst, R.N. Muller, L. Lartigue, F. Gazeau, D. Felder-Flesch, S. Bégin-Colin, Mastering the Shape and Composition of Dendronized Iron Oxide Nanoparticles To Tailor Magnetic Resonance Imaging and Hyperthermia, Chemistry of Materials 26 (2014) 5252–5264. https://doi.org/10.1021/cm5019025.
[1]
L. Valenzuela, F.-B. Yimbou, A. Ewin, C. Lefèvre, R. Manzorro, N. Keller, Ru-modified graphitic carbon nitride for the solar light-driven photocatalytic H2O2 synthesis, Catalysis Today 441 (2024) 114881. https://doi.org/10.1016/j.cattod.2024.114881.
[1]
A. Thomasson, F. Ibrahim, C. Lefèvre, E. Autissier, F. Roulland, C. Mény, C. Leuvrey, S. Choi, W. Jo, O. Crégut, G. Versini, S. Barre, M. Alouani, N. Viart, Effects of iron concentration and cationic site disorder on the optical properties of magnetoelectric gallium ferrite thin films, RSC Advances 3 (2013) 3124–3130. https://doi.org/10.1039/c2ra22681b.
[1]
A. Thomasson, S. Cherifi, C. Lefèvre, F. Roulland, B. Gautier, D. Albertini, C. Mény, N. Viart, Room temperature multiferroicity in Ga0.6Fe1.4O3:Mg thin films, Journal of Applied Physics 113 (2013) 214101. https://doi.org/10.1063/1.4808349.
[1]
A. Thomasson, J. Kreisel, C. Lefèvre, F. Roulland, G. Versini, S. Barre, N. Viart, Raman scattering of magnetoelectric gallium ferrite thin films, Journal of Physics-Condensed Matter 25 (2013) 045401. https://doi.org/10.1088/0953-8984/25/4/045401.
[1]
E. Soszka, M. Jedrzejczyk, C. Lefèvre, D. Ihiawakrim, N. Keller, A.M. Ruppert, TiO2-supported Co catalysts for the hydrogenation of gamma-valerolactone to 2-methyltetrahydrofuran: influence of the support, Catalysis Science & Technology Early Access (2022). https://doi.org/10.1039/d2cy01044e.
[1]
K. Sartori, D. Ihiawakrim, C. Lefèvre, S. Reguer, C. Mocuta, S. Bégin-Colin, F. Choueikani, B.P. Pichon, A detailed investigation of the core@shell structure of exchanged coupled magnetic nanoparticles after performing solvent annealing, Materials Advances Early access (2022). https://doi.org/10.1039/d2ma00629d.
[1]
G.D. Salian, B.M. Koo, C. Lefèvre, T. Cottineau, C. Lebouin, A.T. Tesfaye, P. Knauth, V. Keller, T. Djenizian, Niobium Alloying of Self-Organized TiO2 Nanotubes as an Anode for Lithium-Ion Microbatteries, Advanced Materials Technologies 3 (2018) 1700274. https://doi.org/10.1002/admt.201700274.
[1]
F. Roulland, G. Roseau, A.P. Corredor, L. Wendling, G. Krieger, C. Lefèvre, M. Trassin, G. Pourroy, N. Viart, Promoting the magnetic exchanges in PLD deposited strained films of FeV2O4 thin films, Materials Chemistry and Physics 276 (2022) 125360. https://doi.org/10.1016/j.matchemphys.2021.125360.
[1]
F. Roulland, C. Lefèvre, A. Thomasson, N. Viart, Study of Ga(2-x)FexO3 solid solution: Optimisation of the ceramic processing, in: Journal of the European Ceramic Society, 2013: pp. 1029–1035. https://doi.org/10.1016/j.jeurceramsoc.2012.11.014.
[1]
Z. Raolison, Q. Clement, A.-L. Adenot-Engelvin, N. Mallejac, C. Lefèvre, G. Pourroy, F. Boust, N. Vukadinovic, Broadband Permeability Spectra of Flake-Shaped Ferromagnetic Particle Composites, in: IEEE Transactions on Magnetics, 2017: p. 2801704. https://doi.org/10.1109/TMAG.2017.2735943.
[1]
Z. Raolison, C. Lefèvre, J. Neige, A.-L. Adenot-Engelvin, J.M. Greneche, N. Vukadinovic, G. Pourroy, Structural and microwave properties of silica-coated NiFeMo flakes/polymer composites, Materials Research Express 2 (2015) 026101. https://doi.org/10.1088/2053-1591/2/2/026101.
[1]
Z. Raolison, C. Lefèvre, J. Neige, A.L. Adenot-Engelvin, G. Pourroy, N. Vukadinovic, Preparation and Microwave Properties of Silica Coated Ni-Fe-Mo Flakes Composites, in: IEEE Transactions on Magnetics, 2013: pp. 986–989. https://doi.org/10.1109/tmag.2012.2225025.
[1]
D. Preziosi, S. Homkar, C. Lefèvre, M. Salluzzo, N. Viart, Unusual anisotropic magnetic orbital moment obtained from x-ray magnetic circular dichroism in a multiferroic oxide system, Physical Review B 103 (2021) 184420. https://doi.org/10.1103/PhysRevB.103.184420.
[1]
B.P. Pichon, O. Gerber, C. Lefèvre, I. Florea, S. Fleutot, W. Baaziz, M. Pauly, M. Ohlmann, C. Ulhaq, O. Ersen, V. Pierron-Bohnes, P. Panissod, M. Drillon, S. Bégin-Colin, Microstructural and Magnetic Investigations of Wüstite-Spinel Core-Shell Cubic-Shaped Nanoparticles, Chemistry of Materials 23 (2011) 2886–2900. https://doi.org/10.1021/cm2003319.
[1]
A. Pena Corredor, M. Gamarde, L. El Khabchi, M.J.V. Bernardez, M. Lenertz, C. Leuvrey, L. Schlur, F. Roulland, N. Viart, C. Lefèvre, Room-temperature magnetism and controlled cation distribution in vanadium ferrite thin films, Materials Chemistry and Physics 314 (2024) 128856. https://doi.org/10.1016/j.matchemphys.2023.128856.
[1]
A. Pena Corredor, N. Viart, C. Lefèvre, inserexs: reflection choice software for resonant elastic X-ray scattering., Journal of Applied Crystallography 56 (2023) 854–859. https://doi.org/10.1107/S1600576723002212.
[1]
S.H. Oh, R.H. Shin, C. Lefèvre, A. Thomasson, F. Roulland, Y. Shin, D.-H. Kim, J.-Y. Kim, A. Demchenko, C. Leuvrey, C. Mény, W. Jo, N. Viart, Incorporation of cobalt ions into magnetoelectric gallium ferrite epitaxial films: tuning of conductivity and magnetization, RSC Advances 5 (2015) 34265–34271. https://doi.org/10.1039/c5ra03609g.
[1]
E. Miyako, B.P. Pichon, C. Menard-Moyon, I.A. Vacchi, C. Lefèvre, S. Bégin-Colin, A. Bianco, Design, synthesis, characterization and properties of magnetic nanoparticle-nanocarbon hybrids, Carbon 96 (2016) 49–56. https://doi.org/10.1016/j.carbon.2015.09.045.
[1]
B. Meunier, S. Homkar, F. Choueikani, M.G. Silly, C. Lefèvre, F. Roulland, C. Leuvrey, J. Robert, D. Preziosi, N. Viart, Nonmonotonous temperature fluctuations of the orbital moment and spin-orbit coupling in multiferroic gallium ferrite thin films, Physical Review B 106 (2022) 184410. https://doi.org/10.1103/PhysRevB.106.184410.
[1]
E. Martin, F. Roulland, S. Grenier, F. Appert, J. Juraszek, M. Trassin, C. Bouillet, E. Chikoidze, C. Arnold, B. Berini, Y. Dumont, S. Colis, S. Barre, G. Versini, D. Preziosi, C. Leuvrey, N. Blanc, N. Boudet, G. Pourroy, N. Viart, C. Lefèvre, Non-auxeticiauxetic transitions inducing modifications of the magnetic anisotropy in CoFe2O4 thin films, Journal of Alloys and Compounds 836 (2020) 155425. https://doi.org/10.1016/j.jallcom.2020.155425.
[1]
X. Liu, B.P. Pichon, C. Ulhaq, C. Lefèvre, J.-M. Greneche, D. Begin, S. Bégin-Colin, Systematic Study of Exchange Coupling in Core Shell Fe3-delta O4@CoO Nanoparticles, Chemistry of Materials 27 (2015) 4073–4081. https://doi.org/10.1021/acs.chemmater.5b01103.
[1]
C. Lefèvre, A. Demchenko, C. Bouillet, M. Luysberg, X. Devaux, F. Roulland, G. Versini, S. Barre, Y. Wakabayashi, N. Boudet, C. Leuvrey, M. Acosta, C. Mény, E. Martin, S. Grenier, V. Favre-Nicolin, N. Viart, Nondestructive Method for the Determination of the Electric Polarization Orientation in Thin Films: Illustration on Gallium Ferrite Thin Films, Small Methods 1 (2017) 1700234. https://doi.org/10.1002/smtd.201700234.
[1]
C. Lefèvre, A. Thomasson, F. Roulland, V. Favre-Nicolin, Y. Joly, Y. Wakabayashi, G. Versini, S. Barre, C. Leuvrey, A. Demchenko, N. Boudet, N. Viart, Determination of the cationic distribution in oxidic thin films by resonant X-ray diffraction: the magnetoelectric compound Ga$\sb 2$-$ıt x$Fe$\sb ıt x$O$\sb 3$, Journal of Applied Crystallography 49 (2016) 1308–1314. https://doi.org/10.1107/S1600576716010001.
[1]
C. Lefèvre, R.H. Shin, J.H. Lee, S.H. Oh, F. Roulland, A. Thomasson, E. Autissier, C. Mény, W. Jo, N. Viart, Reduced leakage currents and possible charge carriers tuning in Mg-doped Ga0.6Fe1.4O3 thin films, Applied Physics Letters 100 (2012) 262904 /p.1–4. https://doi.org/10.1063/1.4729872.
[1]
C. Lefèvre, F. Roulland, A. Thomasson, E. Autissier, C. Leuvrey, S. Barre, G. Versini, N. Viart, G. Pourroy, Stabilization of scandium rich spinel ferrite CoFe(2-x)Sc(x)O4 (x <= 1) in thin films, Journal of Solid State Chemistry 232 (2015) 118–122. https://doi.org/10.1016/j.jssc.2015.09.012.
[1]
C. Lefèvre, F. Roulland, A. Thomasson, C. Mény, F. Porcher, G. Andre, N. Viart, Magnetic and Polar Properties’ Optimization in the Magnetoelectric Ga2-xFexO3 Compounds, Journal of Physical Chemistry C 117 (2013) 14832–14839. https://doi.org/10.1021/jp403733b.
[1]
B. Kundys, F. Roulland, C. Lefèvre, C. Mény, A. Thomasson, N. Viart, Room temperature polarization in the ferrimagnetic Ga2-xFexO3 ceramics, Journal of the European Ceramic Society 35 (2015) 2277–2281. https://doi.org/10.1016/j.jeurceramsoc.2015.02.029.
[1]
S. Homkar, E. Martin, B. Meunier, A. Anadon-Barcelona, C. Bouillet, J. Gorchon, K. Dumesnil, C. Lefèvre, F. Roulland, O. Copie, D. Preziosi, S. Petit-Watelot, J.-C. Rojas-Sanchez, N. Viart, Spin Current Transport in Hybrid Pt/Multifunctional Magnetoelectric Ga0.6Fe1.4O3 Bilayers, ACS Applied Electronic Materials 3 (2021) 4433–4440. https://doi.org/10.1021/acsaelm.1c00586.
[1]
S. Homkar, D. Preziosi, X. Devaux, C. Bouillet, J. Nordlander, M. Trassin, F. Roulland, C. Lefèvre, G. Versini, S. Barre, C. Leuvrey, M. Lenertz, M. Fiebig, G. Pourroy, N. Viart, Ultrathin regime growth of atomically flat multiferroic gallium ferrite films with perpendicular magnetic anisotropy, Physical Review Materials 3 (2019) 124416. https://doi.org/10.1103/PhysRevMaterials.3.124416.
[1]
P. Guardia, S. Nitti, M.E. Materia, G. Pugliese, N. Yaacoub, J.-M. Greneche, C. Lefèvre, L. Manna, T. Pellegrino, Gold-iron oxide dimers for magnetic hyperthermia: the key role of chloride ions in the synthesis to boost the heating efficiency, Journal of Materials Chemistry B 5 (2017) 4587–4594. https://doi.org/10.1039/c7tb00968b.
[1]
P. Guardia, A. Riedinger, S. Nitti, G. Pugliese, S. Marras, A. Genovese, M.E. Materia, C. Lefèvre, L. Manna, T. Pellegrino, One pot synthesis of monodisperse water soluble iron oxide nanocrystals with high values of the specific absorption rate, Journal of Materials Chemistry B 2 (2014) 4426–4434. https://doi.org/10.1039/c4tb00061g.
[1]
J. Goetz, A. Nonat, A. Diallo, M. Sy, I. Sera, A. Lecointre, C. Lefèvre, C.F. Chan, K.-L. Wong, L.J. Charbonnière, Ultrabright Lanthanide Nanoparticles, ChemPlusChem 81 (2016) 526–534. https://doi.org/10.1002/cplu.201600007.
[1]
O. Gerber, B.P. Pichon, C. Ulhaq, J.-M. Greneche, C. Lefèvre, I. Florea, O. Ersen, D. Begin, S. Lemonnier, E. Barraud, S. Bégin-Colin, Low Oxidation State and Enhanced Magnetic Properties Induced by Raspberry Shaped Nanostructures of Iron Oxide, Journal of Physical Chemistry C 119 (2015) 24665–24673. https://doi.org/10.1021/acs.jpcc.5b08164.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Influence of the solid titanium source on the activity of La1_xTixFeO3 photo-CWPO catalysts under UV-A light, Catalysis Today 413–415 (2023) 113974. https://doi.org/10.1016/j.cattod.2022.12.005.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Ti- -Modified LaFeO3/beta-SiC Alveolar Foams as Immobilized Dual Catalysts with Combined Photo-Fenton and Photocatalytic Activity, ACS Applied Materials & Interfaces 12 (2020) 57025–57037. https://doi.org/10.1021/acsami.0c16647.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Synergy effect between photocatalysis and heterogeneous photo-Fenton catalysis on Ti-doped LaFeO3 perovskite for high efficiency light-assisted water treatment, Catalysis Science & Technology 10 (2020) 1299–1310. https://doi.org/10.1039/c9cy02269d.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Highly robust La1-xTixFeO3 dual catalyst with combined photocatalytic and photo-CWPO activity under visible light for 4-chlorophenol removal in Chock for water, Applied Catalysis B-Environmental 262 (2020) 118310. https://doi.org/10.1016/j.apcatb.2019.118310.
[1]
P. Garcia-Munoz, C. Lefèvre, D. Robert, N. Keller, Ti-substituted LaFeO3 perovskite as photoassisted CWPO catalyst for water treatment, Applied Catalysis B-Environmental 248 (2019) 120–128. https://doi.org/10.1016/j.apcatb.2019.02.030.
[1]
A. Demchenko, S. Homkar, C. Bouillet, C.T. Lefèvre, F. Roulland, D. Preziosi, G. Versini, C. Leuvrey, P. Boullay, X. Devaux, N. Viart, Unveiling unconventional ferroelectric switching in multiferroic Ga-0.6 Fe1.4O3 thin films through multiscale electron microscopy investigations, Acta Materialia 240 (2022) 118337. https://doi.org/10.1016/j.actamat.2022.118337.
[1]
A. Demchenko, Y. Chang, E. Chikoidze, B. Berini, C. Lefèvre, F. Roulland, C. Ulhaq-Bouillet, G. Versini, S. Barre, C. Leuvrey, V. Favre-Nicolin, N. Boudet, S. Zafeiratos, Y. Dumont, N. Viart, Tuning the conductivity type in a room temperature magnetic oxide: Ni-doped Ga0.6Fe1.4O3 thin films, RSC Advances 6 (2016) 28248–28256. https://doi.org/10.1039/c6ra01540a.
[1]
B. de Tymowski, Y. Liu, C. Mény, C. Lefèvre, D. Begin, P. Nguyen, C. Pham, D. Edouard, F. Luck, C. Pham-Huu, Co-Ru/SiC impregnated with ethanol as an effective catalyst for the Fischer-Tropsch synthesis, Applied Catalysis A-General 419 (2012) 31–40. https://doi.org/10.1016/j.apcata.2012.01.004.
[1]
M. Darcheville, A.-L. Adenot-Engelvin, C. Boscher, J.-M. Greneche, C.T. Lefèvre, J. Robert, O. Ersen, J.M.G. Calbet, M.L.R. Gonzalez, A. Thiaville, C. Sanchez, Magnetism of Iron Oxide Nanoparticles: From Atomic Order to Complexity at the Mesoscopic Scale, Physica Status Solidi-Rapid Research Letters Early access (2024) 2400059. https://doi.org/10.1002/pssr.202400059.
[1]
M. Darcheville, A.-L. Adenot-Engelvin, C. Boscher, N. Vukadinovic, C. Lefèvre, A. Thiaville, C. Sanchez, Evidence of the Superparamagnetic State in the Zero-Field Microwave Susceptibility Spectra of Ferrimagnetic Nanoparticles, IEEE Magnetics Letters 11 (2020) 6105305. https://doi.org/10.1109/LMAG.2020.3026228.
[1]
G. Cotin, C. Kiefer, F. Perton, D. Ihiawakrim, C. Blanco-Andujar, S. Moldovan, C. Lefèvre, O. Ersen, B. Pichon, D. Mertz, S. Bégin-Colin, Unravelling the Thermal Decomposition Parameters for The Synthesis of Anisotropic Iron Oxide Nanoparticles, Nanomaterials 8 (2018) 881. https://doi.org/10.3390/nano8110881.
[1]
G. Cotin, F. Perton, C. Petit, S. Sall, C. Kiefer, V. Begin, B. Pichon, C. Lefèvre, D. Mertz, J.-M. Greneche, S. Bégin-Colin, Harnessing Composition of Iron Oxide Nanoparticle: Impact of Solvent-Mediated Ligand-Ligand Interaction and Competition between Oxidation and Growth Kinetics, Chemistry of Materials 32 (2020) 9245–9259. https://doi.org/10.1021/acs.chemmater.0c03041.
[1]
A.P. Corredor, L. Wendling, D. Preziosi, L. Schlur, C. Leuvrey, D. Thiaudiere, E. Elklaim, N. Blanc, S. Grenier, F. Roulland, N. Viart, C. Lefèvre, Oxygen crystallographic positions in thin films by non-destructive resonant elastic X-ray scattering, Journal of Applied Crystallography 55 (2022) 526–532. https://doi.org/10.1107/S1600576722003673.