Organic-inorganic hybrids

Nowadays, the search for new materials for various applications and new devices led to the development of new synthetic routes combining the concepts used in solid state chemistry, molecular or supramolecular chemistry, or biochemistry. This is particularly clear in the field of multifunctional organic-inorganic hybrid materials, the realization of which is based on the organization of functional blocks specially synthesized by design. Our contribution to the field mainly relies on families of hybrid transition metal hydroxides or oxides based lamellar compounds, their synthesis and the analysis of their optical or electronic magnetic properties. These materials are often found to be attractive model systems for understanding of the relationship between the structural and physical properties induced by the molecular entities grafted onto transition metal based layers. We are particularly interested in the functionalization of nano-sheets. We develop tools to facilitate the understanding of organic-inorganic interfaces and their influence on the overall behavior of hybrid structures. Modeling by numerical approaches (electronic structure calculations and structural optimization) is also used to describe these hybrid systems at the atomic scale.

Team Members :

Post-doctorant, Inorganic Materials Chemistry (DCMI)juan.aguirre@ipcms.unistra.fr
Station: +33(0)3 88 10 71 24Office: 2002
Doctorant, Inorganic Materials Chemistry (DCMI)frederic.payet@ipcms.unistra.fr
Station: +33(0)3 88 10 71 91Office: 3005
Directeur de Recherche, Inorganic Materials Chemistry (DCMI)pierre.rabu@ipcms.unistra.fr
Station: +33(0)3 88 10 71 35, +33(0)3 88 10 71 96Office: 2020
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Directeur de Recherche, Inorganic Materials Chemistry (DCMI)guillaume.rogez@ipcms.unistra.fr
Station: +33(0)3 88 10 72 95, +33(0)3 88 10 71 96Office: 3006
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Recent publications :

[1]
R.M. Abdelhameed, L.D. Carlos, P. Rabu, S.M. Santos, A.M.S. Silva, J. Rocha, Designing Near-Infrared and Visible Light Emitters by Postsynthetic Modification of Ln(+3)-IRMOF-3, European Journal of Inorganic Chemistry. (2014) 5285–5295. https://doi.org/10.1002/ejic.201402789.
[1]
J.J. Armao, P. Rabu, E. Moulin, N. Giuseppone, Long-Range Energy Transport via Plasmonic Propagation in a Supramolecular Organic Waveguide, Nano Letters. 16 (2016) 2800–2805. https://doi.org/10.1021/acs.nanolett.6b00581.
[1]
P. Bag, A. Chakraborty, G. Rogez, V. Chandrasekhar, Pentanuclear Heterometallic MnIII2Ln3 (Ln = Gd, Dy, Tb, Ho) Assemblies in an Open-Book Type Structural Topology: Appearance of Slow Relaxation of Magnetization in the Dy(III) and Ho(III) Analogues, Inorganic Chemistry. 53 (2014) 6524–6533. https://doi.org/10.1021/ic4028833.
[1]
I. Balti, L.S. Smiri, P. Rabu, E. Gautron, B. Viana, N. Jouini, Synthesis and characterization of rod-like ZnO decorated with gamma-Fe2O3 nanoparticles monolayer, Journal of Alloys and Compounds. 586 (2014) S476–S482. https://doi.org/10.1016/j.jallcom.2013.02.118.
[1]
I. Balti, A. Barrere, V. Gueguen, L. Poussard, G. Pavon-Djavid, A. Meddahi-Pelle, P. Rabu, L.S. Smiri, N. Jouini, F. Chaubet, Preparation of cytocompatible luminescent and magnetic nanohybrids based on ZnO, Zn0.95Ni0.05O and core@shell ZnO@Fe2O3 polymer grafted nanoparticles for biomedical imaging, Journal of Nanoparticle Research. 14 (2012) 1266 /p.1–15. https://doi.org/10.1007/s11051-012-1266-x.
[1]
T. Basu, C. Bloyet, J.-M. Rueff, V. Caignaert, A. Pautrat, B. Raveau, G. Rogez, P.-A. Jaffres, Incipient spin-dipole coupling in a 1D helical-chain metal-organic hybrid, Journal of Materials Chemistry C. 6 (2018) 10207–10210. https://doi.org/10.1039/c8tc04328k.
[1]
T. Basu, C. Bloyet, F. Beaubras, V. Caignaert, O. Perez, J.-M. Rueff, A. Pautrat, B. Raveau, J.-F. Lohier, P.-A. Jaffrès, H. Couthon, G. Rogez, G. Taupier, H. Dorkenoo, Designing of a Magnetodielectric System in Hybrid Organic–Inorganic Framework, a Perovskite Layered Phosphonate MnO3PC6H4-m-Br⋅H2O, Advanced Functional Materials. 29 (2019) 1901878. https://doi.org/10.1002/adfm.201901878.
[1]
F. Beaubras, J.-M. Rueff, O. Perez, F. Veillon, V. Caignaert, J.-F. Lohier, J. Cardin, G. Rogez, C. Jestin, H. Couthon, P.-A. Jaffres, M(H2O)(PO3C10H6OH)center dot(H2O)(0.5) (M = Co, Mn, Zn, Cu): a new series of layered metallophosphonate compounds obtained from 6-hydroxy-2-naphthylphosphonic acid, Dalton Transactions. 49 (2020) 3877–3891. https://doi.org/10.1039/c9dt03947c.
[1]
D. Bechu, G. Rogez, M.W. Hosseini, S.A. Baudron, Tetrathiopyridyl-tetrathiafulvalene-based Cd(ii) coordination polymers: one ligand, one metal cation, many possibilities, New Journal of Chemistry. 43 (2019) 14291–14298. https://doi.org/10.1039/c9nj03572a.
[1]
N. Benamara, M. Diop, C. Leuvrey, M. Lenertz, P. Gilliot, M. Gallart, H. Bolvin, F. Setifi, G. Rogez, P. Rabu, E. Delahaye, Octahedral Hexachloro Environment of Dy3+ with Slow Magnetic Relaxation and Luminescent Properties, European Journal of Inorganic Chemistry. early (2021). https://doi.org/10.1002/ejic.202100143.
[1]
V. de Z. Bermudez, F. Leroux, P. Rabu, A. Taubert, Hybrid nanomaterials: from the laboratory to the market, Beilstein Journal of Nanotechnology. 8 (2017) 861–862. https://doi.org/10.3762/bjnano.8.87.
[1]
A. Beziau, S.A. Baudron, G. Rogez, M.W. Hosseini, Assembly, Disassembly, and Reassembly: Conversion of Homometallic Coordination Networks into Mixed Metal-Organic Frameworks, Inorganic Chemistry. 54 (2015) 2032–2039. https://doi.org/10.1021/ic502950k.
[1]
A. Beziau, S.A. Baudron, G. Rogez, M.W. Hosseini, Ni(II) dipyrrin complexes bearing peripheral pyridyl or imidazolyl groups self-assemble into 2-and 3-D coordination polymers, CrystEngComm. 15 (2013) 5980–5985. https://doi.org/10.1039/c3ce40762d.
[1]
S. Biswas, S. Das, G. Rogez, V. Chandrasekhar, Hydrazone-Ligand-Based Homodinuclear Lanthanide Complexes: Synthesis, Structure, and Magnetism, European Journal of Inorganic Chemistry. (2016) 3322–3329. https://doi.org/10.1002/ejic.201600335.
[1]
C. Bloyet, M. Roger, J.-M. Rueff, B. Raveau, J.-F. Lohier, G. Rogez, P.-A. Jaffrès, The Dimeric Pyramidal Cu2O6(H2O)2 Unit – A Structural Invariant of a Homologous Series of Copper-Layered Phosphonates, European Journal of Inorganic Chemistry. 2016 (2016) 4643–4648. https://doi.org/10.1002/ejic.201600613.
[1]
C. Bloyet, J.-M. Rueff, V. Caignaert, B. Raveau, J.-F. Lohier, M. Roger, G. Rogez, P.-A. Jaffrès, Manganese Fluorene Phosphonates: Formation of Isolated Chains, Inorganics. 6 (2018). https://doi.org/10.3390/inorganics6030092.
[1]
C. Bloyet, J.-M. Rueff, O. Perez, A. Pautrat, V. Caignaert, B. Raveau, G. Rogez, P.-A. Jaffrès, One-Dimensional Fluorene-Based Co(II) Phosphonate Co(H2O)2PO3C–C12H9·H2O: Structure and Magnetism, Inorganics. 6 (2018). https://doi.org/10.3390/inorganics6030093.
[1]
C. Bouchameni, C. Beghidja, A. Beghidja, P. Rabu, R. Welter, Synthesis, structural characterizations, spectroscopic and magnetic properties of Mn-II and Mn-III complexes with an unprecedented bridging coordination mode of 2-salicylichydrazono-1,3-dithiolane ligand, Polyhedron. 30 (2011) 1774–1778. https://doi.org/10.1016/j.poly.2011.04.007.
[1]
A.K. Boudalis, G. Rogez, B. Heinrich, R.G. Raptis, P. Turek, Towards ionic liquids with tailored magnetic properties: bmim(+) salts of ferro- and antiferromagnetic Cu-3(II) triangles, Dalton Transactions. 46 (2017) 12263–12273. https://doi.org/10.1039/c7dt02472j.
[1]
A.K. Boudalis, G. Rogez, P. Turek, Determination of the Distributions of the Spin-Hamiltonian Parameters in Spin Triangles: A Combined Magnetic Susceptometry and Electron Paramagnetic Resonance Spectroscopic Study of the Highly Symmetric [Cr3O(PhCOO)6(py)3](ClO4)·0.5py, Inorganic Chemistry. 57 (2018) 13259–13269. https://doi.org/10.1021/acs.inorgchem.8b01764.
[1]
S. Bouheroum, A. Cherouan, A. Beghidja, S. Dahaoui, P. Rabu, A new copper(II) coordination polymer containing chains of interconnected paddle-wheel antiferromagnetic clusters, Acta Crystallographica Section C-Structural Chemistry. 73 (2017) 1050–1055. https://doi.org/10.1107/S2053229617013766.
[1]
R. Bourzami, S. Eyele-Mezui, E. Delahaye, M. Drillon, P. Rabu, N. Parizel, S. Choua, P. Turek, G. Rogez, New metal phthalocyanines/metal simple hydroxide multilayers: experimental evidence of dipolar field-driven magnetic behavior, Inorganic Chemistry. 53 (2014) 1184–1194. https://doi.org/10.1021/ic4027688.
[1]
M.A. Bousnina, F. Turki, F. Schoenstein, F. Tetard, P. Rabu, L.-S. Smiri, N. Jouini, Bulk nanostructured Ni-P alloys: Elaboration from metastable Ni-P nanoparticles by spark plasma sintering; mechanical and magnetic properties, Journal of Alloys and Compounds. 686 (2016) 252–266. https://doi.org/10.1016/j.jallcom.2016.05.349.
[1]
A. Boussadia, A. Beghidja, L. Gali, C. Beghidja, M. Elhabiri, P. Rabu, G. Rogez, Coordination properties of two new Schiff-base phenoxy-carboxylates and comparative study of their antioxidant activities, Inorganica Chimica Acta. 508 (2020). https://doi.org/10.1016/j.ica.2020.119656.
[1]
P. Buchwalter, J. Rosé, B. Lebeau, O. Ersen, M. Girleanu, P. Rabu, P. Braunstein, J.-L. Paillaud, Characterization of cobalt phosphide nanoparticles derived from molecular clusters in mesoporous silica, Journal of Nanoparticle Research. 15 (2013) 1–21. https://doi.org/10.1007/s11051-013-2132-1.
[1]
P. Buchwalter, J. Rose, B. Lebeau, P. Rabu, P. Braunstein, J.L. Paillaud, Stoichiometric molecular single source precursors to cobalt phosphides, Inorganica Chimica Acta. 409 (2014) 330–341. https://doi.org/10.1016/j.ica.2013.09.019.
[1]
M.J. Buehler, P. Rabu, A. Taubert, Advanced Hybrid Materials: Design and Applications (Editorial), European Journal of Inorganic Chemistry. (2012) 5092–5093. https://doi.org/10.1002/ejic.201201263.
[1]
S. Carenco, S. Moldovan, L. Roiban, I. Florea, D. Portehault, K. Valle, P. Belleville, C. Boissiere, L. Rozes, N. Mezailles, M. Drillon, C. Sanchez, O. Ersen, The core contribution of transmission electron microscopy to functional nanomaterials engineering, Nanoscale. 8 (2016) 1260–1279. https://doi.org/10.1039/c5nr05460e.
[1]
M.-A. Carvalho, H. Dekkiche, S. Richeter, C. Bailly, L. Karmazin, D. McKearney, D.B. Leznoff, G. Rogez, B. Vileno, S. Choua, R. Ruppert, Antiferromagnetic coupling in copper(II)porphyrin dimers linked by copper(II) or palladium(II) ion, Journal of Porphyrins and Phthalocyanines. 24 (2020) 238–246. https://doi.org/10.1142/S1088424619501037.
[1]
G. Charron, E. Malkin, G. Rogez, L.J. Batchelor, S. Mazerat, R. Guillot, N. Guihéry, A.-L. Barra, T. Mallah, H. Bolvin, Unraveling σ and π Effects on Magnetic Anisotropy in cis-NiA4B2 Complexes: Magnetization, HF-HFEPR Studies, First-Principles Calculations, and Orbital Modeling, Chemistry – A European Journal. 22 (2016) 16850–16862. https://doi.org/10.1002/chem.201602837.
[1]
A.K. Chaudhari, B. Joarder, E. Riviere, G. Rogez, S.K. Ghosh, Nitrate-Bridged “Pseudo-Double-Propeller”-Type Lanthanide(III)-Copper(II) Heterometallic Clusters: Syntheses, Structures, and Magnetic Properties, Inorganic Chemistry. 51 (2012) 9159–9161. https://doi.org/10.1021/ic3012876.
[1]
K. Cheaib, D. Martel, N. Clement, F. Eckes, S. Kouaho, G. Rogez, S. Dagorne, M. Kurmoo, S. Choua, R. Welter, Structural, magnetic and optical properties of an Fe-III dimer bridged by the meridional planar divergent N,N ’-bis(salicyl)hydrazide and its photo- and electro-chemistry in solution, Dalton Transactions. 42 (2013) 1406–1416. https://doi.org/10.1039/c2dt32310a.
[1]
A.A. Danopoulos, P. Braunstein, M. Wesolek, K.Y. Monakhov, P. Rabu, V. Robert, Three-Coordinate Iron(II) N-Heterocyclic Carbene Alkyl Complexes, Organometallics. 31 (2012) 4102–4105. https://doi.org/10.1021/om300245z.
[1]
E. Delahaye, S. Eyele-Mezui, M. Diop, C. Leuvrey, D. Foix, D. Gonbeau, P. Rabu, G. Rogez, Functional Heterometallic Layered Hybrid Magnets by Double Ion-Exchange, European Journal of Inorganic Chemistry. (2012) 2731–2740. https://doi.org/10.1002/ejic.201101220.
[1]
E. Delahaye, Z. Xie, A. Schaefer, L. Douce, G. Rogez, P. Rabu, C. Guenter, J.S. Gutmann, A. Taubert, Intercalation synthesis of functional hybrid materials based on layered simple hydroxide hosts and ionic liquid guests - a pathway towards multifunctional ionogels without a silica matrix?, Dalton Transactions. 40 (2011) 9977–9988. https://doi.org/10.1039/c1dt10841g.
[1]
M. Dolai, T. Mistri, S. Biswas, G. Rogez, M. Ali, Solvent-Dependent Oxime-Azide and Oxime-Nitrile Coupling: Crystallographic and Catalytic Studies, ChemPlusChem. 79 (2014) 1649–1656. https://doi.org/10.1002/cplu.201402178.
[1]
M. Dolai, H.A. Molla, G. Rogez, M. Ali, Two [Mn-3(mu(3)-O)(7+) based Single Chain Magnets with different solvent ligation, Polyhedron. 127 (2017) 248–256. https://doi.org/10.1016/j.poly.2017.01.043.
[1]
S. Duval, S. Beghin, C. Falaise, X. Trivelli, P. Rabu, T. Loiseau, Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [alpha-SiW9O34](10-) Polyoxometalate, Inorganic Chemistry. 54 (2015) 8271–8280. https://doi.org/10.1021/acs.inorgchem.5b00786.
[1]
H. El Moll, A. Dolbecq, J. Marrot, G. Rousseau, M. Haouas, F. Taulelle, G. Rogez, W. Wernsdorfer, B. Keita, P. Mialane, A Stable Hybrid Bisphosphonate Polyoxometalate Single-Molecule Magnet, Chemistry-a European Journal. 18 (2012) 3845–3849. https://doi.org/10.1002/chem.201200140.
[1]
Q. Evrard, Z. Chaker, M. Roger, C.M. Sevrain, E. Delahaye, M. Gallart, P. Gilliot, C. Leuvrey, J.-M. Rueff, P. Rabu, C. Massobrio, M. Boero, A. Pautrat, P.-A. Jaffrès, G. Ori, G. Rogez, Layered Simple Hydroxides Functionalized by Fluorene-Phosphonic Acids: Synthesis, Interface Theoretical Insights, and Magnetoelectric Effect, Advanced Functional Materials. 27 (2017) 1703576. https://doi.org/10.1002/adfm.201703576.
[1]
Q. Evrard, C. Leuvrey, P. Farger, E. Delahaye, P. Rabu, G. Taupier, K.D. Dorkenoo, J.-M. Rueff, N. Barrier, O. Perez, G. Rogez, Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu-2(OH)(3)(C12H25SO4), Crystal Growth & Design. 18 (2018) 1809–1817. https://doi.org/10.1021/acs.cgd.7601692.
[1]
S. Eyele-Mezui, E. Delahaye, G. Rogez, P. Rabu, Functional Hybrid Materials Based on Layered Simple Hydroxide Hosts and Dicarboxylate Schiff Base Metal Complex Guests, European Journal of Inorganic Chemistry. (2012) 5225–5238. https://doi.org/10.1002/ejic.201200695.
[1]
S. Eyele-Mezui, P. Vialat, C. Higy, R. Bourzami, C. Leuvrey, N. Parizel, P. Turek, P. Rabu, G. Rogez, C. Mousty, Electrocatalytic Properties of Metal Phthalocyanine Tetrasulfonate Intercalated in Metal Layered Simple Hydroxides (Metal: Co, Cu, and Zn), Journal of Physical Chemistry C. 119 (2015) 13335–13342. https://doi.org/10.1021/acs.jpcc.5b02985.
[1]
C. Falaise, C. Volkringer, J.F. Vigier, A. Beaurain, P. Roussel, P. Rabu, T. Loiseau, Isolation of the Large Actinide(38) Poly-oxo Cluster with Uranium, Journal of the American Chemical Society. 135 (2013) 15678–15681. https://doi.org/10.1021/ja4067207.
[1]
C. Falaise, J. Delille, C. Volkringer, H. Vezin, P. Rabu, T. Loiseau, Series of Hydrated Heterometallic Uranyl-Cobalt(II) Coordination Polymers with Aromatic Polycarboxylate Ligands: Formation of U=O-Co Bonding upon Dehydration Process, Inorganic Chemistry. 55 (2016) 10453–10466. https://doi.org/10.1021/acs.inorgchem.6b01697.
[1]
P. Farger, R. Guillot, F. Leroux, N. Parizel, M. Gallart, P. Gilliot, G. Rogez, E. Delahaye, P. Rabu, Imidazolium Dicarboxylate Based Metal-Organic Frameworks Obtained by Solvo-Ionothermal Reaction, European Journal of Inorganic Chemistry. (2015) 5342–5350. https://doi.org/10.1002/ejic.201500825.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, P. Rabu, E. Delahaye, Elaboration of Luminescent and Magnetic Hybrid Networks Based on Lanthanide Ions and Imidazolium Dicarboxylate Salts: Influence of the Synthesis Conditions, Magnetochemistry. 3 (2017) 1. https://doi.org/10.3390/magnetochemistry3010001.
[1]
P. Farger, C. Leuvrey, M. Gallart, P. Gilliot, G. Rogez, J. Rocha, D. Ananias, P. Rabu, E. Delahaye, Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry, Beilstein Journal of Nanotechnology. 9 (2018) 2775–2787. https://doi.org/10.3762/bjnano.9.259.
[1]
P. Farger, C. Leuvrey, G. Rogez, M. Francois, P. Rabu, E. Delahay, Salts and Solvents Effect on the Crystal Structure of Imidazolium Dicarboxylate Salt Based Coordination Networks, Crystal Growth & Design. 19 (2019) 4264–4272. https://doi.org/10.1021/acs.cgd.8b01725.
[1]
S. Fleutot, G.L. Nealon, M. Pauly, B.P. Pichon, C. Leuvrey, M. Drillon, J.L. Gallani, D. Guillon, B. Donnio, S. Bégin-Colin, Spacing-dependent dipolar interactions in dendronized magnetic iron oxide nanoparticle 2D arrays and powders, Nanoscale. 5 (2013) 1507–1516. https://doi.org/10.1039/c2nr32117c.