INTRODUCTION
Si les premiers pas de l’électronique de spin se sont faits à partir de systèmes métalliques, c’est grâce aux oxydes que les dernières grandes avancées dans ce domaine ont été rendues possibles et ce sont encore les oxydes qui sont les plus prometteurs en termes de nouvelles fonctionnalités.
La structure cristalline des oxydes est souvent complexe et rend leur élaboration difficile, mais cette complexité, qui permet d’envisager des interactions entre spin, charge, moment orbital et réseau cristallin, rend possible une très grande modularité de leurs propriétés. Cela fait des oxydes un vaste champ d’étude dont on est encore bien loin d’avoir épuisé le potentiel, aussi bien en amont, côté élaboration, pour les chimistes des matériaux, qu’en aval, côté applications, pour les physiciens des systèmes. D’une manière générale, la recherche dans ce domaine a pour point de départ l’étude de composés déjà connus, leur élaboration sous forme de monocristaux ou films minces d’excellente qualité cristalline (par ablation laser pulsé ou par sputtering), la détermination de l’origine exacte de leurs propriétés, la modélisation théorique de ces propriétés, et enfin la proposition de pistes d’optimisation de ces propriétés. C’est par un aller-retour entre expérience (élaboration-propriétés) et théorie que de nouveaux matériaux répondant aux besoins des dispositifs pourront être créés.
ACTIVITES
Projets en cours:
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Magnetoelectric oxides for spin-orbitronics |
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FOXIES |
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Infinite-Cell |
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Laboratoire Commun de Recherche “MOLIERE” |
MOYENS EXPERIMENTAUX UTILISES
| • Elaboration | |
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Ablation laser pulsé |
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Pulvérisation cathodique |
| • Caractérisations | |
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Diffraction des rayons-X |
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Mesures Magnétiques |
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Mesures Electriques |
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Microscopie Electronique à Balayage (MEB) |
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Microscopie Electronique à Transmission (MET) |
| • Utilisation des Grands Instruments | |
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ESRF (D2am, ID32) |
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Soleil (Diffabs, Cristal, Deimos) |
Membres de l’équipe :
Publications récentes :
[1]
A. Anadon, E. Martin, S. Homkar, B. Meunier, M. Verges, H. Damas, J. Alegre, C. Lefèvre, F. Roulland, C. Dubs, M. Lindner, L. Pasquier, O. Copie, K. Dumesnil, R. Ramos, D. Preziosi, S. Petit-Watelot, N. Viart, J.-C. Rojas-Sanchez, Thermal Spin-Current Generation in the Multifunctional Ferrimagnet Ga0.6Fe1.4O3, Physical Review Applied. 18 (2022) 054087. https://doi.org/10.1103/PhysRevApplied.18.054087.
[1]
W. Belayachi, G. Ferblantier, T. Fix, G. Schmerber, J.-L. Rehspringer, T. Heiser, A. Slaoui, M. Abd-Lefdil, A. Dinia, SnO2 Films Elaborated by Radio Frequency Magnetron Sputtering as Potential Transparent Conducting Oxides Alternative for Organic Solar Cells, ACS Applied Energy Materials. 5 (2022) 170–177. https://doi.org/10.1021/acsaem.1c02711.
[1]
S. Bouzida, M. Battas, E.B. Benamar, G. Schmerber, A. Dinia, M. Abd-Lefdil, M. Regragui, Effect of volume of the solution and sulfurization on properties of Cu2ZnSnS4 thin films fabricated by spray assisted chemical vapour deposition method, Materials Research Innovations. 26 (2022) 127–133. https://doi.org/10.1080/14328917.2021.1904627.
[1]
Y. Chen, M. D’Antuono, N.B. Brookes, G.M. De Luca, R. Di Capua, E. Di Gennaro, G. Ghiringhelli, C. Piamonteze, D. Preziosi, B. Jouault, M. Cabero, J.M. Gonzalez-Calbet, C. Leon, J. Santamaria, A. Sambri, D. Stornaiuolo, M. Salluzzo, Ferromagnetic Quasi-Two-Dimensional Electron Gas with Trigonal Crystal Field Splitting, ACS Applied Electronic Materials. 4 (2022) 3226–3231. https://doi.org/10.1021/acsaelm.2c00447.
[1]
A.P. Corredor, L. Wendling, D. Preziosi, L. Schlur, C. Leuvrey, D. Thiaudiere, E. Elklaim, N. Blanc, S. Grenier, F. Roulland, N. Viart, C. Lefèvre, Oxygen crystallographic positions in thin films by non-destructive resonant elastic X-ray scattering, Journal of Applied Crystallography. 55 (2022) 526–532. https://doi.org/10.1107/S1600576722003673.
[1]
A. Demchenko, S. Homkar, C. Bouillet, C.T. Lefèvre, F. Roulland, D. Preziosi, G. Versini, C. Leuvrey, P. Boullay, X. Devaux, N. Viart, Unveiling unconventional ferroelectric switching in multiferroic Ga-0.6 Fe1.4O3 thin films through multiscale electron microscopy investigations, Acta Materialia. 240 (2022) 118337. https://doi.org/10.1016/j.actamat.2022.118337.
[1]
R. Di Capua, M. Verma, M. Radovic, V.N. Strocov, C. Piamonteze, E.B. Guedes, N.C. Plumb, Y. Chen, M. D’Antuono, G.M. De Luca, E. Di Gennaro, D. Stornaiuolo, D. Preziosi, B. Jouault, F.M. Granozio, A. Sambri, R. Pentcheva, G. Ghiringhelli, M. Salluzzo, Orbital selective switching of ferromagnetism in an oxide quasi two-dimensional electron gas, NPJ Quantum Materials. 7 (2022). https://doi.org/10.1038/s41535-022-00448-4.
[1]
V. Humbert, R. El Hage, G. Krieger, G. Sanchez-Santolino, A. Sander, S. Collin, J. Trastoy, J. Briatico, J. Santamaria, D. Preziosi, J.E. Villegas, An Oxygen Vacancy Memristor Ruled by Electron Correlations, Advanced Science. 9 (2022) 2201753. https://doi.org/https://doi.org/10.1002/advs.202201753.
[1]
G. Krieger, L. Martinelli, S. Zeng, L.E. Chow, K. Kummer, R. Arpaia, M. Moretti Sala, N.B. Brookes, A. Ariando, N. Viart, M. Salluzzo, G. Ghiringhelli, D. Preziosi, Charge and Spin Order Dichotomy in $\mathrmNdNiO_2$ Driven by the Capping Layer, Physical Review Letters. 129 (2022) 027002. https://doi.org/10.1103/PhysRevLett.129.027002.
[1]
B. Meunier, S. Homkar, F. Choueikani, M.G. Silly, C. Lefèvre, F. Roulland, C. Leuvrey, J. Robert, D. Preziosi, N. Viart, Nonmonotonous temperature fluctuations of the orbital moment and spin-orbit coupling in multiferroic gallium ferrite thin films, Physical Review B. 106 (2022) 184410. https://doi.org/10.1103/PhysRevB.106.184410.
[1]
Y. Qiu, X. Zhang, C. Usubelli, D. Mayer, C. Linder, J. Christensen, Understanding thermal and mechanical effects on lithium plating in lithium-ion batteries, Journal of Power Sources. 541 (2022) 231632. https://doi.org/10.1016/j.jpowsour.2022.231632.
[1]
F. Roulland, G. Roseau, A.P. Corredor, L. Wendling, G. Krieger, C. Lefèvre, M. Trassin, G. Pourroy, N. Viart, Promoting the magnetic exchanges in PLD deposited strained films of FeV2O4 thin films, Materials Chemistry and Physics. 276 (2022) 125360. https://doi.org/10.1016/j.matchemphys.2021.125360.
[1]
K. Sartori, D. Ihiawakrim, C. Lefèvre, S. Reguer, C. Mocuta, S. Bégin-Colin, F. Choueikani, B.P. Pichon, A detailed investigation of the core@shell structure of exchanged coupled magnetic nanoparticles after performing solvent annealing, Materials Advances. Early access (2022). https://doi.org/10.1039/d2ma00629d.
[1]
E. Soszka, M. Jedrzejczyk, C. Lefèvre, D. Ihiawakrim, N. Keller, A.M. Ruppert, TiO2-supported Co catalysts for the hydrogenation of gamma-valerolactone to 2-methyltetrahydrofuran: influence of the support, Catalysis Science & Technology. Early Access (2022). https://doi.org/10.1039/d2cy01044e.
[1]
I. Anefnaf, S. Aazou, G. Schmerber, A. Dinia, Z. Sekkat, Tailoring PEIE capped ZnO binary cathode for solution-processed inverted organic solar cells, Optical Materials. 116 (2021) 111070. https://doi.org/10.1016/j.optmat.2021.111070.
[1]
M.M. Besli, C. Usubelli, A. Subbaraman, F.R.P. Safaei, S. Bone, C. Johnston, G. Schneider, F. Beauchaud, N. Ravi, J. Christensen, M.M. Doeff, M. Metzger, S. Kuppan, Location-Dependent Cobalt Deposition in Smartphone Cells upon Long-Term Fast-Charging Visualized by Synchrotron X-ray Fluorescence, Chemistry of Materials. 33 (2021) 6318–6328. https://doi.org/10.1021/acs.chemmater.1c00847.
[1]
M.T. Camci, M. Pauly, C. Lefèvre, C. Bouillet, M. Maaloum, G. Decher, D. Martel, Polarization-dependent optical band gap energy of aligned semiconducting titanium oxide nanowire deposits, Nanoscale. 13 (2021) 8958–8965. https://doi.org/10.1039/d1nr01236c.
[1]
R. Di Capua, M. Verma, M. Radovic, N.C. Plumb, J.H. Dil, E.B. Guedes, G.M. De Luca, D. Preziosi, Z. Wang, A.P. Weber, R. Pentcheva, M. Salluzzo, Z. Ristie, Two-dimensional electron gas at the (001) surface of ferromagnetic EuTiO3, Physical Review Research. 3 (2021) L042038. https://doi.org/10.1103/PhysRevResearch.3.L042038.
[1]
S. Homkar, E. Martin, B. Meunier, A. Anadon-Barcelona, C. Bouillet, J. Gorchon, K. Dumesnil, C. Lefèvre, F. Roulland, O. Copie, D. Preziosi, S. Petit-Watelot, J.-C. Rojas-Sanchez, N. Viart, Spin Current Transport in Hybrid Pt/Multifunctional Magnetoelectric Ga0.6Fe1.4O3 Bilayers, ACS Applied Electronic Materials. 3 (2021) 4433–4440. https://doi.org/10.1021/acsaelm.1c00586.
[1]
N. Kharouf, D. Mancino, J. Zghal, S. Helle, H. Jmal, M. Lenertz, N. Viart, N. Bahlouli, F. Meyer, Y. Haikel, V. Ball, Dual role of tannic acid and pyrogallol incorporated in plaster of Paris: Morphology modification and release for antimicrobial properties, Materials Science & Engineering C-Materials for Biological Applications. 127 (2021) 112209. https://doi.org/10.1016/j.msec.2021.112209.
[1]
H.T. Kim, S.-Y. Lee, A. Slaoui, A. Dinia, H.J. Jeon, C. Park, Properties of Yb-added ZnO (Yb:ZnO) films as an energy-conversion layer on polycrystalline silicon solar cells, Materials Chemistry and Physics. 265 (2021) 124513. https://doi.org/10.1016/j.matchemphys.2021.124513.
[1]
D. Preziosi, S. Homkar, C. Lefèvre, M. Salluzzo, N. Viart, Unusual anisotropic magnetic orbital moment obtained from x-ray magnetic circular dichroism in a multiferroic oxide system, Physical Review B. 103 (2021) 184420. https://doi.org/10.1103/PhysRevB.103.184420.
[1]
I. Anefnaf, S. Aazou, G. Schmerber, S. Refki, N. Zimmermann, T. Heiser, G. Ferblantier, A. Slaoui, A. Dinia, M. Abd-Lefdil, Z. Sekkat, Polyethylenimine-Ethoxylated Interfacial Layer for Efficient Electron Collection in SnO2-Based Inverted Organic Solar Cells, Crystals. 10 (2020). https://doi.org/10.3390/cryst10090731.
[1]
I. Anefnaf, S. Aazou, G. Schmerber, A. Dinia, Z. Sekkat, Study the effect of fullerene derivatives ratio on P3HT-based inverted organic solar cells, in: Z.H. Kafafi, P.A. Lane, K. Lee, H.W. Ade, Y.-L. (Lynn) Loo (Eds.), Organic, Hybrid, and Perovskite Photovoltaics XXI, SPIE, 2020: pp. 57–66. https://doi.org/10.1117/12.2568790.
[1]
M.M. Besli, C. Usubelli, M. Metzger, V. Pande, K. Harry, D. Nordlund, S. Sainio, J. Christensen, M.M. Doeff, S. Kuppan, Effect of Liquid Electrolyte Soaking on the Interfacial Resistance of Li7La3Zr2O12 for All-Solid-State Lithium Batteries, ACS Applied Materials & Interfaces. 12 (2020) 20605–20612. https://doi.org/10.1021/acsami.0c06194.
[1]
X. Chen, M. Boero, O. Lopez-Acevedo, Atomic structure and origin of chirality of DNA-stabilized silver clusters, Physical Review Materials. 4 (2020) 065601. https://doi.org/10.1103/PhysRevMaterials.4.065601.
[1]
G. Cotin, F. Perton, C. Petit, S. Sall, C. Kiefer, V. Begin, B. Pichon, C. Lefèvre, D. Mertz, J.-M. Greneche, S. Bégin-Colin, Harnessing Composition of Iron Oxide Nanoparticle: Impact of Solvent-Mediated Ligand-Ligand Interaction and Competition between Oxidation and Growth Kinetics, Chemistry of Materials. 32 (2020) 9245–9259. https://doi.org/10.1021/acs.chemmater.0c03041.
[1]
M. Darcheville, A.-L. Adenot-Engelvin, C. Boscher, N. Vukadinovic, C. Lefèvre, A. Thiaville, C. Sanchez, Evidence of the Superparamagnetic State in the Zero-Field Microwave Susceptibility Spectra of Ferrimagnetic Nanoparticles, IEEE Magnetics Letters. 11 (2020) 6105305. https://doi.org/10.1109/LMAG.2020.3026228.
[1]
P. Dunne, C. Fowley, G. Hlawacek, J. Kurian, G. Atcheson, S. Colis, N. Teichert, B. Kundys, M. Venkatesan, J. Lindner, A.M. Deac, T.M. Hermans, J.M.D. Coey, B. Doudin, Helium Ion Microscopy for Reduced Spin Orbit Torque Switching Currents, Nano Letters. 20 (2020) 7036–7042. https://doi.org/10.1021/acs.nanolett.0c02060.
[1]
A. El Hat, I. Chaki, R. Essajai, A. Mzerd, G. Schmerber, M. Regragui, A. Belayachi, Z. Sekkat, A. Dinia, A. Slaoui, M. Abd-Lefdil, Growth and Characterization of (Tb,Yb) Co-Doping Sprayed ZnO Thin Films, Crystals. 10 (2020) 169. https://doi.org/10.3390/cryst10030169.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Highly robust La1-xTixFeO3 dual catalyst with combined photocatalytic and photo-CWPO activity under visible light for 4-chlorophenol removal in Chock for water, Applied Catalysis B-Environmental. 262 (2020) 118310. https://doi.org/10.1016/j.apcatb.2019.118310.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Synergy effect between photocatalysis and heterogeneous photo-Fenton catalysis on Ti-doped LaFeO3 perovskite for high efficiency light-assisted water treatment, Catalysis Science & Technology. 10 (2020) 1299–1310. https://doi.org/10.1039/c9cy02269d.
[1]
P. Garcia-Munoz, F. Fresno, C. Lefèvre, D. Robert, N. Keller, Ti- -Modified LaFeO3/beta-SiC Alveolar Foams as Immobilized Dual Catalysts with Combined Photo-Fenton and Photocatalytic Activity, ACS Applied Materials & Interfaces. 12 (2020) 57025–57037. https://doi.org/10.1021/acsami.0c16647.
[1]
C. Greboval, U.N. Noumbe, A. Chu, Y. Prado, A. Khalili, C. Dabard, T.H. Dang, S. Colis, J. Chaste, A. Ouerghi, J.-F. Dayen, E. Lhuillier, Gate tunable vertical geometry phototransistor based on infrared HgTe nanocrystals, Applied Physics Letters. 117 (2020) 251104. https://doi.org/10.1063/5.0032622.
[1]
K.W. Kimura, R. Wilhelm, M.M. Besli, S. Kim, C. Usubelli, J.C. Ziegler, R. Klein, J. Christensen, Y. Gorlin, Interrelationship Between the Open Circuit Potential Curves in a Class of Ni-Rich Cathode Materials, Journal of the Electrochemical Society. 167 (2020) 040510. https://doi.org/10.1149/1945-7111/ab739c.
[1]
E. Martin, F. Roulland, S. Grenier, F. Appert, J. Juraszek, M. Trassin, C. Bouillet, E. Chikoidze, C. Arnold, B. Berini, Y. Dumont, S. Colis, S. Barre, G. Versini, D. Preziosi, C. Leuvrey, N. Blanc, N. Boudet, G. Pourroy, N. Viart, C. Lefèvre, Non-auxeticiauxetic transitions inducing modifications of the magnetic anisotropy in CoFe2O4 thin films, Journal of Alloys and Compounds. 836 (2020) 155425. https://doi.org/10.1016/j.jallcom.2020.155425.
[1]
G. Mathiazhagan, L. Wagner, S. Bogati, K.Y. Unal, D. Bogachuk, T. Kroyer, S. Mastroianni, A. Hinsch, Double-Mesoscopic Hole-Transport-Material-Free Perovskite Solar Cells: Overcoming Charge-Transport Limitation by Sputtered Ultrathin Al2O3 Isolating Layer, ACS Applied Nano Materials. 3 (2020) 2463–2471. https://doi.org/10.1021/acsanm.9b02563.
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Y. Park, G. Ferblantier, A. Slaoui, A. Dinia, H. Park, S. Alhammadi, W.K. Kim, Yb-doped zinc tin oxide thin film and its application solar cells to Cu(InGa)Se-2 solar cells, Journal of Alloys and Compounds. 815 (2020) 152360. https://doi.org/10.1016/j.jallcom.2019.152360.
[1]
V. Roge, J. Didierjean, J. Crepelliere, D. Arl, M. Michel, I. Fechete, A. Dinia, D. Lenoble, Tuneable Functionalization of Glass Fibre Membranes with ZnO/SnO(2)Heterostructures for Photocatalytic Water Treatment: Effect of SnO(2)Coverage Rate on the Photocatalytic Degradation of Organics, Catalysts. 10 (2020) 733. https://doi.org/10.3390/catal10070733.
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C. Usubelli, M.M. Besli, S. Kuppan, N. Jiang, M. Metzger, A. Dinia, J. Christensen, Y. Gorlin, Understanding the Overlithiation Properties of LiNi0.6Mn0.2Co0.2O2 Using Electrochemistry and Depth-Resolved X-ray Absorption Spectroscopy, Journal of the Electrochemical Society. 167 (2020) 080514. https://doi.org/10.1149/1945-7111/ab8a9d.