Matériaux moléculaires fonctionnels

L’activité de l’équipe porte sur le développement des systèmes moléculaires présentant notamment des propriétés de fluorescence ou de transport de charge pour des applications variées telles que les diodes laser, le photovoltaïque, les détecteurs de neutrons… Une attention toute particulière est portée sur le contrôle de l’organisation de ces systèmes moléculaires qui peuvent être liquides, mésomorphes ou monocristallins. Outre la conception et la synthèse de ces systèmes moléculaires, l’équipe s’intéresse également à l’étude des propriétés photophysiques.

Les activités

Liquides moléculaires pi-conjugués

Photophysique et photonique pour l’électronique organique

Matériaux ioniques luminescents

Matériaux pi-conjugués auto-organisés

Le personnel

Doctorant, Matériaux Organiques (DMO)romain.berthiot@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 57Bureau: 2036
Doctorant, Matériaux Organiques (DMO)lilian.colin@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 62Bureau: 2041
Chargé de Recherche, Matériaux Organiques (DMO)anthony.daleo@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 47Bureau: 2033
Voir la page personnelle
Doctorant, Matériaux Organiques (DMO)nicolas.delgiudice@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 57Bureau: 2036
Voir la page personnelle
Professeur, Matériaux Organiques (DMO)Laurent.Douce@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 07Bureau: 2028
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Maîtresse de conférences, Matériaux Organiques (DMO)Isabelle.Kraus@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 46Bureau: 2025
Chargé de Recherche, Matériaux Organiques (DMO)Stephane.Mery@ipcms.unistra.fr
Tél: +33(0)3 88 10 71 45Bureau: 2044
Voir la page personnelle
Doctorant, Matériaux Organiques (DMO)guillaume.michaluszko@ipcms.unistra.fr
Tél: +33(0)3 88 10 70 91Bureau: 1030
Doctorante, Matériaux Organiques (DMO)yamini.sharma@ipcms.unistra.fr
Tél: +33(0)3 88 10 70 91Bureau: 1030

Les publications récentes

[1]
X. Zhu, C. Hessin, A. Salame, L. Sosa-Vargas, D. Kreher, C. Adachi, A. Proust, P. Mialane, J. Marrot, A. Bouchet, M. Sliwa, S. Méry, B. Heinrich, F. Mathevet, G. Izzet, Photoactive Organic/Inorganic Hybrid Materials with Nanosegregated Donor-Acceptor Arrays, Angewandte Chemie-International Edition 60 (2021) 8419–8424. https://doi.org/10.1002/anie.202014319.
[1]
E. Zaborova, P. Chavez, R. Bechara, P. Leveque, T. Heiser, S. Méry, N. Leclerc, Thiazole as a weak electron-donor unit to lower the frontier orbital energy levels of donor-acceptor alternating conjugated materials, Chemical Communications 49 (2013) 9938–9940. https://doi.org/10.1039/c3cc45481a.
[1]
W. Yu, C.A. Serra, I.U. Khan, M. Er-Rafik, M. Schmutz, I. Kraus, S. Ding, L. Zhang, M. Bouquey, R. Muller, Development of an Elongational-Flow Microprocess for the Production of Size-Controlled Nanoemulsions: Application to the Preparation of Monodispersed Polymer Nanoparticles and Composite Polymeric Microparticles, Macromolecular Reaction Engineering 11 (2017) 1600025. https://doi.org/10.1002/mren.201600025.
[1]
W. Yu, N. Visaveliya, C.A. Serra, J.M. Köhler, S. Ding, M. Bouquey, R. Muller, M. Schmutz, I. Kraus, Preparation and Deep Characterization of Composite/Hybrid Multi-Scale and Multi-Domain Polymeric Microparticles, Materials 12 (2019) 3921. https://doi.org/10.3390/ma12233921.
[1]
J. Shaya, J.-C. Ribierre, G. Correia, Y.J. Dappe, F. Mathevet, L. Mager, B. Heinrich, S. Méry, Control of the Organization of 4,4’-bis(carbazole)-1,1’-biphenyl (CBP) Molecular Materials through Siloxane Functionalization., Molecules 28 (2023) 2038. https://doi.org/10.3390/molecules28052038.
[1]
J. Shaya, G. Correia, B. Heinrich, J.-C. Ribierre, K. Polychronopoulou, L. Mager, S. Méry, Functionalization of Biphenylcarbazole (CBP) with Siloxane-Hybrid Chains for Solvent-Free Liquid Materials, Molecules 27 (2022) 89. https://doi.org/10.3390/molecules27010089.
[1]
C.A. Serra, I.U. Khan, Z.Q. Chang, M. Bouquey, R. Muller, I. Kraus, M. Schmutz, T. Vandamme, N. Anton, C. Ohm, R. Zentel, A. Knauer, M. Kohler, Engineering Polymer Microparticles by Droplet Microfluidics, Journal of Flow Chemistry 3 (2013) 66–75. https://doi.org/10.1556/jfc-d-13-00014.
[1]
P.-O. Schwartz, F. Moingeon, J. Roeser, E. Couzigne, E. Voirin, P. Masson, S. Méry, Preparation of multi-allylic dendronized polymers via atom-transfer radical polymerization, European Polymer Journal 118 (2019) 358–364. https://doi.org/10.1016/j.eurpolymj.2019.06.009.
[1]
P.O. Schwartz, E. Zaborova, R. Bechara, P. Leveque, T. Heiser, S. Méry, N. Leclerc, Impact of the arrangement of functional moieties within small molecular systems for solution processable bulk heterojunction solar cells, New Journal of Chemistry 37 (2013) 2317–2323. https://doi.org/10.1039/c3nj00218g.
[1]
P.-O. Schwartz, L. Biniek, E. Zaborova, B. Heinrich, M. Brinkrnann, N. Leclerc, S. Méry, Perylenediimide-Based Donor-Acceptor Dyads and Triads: Impact of Molecular Architecture on Self-Assembling Properties, Journal of the American Chemical Society 136 (2014) 5981–5992. https://doi.org/10.1021/ja4129108.
[1]
T. Roland, G.H. Ramirez, J. Léonard, S. Méry, S. Haacke, Ultrafast broadband laser spectroscopy reveals energy and charge transfer in novel donor-acceptor triads for photovoltaic applications, in: Ye, C and Wang, ZL and Zhou, B (Ed.), Journal of Physics: Conference Series, 2011: p. 012006 /p. 1–6. https://doi.org/10.1088/1742-6596/276/1/012006.
[1]
T. Roland, J. Léonard, G.H. Ramirez, S. Méry, O. Yurchenko, S. Ludwigs, S. Haacke, Sub-100 fs charge transfer in a novel donor-acceptor-donor triad organized in a smectic film, Physical Chemistry Chemical Physics 14 (2012) 273–279. https://doi.org/10.1039/c1cp22122a.
[1]
J. Roeser, F. Moingeon, B. Heinrich, P. Masson, F. Arnaud-Neu, M. Rawiso, S. Méry, Dendronized Polymers with Peripheral Oligo(ethylene oxide) Chains: Thermoresponsive Behavior and Shape Anisotropy in Solution, Macromolecules 44 (2011) 8925–8935. https://doi.org/10.1021/ma2016776.
[1]
J. Roeser, B. Heinrich, C. Bourgogne, M. Rawiso, S. Michel, V. Hubscher-Bruder, F. Arnaud-Neu, S. Méry, Dendronized Polymers with Silver and Mercury Cations Recognition: Complexation Studies and Polyelectrolyte Behavior, Macromolecules (Washington, DC, U. S.) 46 (2013) 7075–7085. https://doi.org/10.1021/ma400348v.
[1]
J.-C. Ribierre, Z. Li, X. Liu, E. Lacaze, B. Heinrich, S. Méry, P. Sleczkowski, Y. Xiao, F. Lafolet, D. Hashizume, T. Aoyama, M. Uchiyama, J.W. Wu, E. Zaborova, F. Fages, A. D’Aleo, F. Mathevet, C. Adachi, A solvent-free and vacuum-free melt-processing method to fabricate organic semiconducting layers with large crystal size for organic electronic applications, J. Mater. Chem. C (2019). https://doi.org/10.1039/C8TC04834G.
[1]
J.-C. Ribierre, T. Tanaka, L. Zhao, Y. Yokota, S. Matsumoto, D. Hashizume, K. Takaishi, T. Muto, B. Heinrich, S. Méry, F. Mathevet, T. Matsushima, M. Uchiyama, C. Adachi, T. Aoyama, Simultaneous Edge-on to Face-on Reorientation and 1D Alignment of Small pi-Conjugated Molecules Using Room-Temperature Mechanical Rubbing, Advanced Functional Materials 28 (2018). https://doi.org/10.1002/adfm.201707038.
[1]
J.-C. Ribierre, L. Zhao, M. Inoue, P.-O. Schwartz, J.-H. Kim, K. Yoshida, A.S.D. Sandanayaka, H. Nakanotani, L. Mager, S. Méry, C. Adachi, Low threshold amplified spontaneous emission and ambipolar charge transport in non-volatile liquid fluorene derivatives, Chemical Communications 52 (2016) 3103–3106. https://doi.org/10.1039/c5cc08331a.
[1]
M. Polkehn, P. Eisenbrandt, H. Tamura, S. Haacke, S. Méry, I. Burghardt, Ultrafast excitonic and charge transfer dynamics in nanostructured organic polymer materials, in: Andrews, DL and Nunzi, JM and Ostendorf, A (Ed.), NANOPHOTONICS VI, SPIE-INT SOC OPTICAL ENGINEERING, 1000 20TH ST, PO BOX 10, BELLINGHAM, WA 98227-0010 USA, 2016. https://doi.org/10.1117/12.2230314.
[1]
M. Polkehn, H. Tamura, P. Eisenbrandt, S. Haacke, S. Méry, I. Burghardt, Molecular Packing Determines Charge Separation in a Liquid Crystalline Bisthiophene–Perylene Diimide Donor–Acceptor Material, Journal of Physical Chemistry Letters 7 (2016) 1327–1334. https://doi.org/10.1021/acs.jpclett.6b00277.
[1]
T. Olla, R. Jabbour, A. Labiod, O. Boyron, S. Méry, B. Heinrich, T. Heiser, D. Jacquemin, P. Leveque, A. Lesage, N. Leclerc, How Halogenation Impacts the Polymer Backbone Conformation: Learning from Combination of Solid-State MAS NMR and X-Ray Scattering, Advanced Functional Materials 32 (2022) 2204929. https://doi.org/10.1002/adfm.202204929.
[1]
T. Olla, O.A. Ibraikulov, S. Ferry, O. Boyron, S. Méry, B. Heinrich, T. Heiser, P. Lévêque, N. Leclerc, Benzothiadiazole Halogenation Impact in Conjugated Polymers, a Comprehensive Study, Macromolecules 52 (2019) 8006–8016. https://doi.org/10.1021/acs.macromol.9b01760.
[1]
S.T. Nestor, B. Heinrich, R.A. Sykora, X. Zhang, G.J. McManus, L. Douce, A. Mirjafari, Methimazolium-based ionic liquid crystals: Emergence of mesomorphic properties via a sulfur motif, Tetrahedron 73 (2017) 5456–5460. https://doi.org/https://doi.org/10.1016/j.tet.2017.07.056.
[1]
F. Mouillard, T. Ferté, E. Voirin, S. Méry, P. Masson, A. Carradò, Use of a Photocleavable Initiator to Characterize Polymer Chains Grafted onto a Metal Plate with the Grafting-from Method., Polymers 15 (2023) 1265. https://doi.org/10.3390/polym15051265.
[1]
S. Marzuk, B. Heinrich, P. Leveque, N. Leclerc, J. Khiari, S. Méry, Phthalocyanine-based dumbbell-shaped molecule: Synthesis, structure and charge transport studies, Dyes and Pigments 154 (2018) 282–289. https://doi.org/10.1016/j.dyepig.2018.03.017.
[1]
S. Marzouk, A. Khalfallah, B. Heinrich, J.E. Khiari, A. Kriaa, S. Méry, Synthesis and mesomorphic properties of liquid crystals containing a perfluorinated segment via different linkers, Journal of Fluorine Chemistry 197 (2017) 15–23. https://doi.org/10.1016/j.jfluchem.2017.02.006.
[1]
C. Mahmoudi, I. Bulut, J. Jing, S. Fall, B. Heinrich, S. Méry, T. Heiser, P. Leveque, E. Steveler, M. Majdoub, N. Leclerc, Regioisomers of Organic Semiconducting Dumbbell-Shaped Molecules: Synthesis and Structure-Properties Relationship, European Journal of Organic Chemistry (2021) 3170–3177. https://doi.org/10.1002/ejoc.202100473.
[1]
L. Liu, P. Eisenbrandt, T. Roland, M. Polkehn, P.-O. Schwartz, K. Bruchlos, B. Omiecienski, S. Ludwigs, N. Leclerc, E. Zaborova, J. Léonard, S. Méry, I. Burghardt, S. Haacke, Controlling Charge Separation and Recombination by Chemical Design in Donor-Acceptor Dyads, Physical Chemistry Chemical Physics 18 (2016) 18536–18548. https://doi.org/10.1039/C6CP00644B.
[1]
K.J. Lee, J.H. Woo, Y. Xiao, E. Kim, L. Mazur, D. Kreher, A.-J. Attias, K. Matczyszyn, M. Samoc, B. Heinrich, S. Méry, F. Fages, L. Mager, A. D’Aleo, J.W. Wu, F. MATHEVET, P. Andre, J.-C. Ribierre, Structure-charge transfer property relationship in self-assembled discotic liquid-crystalline donor-acceptor dyad and triad thin films, RSC Advances 6 (2016) 57811–57819. https://doi.org/10.1039/C6RA08039A.
[1]
A. Labiod, O.A. Ibraikulov, S. Dabos-Seignon, S. Ferry, B. Heinrich, S. Méry, S. Fall, H.J.T. Nkuissi, T. Heiser, C. Cabanetos, N. Leclerc, P. Leveque, Photo-degradation in bulk heterojunction organic solar cells using a fullerene or a non-fullerene derivative electron acceptor, Organic Electronics 107 (2022) 106549. https://doi.org/10.1016/j.orgel.2022.106549.
[1]
M. L’Her, Y. Atoini, J. Fouchet, B. Heinrich, N. Del-Giudice, E. Scrafton, E. Bordes, L. Karmazin, L. Charbonniere, L. De Cola, L. Douce, Luminescent imidazolium-naphthalene salts in liquid and solid states (vol 43, pg 12529, 2019), New Journal of Chemistry 44 (2020) 2669. https://doi.org/10.1039/d0nj90011g.
[1]
M. L’Her, Y. Atoini, J. Fouchet, B. Heinrich, N. Del-Giudice, E. Scrafton, E. Bordes, L. Karmazin, L. Charboniere, L. De Cola, L. Douce, Luminescent imidazolium-naphthalene salts in liquid and solid states, New Journal of Chemistry 43 (2019) 12529–12532. https://doi.org/10.1039/c9nj02972a.
[1]
K.S. Kumar, N. Del Giudice, B. Heinrich, L. Douce, M. Ruben, Bistable spin-crossover in a new series of [Fe(BPP-R)(2)](2+) (BPP=2,6-bis(pyrazol-1-yl)pyridine; R = CN) complexes, Dalton Transactions 49 (2020) 14258–14267. https://doi.org/10.1039/d0dt02214d.
[1]
I. Kraus, S. Li, A. Knauer, M. Schmutz, J. Faerber, C.A. Serra, M. Kohler, Continuous-Microflow Synthesis and Morphological Characterization of Multiscale Composite Materials Based on Polymer Microparticles and Inorganic Nanoparticles, Journal of Flow Chemistry 4 (2014) 72–78. https://doi.org/10.1556/JFC-D-13-00029.
[1]
J.M. Köhler, A. März, J. Popp, A. Knauer, I. Kraus, J. Faerber, C. Serra, Polyacrylamid/Silver Composite Particles Produced via Microfluidic Photopolymerization for Single Particle-Based SERS Microsensorics, Analytical Chemistry 85 (2013) 313–318. https://doi.org/10.1021/ac302751t.
[1]
J.M. Köhler, I. Kraus, J. Faerber, C. Serra, Continuous-flow preparation of nanoporous metal/polymer composite particles by in situ synthesis of silver nanoparticles in photopolymerized acrylate/diethylene glycol droplets, Journal of Materials Science 48 (2013) 2158–2166. https://doi.org/10.1007/s10853-012-6991-0.
[1]
M. Kim, K.R. Choi, Y.U. Lee, B. Heinrich, S.Y. Ko, F. Mathevet, J.-C. Ribierre, A. D’Aleo, J.W. Wu, V. Placide, Natural Hyperbolic Dispersion with Anisotropic Epsilon-Near-Zero and Epsilon-Near-Pole in Squaraine Molecular Film, Advanced Optical Materials (2021) 2101091. https://doi.org/10.1002/adom.202101091.
[1]
I.U. Khan, C.A. Serra, N. Anton, M. Er-Rafik, C. Blanck, M. Schmutz, I. Kraus, N. Messaddeq, C. Sutter, H. Anton, A.S. Klymchenko, T.F. Vandamme, Microfluidic conceived Trojan microcarriers for oral delivery of nanoparticles, International Journal of Pharmaceutics 493 (2015) 7–15. https://doi.org/10.1016/j.ijpharm.2015.06.028.
[1]
I.U. Khan, C.A. Serra, N. Anton, X. Li, R. Akasov, N. Messaddeq, I. Kraus, T.F. Vandamme, Microfluidic conceived drug loaded Janus particles in side-by-side capillaries device, International Journal of Pharmaceutics 473 (2014) 239–249. https://doi.org/10.1016/j.ijpharm.2014.06.035.
[1]
N. Kamatham, O.A. Ibraikulov, P. Durand, J. Wang, O. Boyron, B. Heinrich, T. Heiser, P. Leveque, N. Leclerc, S. Méry, On the Impact of Linear Siloxanated Side Chains on the Molecular Self-Assembling and Charge Transport Properties of Conjugated Polymers, Advanced Functional Materials 31 (2021) 2007734. https://doi.org/10.1002/adfm.202007734.
[1]
J. Jing, E. Steveler, N. Leclerc, A. D’Aleo, B. Heinrich, W. Uhring, T. Heiser, Exciton lifetime in donor-acceptor-donor planar dumbbell-shaped triazatruxene-thienopyrroledione derivatives, in: S. Reineke, K. Vandewal, W. Maes (Eds.), ORGANIC ELECTRONICS AND PHOTONICS: FUNDAMENTALS AND DEVICES III, SPIE-INT SOC OPTICAL ENGINEERING, 2022. https://doi.org/10.1117/12.2615963.
[1]
J. Jing, B. Heinrich, A. Prel, E. Steveler, T. Han, I. Bulut, S. Méry, Y. Leroy, N. Leclerc, P. Leveque, M. Rosenthal, D.A. Ivanov, T. Heiser, Efficient 3D charge transport in planar triazatruxene-based dumbbell-shaped molecules forming a bridged columnar phase, Journal of Materials Chemistry A 9 (2021) 24315–24324. https://doi.org/10.1039/d1ta06300f.
[1]
Olzhas.A. Ibraikulov, J. Wang, N. Kamatham, B. Heinrich, S. Méry, M. Kohlstädt, U. Würfel, S. Ferry, N. Leclerc, T. Heiser, P. Lévêque, ITO-Free Organic Photovoltaic Modules Based on Fluorinated Polymers Deposited from Non-Halogenated Solution: A Major Step Toward Large-Scale Module Production, Solar RRL 3 (2019) 1900273. https://doi.org/10.1002/solr.201900273.
[1]
O.A. Ibraikulov, C. Ngov, P. Chavez, I. Bulut, B. Heinrich, O. Boyron, K.L. Gerasimov, D.A. Ivanov, S. Swaraj, S. Méry, N. Leclerc, P. Leveque, T. Heiser, Face-on orientation of fluorinated polymers conveyed by long alkyl chains: a prerequisite for high photovoltaic performances, Journal of Materials Chemistry A 6 (2018) 12038–12045. https://doi.org/10.1039/c8ta04127j.
[1]
C.T. Howells, K. Marbou, H. Kim, K.J. Lee, B. Heinrich, S.J. Kim, A. Nakao, T. Aoyama, S. Furukawa, J.-H. Kim, E. Kim, F. Mathevet, S. Méry, I.D.W. Samuel, A. Al Ghaferi, M.S. Dahlem, M. Uchiyama, S.Y. Kim, J.W. Wu, J.-C. Ribierre, C. Adachi, D.-W. Kim, P. Andre, Enhanced organic solar cells efficiency through electronic and electro-optic effects resulting from charge transfers in polymer hole transport blends, Journal of Materials Chemistry A 4 (2016) 4252–4263. https://doi.org/10.1039/c6ta00677a.
[1]
T. Han, I. Bulut, S. Méry, B. Heinrich, P. Leveque, N. Leclerc, T. Heiser, Improved structural order by side-chain engineering of organic small molecules for photovoltaic applications, Journal of Materials Chemistry C 5 (2017) 10794–10800. https://doi.org/10.1039/c7tc03155f.
[1]
B. Grévin, P.-O. Schwartz, L. Biniek, M. Brinkmann, N. Leclerc, E. Zaborova, S. Méry, High-resolution noncontact AFM and Kelvin probe force microscopy investigations of self-assembled photovoltaic donor–acceptor dyads, Beilstein Journal of Nanotechnology 7 (2016) 799–808. https://doi.org/10.3762/bjnano.7.71.
[1]
J. Fouchet, B. Heinrich, M. L’Her, E. Voirin, L. Karmazin, C. Bailly, R. Welter, A. Mirjafari, L. Douce, Heterogeneous microwave-assisted Ullmann type methodology for synthesis of rigid-core ionic liquid crystals, New Journal of Chemistry 42 (2018) 10421–10431. https://doi.org/10.1039/c8nj01609g.
[1]
C. Demangeat, Y. Tang, Y. Dou, S. Dale, J. Cielo, E. Kim, H.-J. Lee, A. D’Aleo, B. Hu, A.-J. Attias, Necessary and Sufficient Condition for Organic Room-Temperature Phosphorescence from Host-Guest Doped Crystalline Systems, Advanced Optical Materials 11 (2023) 2300289. https://doi.org/10.1002/adom.202300289.
[1]
E. Delahaye, Z. Xie, A. Schaefer, L. Douce, G. Rogez, P. Rabu, C. Guenter, J.S. Gutmann, A. Taubert, Intercalation synthesis of functional hybrid materials based on layered simple hydroxide hosts and ionic liquid guests - a pathway towards multifunctional ionogels without a silica matrix?, Dalton Transactions 40 (2011) 9977–9988. https://doi.org/10.1039/c1dt10841g.
[1]
N. Del Giudice, G. Voegeli, J.-M. Strub, B. Heinrich, L. Douce, Ionic Liquid Crystals Based on Loop-Shaped Copper(I) Complexes., Inorganic Chemistry 63 (2024) 6103–6110. https://doi.org/10.1021/acs.inorgchem.4c00728.

Photophysique et photonique pour l'électronique organique

Matériaux ioniques luminescents

Functional molecular liquids

Matériaux pi-conjugués auto-assemblés